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1.
Yan-Jie Tang Hong-Fu Zhang Eizo Nakamura Ji-Feng Ying 《Contributions to Mineralogy and Petrology》2011,161(6):845-861
Elemental and Li–Sr–Nd isotopic data of minerals in spinel peridotites hosted by Cenozoic basalts allow us to refine the existing
models for Li isotopic fractionation in mantle peridotites and constrain the melt/fluid-peridotite interaction in the lithospheric
mantle beneath the North China Craton. Highly elevated Li concentrations in cpx (up to 24 ppm) relative to coexisting opx
and olivine (<4 ppm) indicate that the peridotites experienced metasomatism by mafic silicate melts and/or fluids. The mineral
δ7Li vary greatly, with olivine (+0.7 to +5.4‰) being isotopically heavier than coexisting opx (−4.4 to −25.9‰) and cpx (−3.3
to −21.4‰) in most samples. The δ7Li in pyroxenes are considerably lower than the normal mantle values and show negative correlation with their Li abundances,
likely due to recent Li ingress attended by diffusive fractionation of Li isotopes. Two exceptional samples have olivine δ7Li of −3.0 and −7.9‰, indicating the existence of low δ7Li domains in the mantle, which could be transient and generated by meter-scale diffusion of Li during melt/fluid-peridotite
interaction. The 143Nd/144Nd (0.5123–0.5139) and 87Sr/86Sr (0.7018–0.7062) in the pyroxenes also show a large variation, in which the cpx are apparently lower in 87Sr/86Sr and slightly higher in 143Nd/144Nd than coexisting opx, implying an intermineral Sr–Nd isotopic disequilibrium. This is observed more apparently in peridotites
having low 87Sr/86Sr and high 143Nd/144Nd ratios than in those with high 87Sr/86Sr and low 143Nd/144Nd, suggesting that a relatively recent interaction existed between an ancient metasomatized lithospheric mantle and asthenospheric
melt, which transformed the refractory peridotites with highly radiogenic Sr and unradiogenic Nd isotopic compositions to
the fertile lherzolites with unradiogenic Sr and radiogenic Nd isotopic compositions. Therefore, we argue that the lithospheric
mantle represented by the peridotites has been heterogeneously refertilized by multistage melt/fluid-peridotite interactions. 相似文献
2.
Li-Sr-Nd isotope signatures of the plume and cratonic lithospheric mantle beneath the margin of the rifted Tanzanian craton (Labait) 总被引:3,自引:2,他引:1
Sonja Aulbach Roberta L. Rudnick William F. McDonough 《Contributions to Mineralogy and Petrology》2008,155(1):79-92
Lithium concentrations and isotopic compositions of olivine and 87Sr/86Sr and 143Nd/144Nd of coexisting clinopyroxene from peridotite xenoliths from the Quaternary Labait volcano, Tanzania, document the influence
of rift-related metasomatism on the ancient cratonic mantle. Olivines show negative correlations between Fo content and both
δ7Li and Li concentrations. Olivines in iron-rich peridotites (Fo85–87) have high Li concentrations (3.2–4.8 ppm) and heavy δ7Li (+5.2 to +6.6). In contrast, olivines in ancient, refractory peridotites have lower Li concentrations (∼2 ppm) and relatively
light δ7Li (+2.6 to +3.5). This reflects mixing between ancient, refractory cratonic lithosphere and asthenosphere-derived rift magmas.
A uniquely fertile, deformed, high-temperature garnet lherzolite, interpreted to be from the base of the lithosphere, has
a 87Sr/86Sr of 0.7029 and 143Nd/144Nd of 0.51286, similar to HIMU oceanic basalts. It provides the best estimate of the Sr–Nd isotope composition of the upwelling
mantle (i.e., plume, sensu lato) underlying this portion of the East African Rift, and is slightly less radiogenic compared
to previous estimates of the plume that were based on rift basalts. Although elevated δ7Li are not exclusive to HIMU source regions, the data collectively indicate that the plume beneath Labait has HIMU characteristics
in Sr, Nd and Li isotope composition.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
3.
Signatures of the source for the Emeishan flood basalts in the Ertan area: Pb isotope evidence 总被引:2,自引:0,他引:2
The Emeishan flood basalts can be divided into high-Ti (HT) basalt (Ti/Y>500) and low-Ti (LT) basalt (Ti/Y<500). Sr, Nd isotopic characteristics of the lavas indicate that the LT- and the HT-type magmas originated from distinct mantle sources and parental magmas. The LT-type magma was derived from a shallower lithospheric mantle, whereas the HT-type magma was derived from a deeper mantle source that may be possibly a mantle plume. However, few studies on the Emeishan flood basalts involved their Pb isotopes, especially the Ertan basalts. In this paper, the authors investigated basalt samples from the Ertan area in terms of Pb isotopes, in order to constrain the source of the Emeishan flood basalts. The ratios of 206Pb/204Pb (18.31–18.41), 207Pb/204Pb (15.55–15.56) and 208Pb/204Pb (38.81–38.94) are significantly higher than those of the depleted mantle, just lying between EM I and EM II. This indicates that the Emeishan HT basalts (in the Ertan area) are the result of mixing of EMI end-member and EMII end-member. 相似文献
4.
