The tunica hills,Louisiana-Mississippi: Late glacial locality for spruce and deciduous forest species

Reinvestigation of Quaternary sediments in West Feliciana Parish, southeastern Louisiana, and adjacent Wilkinson County, southwestern Mississippi, has resulted in revision of previous terrace stratigraphy of this portion of the Gulf Coastal Plain. Plant-macrofossil and pollen assemblages incorporated in fluviatile terrace deposits in the study area are reexamined in light of the current stratigraphic understanding. Macrofossils identified as white spruce (Picea glauca), tamarack (Larix laricina), and northern white cedar (Thuja occidentalis), recovered from these terrace deposits along with fossil remains of distinctly southern plant species, were initially interpreted as the result of dynamic intermixing of aggressive boreal species within a southern forest during the early Wisconsin (Brown, 1938). Failure to distinguish chronologically separate fossiliferous deposits resulted in the conceptual “mixing” of northern and southern plant species which came from two distinct fluviatile terrace sequences. Terrace 2 is now believed to be a fluviatile and coastwise depositional terrace of Sangamon Interglacial age; deposits of terrace 2 contain a distinctly warm-temperate plant assemblage. Fluviatile terrace 1 dates from 12,740 ± 300 to 3457 ± 366 BP and is now considered to be related to late glacial and Holocene aggradation and lateral migration of the Mississippi River (the local base level for streams in the study area); basal portions of terrace 1 contain fossils of white spruce, tamarack, and many plant species today characteristic of the cool-temperate Mixed Mesophytic Forest Association. Terrace 1 fossil deposits occur in fluviatile terraces along tributary streams of the Mississippi River at elevations 15 to 30 m above the maximum recorded historic flood stage of the Mississippi River. The plant macrofossils represent remains of species that grew at or very near the site of deposition; they were not “rafted in” by floodwaters of the Mississippi River. We present quantitative data for plant macrofossils and pollen that support our hypothesis that at least local cooling along the Blufflands of Mississippi and Louisiana promoted southward migrations of mixed mesophytic forest species and certain boreal species along this major pathway during late Wisconsin continental glaciation.     

Environmental constraints of human settlement in an evolving holocene alluvial system,the lower Mississippi valley

The lower Mississippi River has aggraded throughout the Holocene, resulting in stratification of cultural materials. Determination of this landscape evolution adds a temporal dimension to a model of human settlement. Sites most likely to be settled are high, well-drained surfaces near a stream. In the middle Holocene, conditions began to be suitable for settlement near Big Lake, Arkansas. A stream developed on the flood plain adjacent to a braided stream terrace. Flooding of the terrace formed a natural levee composed of well-drained, fertile, loam that was better suited for agriculture, if it existed at this time, and a living substrate than terrace sand to the west and backswamp clay to the east. Water and aquatic food sources were nearby. Open swamp conditions, present during middle Holocene, diminished by Late Holocene as bottomland arboreal habitats were becoming reestablished. This ideal environment has been intensely exploited for the past 3000 years, despite the temporary inconvenience of flooding.     

Palaeoenvironmental significance of fluvial facies and archives of Late Quaternary deposits in the floodplain of Damodar River,India

Statigraphic exposures, fluvial archives and borehole data have been allowed to reconstruct the alluvial history of Late Pleistocene to Early Holocene and climate changes in the monsoonal wet–dry region of lower Damodar Basin (West Bengal, India). The facies architectures and climate proxies suggest that five to six climate changes occurred in between ～14 and 6 kiloannum (ka). Supporting evidence from the floodplain of Damodar River demonstrates that the successive phases of aggradation and incision were linked to the south-west monsoonal variability of Late Quaternary period. The onset of semi-arid climate was associated with caliches, pond and backswamp deposits of waning low-energy floods. The relatively warm-humid climate was associated with sandy bedforms, valley fills, slack water deposits and ferruginous nodules. This paper presents a synthesis of the available palaeoclimatic records from the lower Ganga Basin and the rivers of western and central India for the palaeoenvironmental significance of Late Quaternary deposits and discusses the influence of palaeoclimatic controls on the fluvial architectures and archives that developed below the floodplain of Damodar River. We have taken some representative studies from the region to reveal the spatial variability in fluvial successions in response to climate changes during this period.     

