Correlated seasonal and climatic variations of trace constituents in the stratosphere

Summary Spectrometric experiments performed, in November 1976, within the framework of the Latitude Survey Mission on board the NASA Convair 990 from Ames Research Center are briefly deseribed. The results presented concern odd nitrogen molecules, HCl and water vapor. In terms of vertical column density, HNO₃ is predominant over NO+NO₂ at all latitudes higher than 40 degrees. A seasonal variation of NO₂ abundance is observed, with larger values in the summer hemisphere at high latitude. The mean zenith column density of HCl above 11 km is 1.5×10¹⁵ mol.cm^–2, with no evidence for any seasonal or climatic variation. Local number densities as high as 1.4×10¹⁰ mol.cm^–3 for HNO₃ and 5.4×10¹⁴ mol.cm^–3 for water vapor have been measured during the same flight near 11 km.     

Instantaneous photochemical rates in the global stratosphere

Starting with the average actual distribution of ozone (Dütsch [15]) and temperature in the stratosphere, we have calculated the solar intensity as a function of wavelength and the instantaneous rates (molecules cm^–3 sec^–1) for each Chapman reaction and for each of several reactions of the oxides of nitrogen. The calculation is similar to that ofBrewer andWilson [5]. These reaction rates were calculated independently in each volume element in spherical polar coordinates defined by R=1 km from zero to 50, =5° latitude, and ø=15° longitude (thus including day and night conditions). Calculations were made for two times: summer-winter (January 15) and spring-fall (March 22). As input data we take observed solar intensities (Ackerman [1]) and observed, critically evaluated. constants for elementary chemical and photochemical reactions; no adjustable parameters are employed. (These are not photochemical equilibrium calculations.) According to the Chapman model, the instantaneous, integrated, world-wide rate of formation of ozone from sunlight is about five times faster than the rate of ozone destruction, and locally (lower tropical stratosphere) the rate of ozone formation exceeds the rate of destruction by a factors as great as 1000. The global rates of increase of ozone are more than 50 times faster thanBrewer andWilson's [5] estimate of the average annual transfer rate of ozone to the troposphere. The rate constants of the Chapman reactions are believed to be well-enough known that it is highly improbable that these discrepancies are, due to erroneous rate constants. It is concluded that something else besides neutral oxygen species is very important in stratospheric ozone photochemistry. The inclusion of a uniform concentration of the oxides of nitrogen (NO_x as, NO and NO₂) averaging 6.6×10^–9 mole fraction gives a balance between global ozone formation and destruction rates. The inclusion of a uniform mole fraction of NO_x at 28×10^–9 also gives a global balance. These calculations support the hypethesis (Crutzen [10],Johnston [24]) that the oxides of nitrogen are the most important factor in the global, natural ozone balance. Several authors have recently evaluated the natural source strength of NO_x in the stratosphere; the projected fleets of supersonic transports would constitute an artificial source of NO_x about equal to the natural value, thus promising more or less to double an active natural stratospheric ingredient.     

The structure of the natural stratosphere and the impact of chlorofluoromethanes on the ozone layer investigated in a 2-D time dependent model

two-dimensional time dependent model of the stratosphere incorporating the major interactions between radiative-photochemical and dynamical processes is described. The main prognostic equations considered are the thermodynamic equation and the general conservation equation for the minor chemical constituents representing the odd oxygen (O _x =O+('D)+O₃), odd hydrogen (HO _x =HO+HO₂), N₂O, odd nitrogen (NO _x =NO+NO₂+HNO₃), CF₂Cl₂, CFCl₃ and odd chlorine (Cl _x =Cl+ClO+HCl). The zonal wind and mean meridional circulations are determined diagnostically by the integration of the thermal wind equation and the stream function equation in the meridional plane espectively. The large scale eddy processes are parameterized in terms of zonal mean quantities using the generalized diffusion formulation on a sloping surface. The radiative heating and cooling and the hotochemical sources and sinks are incorporated in a form which allows for the major interactions among the minor trace constituents, temperature and mean circulation.Two integrations consisting of natural stratosphere and a stratosphere contaminated by the chlorofluoromethanes through lower boundary fluxes are carried out for 23 model years by changing the declination of the sun every day and using 6-hour time step. The model simulations of temperature, mean circulation, ozone, HO _x , N₂O and NO _x in the meridional plane for the normal stratosphere, show satisfactory agreement with the available observations. Based on the results of second integration it is found that the injection of chlorofluoromethanes in the atmosphere at the estimated current production rates can lead to significant changes in the meridional distribution of ozone, temperature and NO _x in the middle and upper stratosphere. The results also indicate that the percentage total ozone depletion increases from tropics to high latitudes and from summer to winter high latitudes. Also discussed are the results of additional experiments incorporating the reaction of HO₂ with NO and the reactions involving ClNO₃.     