N. M. Sushchevskaya E. A. Korago B. V. Belyatsky A. N. Sirotkin 《Geochemistry International》2009,47(10):966-978
Petrological and geochemical data obtained on Neogene magmatism restricted to a deep fault in Andree Land at Spitsbergen Island,
which was related to the overall restyling of the Arctic territory at 25–20 Ma, indicate that the derivation of the Neogene
magmas was significantly affected by the continental pyroxenite mantle. The Neogene basalts are noted for a radiogenic isotopic
composition of Pb (207Pb/204Pb= 15.5–15.55, 206Pb/204Pb = 18.4–18.6, 208Pb/204 Pb = 38.4–38.6) and Sr(87Sr/86Sr = 0.7038–0.7048) at low 143Nd/144Nd = 0.5129. Melts of this type are the extremely enriched end member of the isotopic mixing of a depleted and enriched sources
and determine a geochemical trend that passes through the compositions of alkaline magmas from Quaternary volcanoes at Spitsbergen
and weakly enriched tholeiites of the Knipovich Ridge, which started to develop simultaneously with the onset of Neogene magmatism
in the western part of Spitsbergen. The composition of the liquidus olivine (which is rich in NiO) indicates that melting
occurred in the olivine-free mantle. Our data thus testify that a significant role in the genesis of the Neogene magmas was
played by continental pyroxenite mantle. 相似文献
5.
The lava sequence of the central-western Deccan Traps (from Jalgaon towards Mumbai) is formed by basalts and basaltic andesites
having a significant variation in TiO2 (from 1.2 to 3.3 wt%), Zr (from 84 to 253 ppm), Nb (from 5 to 16ppm) and Ba (from 63 to 407 ppm), at MgO ranging from 10
to 4.2 wt%. Most of these basalts follow a liquid line of descent dominated by low pressure fractionation of clinopyroxene,
plagioclase and olivine, starting from the most mafic compositions, in a temperature range from 1220° to 1125°C. These rocks
resemble those belonging to the lower-most formations of the Deccan Traps in the Western Ghats (Jawhar, Igatpuri and Thakurvadi)
as well as those of the Poladpur formation. Samples analyzed for87Sr/86Sr give a range of initial ratios from 0.70558 to 0.70621. A group of flows of the Dhule area has low TiO2 (1.2–1.5 wt%) and Zr (84–105 ppm) at moderate MgO (5.2–6.2 wt%), matching the composition of low-Ti basalts of Gujarat, low-Ti
dykes of the Tapti swarm and Toranmal basalts, just north of the study area. This allows chemical correlations between the
lavas of central Deccan, the Tapti dykes and the north-western outcrops. The mildly enriched high field strength element contents
of the samples with TiO2 > 1.5 wt% make them products of mantle sources broadly similar to those which generated the Ambenali basalts, but their high
La/Nb and Ba/Nb, negative Nb anomalies in the mantle normalized diagrams, and relatively high87Sr/86Sr, make evident a crustal input with crustally derived materials at less differentiated stages than those represented in
this sample set, or even within the sub-Indian lithospheric mantle. 相似文献
6.
Stefanie S. Schmidberger Ernst Hegner 《Contributions to Mineralogy and Petrology》1999,135(4):373-385
Late Carboniferous (300–290 Ma) calc-alkaline basalts, andesites, and rhyolites typical of volcanic arc settings occur in
the intermontane Saar-Nahe basin (SW Germany) within the Variscan orogenic belt. The volcanic rock suite was emplaced under
a regime of tensional tectonics during orogenic collapse and its origin has been explained by melting of mantle and crust
in the course of limited lithospheric rifting. We report major, trace and rare-earth-element data (REE), and Nd-Pb-Sr-O isotope
ratios for a representative sample suite, which are fully consistent with an origin closely related to plate subduction. Major
and trace element data define continuous melt differentiation trends from a precursor basaltic magma involving fractional
crystallization of olivine, pyroxene, plagioclase, and magnetite typical of magma evolution in a volcanic arc. This finding
precludes an origin of the andesitic compositions by mixing of mafic and felsic melts as can be expected in anorogenic settings.
The mafic samples have high Mg numbers (Mg# = 65–73), and high Cr (up to 330 ppm) and Ni (up to 200 ppm) contents indicating
derivation from a primitive parental melt that was formed in equilibrium with mantle peridotite. We interpret the geochemical
characteristics of the near-primary basalts as reflecting their mantle source. The volcanic rocks are characterized by enrichment
in the large ion lithophile elements (LILE), negative Nb and Ti, and positive Pb anomalies relative to the neighboring REE,
suggesting melting of a subduction-modified mantle. Initial Nd values of −0.7 to −4.6, Pb, and 87Sr/86Sr(t) isotope ratios for mafic and felsic volcanics are similar and indicate partial melting of an isotopically heterogeneous and
enriched mantle reservoir. The enrichment in incompatible trace elements and radiogenic isotopes of a precursor depleted mantle
may be attributed to addition of an old sedimentary component. The geochemical characteristics of the Saar-Nahe volcanic rocks
are distinct from typical post-collisional rock suites and they may be interpreted as geochemical evidence for ongoing plate
subduction at the margin of the Variscan orogenic belt not obvious from the regional geologic context.
