Theoretical Analyses of the Infrared Spectrum of Baiyuneboite—（Ce）

Baiyuneboite-(Ce) is a new fluor-carbonate mineral.Based on the fine data on the structure of the mineral,the factor group and normal coordinate analyses for its infrared spectrum have been carried out.The factor group analyses indicate that the site group and factor group splittings of the internal vibration bands of CO3^2- ions do not occur and that the double bands of normal modes result from two non-equal sets of CO3^2- ions in the crystal structure,The normal coordinate analyses give the stretching force constants.bend force constants and calculated frequencies of CO3^2- ions.The calculations of potential energy distribution allow us to assign v3 and v4 to the stretching vibration and the bend vibration of CO3^2- ions.respectively.     

Molar-tooth Carbonate Sequences and Sr Isotopes in the Neoproterozoic for Stratigraphic Correlation： Research in the JUin-Liaoning-Xuzhou-Huaiyang Area of the Sino-Korean Plate and Its Correlation with the Yangtze Plate

Based on a study of Neoproterozoic carbonates in the Jilin-Liaoning-Xuzhou-Huaiyang area, especially its cyclic sequence stratigraphy and Sr isotopes, two maximum sea flooding events (at 820 Ma and 835 Ma) have been identified. The resulting isochronous stratigraphic correlation proves that these Precambrian strata were connected between the Qingbaikou and the Nanhuan systems with a time range from 750 Ma to 850 Ma. The disappearance of microsparite carbonate and coming of a glacial stage offer important evidence for worldwide stratigraphic correlation and open a window for further correlation of the stratigraphic successions across the Sino-Korean and Yangtze Plates. A new correlation scheme is therefore provided based on our work.     

Biomarkers in the Molar Tooth （MT）-Bearing Limestones in the Jilin-Liaoning Area of China

The origin of Molar Tooth (MT) carbonates has been argued for more than 100 years, which are a kind of Proterozoic carbonates especially composed of microsparite with ptygmatically folded and sheet-like structures. Biomarkers detected in the microcalcsparite from the Wanlong and Xingmincun formations in the Jilin-Liaoning area showed there are abundant normal alkanes, isoprenoids, hopanes, steranes, alkylmethylcyclohexanes, and alkyleyclohexanes, indicating a diversity of biological source: long-chain isoprenoids, the major components of chlorophyll, such as C19, C20, a kind of major biomarkers synthesized early by isoprenoid monomers; hopanes a type of characteristic biomarkers from prokaryote, such as archaebacteria and cyanobacteria; sterane a biomarker for eukaryote; and two kinds of alkanes with C17, C18 as the main peaks representing aquatic bacteria and with C23, C24 as the main peaks representing fungi, respectively. Biomarker analysis showed that MT is the result of bacterial and algal activities, which is a kind of organisms between aerobic and anaerobic bacteria, reproducing well in normal or slightly saline sea water under weak oxidation-reduction conditions, resulting in rapid deposition of calcite as microsparite clue to some mechanisms.     

Tourmaline from the Archean G.R.Halli gold deposit,Chitradurga greenstone belt,Dharwar craton （India）： Implications for the gold metallogeny

Tourmaline occurs as a minor but important mineral in the alteration zc,ne of the Archean orogenic gold deposit of Guddadarangavanahalli （G.R.Halli） in the Chitradurga greenst~ne belt of the western Dharwar craton, southern India. It occurs in the distal alteration halo of the G.R.Halli golcl deposit as （a） clusters of very fine grained aggregates which form a minor constituent in the natrix of the altered metabasalt （AMB tourmaline） and （b） in quartz-carbonate veins （vein tourmaline）. ~[＇he vein tourmaline, based upon the association of specific carbonate minerals, is further grouped as （i） albite-tourmaline-ankerite-quartz veins （vein-1 tourmaline） and （ii） albite-tourmaline-calcite-quartz veins （vein-2 tourmaline）. Both the AMB tourmaline and the vein tourmalines （vein-I and vein-2） belong to the alkali group and are clas- sified under schorl-dravite series. Tourmalines occurring in the veins are zoned while the AMB tour- malines are unzoned. Mineral chemistry and discrimination diagrams 1eveal that cores and rims of the vein tourmalines are distinctly different. Core composition of the ve：n tourmalines is similar to the composition of the AMB tourmaline. The formation of the AMB tourmaline and cores of the vein tour- malines are proposed to be related to the regional D1 deformational event associated with the emplacement of the adjoining ca. 2.61 Ga Chitradurga granite whilst rims of the vein tourmalines vis-a- vis gold mineralization is spatially linked to the juvenile magmatic accretion （2.56-2.50 Ga） east of the studied area in the western part of the eastern Dharwar craton.     