Influences of catchment characteristics on nitrogen concentration in largely forested streams during the base flow period

Based on measured stream nitrogen concentrations at outlets of 12 small sub‐areas (1·3–54·7 km²) in a largely forested catchment during the base flow period, we investigated the influences of discharges and different catchment characteristics on stream nitrogen concentration. Our field surveys were carried out during the 11‐month's period from April 2001 to February 2002 and the correlations between nitrogen concentrations and catchment characteristics were studied. The results showed that the vegetation cover was strongly correlated to total nitrogen (TN) and nitrate + nitrite ? nitrogen (NO_x‐N) concentrations. That is, the TN and NO_x‐N concentrations had positive correlations with mean normalized difference vegetation cover index (NDVI) of each sub‐area during dormant seasons (mean NDVI < 0 · 70) and had negative correlations during the growing season (mean NDVI ≥ 0 . 70). The significance of catchment characteristics to TN and NO_x‐N concentrations was ranked as vegetation cover > soil > topography > land use, and the best models can account for 55–64% of the variance of TN and NO_x‐N concentrations. Copyright © 2006 John Wiley & Sons, Ltd.     

Planar charged-particle trajectories in multipole magnetic fields

This paper provides a complete generalization of the classic result that the radius of curvature () of a charged-particle trajectory confined to the equatorial plane of a magnetic dipole is directly proportional to the cube of the particles equatorial distance () from the dipole (i.e. ³). Comparable results are derived for the radii of curvature of all possible planar chargedparticle trajectories in an individual static magnetic multipole of arbitrary order m and degree n. Such trajectories arise wherever there exists a plane (or planes) such that the multipole magnetic field is locally perpendicular to this plane (or planes), everywhere apart from possibly at a set of magnetic neutral lines. Therefore planar trajectories exist in the equatorial plane of an axisymmetric (m = 0), or zonal, magnetic multipole, provided n is odd: the radius of curvature varies directly as ⁿ⁼². This result reduces to the classic one in the case of a zonal magnetic dipole (n = 1). Planar trajectories exist in 2m meridional planes in the case of the general tesseral (0 < m < n) magnetic multipole. These meridional planes are defined by the 2m roots of the equation cos[m()–_n^m)] = 0, where _n^m = (1/m) arctan (h_n^m/g_n^m); g_n^m and h_n^m denote the spherical harmonic coefficients. Equatorial planar trajectories also exist if (n – m) is odd. The polar axis ( = O,) of a tesseral magnetic multipole is a magnetic neutral line if m > I. A further 2_m(n – m) neutral lines exist at the intersections of the 2_m meridional planes with the (n – m) cones defined by the (n – m) roots of the equation P_n^m(cos ) = 0 in the range 0 < 9 < , where P_n^m(cos ) denotes the associated Legendre function. If (n – m) is odd, one of these cones coincides with the equator and the magnetic field is then perpendicular to the equator everywhere apart from the 2m equatorial neutral lines. The radius of curvature of an equatorial trajectory is directly proportional to ⁿ⁼² and inversely proportional to cos[m(–)]. Since this last expression vanishes at the 2m equatorial neutral ines, the radius of curvature becomes infinitely large as the particle approaches any one of these neutral lines. The radius of curvature of a meridional trajectory is directly proportional to rⁿ⁺², where r denotes radial distance from the multiple, and inversely proportional to P_n^m(cos )/sin . Hence the radius of curvature becomes infinitely large if the particle approaches the polar magnetic neutral ine (m > 1) or any one of the 2m(n – m) neutral ines located at the intersections of the 2m meridional planes with the (n – m) cones. Illustrative particle trajectories, derived by stepwise numerical integration of the exact equations of particle motion, are pressented for low-degree (n 3) magnetic multipoles. These computed particle trajectories clearly demonstrate the non-adiabatic scattering of charged particles at magnetic neutral lines. Brief comments are made on the different regions of phase space defined by regular and irregular trajectories.Also Visiting Reader in Physics, University of Sussex, Falmer, Brighton, BN1 9QH, UK     