Received: 3 August 1998 / Accepted: 2 January 1999 相似文献
7.
M.-S. Krienitz K. M. Haase K. Mezger V. Eckardt M. A. Shaikh-Mashail 《Contributions to Mineralogy and Petrology》2006,151(6):698-716
The Miocene to Quaternary lavas of northwestern Syria range from basanite, alkali basalts, and tholeiites to basaltic andesites, hawaiites, and mugearites. Crustal assimilation and fractional crystallization processes (AFC) modified the composition of the mantle derived magmas. Crustal assimilation is indicated by decreasing Nb/U (52.8–17.9) and increasing Pb/Nd (0.09–0.21) and by variable isotopic compositions of the lavas (87Sr/86Sr: 0.7036–0.7048, 143Nd/144Nd: 0.51294–0.51269, 206Pb/204Pb: 18.98–18.60) throughout the differentiation. Modeling of the AFC processes indicates that the magmas have assimilated up to 25% of continental upper crust. The stratigraphy of the lavas reveals decreasing degrees and increasing depths of melting with time and the strongly fractionated heavy rare earth elements indicate melt generation in the garnet stability field. Modeling of melt formation based on trace element contents suggests that 8–10% melting of the asthenospheric mantle source produced the tholeiites, whereas basanite and alkali basalts are formed by 2–4% melting of a similar source.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users. 相似文献
8.
Kopparapu Vijaya Kumar Chakradhar Chavan Sariput Sawant K. Naga Raju Prachiti Kanakdande Sangita Patode Krishna Deshpande S. K. G. Krishnamacharyulu T. Vaideswaran V. Balaram 《Contributions to Mineralogy and Petrology》2010,159(6):839-862
Spatial and temporal variations in the geochemistry of an extrusive basaltic section of Deccan traps record progressive changes
in mantle melting and crustal filtration and are relevant to understand continental flood basalt (CFB) magmatism. In the present
work we have carried out detailed field, petrographic, density and magnetic susceptibility, and geochemical investigations
on a small, semi-continuous extrusive section in the eastern Deccan Volcanic Province (DVP) to understand the role of shallow
magma chambers in CFB magmatism. Four formations, Ajanta, Chikhli, Buldhana and Karanja crop out in the Gangakhed–Ambajogai
area with increasing elevation. Our studies indicate that: (1) the Karanja Formation represents a major magma addition, as
indicated by abrupt change in texture, increases in MgO, CaO, Ni, Cr, and Sr, and drastic decreases in Al2O3, Na2O, K2O, Rb, Ba, REE, bulk-rock density and magnetic susceptibility; (2) assimilation fractional crystallization, crystal-laden
magmas, and accessory cumulus phases influence the trace element chemistry of Deccan basalts; (3) the predicted cumulate sequence
of olivine gabbro–leucogabbro–oxide-apatite gabbro is supported by the observed layered series in a shallow magma chamber
within the DVP; (4) the initial magma was saturated with olivine, plagioclase, and augite, and final the pressure of equilibration
for the Gangakhed–Ambajogai section basalts is ~2 kbar (~6 km depth); (5) petrophysical parameters act as proxies for magmatic
processes; (6) a small layer of oxide-rich basalts may represent the latest erupted pulse in a given magmatic cycle in the
DVP; (7) parental basalts to some of the red boles, considered as formation boundaries, might represent small degree partial
melts of the mantle; (8) SW Deccan basaltic-types continue into the eastern DVP; and (9) in addition to the magma chamber
processes, dynamic melting of the mantle may have controlled DVP geochemistry. The present study underscores the importance
of mapping specific stratigraphic intervals in limited areas to understand mantle and magma chamber processes relevant to
CFB magmatism. 相似文献
9.