List of Publication for Journal of China University of Geosciences （English Version） in 2007

No.1 Balanced Cross Section for Restoration of Tectonic Evolution in the Southwest Okinawa Trough 001 Wu Shiguo, Ni Xianglong and Guo Junhua Precise Timing of Caledonian Structural Deformation Chronology and Its Implications in Southeast Qilian Mountains, China 011 Fan Guangming and Lei Dongning . i LA-ICP-MS U-Pb Zircon Geochronology of Basic Dikes within Maxianshan Rock Group in the Central Qilian Orogenic Belt and Its Tectonic Implications 019 He Shi ping , Wang Hongli…     

List of Publication for Journal of China University of Geosciences （English Version） in 2006

No. 1 Petrochemistry, Chronology and Tectonic Setting of Strong Peraluminous Anatectic Granitoids in Yunkai Orogenic Belt, Western Guangdong Province, China 001 Peng Songbai, Jin Zhenmin , Liu Yunhua , Fu Jianming , He Longqing , Cai Minghai and Wang Yanbin Lamprophyre or Lamproite Dyke in the SW Tarim Block? -Discussion on the Petrogenesis of These Rocks and Their Source Region 013 Chai Fengmei, Zhang Zhaochong , Mao jingwen, Parat Abudukadir, Wang Lijin , Dong…     

List of Publication for Journal of China University of Geosciences （English Version） in 2004

No .1(SpecialIssuefor 32ndInternationalGeologicalCongress ,Florence ,Italy ,August 2 0 - 2 8,2 0 0 4 )TectonicEvolutionofChinaandItsControloverOilBasins 0 0 1…………………………………………………WangHongzhenandLiSitianResearchonSuperimposedMetallogenicSystem 0 0 9………………………………………………………………ZhaiYusheng ,WangJianping ,DengJunandPengRunminGeochemistryofSulfurandHazardousElementsinLatePaleozoicCoalsandPartingsfromTaozaoCoalfield ,ShandongProvince ,China 0 15……     

《Strategic Study for Water Management in China》（中国水管理战略研究）即将出版

由张海仑教授撰写的《Strategic Study for Water Management in China》将于2004年年底由东南大学出版社正式出版。     

离子色谱法同时测定地质样品中氟氯磷硫

本文研究了离子色谱同时测定地质样品中F~-、Cl~-、PO_4~(3-)、SO_4~(2-)的前处理过程,选择了色谱测定最佳条件。在Na_2CO_3全熔的样品溶液中,加入(NH_4)_2CO_3使Si、Al随大多数金属离子同时沉淀;再用预处理柱除去熔剂引入的大量Na~+及CO_3~(2-)消除其干扰;并在流出液中补加相应试剂与淋洗液相匹配,实现了多种地质样品中F~-、Cl~-、PO_4~(3-)和SO_4~(2-)的测定。方法检出限(3s,μg/ml)分别为F~-0.05、Cl~-0.1、PO_4~(3-)0.3、SO_4~(2-)0.5。测定范围为F~-0.05—3μg/ml,Cl~-0.1—6μg/ml,PO_4~(3-)0.3 —30μg/ml,SO_4~(2-)0.5—30μg/ml。     

热电离质谱铀系法测定碳酸盐标样

用高精度热电离质谱（ＴＩＭＳ）铀系法测定碳酸盐标样的年龄,测定结果与α谱仪铀系法进行比较,铀含量和年龄值均吻合。方法对Ｕ的回收率可达９５％,Ｔｈ为９２％。ＴＩＭＳ铀系法具有样品用量少、测试时间短、精度高的优点。     