Instantaneous global ozone balance including observed nitrogen dioxide

The catalytic destruction of stratospheric ozone by the oxides of nitrogen is believed to be an important part of the global ozone balance. The lack of sufficient measurements of NO _x concentrations has impeded efforts to quantify this process. Recent measurements of stratospheric nitrogen dioxide from ground-based stations as well as aircraft and balloons have provided a first approximation to a global distribution of NO₂ vertical columns at sunset. These observed vertical columns have been translated into time-dependent vertical NO₂ profiles by means of a one-dimensional atmospheric photochemical model. Using recent observations of air temperature and ozone along with this information, the independent instantaneous (one second) rates of ozone production from oxygen photolysis P(O₃), of ozone destruction from pure oxygen species (Chapman reactions) L(O _x ), and of ozone destruction by nitrogen oxides L(NO _x ) were estimated over the three-dimensional atmosphere. These quantities are displayed as zonal average contour maps, summed over various latitude zones, summed over various altitude bands, and integrated globally between 15 and 45 km. Although the global summation between 15 and 45 km by no means tells the complete story, these numbers are of some interest, and the relative values are: P(O₃), 100; L(O _x ), 15; L(NO _x ), 45±15. It is to be emphasized that this relative NO _x contribution to the integrated ozone balance is not a measure of the sensitivity of ozone to possible perturbations of stratospheric NO _x ; recent model results must be examined for current estimates of this sensitivity.     

The role of the SO2 oxidation for the background stratospheric sulfate layer in the light of new reaction rate data

Presently available data on the reaction of SO₂ with OH radicals (OH + SO₂ + \(M\xrightarrow[{k_1 }]{}\) HSO₃ +M) are critically reviewed in light of recent stratospheric sulfur budget calculations. These calculations impose that the net oxidation ratek of SO₂ within the stratosphere should fall within the range 10^?7≤k≤10^?9, if the SO₂ oxidation model for the stratospheric sulfate layer is assumed to be correct. The effective reaction rate constantk ₁ ^* =k ₁[M] at the stratospheric temperature is estimated as $$k_1^* = \frac{{(8.2 \pm 2.2) \times 10^{ - 13} \times [M]}}{{(0.79 \mp 0.34) \times 10^{ - 13} + [M]}}cm^3 /molecules sec$$ where [M] refers to the total number density (molecules/cm³). Using the above limiting values ofk ₁ ^* , and the estimated OH density concentrations, the net oxidation rate is calculated as 3.6×10^?7≤k≤1.3×10^?8 at 17 km altitude. This indicates that the upper limit of thesek values exceeds the tolerable range imposed by the model by a factor of about four. Obviously the uncertainty of thek ₁ ^* values and of the OH concentrations in the stratosphere is still too large to make definite conclusions on the validity of the SO₂ model.     

Tidal currents and residual currents at Norderney,Elbe 1, and Aussen-Eider lightships and their variation under the influence of prevailing winds

Summary Four hourly current-and wind observations during the years 1924–1927 at the German lightvessels Norderney, Elbe 1, and Aussen-Eider were subjected to harmonic analysis with emphasis on the influence of the wind on the residual as well as on the tidal current. The tidal current is strongest at Elbe 1 and weakest at Aussen-Eider. The half-monthly inequality of the current is strongly influenced by a ₂ tidal component. Wind influences the velocity, phase and duration of ebb-and flow current in a systematic way at Norderney and Elbe 1. Deviations from the mean tidal current are caused mainly by the change in wind direction rather than by wind velocity. The mean residual current is weak at the three stations. But wind driven currents have a velocity up to 5 times as great as the mean residual current and reverse their direction with the wind. The annual variation of the mean residual current, however, is caused only to a small part by the annual wind variation.Abbreviations used in this paper Gr. M. Tr. Greenwich moon transit, i.e. Greenwich civil time of the upper or lower transit of the moon through the meridian of Greenwich - C _n computed tidal current at M1/2Hn - C _n ^m computed mean tidal current at M1/2Hn - M _n Moon-half hour mean, i.e. mean of all current velocities observed during M1/2Hn - M.A. Moon age of an observation, true Greenwich time of Gr.M.Tr. directly preceeding the time of observation, expressed in 12 integral numbers, each representing M.A. falling in 12 different hourly intervals - M1/2H Moon-half hour, 1/2 of the interval between one moon transit and the next, i.e. 1/24 of 12h25m - R _n ^o ,R _n ^' ,R _n ^" residual current computed by harmonic analysis ofn M1/2H means of the mean current, the current at weak winds, and the current at strong winds respectively - d.o.f. degrees of freedom - standard deviation ofC _n fromM _n - ^* mean standard deviation ofC _n fromM _n for analysis with weighted means - A _o Standard error of the residual currentA _o - AB standard error of the harmonic coefficientsA ₁,B ₁,A ₂,B ₂,... - S ₂ Phase of the current componentS ₂     