A detailed Sr−Nd isotopic study of primary apatite, calcite and dolomite from phoscorites and carbonatites of the Kovdor massif
(380 Ma), Kola peninsula, Russia, reveals a complicated evolutionary history. At least six types of phoscorites and five types
of carbonatite have been identified from Kovdor by previous investigators based on relative ages and their major and accessory
minerals. Isotopic data from apatite define at least two distinct groups of phoscorite and carbonatite. Apatite from the earlier
phoscorites and carbonatites (group 1) are characterized by relatively low87Sr/86Sr (0.70330–0.70349) and143Nd/144Nd initial ratios (0.51230–0.51240) with F=2.01–2.23 wt%, Sr=2185–2975 ppm, Nd=275–660 ppm and Sm=31.7–96.2 ppm. Apatite from
the second group has higher87Sr/86Sr (0.70350–0.70363) and143Nd/144Nd initial ratios (0.51240–0.51247) and higher F (2.63–3.16 wt%), Sr (4790–7500 ppm), Nd (457–1074 ppm) and Sm (68.7–147.6
ppm) contents. This group corresponds to the later phoscorites and carbonatites. One apatite sample from a carbonatite from
the earlier group fits into neither of the two groups and is characterized by the highest initial87Sr/86Sr (0.70385) and lowest143Nd/144Nd (0.51229) of any of the apatites. Within both groups initial87Sr/86Sr and143Nd/144Nd ratios show negative correlations. Strontium isotope data from coexisting calcite and dolomite support the findings from
the apatite study. The Sr and Nd isotopic similarities between carbonatites and phoscorites indicate a genetic relationship
between the two rock types. Wide variations in Sr and Nd isotopic composition within some of the earlier carbonatites indicate
several distinct intrusive phases. Oxygen isotopic data from calcite and dolomite (δ18O=+7.2 to +7.7‰ SMOW) indicate the absence of any low-temerature secondary processes in phoscorites and carbonatites, and
are consistent with a mantle origin for their parental melts. Apatite data from both groups of phoscorite plot in the depleted
quadrant of an εNd versus εSr diagram. Data for the earlier group lie along the Kola Carbonatite Line (KCL) as defined by Kramm (1993) and data from the
later group plot above the KCL. The evolution of the phoscorites and carbonatites cannot be explained by simple magmatic differentiation
assuming closed system conditions. The Sr−Nd data can best be explained by the mixing of three components. Two of these are
similar to the end-members that define the Kola Carbonatite Line and these were involved in the genesis of the early phoscorites
and carbonatites. An additional component is needed to explain the isotopic characteristics of the later group. Our study
shows that apatite from rocks of different mineralogy and age is ideal for placing constraints on mantle sources and for monitoring
the Sr−Nd evolution of carbonatites.
Editorial responsibility: W. Schreyer 相似文献
10.
L. Melluso S. F. Sethna M. D’Antonio P. Javeri L. Bennio 《Mineralogy and Petrology》2002,74(2-4):323-342
Summary Major element, trace element, Sr- and Nd-isotopes and mineral chemical data are reported for alkaline rocks (lamprophyres,
tephrites, melanephelinites, nephelinites and nepheline syenites) cross-cutting the Deccan Trap lava flows south (Murud-Janjira
area) and north of Mumbai (Bassein). These rocks range from sodic to potassic and have a large span in MgO (12–2 wt%). The
lamprophyres have high content of incompatible elements (e.g., TiO2 > 3.8 wt%, Nb > 130 ppm, Zr > 380 ppm, Ba > 1200 ppm), and relatively high initial (at 65 Ma) 143Nd/144Nd (0.5128) and low 87Sr/86Sr (0.7038–0.7042). They are likely to be small-degree melts (2–3%) of volatile- and incompatible element-enriched mantle
sources, similar to other alkaline rocks in the northern Deccan, though slightly more potassium-rich. The nepheline-rich rocks
have highly porphyritic textures (up to 57% phenocrysts of diopside ± olivine), and anomalously low contents of incompatible
elements (e.g., TiO2 < 1.3 wt%, Nb < 24 ppm, Zr < 100 ppm) indicating that they could not represent liquid compositions. Moreover, their very
low initial 143Nd/144Nd ratios (0.5116–0.5120), at 87Sr/86Sr = 0.7045–0.7049, are unusual in the rocks related to the Deccan Traps and identify a new end-member in this province, that
could be identified as “Lewisian-type” lower crust and/or enriched mantle. The melting episode that generated these alkaline
rocks likely occurred close to the base of the ca. 100 km-thick Indian lithosphere, very shortly after the main eruption of
the Deccan tholeiites.
Received January 14, 2000; revised version accepted September 28, 2001 相似文献
11.
Petrogenesis of isotopically unusual Pliocene olivine leucitites from Deep Springs Valley, California 总被引:2,自引:0,他引:2
High-K mafic alkalic lavas (5.4 to 3.2 wt% K2O) from Deep Springs Valley, California define good correlations of increasing incompatible element (e.g., Sr, Zr, Ba, LREE)
and compatible element contents (e.g., Ni, Cr) with increasing MgO. Strontium and Nd isotope compositions are also correlated
with MgO; 87Sr/86Sr ratios decrease and ɛNd values increase with decreasing MgO. The Sr and Nd isotope compositions of these lavas are extreme compared to most other
continental and oceanic rocks; 87Sr/86Sr ratios range from 0.7121 to 0.7105 and ɛNd values range from −16.9 to −15.4. Lead isotope ratios are relatively constant, 206Pb/204Pb ∼17.2, 207Pb/204Pb ∼15.5, and 208Pb/204Pb ∼38.6. Depleted mantle model ages calculated using Sr and Nd isotopes imply that the reservoir these lavas were derived
from has been distinct from the depleted mantle reservoir since the early Proterozoic. The Sr-Nd-Pb isotope variations of
the Deep Springs Valley lavas are unique because they do not plot along either the EM I or EM II arrays. For example, most
basalts that have low ɛNd values and unradiogenic 206Pb/204Pb ratios have relatively low 87Sr/86Sr ratios (the EM I array), whereas basalts with low ɛNd values and high 87Sr/86Sr ratios have radiogenic 206Pb/204Pb ratios (the EM II array). High-K lavas from Deep Springs Valley have EM II-like Sr and Nd isotope compositions, but EM
I-like Pb isotope compositions. A simple method for producing the range of isotopic and major- and trace-element variations
in the Deep Springs Valley lavas is by two-component mixing between this unusual K-rich mantle source and a more typical depleted
mantle basalt. We favor passage of MORB-like magmas that partially fused and were contaminated by potassic magmas derived
from melting high-K mantle veins that were stored in the lithospheric mantle. The origin of the anomalously high 87Sr/86Sr and 208Pb/204Pb ratios and low ɛNd values and 206Pb/204Pb ratios requires addition of an old component with high Rb/Sr and Th/Pb ratios but low Sm/Nd and U/Pb ratios into the mantle
source region from which these basalts were derived. This old component may be sediments that were introduced into the mantle,
either during Proterozoic subduction, or by foundering of Proterozoic age crust into the mantle at some time prior to eruption
of the lavas.