Possible impact of shallow interfluve traps on groundwater remediation

Shallow stratigraphic traps exist in certain geologic environments, which might complicate groundwater remediation efforts. Too often, pump-and-treat remediation wells are installed in geometric patterns designed to maximize cleanup operations. If, however, shallow stratigraphic traps are present, certain contaminants may be locally trapped and thus missed during cleanup operations. Alternatively, if shallow stratigraphic traps are delineated prior to location of cleanup wells, fewer wells may be needed for remediation. For example, a single well located at the trap apex, coupled with a single injection well, might be sufficient if: (1) all contaminants were contained in the trap, and (2) the trap was not laterally extensive. Interfluve stratigraphic traps are formed when braided outwash sands are subsequently covered by backswamp or lacustrine clay deposits. Such traps are common near-surface features of the valley train deposits of the Lower Mississippi River Valley and have relief of a few tens of centimeters to perhaps in excess of 10 m. Interfluve traps are also expected to commonly occur in many glaciated regions. Due to channel migration during backswamp clay deposition, and differing thicknesses of clay cover, it is unlikely that all interfluve traps can be delineated by a single method. Therefore, several geological techniques that might be useful in delineating shallow interfluve traps are briefly discussed here, as well as potential complications in using the described methods.     

东胜煤田北部延安组沉积体系及聚煤特征

鄂尔多斯盆地延安组在全盆地发育,是盆地内最重要的含煤、油、气地层之一,依据大量的钻井、测井资料,运用沉积学的方法,对东胜煤田艾来五库沟-台吉召延安组沉积体系及聚煤特征进行了分析。研究认为延安组为辫状河、曲流河及辫状河三角洲沉积,沉积微相主要发育有辫状河体系的河床滞留沉积及心滩、河漫滩和河漫沼泽沉积;曲流河体系的河床滞留沉积、边滩、天然堤、河漫滩、河漫沼泽和河漫湖泊沉积;辫状河三角洲体系的分支河道、天然堤和河漫沼泽沉积等。辫状河及曲流河垂向上表现为下粗上细的间断性正韵律或正旋回,为典型的河流二元结构特征。聚煤特征分析认为,辫状河和曲流河体系河漫沼泽环境是有利成煤场所,由于河道的冲刷、下切作用,辫状河道和曲流河道形成的煤层厚度较小、侧向连续性差;三角洲体系的三角洲平原是有利的成煤带,其煤层具有厚度较大、结构较为简单、分布范围较广、连续性较好的特征。     

Upper Mississippi embayment shallow seismic velocities measured in situ

Vertical seismic compressional- and shear-wave (P-and S-wave) profiles were collected from three shallow boreholes in sediment of the upper Mississippi embayment. The site of the 60-m hole at Shelby Forest, Tennessee, is on bluffs forming the eastern edge of the Mississippi alluvial plain. The bluffs are composed of Pleistocene loess, Pliocene-Pleistocene alluvial clay and sand deposits, and Tertiary deltaic-marine sediment. The 36-m hole at Marked Tree, Arkansas, and the 27-m hole at Risco, Missouri, are in Holocene Mississippi river floodplain sand, silt, and gravel deposits. At each site, impulsive P- and S-waves were generated by man-made sources at the surface while a three-component geophone was locked downhole at 0.91-m intervals.

Consistent with their very similar geology, the two floodplain locations have nearly identical S-wave velocity (V_S) profiles. The lowest V_S values are about 130 m s⁻¹, and the highest values are about 300 m s⁻¹ at these sites. The shear-wave velocity profile at Shelby Forest is very similar within the Pleistocene loess (12 m thick); in deeper, older material, V_S exceeds 400 m s⁻¹.