草源型可溶性有机物降解过程中活性氧物种产生过程

活性氧物种(ROS)参与天然水体系统中的光化学反应、氧化还原反应,是影响水体中有机污染物的迁移、转化、环境归宿及生态效应的重要因素.然而目前对草源型可溶性有机物(DOM)分解过程中ROS的产生过程并不清楚.本文通过室内模拟实验首先构建了室内测定3种ROS(~3CDOM~*、~1O_2、·OH)的方法,进而分析草源植物——苔草(Carex tristachya)残体浸出液中DOM光降解过程中ROS的产生过程.结果表明:ROS累积含量的产生随着DOM的降解逐渐升高在3种自由基含量中,~3CDOM*的产生含量最多,·OH产生含量低于另外2种ROS两个数量级.CDOM含量与~3CDOM~*、~1O2、·OH浓度呈现正相关关系,尤其与~3CDOM~*和~1O_2浓度的显著性水平最高,·OH次之.ROS浓度与水质指标呈现出不同的线性相关关系,与硝态氮浓度呈负相关关系,而与亚硝态氮浓度呈现正相关关系,并且亚硝态氮对ROS浓度影响效果极显著.同时类蛋白荧光峰值强度的衰减与ROS累积含量呈现极显著负相关关系,脱明在DOM的光降解过程中蛋白质小分子的降解是产生ROS很重要的一个部分.综上通过对草源型DOM光降解过程中ROS产生过程的研究,增加了对湖泊生态系统中水生植物产生ROS的过程、迁移、转化、归宿及其作用机制的认识.     

硝态氮对库区水体藻类和细菌群落的影响

水体富营养化极易引起湖泊水库如藻类水华等水生态系统环境问题。氮素作为初级生产力的限制性生源要素之一,认识其在水华形成过程中潜在作用至关重要。本研究选取胶东半岛低碳高氮水库水体进行模拟实验,通过添加不同剂量硝态氮,探究高硝态氮输入对库区水体藻类和细菌群落结构的影响。结果表明:(1)当硝态氮作为唯一氮源,随着培养时间延长,硝态氮浓度显著下降,亚硝态氮和氨氮浓度逐渐升高,表明微藻和细菌共同作用可能将硝态氮转化为亚硝态氮和氨氮;(2)当硝态氮浓度为6 mg/L时,藻类叶绿素a浓度达到最高值,随着硝态氮浓度升高,叶绿素a浓度则会降低;(3)添加硝态氮后,蓝藻门成为优势藻类,绿藻门次之;变形菌门相对丰度显著升高。研究结果为低碳高氮类水体暴发蓝绿藻水华及有效防控提供理论依据和技术支撑。     

A numerical study of the heat transfer through a fluid layer with recirculating flow between concentric and eccentric spheres