Received: 28 February 1997 / Accepted: 9 July 1998 相似文献
12.
The Urach volcanic field is unique within the Tertiary–Quaternary European volcanic province (EVP) due to more than 350 tuffaceous
diatremes and only sixteen localities with extremely undersaturated olivine melilitite. We report representative Pb-Sr-Nd
isotopic compositions and incompatible trace element data for twenty-two pristine augite, Cr-diopside, hornblende, and phlogopite
megacryst samples from the diatremes, and seven melilitite whole rocks. The Pb isotopic compositions for melilitites and comagmatic
megacrysts have very radiogenic 206Pb/204Pb ratios of 19.4 to 19.9 and plot on the northern hemisphere mantle reference line (NHRL). The data indicate absence of an
old crustal component as reflected in the high 207Pb/204Pb ratios of many basalts from the EVP. This inference is supported by 206Pb/204Pb ratios of ∼17.6 to 18.3 and ɛNd of ∼−7.8 to +1.6 for five phlogopite xenocryst samples reflecting a distinct and variably rejuvenated lower Hercynian basement.
The 87Sr/86Sr ratios of 0.7033 to 0.7035 in the comagmatic megacrysts are low relative to their moderately radiogenic Nd isotopic compositions
(ɛNd +2.2 to +5.1) and consistent with a long-term source evolution with a low Rb/Sr ratio and depletion in light rare-earth elements
(LREE). The melilitite whole-rock data show a similar range in Nd isotopic ratios as determined for the megacrysts but their
Sr isotopic compositions are often much more radiogenic due to surface alteration. The REE patterns and incompatible trace
element ratios of the melilitites (e.g. Nb/Th, Nb/U, Sr/Nd, P/Nd, Ba/Th, Zr/Hf) are similar to those in ocean island basalts
(OIB); negative anomalies for normalized K and Rb concentrations support a concept of melt evolution in the lithospheric mantle.
Highly variable Ce/Pb ratios of 29 to 66 are positively correlated with La/Lu, La/K2O, and Ba/Nd and interpreted to reflect melting in the presence of residual amphibole and phlogopite. The data suggest an
origin of the melilitites from a chemical boundary layer very recently enriched by melts from old OIB sources. We suggest
that the OIB-like mantle domains represent low-temperature melting heterogeneities in an upwelling asthenosphere under western
Europe.
Received: 9 March 1995/Accepted: 24 July 1995 相似文献
13.
The western Anatolian volcanic province formed during Eocene to Recent times is one of the major volcanic belts in the Aegean–western
Anatolian region. We present new chemical (whole-rock major and trace elements, and Sr, Nd, Pb and O isotopes) and new Ar/Ar
age data from the Miocene volcanic rocks in the NE–SW-trending Neogene basins that formed on the northern part of the Menderes
Massif during its exhumation as a core complex. The early-middle Miocene volcanic rocks are classified as high-K calc-alkaline
(HKVR), shoshonitic (SHVR) and ultrapotassic (UKVR), with the Late Miocene basalts being transitional between the early-middle
Miocene volcanics and the Na-alkaline Quaternary Kula volcanics (QKV). The early-middle Miocene volcanic rocks are strongly
enriched in large ion lithophile elements (LILE), have high 87Sr/86Sr(i) (0.70631–0.71001), low 143Nd/144Nd(i) (0.512145–0.512488) and high Pb isotope ratios (206Pb/204Pb = 18.838–19.148; 207Pb/204Pb = 15.672–15.725; 208Pb/204Pb = 38.904–39.172). The high field strength element (HFSE) ratios of the most primitive early-middle Miocene volcanic rocks
indicate that they were derived from a mantle source with a primitive mantle (PM)-like composition. The HFSE ratios of the
late Miocene basalts and QKV, on the other hand, indicate an OIB-like mantle origin—a hypothesis that is supported by their
trace element patterns and isotopic compositions. The HFSE ratios of the early-middle Miocene volcanic rocks also indicate
that their mantle source was distinct from those of the Eocene volcanic rocks located further north, and of the other volcanic
provinces in the region. The mantle source of the SHVR and UKVR was influenced by (1) trace element and isotopic enrichment
by subduction-related metasomatic events and (2) trace element enrichment by “multi-stage melting and melt percolation” processes
in the lithospheric mantle. The contemporaneous SHVR and UKVR show little effect of upper crustal contamination. Trace element
ratios of the HKVR indicate that they were derived mainly from lower continental crustal melts which then mixed with mantle-derived
lavas (~20–40%). The HKVR then underwent differentiation from andesites to rhyolites via nearly pure fractional crystallization
processes in the upper crust, such that have undergone a two-stage petrogenetic evolution. 相似文献
14.