塔河油田奥陶系岩溶型碳酸盐岩油藏储集空间发育特征及地质模式探讨

碳酸盐岩表生岩溶作用控制着塔河油田奥陶系油藏缝洞系统的发育及分布。塔河油田奥陶系油藏经历了加里东期和海西早期两次岩溶作用,造成了储层极强的非均质性。通过塔河油田岩溶作用演化及发育期次的研究,将塔河油田奥陶系垂向岩溶带划分为地表岩溶带、纵向渗滤岩溶带和水平潜流岩溶带,平面上发育岩溶高地、岩溶斜坡和岩溶洼地3个地貌单元。通过对野外露头、岩心、钻井、测井、地震及生产动态资料的综合研究,认为溶洞、溶蚀裂缝及蜂窝状孔洞等连续孔隙是该区有效储集空间,基质作为不渗透（低渗）层对缝洞系统有一定的隔挡作用。结合表生岩溶洞穴的原理及对孔隙状态的控制作用,将塔河油田溶洞储集体根据不同成因分为落水洞、潜流洞和小溶洞,按溶洞充填物类型分为垮塌充填洞、机械充填洞和化学充填洞,同时建立了不同类型孔洞系统的识别特征及地质模式。结合塔河油田洞穴储层发育特征及生产实际,最终建立了塔河油田岩溶储集空间展布模式。     

湿地溶解性有机质（DOM）源识别方法研究

湿地是位于水陆生态系统之间的重要生态交错带,而溶解性有机质(DOM)是陆地向水生生态系统输送营养物质的重要载体物质。湿地中DOM的来源分为内源和外源。对湿地中DOM的来源进行识别有助于认识湿地中营养物质的生物化学循环特征,从而进一步了解水陆生态系统之间的物质循环。目前,对湿地DOM进行源识别的方法较多。根据各种方法在研究中应用的广泛性和可用性,本文主要介绍了光学法、同位素法、C/N比值法和生物标志法在湿地DOM源识别中的应用。综合分析表明,光学法、同位素法和C/N比值法在湿地DOM源识别研究中的应用较多。近几年,由于生物标志物(特别是木质素)不仅能够对来源进行识别,而且对源的变化很敏感,因此生物标志法在湿地DOM源识别中的应用成为研究的热点。论文在分析各种湿地DOM源识别方法的基础上,指出了目前研究中存在的问题,并提出进一步研究的方向。     

微生物诱导碳酸盐在土体加固中的应用进展

微生物矿化是近年来在土体改良工程发展起来的一个新分支,主要研究微生物活性在改善土体颗粒特性方面的应用。微生物诱导碳酸盐沉积（MICP）是实现土体生物胶结最常用的方法之一,该技术借助脲酶菌的代谢行为诱导碳酸钙,将松散的砂颗粒胶结成整体,从而提高了土体的力学性能。文章系统性地介绍了MICP研究中的脲酶菌矿化机理、相关处理方法、影响因素、衍生新工艺脲酶诱导碳酸盐沉积EICP及MICP技术在岩土领域的相关现场试验,并对MICP的实用性进行了总结,最后简要讨论了现研究阶段MICP工程应用所面临的挑战和潜在解决方案。     

静电场轨道阱质谱在水中溶解性有机质表征中的应用进展

溶解性有机质(Dissolved Organic Matter,DOM)在水生生态环境中广泛存在,影响着水环境中多种物质的生物地球化学性质.分析其组成与含量具有重要的生态环境意义,是生态环境科学领域研究的热点.溶解性有机质组成非常复杂,其分子组成的解析一直是难题.近年来,具有高分辨率、高灵敏度、高通量、高扫描速率等特性...     