At Marked Tree, and at Risco, the compressional-wave velocity (V_P) values above the water table are as low as about 230 m s⁻¹, and rise to about 1.9 km s⁻¹ below the water table. At Shelby Forest, V_P values in the unsaturated loess are as low as 302 m s⁻¹. V_P values below the water table are about 1.8 km s⁻¹. For the two floodplain sites, the V_P/V_S ratio increases rapidly across the water table depth. For the Shelby Forest site, the largest increase in the V_P/V_S ratio occurs at 20-m depth, the boundary between the Pliocene-Pleistocene clay and sand deposits and the Eocene shallow-marine clay and silt deposits.

Until recently, seismic velocity data for the embayment basin came from eartquake studies, crustal-scale seismic refraction and reflection profiles, sonic logs, and from analysis of dispersed earthquake surface waves. Since 1991, seismic data for shallow sediment obtained from reflection, refraction, crosshole and downhole techniques have been obtained for sites at the northern end of the embayment basin. The present borehole data, however, are measured from sites representative of large areas in the Mississippi embayment. Therefore, they fill a gap in information needed for modeling the response of the embayment to destructive seismic shaking.     

Iron mineralization in the Garagu Formation of Gara Mountain,Duhok Governorate,Kurdistan, NE Iraq: geochemistry,mineralogy and origin

The iron mineralization is hosted in carbonate beds of the Garagu Formation (Early Cretaceous) at Gara Mountain, Duhok Governorate, Kurdistan Region, NE Iraq. The Garagu Formation is composed of a series of limestone and siltstone beds with iron-rich beds in the middle part. The iron-rich limestones are iron-rich oolitic grainstone and bioclastic wackestone with hematite and goethite minerals. Geochemical results drawn from this study indicate that the percentage of iron in these beds reaches 19.73 %. Moreover, petrographical investigation of thin and polished sections reveals the presence of different types of fossils, indicating an open marine interior platform depositional environment. Different iron minerals, including hematite, goethite, siderite, pyrite and magnetite, were identified in the sections, and their geneses were related to syngenetic and diagenetic processes. The geochemical distribution of major and trace elements, as well as the V/Ni, V/(V+Ni), V/Cr and Sr/Ba ratios, indicates a reducing environment during the precipitation of carbonate sediments and a subsequent oxidizing condition during the concentration of iron minerals via diagenesis.     

Nutrient enrichments and phytoplankton growth in the surface waters of the Louisiana Bight

Nitrate concentrations have increased twofold in the Mississippi River during the past three decades. The increased nitrogen loading to the Louisiana shelf has been postulated as a factor leading to eutrophication and the subsequent development of hypoxia west of the Mississippi River delta. While ratios of nitrogen:phosphorus and nitrogen:silica are relatively high in surface waters on the western Louisiana shelf, nitrogen has been posed as the ‘limiting’ nutrient in this region. Bioassays were performed with nutrient additions to surface waters collected from the Louisiana shelf to examine the potential for specific nutrient limitation. Experiments were conducted in March and September 1991, and May 1992. The growth responses of natural and cultured phytoplankton populations were determined by measuring the time course of in vivo and 3-(3,4 dichlorophenyl)-1, 1-dimethylurea (DCMU)-induced fluorescence, as well as initial and final chlorophylla concentrations. The results suggest that phosphate and silicate potentially limit phytoplankton growth during the winter-spring, particularly at low salinities. In late summer, in contrast, nitrogen limitation may be prominent at higher salinities.     