A total of 17 alkali basalts (alkali olivine basalt, limburgite, olivine nephelinite) and quartz tholeiites, and of 10 peridotite xenoliths (or their clinopyroxenes) were analyzed for Nd and Sr isotopes. 143Nd/144Nd ratios and 87Sr/86Sr ratios of all basalts and of the majority of ultramafic xenoliths plot below the mantle array with a large variation in Nd isotopes and a smaller variation in Sr isotopes. The tholeiites were less radiogenic in Nd than the alkali basalts. Volcanics from the Eifel and Massif Central regions contain Nd and Sr, which is more radiogenic than that of the basalts from the Hessian Depression. Nd and Sr isotopic compositions of all rocks from the latter area, with the exception of one tholeiite and one peridotite plot in the same field of isotope ratios as the Ronda ultramafic tectonite (SW Spain), which ranges in composition from garnet to plagioclase peridotite. The alkali basaltic rocks are products of smaller degrees of partial melting of depleted peridotite, which has undergone a larger metasomatic alteration compared with the source rock of tholeiitic magmas. For the peridotite xenoliths such metasomatic alteration is indicated by the correlation of their K contents and isotopic compositions. We assume that the upper mantle locally can acquire isotopic signatures low in radiogenic Nd and Sr from the introduction of delaminated crust. Such granulites low in radiogenic Nd and Sr are products of early REE fractionation and granite (Rb) separation. 相似文献
15.
S. König S. Schuth C. Münker C. Qopoto 《Contributions to Mineralogy and Petrology》2007,153(1):85-103
The petrogenesis of high-Mg andesites (HMA) in subduction zones involves shallow melting of refractory mantle sources or, alternatively, the interaction of ascending slab-derived melts with mantle peridotite. To unravel the petrogenesis of HMA, we report major, trace element and Sr–Nd–Hf–Pb isotope data for a newly found occurrence of HMA in the New Georgia group, Solomon Islands, SW-Pacific. Volcanism in the Solomon Islands was initiated by subduction of the Pacific plate beneath the Indian–Australian plate until a reversal of subduction polarity occurred ca. 10 Ma ago. Currently, the Indian–Australian plate is subducted northeastwards along the San Cristobál trench, forming the younger and still active southwestern Solomon island arc. However, a fossil slab of Pacific crust is still present beneath the arc. The edifice of the active volcano Simbo is located directly in the San Cristobál trench on top of the subducting Indian–Australian plate. Simbo Island lies on top of a strike-slip fault of the adjacent Woodlark spreading centre that is subducted beneath the Pacific plate. Geochemical and petrological compositions of volcanic rocks from Simbo are in marked contrast to those of volcanic rocks from islands north of the trench (mostly arc basalts). Simbo-type rocks are opx-bearing HMA, displaying 60–62 wt% SiO2 but rather primitive Mg–Ni–Cr characteristics with 4–6 wt% MgO, up to 65 ppm Ni, up to 264 ppm Cr and Mg# from 67 to 75. The compositions of the Simbo andesites are explained by a binary mixture of silicic and basaltic melts. Relict olivine phenocrysts with Fo88–90 and reaction-rims of opx also support a mixing model. The basaltic endmember is similar to back-arc basalts from the Woodlark Ridge. A slab melt affinity of the silicic mixing component is indicated by Gd(N)/Yb(N) of up to 2.2 that is higher if compared to MORB and other arc basalts from the Solomon Islands. 87Sr/86Sr, ɛNd and ɛHf values in the analysed rocks range from 0.7035 to 0.7040, +6.4 to +7.9 and +12 to +14.4, respectively. These values reveal the presence of the Indian–Australian mantle domain beneath Simbo (i.e. the Indian–Australian plate) and also beneath all other volcanic islands of the New Georgia group, which are located north of the San Cristobál trench. 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb values (18.43–18.52, 15.49–15.55 and 18.13–18.34, respectively) confirm the presence of slab melts from the subducted Pacific plate beneath southern Simbo where the highest Gd(N)/Yb(N) ratios are reported. A spatial shift towards an Indian–Australian slab signature is observed when approaching the active San Cristobál trench on northern Simbo, reflecting the decreasing influence of slab melts from the old subducted Pacific plate. 相似文献
16.