A numerical study has been made of the heat transfer through a fluid layer with recirculating flow. The outer fluid surface was assumed to be spherical, while the inner surface consisted of a sphere concentrically or eccentrically located with respect to the outer spherical surface. The recirculating flow was assumed to be driven by a gas flow creating stress on the fluid's outer surface so that creeping (low Reynolds number) flow developed in its interior. The present study solves the Stokes equation of motion and the convective diffusion equation in bispherical coordinates and presents the streamline and isotherm patterns.Nomenclature a _i inner sphere radius - a _d outer sphere radius - A ₁ defined by equation (5) - A ₂ defined by equation (6) - B ₁ defined by equation (7) - B ₂ defined by equation (8) - c dimensional factor for bispherical coordinates - C constant in equation (4) - d narrowest distance between the two eccentric spheres - E ² operator defined by equation (1) in spherical coordinates and by equation (21) in bispherical coordinates - G modified vorticity, defined in equation (22) - G ^* non-dimensional modified vorticity, defined in equation (28) - h metric coefficient of bispherical coordinate system, defined in equation (18) - k _w thermal conductivity of water - K ₁ defined by equation (9) - K ₂ defined by equation (10) - N _Re Reynolds number=2a _dU/gn - N _Pe,h Peclet number=2a _dU/ - n integer counter - q heat flux - r radius - r ^* non-dimensional radius=r/a _d - S surface area - t time - t ^* non-dimensional time=t/a _d ² - T temperature - T _o temperature at inner sphere surface - T _a temperature at outer sphere surface - T ^* non-dimensional temperature;=(T–T _o)/(T_a–T_o) - u velocity - u _r radial velocity in spherical coordinates - u angular velocity in spherical coordinates - u radial velocity in bispherical coordinates - u angular velocity in bispherical coordinates - U free stream velocity - u _r ^* =u _r/U - u ^* =u /U - u ^* =u /U - u ^* =u /U Greek symbols a ₁ small displacement - vorticity, defined in equation (17) - ^* non-dimensional vorticity, defined in equation (27) - radial bispherical coordinates - _o bispherical coordinate of inner sphere - _a bispherical coordinate of outer sphere - angular coordinate in spherical coordinates - thermal diffusivity - _w thermal diffusivity of water - kinematic viscosity - angular bispherical coordinate - spherical coordinate - streamfunction - non-dimensional streamfunction for spherical coordinates, = /(U a _d ² ) - ^* non-dimensional streamfunction for bispherical coordinates, defined in equation (26)     

Nonlinear behavior on an ozone photochemical system in the stratosphere

A nonlinear box system describing ozone photochemistry in the stratosphere is presented. Influences of pollutants, such as odd chlorine (Cl_x) and odd nitrogen (NO_x) discharged by human activities, on photochemical states of the system are investigated in detail. The results show that the solutions of the box system constitute a ‘cusp’ catastrophe manifold in the state-parameter space. An increase of about 30% for Cl_x source strength or a decrease of about 30% for NO_x source strength from their current level may lead to catastrophic transition and results in a reduction of ozone concentration about 50 times. Project supported by the National Natural Science Foundation of China and Laboratory for Aeronomy and Global Environmental Observation of IAP.     

中国太湖物理—生物工程实验中菱对水质影响的模式

A model on a physico-biological engineering experiment for purifying water in Wulihu Bay of Lake Taihu by using Trapa natans var. bispinosa was constructed. The state variables in water in the physico-biological engineering were ammonium nitrogen (NH₄⁺-N); nitrate nitrogen (NO₃^--N); nitrite nitrogen (NO₂^--N); phosphate phosphorus (PO₄^3--P); dissolved oxygen (DO); nitrogen (N) and phosphorus (P) in detritus; biomass density, N and P in phytoplankton and in Trapa natans var. bispinosa, N and P in the substance adsorbed by the membrane of the engineering and the rootstocks of Trapa natans var. bispinosa. The state variables in bottom mud layer were PO₄^3--P in the core water,exchangeable P and N. The external forcing functions were solar radiation, water temperature, NH₄⁺-N; NO₃^--N; NO₂^--N; PO₄^3--P; N and P in detritus; DO; phytoplankton concentrations in inflow water and the retention time of the water in physico-biological engineering channel. The main physical, chemical and biological processes considered in the model were:growth of Trapa natans var. bispinosa and phytoplankton; oxidation of NH₄⁺-N and NO₂^--N, of detritus break down; N and P sorption by the enclosure cloth of the experimental engineering and by the rootstocks of Trapa natans var. bispinosa in water; reaeration of water; uptake of P, NH₄⁺-N, NO₃^--N by phytoplankton and Trapa natans var. bispinosa:mortality of the phytoplankton and Trapa natans var. bispinosa:settling of detritus; and nutrient release from sediment. Comparison of calculated results and observed results showed that the model was constructed reasonably for the experiment. The mechanism of purifying lake water in the experiment engineering was discussed by the use of the model.     