A preliminary mass balance model of primary productivity and dissolved oxygen in the Mississippi River Plume/Inner Gulf Shelf Region

A deterministic, mass balance model for phytoplankton, nutrients, and dissolved oxygen was applied to the Mississippi River Plume/Inner Gulf Shelf (MRP/IGS) region. The model was calibrated to a comprehensive set of field data collected during July 1990 at over 200 sampling stations in the northern Gulf of Mexico. The spatial domain of the model is represented by a three-dimensional, 21-segment water-column grid extending from the Mississippi River Delta west to the Louisiana-Texas border, and from the shoreline seaward to the 30–60 m bathymetric contours. Diagnostic analyses and numerical experiments were conducted with the calibrated model to better understand the environmental processes controlling primary productivity and dissolved oxygen dynamics in the MRP/IGS region. Underwater light attenuation appears relatively more important than nutrient limitation in controlling rates of primary productivity. Chemical-biological processes appear relatively more important than advective-dispersive transport processes in controlling bottom-water dissolved oxygen dynamics. Oxidation of carbonaceous material in the water column, phytoplankton respiration, and sediment oxygen demand all appear to contribute significantly to total oxygen depletion rates in bottom waters. The estimated contribution of sediment oxygen demand to total oxygen-depletion rates in bottom waters ranges from 22% to 30%. Primary productivity appears to be an important source of dissolved oxygen to bottom waters in the region of the Atchafalaya River discharge and further west along the Louisiana Inner Shelf. Dissolved oxygen concentrations appear very sensitive to changes in underwater light attenuation due to strong coupling between dissolved oxygen and primary productivity in bottom waters. The Louisiana Inner Shelf in the area of the Atchafalaya River discharge and further west to the Texas border appears to be characterized by significantly different light attenuation-depth-primary productivity relationships than the area immediately west of the Mississippi Delta. Nutrient remineralization in the water column appears to contribute significantly to maintaining chlorophyll concentrations on the Louisiana Inner Shelf.     

Chronostratigraphy of upper James river floodplain sediments: Implications for southeastern North Dakota archaeology

Test excavations have been conducted at several dozen prehistoric archaeological sites on the James River floodplain in southeastern North Dakota. Radiocarbon dates and other evidence from these tested artifact deposits indicate that floodplain sedimentary contexts above today's river level are entirely Late Holocene in age. Middle and Early Holocene sediments are more deeply buried. Cultural strata from Late Plains Archaic, Early Plains Woodland, Middle Plains Woodland, and Plains Village settlements are characteristically contained within paleosols in the Late Holocene floodplain sediments. There is a positive correlation between periods of floodplain soil development and mesic climatic episodes identified in current paleoclimatic models for the Plains. There is also evidence for climatic variability within episodes. © 1993 John Wiley & Sons, Inc.     

Impoverishment of recent floodplain forest mollusc fauna in the lower Ohře River (Czech Republic) as a result of prehistoric human impact

Analyses of fossil mollusc successions have rarely been used to study the development of floodplain forests during the Holocene. The Oh?e River, located in a prehistorically settled chernozem area in the Czech Republic, is partly situated in Cretaceous marlstones, yielding sediments suitable for fossilization directly in floodplain deposits. We analysed five fossil mollusc successions situated in the lower stretch of the Oh?e River and compared the results with recent mollusc assemblages studied along the entire 256 km of the river. Fossil samples were composed mostly of open‐country species throughout the Holocene or the whole preserved succession. Only some samples also contained woodland assemblages, but these were always greatly impoverished, with a very low frequency of strictly woodland species. Although the natural‐looking appearance of the present‐day floodplain forests of the lower river stretch has resulted in its being declared a nature reserve, modern floodplain forest mollusc assemblages there are also impoverished. This reduction in the distribution of strictly woodland species compared with modern assemblages in the upper stretch of the river seems to be the result of an ancient human settlement and continuous disturbances of the floodplain forest development since the Neolithic. Thus, fully developed floodplain forest assemblages occur recently only in the upper non‐impacted stretch of the river. Based on the studied fossil successions we can conclude that the lower Oh?e River floodplain was probably a mosaic of open and disturbed forest habitats throughout the Holocene. This area is part of a central European landscape island, where forests probably never fully developed and open patches from the early Holocene continually developed into an agricultural landscape.     