Petrogenesis of the Swartruggens and Star Group II kimberlite dyke swarms,South Africa: constraints from whole rock geochemistry 总被引:1,自引:0,他引:1
Nancy Coe Anton le Roex John Gurney D. Graham Pearson Geoff Nowell 《Contributions to Mineralogy and Petrology》2008,156(5):627-652
Thirty-seven samples from the Swartruggens and Star Group II kimberlite dyke swarms, emplaced through the Kaapvaal craton,
have been analysed for their major and trace element and Sr, Nd and Hf isotope compositions. The samples are all MgO-rich
(~12–35 wt%) with high Mg# (0.72–0.90) and Ni (~610–2700 ppm) contents. The kimberlites are strongly enriched in incompatible
elements (Zr = 140–668 ppm; La = 124–300 ppm; Nb = 68–227 ppm; Ba = 1500–7000), and have high and variable chondrite normalised
La/Yb ratios (Swartruggens = 94 ± 21; Star = 202 ± 36). 87Sr/86Sr (0.70718–0.71050) ratios are elevated, whereas εNd (−11.95 to −7.84) and 176Hf/177Hf ratios (0.282160–0.282564) are low. Inter- and intra-dyke compositional variation is significant, and there are systematic
differences between the kimberlites found at the two localities. Intra-locality differences can largely be attributed to a
combination of the effects of alteration, crustal contamination, macrocryst entrainment and phenocryst fractionation. There
is some evidence for distinct parental magmas formed through variable and low degrees (0.5–2%) of partial melting, as illustrated
by crossing rare earth element patterns. The Star kimberlites have derived from a less radiogenic source, with higher LREE
enrichment than the Swartruggens kimberlites. Inferred primary magmas at each locality have high Mg# (~0.83), are Ni-rich
(850–1220 ppm) and are strongly enriched in incompatible elements. Calculated mantle source compositions are strongly enriched
in incompatible elements (La/Ybn ~ 10–50), but refractory in terms of Mg# and Ni contents. Incompatible element ratios such as Ba/Nb (>13.5), La/Nb (> 1.1)
and Ce/Pb (< 22) are unlike those characteristic of Group I kimberlites or ocean island basalts, but indistinguishable from
calc-alkaline magmas. Taken together with extremely low εNd and εHf, these compositional characteristics are used to argue
for derivation of these Group II kimberlite magmas from the deep subcontinental lithospheric mantle, metasomatised during
the Proterozoic by calc-alkaline fluids/melts. 相似文献
17.
《International Geology Review》2012,54(6):508-522
The Mt. Erciyes stratovolcano was built up in an intraplate tectonic environment as a consequence of Eurasian and Afro-Arabian continental collision. However, the volcanic products generally exhibit a calc-alkaline character; minor amounts of tholeiitic basalts are also present. Tholeiitic basalts show high Fe2O3, MgO, CaO, low K2O, and depleted Ba, Nb, and especially Rb (2.3-5.97 ppm) contents, low 87Sr/86Sr (0.703344-0.703964), and high 143Nd/144Nd (0.512920-0.512780) isotopic ratios. These compositional features show that they were derived from a depleted asthenospheric mantle source, possibly a MORB-like source component. In contrast, calc-alkaline basaltic rocks exhibit relatively high large-ion-lithophile and high-field-strength elements, high 87Sr/86Sr (0.704591-0.70507) and low 143Nd/144Nd (0.51272-0.512394) isotopic ratios. The bulk-rock chemistry of the tholeiitic basalts reflects the chemical composition of the extracted source component. Furthermore, trace-element concentrations may be calculated from an accepted mantle source component (starting composition) for different degrees of partial melting. These calculations also provide a sensitive approach to the origin of tholeiitic basalts. Modeled trace-element compositions of tholeiitic basalts are calculated from a primitive mantle composition. Calculated trace-element compositions imply that tholeiitic basalts are derived by minor fractional melting (1-1.5 %), in the absence of assimilation or deep-crustal melting. The calc-alkaline basalts were subsequently produced from initially tholeiitic basalts by the way of an AFC (assimilation-fractional crystallization) process, with a crustal assimilation of 10-15 %. The geochemical data, partial melting, and AFC modeling all indicate that basaltic products have a complex evolutionary history involving partial melting from a MORB-like mantle source. The assimilation and fractional crystallization processes are considered as providing an example for the chemical evolution of basaltic products, from tholeiitic to calc-alkaline, in an intraplate environment. 相似文献
18.
Yung-Tan LEE Ju-Chin CHEN Jyh-Yi SHIH Kung-Suan HO Huai-Jen YANG Meng-Lung LIN Yen-Tsui HU Ching-Hsing CHIU 《《地质学报》英文版》2013,87(1):102-117
Cenozoic(Miocene to Pleistocene) basaltic rocks in Jiangsu province of eastern China include olivine tholeiite and alkali basalt.We present major,trace element and Sr-Nd isotopic data as well as Ar-Ar dating of these basalts to discuss the petrogenesis of the basalts and identify the geological processes beneath the study area.On the basis of chemical compisitions and Ar-Ar dating of Cenonoic basaltic rocks from Jiangsu province,we suggest that these basalts may belong to the same magmatic system.The alkali basalts found in Jiangsu province have higherΣFeO,MgO,CaO,Na2O, TiO2 and P2O5 and incompatible elements,but lower Al2O3 and compatible elements contents than olivine tholeiite which may be caused by fractional crystallization of olivine,pyroxene and minor plagioclase.In Jiangsu basaltic rocks the incompatible elements increase with decreasing MgO/ΣFeO ratios.The primitive mantle-normalized incompatible elements and chondrite-normalized REE patterns of basaltic rocks found in Jiangsu province are similar to those of OIB.Partial loss of the mantle lithosphere accompanied by rising of asthenospheric mantle may accelerate the generation of the basaltic magma.The 143Nd/144Nd vs.87Sr/86Sr plot indicates a mixing of a depleted asthenospheric mantle source and an EMI component in the study area.According to Shaw’s equation,the basalts from Jiangsu province may be formed by l%-5%partial melting of a depleted asthenospheric mantle source.On the basis of Ar-Ar ages of this study and the fractional crystallization model proposed by Brooks and Nielsen(1982),we suggest that basalts from Jiangsu province may belong to a magmatic system with JF-2 as the primitive magma which has undergone fractional crystallization and evolved progressively to produce other types of basalts. 相似文献
19.