晚三叠世卡尼期碳酸盐生产危机在东特提斯地区的地质记录

欧洲学者基于阿尔卑斯地区上三叠统卡尼阶地质研究提出卡尼期碳酸盐生产危机(carbonate productivity crisis)或者卡尼期洪水事件(Carnian Pluvial Event)的概念,其主要表现为黑色页岩(或绿色页岩、放射虫硅质岩)覆盖于特提斯范围的碳酸盐岩之上,反映了早、晚卡尼期界面处一次明显的碳酸盐沉积中止事件,之上沉积有厚度逐步增加的硅质碎屑岩;这一地质现象在东特提斯地区(中国)卡尼阶中亦有显现,但远未引起重视。实际野外地质调查与前人文献显示,与古特提斯西部、喜马拉雅等地卡尼阶类似,在中国西南部古特提斯范围内的四川盆地西缘、黔中、滇西北、金沙江沿岸等地,卡尼期碳酸盐岩沉积多被一套灰黑色、深灰色页岩(或深色板岩)及之上的陆源碎屑岩覆盖,显示该时期碳酸盐生产的突然中止和生物礁的突然死亡。卡尼期特提斯范围的构造变动很可能对晚三叠世巨型季风气候造成巨大影响,古太平洋暖流向特提斯地区水汽输入增强,相对干旱的气候向相对潮湿的气候转换,大陆风化速率增加,陆源硅质碎屑输入增多,造成了这一显著的地质事件。     

桂林洞穴滴水及现代碳酸钙(CaCO_3)沉积的碳同位素记录及其环境意义

经过前期(1995~2000年)及近2 a对桂林盘龙洞13个滴水点的2个水文年的滴水和现代碳酸钙沉积的动态监测,发现现代洞穴碳酸钙(CaCO_3)沉积有两种类型:①常年性滴水沉积碳酸盐,其δ~(13)C值记录了全年气候变化特征;②季节性滴水沉积碳酸盐,其δ~(13)C值记录了季节性气候变化特征.现代碳酸盐沉积监测和碳同位素分析表明,桂林盘龙洞外部峰体主要为C_3植物(几乎没有C_4植物),现代沉积碳酸盐的δ~(13)C记录显示.在夏半年,夏季风强、降水丰沛、生物的活动量大,现代碳酸盐沉积量大,δ~(13)C值则较偏负,平均为-13.13‰:现代碳酸盐的δ~(13)C全年平均值为-12.23‰,最负值达-14.5‰;而在冬半年,由于降水相对较少,新沉积碳酸盐的艿δ~(13)C值,显示稍有增加(或偏正),其δ~(13)C值为-10‰~11‰.此外,当在降大雨或暴雨后(无论是在夏半年或是在冬半年),滴水在滞后半个月或1个月后沉积形成的碳酸盐,其艿δ(13)C值显示突然偏负,主要反映的是降雨效应引起的CO_2效应的影响.     

电感耦合等离子体发射光谱法同时测定碳酸盐岩石中19个元素

使用ＪＹ７０Ｐ 电感耦合等离子体发射光谱仪,分别考察了一些主要基体对待测元素的各种干扰。综合各种干扰因素,采用干扰系数校正法消除综合干扰,拟定了适用于包括碳酸盐岩石的区域化探样品中１９ 个元素的电感耦合等离子体原子发射光谱同时测定方法。１９ 个元素的测定限在０ ．２０ ～８ ．０ μｇ／ｇ 。对碳酸盐岩石国家一级标准物质ＧＢＷ０７１０８ 进行检测,各元素的结果与标准值吻合,相对标准偏差（ｎ ＝ １１） 在１ ．２ ％ ～５ ．３ ％ 。     

邻二氮菲分光光度法测定碳酸盐相中微量亚铁

建立了在超声波作用下，HAc—NaAc缓冲溶液和邻二氮菲选择性溶解分光光度法直接测定碳酸盐相中微量亚铁的方法。结果表明，在适宜条件下，含2g／L邻二氮菲的HAc—NaAc缓冲溶液（pH3）可选择性溶解并络合碳酸盐相中的Fe（Ⅱ），通过加入EDTA溶液有效地抑制了Fe（Ⅲ）的光还原作用。常见含铁矿物如赤铁矿、磁铁矿及硅酸盐等均对碳酸盐中Fe（Ⅱ）的测定无干扰。样品经30％的H2O2浸泡、过滤、晾干预处理，能有效地消除黄铁矿和有机物的干扰。方法用于石灰岩国家一级标准物质的测定，结果与标准值相符。