Petrographic and geochemical arguments for hydrothermal formation of the Ouenza siderite deposit (NE Algeria)

The Ouenza siderite deposit is located proximal to evaporitic diapirs of Triassic age. Mineralization occurs mainly in Aptian neritic limestones which host important iron concentrations (120–150 MT) and minor Pb, Zn, Cu, Ba and F occurrences. The iron ore consists of iron carbonate minerals which have been oxidized partially to hematite. Fine-grained ankerite and siderite replace limestones, whereas sparry ankerite and siderite were emplaced in veins. Limited variation in the chemical and isotopic compositions of ankerite and siderite were observed, which indicate that they precipitated from the same fluid. Stable isotope compositions (δ¹⁸O and δ¹³C) of iron carbonates and limestones allow estimation of the isotopic composition of the mineralizing fluid and precipitation temperature: δ¹⁸O = 7.5‰ SMOW, T = 100–120 °C. Later deposition of Pb, Zn, Cu, Ba and F minerals is controlled by fractures oriented NE–SW and SE–NW. Fluid inclusion studies of quartz yield salinities of 18–22 wt.% equivalent NaCl and homogenization temperatures between 150 and 180 °C. These values are similar to those of Mississippi Valley type deposits which are associated with basinal brines. Received: 4 January 1996 / Accepted: 17 July 1996     

Gold Content in Siliceous Deposits Formed from Acidic and Iron-rich Geothermal Waters at Hatchobaru, Central Kyushu, Japan

Abstract: The gold content in siliceous deposits formed from geothermal waters at the Hatchobaru geothermal power station in central Kyushu, Japan, was determined by inductively coupled plasma quadrupole mass spectrometry (ICP–MS). It ranges from 1.3 to 4.6 mg/kg. The highest gold content was obtained from the siliceous deposit formed from acidic waters. In this siliceous deposit, hydrous iron(III) oxide of amorphous state is a major constituent, suggesting that hydrous iron(III) oxide might play an important role when gold is concentrated into siliceous deposits formed from acidic and iron-rich geothermal waters.     

Sources of elevated salinity in the Mississippi River Alluvial Aquifer, south-central Louisiana, USA

Salinization is a process impacting groundwater quality and availability across much of southern Louisiana, USA. However, a broad divergence of opinion exists regarding the causes of this elevated salinity: updip-migrating marine waters from the Gulf of Mexico, saline fluids migrating up fault planes, movement of water from salt domes, and/or remnant seawater from the last major marine transgression. The Mississippi River Alluvial Aquifer (MRAA) in south-central Louisiana is recharged by the Mississippi River, and there are discharge zones to the west and east. Recharge waters from the Mississippi River are fresh, but Cl⁻ levels in the western portions of the aquifer are as high as 1000 mg/L. The aquifer is an important source of water for several municipalities and industries, but prior to this study the source(s) of the elevated salinity or whether the salinization can be remediated had not been determined.The low Br/Cl ratios in the groundwaters are consistent with a saline endmember produced by subsurface dissolution of salt domes, not a marine source. The H and O isotopic systematics of the aquifer waters indicate meteoric sources for the H₂O, not marine waters or diagenetically-altered deep brines. The westward salinization of aquifer water represents a broad regional process, instead of contamination by point sources. Mapping of spatial variations in salinity has permitted the identification of specific salt domes whose subsurface dissolution is producing waters of elevated salinity in the aquifer. These include the Bayou Choctaw and St. Gabriel domes, and possibly the Bayou Blue dome. Salinization is a natural, on-going process, and the potential for remediation or control is slight, if not non-existent.     