Hydrochemical behaviour of dissolved nitrogen and carbon in a headwater stream of the Canadian Shield: relevance of antecedent soil moisture conditions

This paper examines the impact of contrasting antecedent soil moisture conditions on the hydrochemical response, here the changes in dissolved nitrogen (NO₃^?, NH₄⁺ and dissolved organic nitrogen (DON)) and dissolved organic carbon (DOC) concentrations, of a first‐order stream during hydrological events. The study was performed in the Hermine, a 5 ha forested watershed of the Canadian Shield. It focused on a series of eight precipitation events (spring, summer and fall) sampled every 2 or 3 h and showing contrasted antecedent moisture conditions. The partition of the eight events between two groups (dry or wet) of antecedent moisture conditions was conducted using a principal component analysis (PCA). The partition was controlled (first axis explained 86% of the variability) by the antecedent streamflow, the streamflow to precipitation ratio Q/P and by the antecedent groundwater depth. The mean H⁺, NO₃^?, NH₄⁺, total dissolved nitrogen and DOC concentrations and electrical conductivity values in the stream were significantly higher following dry antecedent conditions than after wetter conditions had prevailed in the Hermine, although the temporal variability was high (17 to 138%). At the event scale, a significantly higher proportion of the changes in DON, NO₃^?, and DOC concentrations in the stream was explained by temporal variations in discharge compared with the seasonal and annual scales. Two of the key hydrochemical features of the dry events were the synchronous changes in DOC and flow and the frequent negative relationships between discharge and NO₃^?. The DON concentrations were much less responsive than DOC to changes in discharge, whereas NH was not in phase with streamflow. During wet events, the synchronicity between streamflow and DON or NO₃^? was higher than during dry events and discharge and NO₃^? were generally positively linked. Based on these observations, the hydrological behaviour of the Hermine is conceptually compatible with a two‐component model of shallow (DON and DOC rich; variable NO₃^?) and deep (DON and DOC poor; variable NO₃^?) subsurface flow. The high NO₃^? and DOC levels measured at the early stages of dry events reflected the contribution from NO₃^?‐rich groundwaters. The contribution of rapid surface flow on water‐repellent soil materials located close to the stream channel is hypothesized to explain the DOC levels. An understanding of the complex interactions between antecedent soil moisture conditions, the presence of soil nutrients available for leaching and the dynamics of soil water flow paths during storms is essential to explain the fluxes of dissolved nitrogen and carbon in streams of forested watersheds. Copyright © 2007 John Wiley & Sons, Ltd.     

Transport of oceanic nitrate from the continental shelf to the coastal basin in relation to the path of the Kuroshio

Hydrographic and biogeochemical observations were conducted along the longitudinal section from Ise Bay to the continental margin (southern coast of Japan) to investigate changes according to the Kuroshio path variations during the summer. The strength of the uplift of the cold deep water was influenced by the surface intrusion of the Kuroshio water to the shelf region. When the intrusion of the Kuroshio surface water to the shelf region was weak in 2006, the cold and NO₃⁻-rich shelf water intruded into the bottom layer in the bay from the shelf. This bottom intrusion was intensified by the large river discharge. The nitrogen isotope ratio (δ¹⁵N) of NO₃⁻ (4–5‰) in the bottom bay water was same as that in the deeper NO₃⁻ over the shelf, indicating the supply of new nitrogen to the bay. The warm and NO₃⁻-poor shelf water intruded into the middle layer via the mixing region at the bay mouth when the Kuroshio water distributed in the coastal areas off Ise Bay in 2005. The regenerated NO₃⁻ with isotopically light nitrogen (δ¹⁵N=−1‰) was supplied from the shelf to the bay. This NO₃⁻ is regenerated by the nitrification in the upper layer over the shelf. The contribution rate of regenerated NO₃⁻ over the shelf to the total NO₃⁻ in the subsurface chlorophyll maximum layer in the bay was estimated at 56% by a two-source mixing model coupled with the Rayleigh equation.     

Introductory notes on shock remanent magnetization and shock demagnetization of igneous rocks

Summary Effects of mechanical shocks of about 0.5 msec in duration on the remanent magnetization of igneous rocks are experimentally studied. The remanent magnetization acquired by applying a shock (S) in the presence of a magnetic field (H), which is symbolically expressed asJ _R (H₊S H_o), is very large compared with the ordinary isothermal remanent magnetization (IRM) acquired in the same magnetic field.J _R (H₊S H_o) is proportional to the piezo-remanent magnetization,J _R (H₊P₊P_o H_o).The effect of applyingS in advance of an acquisition of IRM is represented symbolically byJ _R (S H₊ H_o).J _R (S H₊ H_o) can become much larger than the ordinary IRM, and is proportional to the advance effect of pressure on IRM,J _R(P₊ P₀ H₊ H₀).The effect of shockS applied on IRM in non-magnetic space is represented by the shock-demagnetization effect,J _R(H₊ H₀ S), which also is proportional toJ _R(H₊ H₀ P₊ P₀).Because, the duration of a shock is very short, a single shock effect cannot achieve the final steady state. The effect ofn-time repeated shocks, is represented byJ ₀+J ^*(n), whereJ ₀ means the immediate effect and J ^*(n) represent the resultant effect of repeating, which is of mathematical expression proportional to [1–exp {–(n–1)}].