Anton P le Roex Henry J B Dick Ronald T Watkins 《Contributions to Mineralogy and Petrology》1992,110(2-3):253-268
Glassy pillow basalts with unusual geochemical characteristics for mid-ocean ridge basalt (MORB) have been dredge sampled from the Southwest Indian Ridge between 12 and 15°E during Leg ANT IV/4 of the F.S. POLARSTERN. Lavas from 4 of 6 dredges are moderately nepheline normative, highly K-enriched (0.5–1.77 wt% K2O) alkali basalts and hawaiites. Mg-numbers indicate that many of the lavas are fairly primitive (Mg No.=63–67), yet show extreme enrichment in incompatible elements; e.g. Nb (24–60 ppm), Ba (170–470 ppm) and Sr (258–460 ppm). Incompatible-element ratios such as Zr/Nb (3–5) and Y/Nb (0.46–1.1) are extremely low even for E-type (enriched) MORB, whereas (La/Yb)n ratios are particularly high (3.4–7.8). 87Sr/86Sr (0.70290–0.70368), 143Nd/144Nd (0.51302–0.51284) and 206Pb/204Pb (18.708–19.564) isotopic ratios further indicate the geochemically enriched nature of these lavas, which range from the compositional field for depleted N-type (normal) MORB towards the composition of Bouvet Island lavas. Mutually correlated incompatible-element and Sr-, Nd- and Pb-isotopic ratios allow a fairly well constrained model to be developed for the petrogenesis of these unusually alkalic mid-ocean ridge lavas. The alkalic nature and degree of enrichment in incompatible elements is ascribed to particularly low degrees of partial melting (3–5 wt%), at greater than usual depth, of a source region that has experienced prior geochemical enrichment (by veining) related to the upwelling Bouvet mantle plume. To account for the observed compositional variations, a model is proposed whereby mixing between partial melts derived from these geochemically enriched silicate veins, and an incipient to low percentage (±2%) melt from the surrounding geochemically depleted suboceanic asthenosphere occurs as a consequence of increasing degree of melting with adiabatic upwelling. Eruption of these alkalic lavas in this spreading ridge environment is attributed to a temporary hiatus in tholeiitic volcanism and associated spreading along this section of the Southwest Indian Ridge, related to readjustment of spreading direction to a more stable plate geometry. 相似文献
20.
Adakite-like porphyries from the southern Tibetan continental collision zones: evidence for slab melt metasomatism 总被引:21,自引:0,他引:21
Yongfeng Gao Zengqian Hou Balz S. Kamber Ruihua Wei Xiangjin Meng Rongsheng Zhao 《Contributions to Mineralogy and Petrology》2007,153(1):105-120
We present new whole rock trace element and Pb-isotope data for a suite of Neogene adakitic rocks that formed during the post-collisional stage of the India-Asia collision in an east-west- trending array along the Yalu Tsangpo suture. Compared to classic ‘adakites’ that form along certain active convergent plate margins, the Tibetan adakitic rocks show even stronger enrichment in incompatible elements (i.e. Rb, Ba, Th, K and LREEs) and even larger variation in radiogenic (Pb, Sr, Nd) isotope ratios. Tibetan adakitic rocks have extraordinarily low HREE (Yb: 0.34–0.61 ppm) and Y (3.71–6.79 ppm), high Sr/Y (66–196), high Dyn/Ybn and Lan/Ybn. They show strong evidence of binary mixing both in isotopic space (Sr-Nd, common Pb, thorogenic Pb) and trace element systematics. The majority of the adakitic rocks in south Tibet, including published and our new data, have variational Mg# (0.32–0.70), clear Nb (and HFSE) enrichment, the lowest initial 87Sr/86Sr and 206Pb/204Pb ratios, and the highest 144Nd/143Nd ratios of all Neogene volcanic rocks in south Tibet. These results indicate an involvement of slab melts in petrogenesis. Major and trace element characteristics of the isotopically more enriched adakites are compatible with derivation from subducted sediment but not with assimilation of crustal material. Thus, the south Tibetan adakitic magmas are inferred to have been derived from an upper mantle source metasomatised by slab-derived melts. An interesting observation is that temporally coeval and spatially related lamproites could be genetically related to the adakitic rocks in representing partial melts of distinct mantle domains metasomatised by subducted sediment. Our favoured geodynamic interpretation is that along-strike variation in south Tibetan post-collisional magma compositions may be related to release of slab melts and fluids along the former subduction zone resulting in compositionally distinct mantle domains. 相似文献