蓟县下马岭组富菱铁矿地层的基本地质特征

天津蓟县铁岭子村附近新出露的下马岭组下部黑色岩系中富含菱铁矿,本文从野外产出特征、岩石学特征及常量元素特征等3个方面对这一富菱铁矿地层的基本地质特征进行了报道.该剖面地层主要以黑色页岩、粉砂质富铁层/菱铁矿结核层互层产出为特征,夹有少量粉砂岩.部分富铁层由于风化严重,野外露头以褐铁矿层出现.菱铁矿为地层中主要的铁矿物相,可以形成菱铁矿结核,显微镜下具泥晶或微晶结构;也可以与含量相当的石英粉砂一起,构成致密粉砂质富铁层;亦或呈颗粒状零星分布于黑色页岩、粉砂岩中;另外褐铁矿层中亦存在极少量的菱铁矿残余.地层的常量元素特征整体表现为富含SiO2、TFe及有机质,而贫MnO、CaO、MgO、P2O5及S元素,且除风化层位中的铁多呈三价外,其余多呈二价.总有机碳(TOC)含量由高到低依次为菱铁矿结核、粉砂质富铁层、黑色页岩、粉砂岩.TFe与Al2O3含量的相关性图解显示,在富铁地层中,二者呈现出很好的负相关关系,而在正常的黑色页岩和粉砂岩中,二者则呈现一定的正相关关系,表明富铁地层中的铁主要为海洋自身铁的化学沉积,而正常的黑色页岩和粉砂岩中的铁主要源自陆源碎屑.同时新鲜样品中FeO与TOC含量呈现出很好的正相关关系,表明菱铁矿的形成可能与有机质有关.     

Fluvial geomorphic features of the Lower Mississippi alluvial valley

The Lower Mississippi Valley (LMV) has been one of the most intensively studied alluvial valleys in the world in terms of it's geological and geomorphic framework and history. A brief outline of the history of the major geological and geomorphological investigations of the LMV is provided. The results of these investigations are discussed in terms of the fluvial geomorphic framework of the valley and the apparent significant changes in the regime of the Mississippi River during the Late Wisconsinan and Holocene stages.

The LMV occupies the broad deep synclinal trough of the Mississippi Embayment which extends from Cairo, Illinois, to the Gulf of Mexico in a slightly sinuous north-south trend. The embayment is filled with a north to south thickening wedge of non-marine and marine sediment ranging in age from Jurassic to Holocene. The major landscapes of the LMV may be considered in four regions: (1) a narrow active meander belt in a broad valley of Late Pleistocene valley train in the northern third; (2) a wide mosaic of interwoven Holocene meander belts in the middle third; (3) a relatively narrow valley of the Atchafalaya Basin bounded on each side by narrow meander belts in the upper part of the lower third; and (4) the broad distributary wedge of the deltaic plain in the southernmost region of the valley. The valley trains vary in age and landform with the oldest occurring as slightly dissected low ridges and the youngest as broad flats separated by shallow interwoven former braided channels. Meander belts formed throughout the Holocene are comprised of low natural levee ridges flanking abandoned courses and bordered by crescent-shaped oxbow lakes and ridge and swale topography. In the middle third of the valley, meander belts are separated by expansive backswamps of very little relief. The deltaic plain is also exceptionally flat, interrupted by the low natural levee ridges of the abandoned deltaic distributaries.

The floodplain of the LMV is a complex mosaic of fluvial features and landscapes within the four landscape regions. Included in this mosaic are abandoned channels and courses, lateral accretion topography of ridges and swales, natural levees, crevasses and crevasse channels, distributary channels, backswamps and rimswamps, alluvial fans and aprons, valley trains (braided stream terraces), lakes and lacustrine deltas, terraces, and the alluvial valley bluff.

Changes in the hydraulic regime of the Lower Mississippi River (LMR) since the Late Pleistocene have played a major role in the development of the landscape of the valley. The most important regime change was the diminishment of the influence of Wisconsinan glaciation in the upper Midwest and the resultant evolution of the Mississippi River from a broad braided outwash channel to a more narrow but sinuous meandering channel at the end of the Pleistocene. During the Holocene, the Mississippi River undoubtedly responded to major climatic changes, rising sea level, tributary stream influence, and possibly tectonism, diapirism, and subsidence through the growth and evolution, and abandonment of it's meander belts and deltas.     