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Zusammenfassung Die Effekte des mechanischen Stosses mit der Dauer von etwa 0.5 ms auf der remanenten Magnetisierung wurden experimentell nachgesucht. Das erworbene Remanenz der Magnetisierung nach dem Stoss (S) unter dem magnetischen Feld (H), das hier symbolisch alsJ _R(H₊ SH₀) bezechnet wird, ist sehr stark im Vergleich mit der normalen isothermischen remanenten Magnetisierung (IRM) unter demselben magnetischen Feld.J _R(H₊ S H₀) ist im Verhältnis zur piezoremanenten Magnetisierung,J _R(H₊ P₊ P₀ H₀).Der Effekt vom Stoss vor der Erwerbung von IRM wird symbolisch alsJ _R(S H₊ H₀) bezeichnet.J _R(S H₊ H₀) kann viel stärker als die normale IRM werden, im verhältnis zum Effekt des vorausgegebenen Drucks auf IRMJ _R(P₊ P₀ H₊ H₀).Der Effekt des Stosses auf IRM im Raum ohne magnetisches Feld wird mit dem Stossentmagnetisierungseffekt dargestellt,J _R(H₊ H₀ S), der auch proportional zuJ _R(H₊ H₀ P₊ P₀) ist.Da die Dauer einzelnen Stosses sehr kurz ist, kann der Effekt des einmaligen Stosses den endgültigen stabilen Zustand nicht erreichen. Der Effekt nachn-maligen wiederholten Stossen wird alsJ ₀+J ^*(n) bezeichnet, wobeiJ ₀ den unverzüglichen Effekt bedeutet, und J ^*(n) beschreibt den resultanten Effekt der Stosswiederholung, dessen mathematische Darstellung proporational zu [1–exp {–(n–1)}] ist.

     

The effect of the number of charges carried by the argon ion on the darkening of ilford Q2 emulsion as ion detectors in mass-spectrometer

Summary The darkening (S) of Illford Q₂ photographic plates as ion detectors in mass spectrometer has been investigated. The dependence of the darkening (S) on the ion density (n=ions/mm²) i.e.S=S(n)E for constant energy (E)=z U ranging from 4U20 Kv of the impinging⁴⁰A⁺¹-,⁴⁰A⁺²- and⁴⁰A⁺³-ions whenS does not exceed the value 0.15 and the second relationn=n(z U) _S for darkening 0.05S0.15 constructed from the above relationS=S(n) _E has been determined. The darkening was found to increase with increasing ion-density which inturn decreases with the ionenergy. For⁴⁰A⁺¹-,⁴⁰A⁺²-, and⁴⁰A⁺³-ion of equal energy and ion-density the darkening effect was independent of the number of the charges carried by the argon ion.     

Nährstoff- und Sauerstoffbilanz eines hochbelasteten Klärwerksableiters unter besonderer Berücksichtigung der submersen Makrophyten