Origin of high manganese concentrations in coal mine drainage, eastern Tennessee

The origin of high dissolved manganese concentrations in slightly acidic mine runoff from a surface mine operated by the Cumberland Coal Company in eastern Tennessee was investigated. Mineralogical and chemical analyses were performed on 31 samples of sandstone, shale, coal, and mudstone from the mine to identify the sources and stratigraphic distribution of high extractable manganese contents in the spoil materials. The samples were analyzed for their bulk mineral content by X-ray diffraction, net acid-base potential, and reaction to 2 or 4 chemical extraction procedures. A limited number of samples were analyzed for petrographic characteristics, clay mineral composition by X-ray diffraction, and mineral compositions by electron microprobe. Analysis of the data and consideration of the geochemical conditions at the mine were used to identify probable sources for the high extractable manganese contents.The results indicate 2 prominent, independent sources of extractable manganese. The first source is exchangeable manganese on clay minerals (mainly illite + muscovite and chlorite) and is concentrated in shale and mudstone rock types. The second and more significant source is manganese in siderite concretions and cement, mainly in shale and mudstone. Comparison to other coal-bearing strata indicates that manganese-rich siderite is common in fresh- to brackish-water subaqueous sediments that overlie coal. This is especially the case for coals formed in wet, tropical environments.Ratios of manganese to calcium and magnesium in mine runoff suggest that manganese from siderite is the major cause of the high dissolved manganese contents. A conceptual model is developed to explain the high manganese contents of the mine runoff. Oxidation of pyrite creates mildly acidic waters that are subsequently partially neutralized by reaction with impure siderite. Solubilized manganese remains dissolved in the slightly acidic runoff water, whereas dissolved iron precipitates as ferric hydroxide or goethite. Consideration of data from other coal mining regions suggests that similar reactions involving impure siderite may be responsible for high manganese concentrations in acidic to slightly acidic mine runoff. Geochemical reaction path modeling of pyrite and impure siderite with rainwater illustrate how resulting water compositions may vary depending on pyrite to siderite ratios in spoil materials. Spoil water compositions from the Cumberland mine are largely consistent with reaction of pyrite and impure siderite in proportions observed in the sediments; however, deviations may be explained by minor mixing with waters that reacted only with impure siderite or clay mineral exchange reactions.     

Trace metals in acid sediments and waters, Pimpama catchment, southeast Queensland, Australia

The Pimpama River floodplain has developed over the last several thousand years as a result of sea-level fluctuations that shaped the lower catchment and enabled the formation of sedimentary pyrite. The subsequent production of sulfuric acid due to the oxidation of this pyrite enhances the breakdown of metal-bearing sediments and can lead to leaching of major and trace metals into the waters of the region. The seasonal pattern of rainfall and current land-use activities are important aspects that intensify the natural production of acid and influence the release and distribution of metals. To identify the source and migration of metals in the Pimpama catchment and to understand the impact of pyrite oxidation on the distribution of metals in sediments and waters, several components of the drainage system were analyzed: bedrock, sediments from river bed and bank, and water. The elements analyzed in this study (V, Cr, Co, Ni, Cu, Zn and Pb) are all present in the bedrock material which explains their occurrence in the unconsolidated sediments of the floodplain. These metals concentrate in the upper section of the sedimentary sequence and their presence is related to clay minerals such as smectite, organic matter and iron phases. However, Zn, Mo and Co occur in higher amounts than the local background and within standard shale. This comparison suggests that the diagenetic processes alone cannot explain the higher concentrations and it is concluded that these metals also have an anthropogenic source. The formation of sulfuric acid creates conditions for higher mobility of some metals, such as Cr, Co, Ni, Cu, Zn, but does not affect less mobile ones such as Mo and Pb. Over the longterm, the production of acid influences the breakdown of mineral phases and enhances the process of weathering. Over the short term, every rain event leaches acid from sediments and mobilizes metals resulting in a substantial reduction in the quality of river water. Received: 2 October 1998 · Accepted: 16 February 1999     

Conditions and mechanism for the formation of iron-rich Montmorillonite in deep sea sediments (Costa Rica margin): Coupling high resolution mineralogical characterization and geochemical modeling

Iron-rich smectite is commonly described in the diagenetic fraction of deep-sea sediment, as millimeter to centimeter aggregates dispersed in the sediment, or as a coating on sedimentary particles or nodules. This study examines several factors to elucidate formation mechanisms of a particular iron-rich smectite and its potential transformation to glauconite. The study combines a detailed mineralogical investigation on natural samples and a chemical modeling approach to assess mineralogical reactions and pathways.Transmission electron microscopy (TEM) observations and analytical electron microscopy (TEM-AEM) analyses were conducted on microtomed samples of millimeter- to centimeter-long green grains. These grains are widespread in pelagic calcareous sediment from the Costa Rica margin. They are composed of pyrites that are partially dissolved and are surrounded by amorphous or very poorly crystallized iron-rich particles. Iron-rich montmorillonite grows from an amorphous precursor and its formation requires the input of Si, O, Mg, K, Na and Ca; our results suggest that these inputs are supported by the dissolution of sedimentary phases such as volcanic glasses, siliceous fossils and silicates.Thermodynamic modeling of fluid-sediment interactions was conducted with the geochemical computer code PhreeqC, using mineralogical and pore fluid compositions from sediment samples and calculated estimates for thermodynamic constants of smectites that are not maintained by the computer code. Simulations confirm the possibility that the green grains are the product of pyrite alteration by seawater under oxidizing conditions. The extent of smectite production is controlled by the kinetics of pyrite dissolution and fluid migration. The absence of aluminum in the Costa Rica margin system explains the formation of an iron-rich montmorillonite instead of glauconite, whereas the presence of calcite that buffers the system explains the formation of an iron-rich montmorillonite instead of iron oxides.     

Will lowering estuarine salinity increase Gulf of Mexico oyster landings?

Previous studies provide conflicting opinions on whether lower than average salinities in Gulf of Mexico (GOM) estuaries are likely to increase or decrease oyster harvests (Crassostrea virginica), which represented 69% and 54% of the United States oyster landings by weight, and dockside value, respectively, in 2003. The present study examined a 54-yr record (1950–2003) of oyster harvests and river discharge in five major estuaries in GOM states (Florida, Alabama, Mississippi, Louisiana, and Texas). Oyster landings were inversely related to freshwater inflow. Peaks in landings, 21 of 23 in West Florida, Alabama, Mississippi, and Texas combined, were coincidental with lows in river discharge from the major rivers in the estuaries. Lows in landings in these states (17 of 19) coincided with peaks in discharge of the major rivers feeding their estuaries. Landings in Breton Sound, Louisiana, were also inversely related to river discharge. The only exception to this pattern was for landings in the Plaquemines Parish, Louisiana, part of the Breton Sound estuary, where there were higher landings following increased Mississippi River discharge. The Bonnet Carré spillway, completed in 1931, diverts flood waters from the Mississippi River to Lake Pontchartrain, and it has been opened to reduce flood heights in 1937, 1950, 1973, 1975, 1979, 1983, and 1997. Twenty-five of 28 times after the spillway was opened, oyster landings in Mississippi were lower than in the other four states. The inverse relationship between freshwater inflow and oyster landings suggests that the proposed Bonnet Carré Freshwater Project, designed to reduce estuarine salinity, cannot be justified on the basis of anticipated higher oyster yields in Mississippi or Louisiana. Manipulating estuarine salinity in the GOM should be done within the context of the whole estuary and not just part of the estuary.