Nutrient and Oxygen Balance of a Highly Polluted Treated Sewage Channel with Special Regard to the Submerged Macrophytes The changes of the concentrations of inorganic nitrogen compounds, orthophosphate, and oxygen were measured in the flowing wave along the flowing stretch of the Berlin treated sewage channel Wuhle monthly over a period of two years (1993/94) to estimate the nutrient and oxygen balances. This treated sewage channel is rich in nutrients and densely covered with submerged macrophytes. During the period of investigation in 1993 (1994), the effluent of the sewage treatment plant Falkenberg, which is lacking in adjustable nitrification and denitrification. contained in average 16.1 (12.7) mg/L of NH-N, 13.7 (9.4) mg/L of NO₃^?-N. 0.94 (0.69) mg/L of NO-N. and 0.36 (0.26) mg/L of PO-P. Due to the neglectable influence of other processes like nutrient uptake by submerged macrophytes and algae, desorption of ammonia or dilution, the changes of the concentrations of the inorganic nitrogen compounds are mainly influenced by nitrification and denitrification. The nitrification is mainly done by sessile nitrifiers in the treated sewage channel Wuhle. The nitrification rates. calculated from the decrease of the ammonium concentrations, were between 0.5 and 20 g/(m²d) related to the flowing stretch area. The ammonium concentrations decreased along the flowing stretch in average by 20 to 44%. The highest nitrification rates could be found at the stretches with a dense colonization with submerged macrophytes and a good oxygen supply due to low water depth and high flowing velocities. The denitrification rates, calculated from the decrease of the total of the concentrations of the inorganic nitrogen compounds, were between 0.5 and 23 g/(m²d) related to the flowing stretch area. The total loss of nitrogen due to denitrification was between 10 and 20% along the flowing stretch of the treated sewage channel Wuhle. This corresponds to a total amount of up to 530 kg nitrogen per day. The main part of the phosphorus occured as orthophosphate in concentrations between 0.04 and 0.87 mg/L of PO-P in the effluent of the treatment sewage plant Falkenberg. The orthophosphate concentration changed along the flowing stretch mostly in such a manner that it were at the same level at the end of the flowing stretch at the mouth into the river Spree. The self-purification capacity of the channel does not lead to a relevant reduction of the very high nutrient load under the present conditions. The rates of the photosynthetic production (P) and the community respiration (R) were calculated from the rates of the total changes of oxygen with regard to the physical aeration. The rates of the photosynthetic production were between 0 and 33 g/(m²d), the rates of the community respiration between 15 and 75 g/(m²d). Therewith, the Wuhle treatment sewage channel belongs to the very productive waters. A positive balance (P > R) could only be measured on two segments in May. The rates of oxygen production depend on the ratio width to depth of the water. It is possible that the positive influence of the submerged macrophytes on the oxygen balance also at higher biomasses than 250 g/m² (as dry weight) predominates at the segments with a favourable ratio. The portion of the oxygen input through diffusion along the flowing stretch and at the weirs was 30%, respectively, that of the photosynthic production 40% in summer. The rates of community respiration decreased along the flowing stretch by 50 to 90%. The nitrification had the main portion of the oxygen depletion in the Wuhle treated sewage channel with 60…80%. Despite the high biomass, the respiration of the submerged macrophytes had only a small portion of the total oxygen depletion. Nevertheless, the submerged macrophytes contributed to the nearly total oxygen depletion at the most densely covered segment 2 at night. The decrease of the content of particular organic material and the ammonia concentrations at the effluent of the sewage treatment plant, a diminishing of the biomass of submerged macrophytes by shading, and the widening of a few flowing stretches are demanded for the improvement of the oxygen balance of the Wuhle treated sewage channel.     

Density‐Driven Free‐Convection Model for Isotopically Fractionated Geogenic Nitrate in Sabkha Brine

Subsurface brines with high nitrate (NO₃^?) concentration are common in desert environments as atmospheric nitrogen is concentrated by the evaporation of precipitation and little nitrogen uptake. However, in addition to having an elevated mean concentration of ～525 mg/L (as N), NO₃^? in the coastal sabkhas of Abu Dhabi is enriched in ¹⁵N (mean δ¹⁵N ～17‰), which is an enigma. A NO₃^? solute mass balance analysis of the sabkha aquifer system suggests that more than 90% of the nitrogen is from local atmospheric deposition and the remainder from ascending brine. In contrast, isotopic mass balances based on Δ¹⁷O, δ¹⁵N, and δ¹⁸O data suggest approximately 80 to 90% of the NO₃^? could be from ascending brine. As the sabkha has essentially no soil, no vegetation, and no anthropogenic land or water use, we propose to resolve this apparent contradiction with a density‐driven free‐convection transport model. In this conceptual model, the density of rain is increased by solution of surface salts, transporting near‐surface oxygenated NO₃^? bearing water downward where it encounters reducing conditions and mixes with oxygen‐free ascending geologic brines. In this environment, NO₃^? is partially reduced to nitrogen gas (N₂), thus enriching the remaining NO₃^? in heavy isotopes. The isotopically fractionated NO₃^? and nitrogen gas return to the near‐surface oxidizing environment on the upward displacement leg of the free‐convection cycle, where the nitrogen gas is released to the atmosphere and new NO₃^? is added to the system from atmospheric deposition. This recharge/recycling process has operated over many cycles in the 8000‐year history of the shallow aquifer, progressively concentrating and isotopically fractionating the NO₃^?.