砂体对煤层硫分控制的探讨

山西霍西、西山、平朔、大同、沁水、内蒙准旗和河南禹县煤田或矿区的煤层全硫峰值闰于下伏砂体较薄带或尖灭处，呈错位关系，可靠性可达９０％。其控制因素是下伏砂体决定的成煤泥炭沼泽基底地形的差异。下伏砂伏厚时，沼泽基底常呈现较状地形；在砂体较薄或尖灭的低凹处，常由潜流或迳流带来较多含砂吸附铁离子的细悬浮粘土及硫酸钙，经还原作用可形成较多的硫铁矿硫，使低凹处形成的煤硫含量较高。这种关系可用来预测低硫煤区及勘     

豫西荥巩——新密煤田太原组、山西组的沉积环境和聚煤规律

荥巩和新密煤田是豫西北部的两个相邻煤田。主要含煤地层为晚古生代晚石炭世太原组和早二叠世山西组,总厚100—150m;下石盒子组及晚二叠世的上石盒子组在本区仅偶含薄煤层。太原组位于含煤岩系最底部,为碳酸盐岩和碎屑岩交替沉积,灰岩形成于清澈、温暖、浅水的陆表海潮下环境,碎屑岩则为潮道和潮间带为主的潮道、潮坪沉积。太原组含有6—7层薄煤层,形成于咸水或半咸水的泥炭沼泽中。山西组几乎全由碎屑岩组成,下部发育本区的主要可采煤层二1煤。二1煤以下层位为潮坪和横向与之共生的潮道、潮沟及河口潮汐砂脊沉积,二1煤以上为河流作用为主的三角洲沉积,三角洲由北向南进积到半咸水的海湾中。二1煤形成于海退时期,它们堆积在滨海平原的淡水泥炭沼泽中,其厚度变化及发育程度主要受成煤前沉积环境控制,但在本区西部构造较复杂处,煤层厚度受后期构造影响较大。沉积环境对煤层原生厚度的影响主要表现在潮坪和废弃的潮道、潮沟、河口潮汐砂背沉积物之上,煤层发育好,而在二1煤之下有活动的潮道及河口潮汐砂脊发育时,煤层较薄或不发育。     

Melanite garnet-bearing nepheline syenite minor intrusion in Mawpyut ultramafic–mafic complex,Jaintia Hills,Meghalaya

Mawpyut igneous suite in Jaintia Hills of Meghalaya plateau comprises differentiated suite of ultramafic–mafic rocks. The complex differs from other ultramafic–alkaline–carbonatite igneous emplacements of Shillong plateau and Mikir Hills like Jesra, Sung, Samchampi complexes, by the absence of alkaline–carbonatite rocks as major litho-units. Melanite garnet-bearing nepheline syenite, occurs as late phase minor intrusion in Mawpyut igneous complex, posseses alkaline character and shows inubiquitous relation with the host ultramafic–mafic rocks. On the other hand, this alkaline intrusive bodies of the Mawpyut igneous complex shows chemico-mineralogical resemblance with garnet-bearing nepheline syenite, ijolite litho-members of Jesra, Sung, Samchampi complexes of the region. It is interpreted that melanite garnet-bearing nepheline syenite intrusion in Mawpyut is contemporaneous with Jesra, Sung, Samchampi ultramafic–alkaline–carbonatite complexes and the host rocks of Mawpyut complex is an earlier magmatic activity possibly from a comparatively least enriched source.     

河北兴隆煤田巨厚煤层的地层归属

限据海水进退规程、植物化石、火山碎屑岩分布及煤层发育等情况进行对比,华北地台北部晚古生代普遍存在的巨厚煤层应归属太原组。     

Petrographic characteristics and depositional conditions of Eocene coals of platform basins, Meghalaya, India

The coal deposits of Meghalaya occur in the Lakadong Sandstone (25–250 m thick) of Eocene age. The coal-bearing formations are understood to have been deposited over platform areas in estuarine and lagoonal environments and subjected to recurrent marine transgressions and regressions during the Eocene period. There are three major groups of coalfields in Meghalaya, viz. Garo Hills (West Daranggiri and Siju Coalfields), Khasi Hills (Langrin and Mawlong–Shella Coalfields) and minor coalfields (Laitryngew, Cherrapunji and Bapung Coalfields). Pillar coal samples have been collected from 10 seams at 15 locations and have been subjected to a detailed petrographic examination for their characterization. An effort has been made to trace the path of their evolution based on coal petrography-based models. The quantitative petrographic analysis shows that these coals are vitrinite rich (45.0–92.9%, mean 73.4% mmf basis) with low concentration of inertinite (0.0–13.8%, mean 3.0% mmf basis), whereas the liptinite occurs in appreciable concentration (5.5–53.1%, mean 22.5% mmf basis). Further, these coals are rich in vitrite (51.6–100%, mean 78.3% mmf basis). The volatile matter (from 38.5% to 70.0%, d.a.f.) and vitrinite reflectance (Rom from 0.37% to 0.68%) characterize these coals, as per German (DIN) and North American classification, approximately as sub-bituminous ‘C' to high volatile ‘C' bituminous. The occurrence of teleutospore (single, double and triple celled) suggests that these coals have originated from a characteristic Tertiary flora. The maceral and microlithotype composition in the coal petrography-based depositional models suggest that the coals of Garo Hills were formed in reed to open water swamps in telmatic to limnic conditions. The coals of Khasi Hills were dominated by forest swamps and telmatic to limno-telmatic conditions. In addition, the occurrence of large-size resins suggests prolific growth of conifers in the swamps.     

Sulphur saturation in the lower and critical zones of the Eastern Bushveld Complex

A suite of ultramafic and mafic rocks from the lower, critical and lower portion of the main zones of the Bushveld Complex has been analysed for Th, Cs, Zr, Ni, Cr and Au by INAA and XRF spectrometry. The incompatible elements Th, Cs, and Zr correlate positively, and show a gradual upward increase in abundance. Assuming constant average proportion of intercumulus material, this upward increase implies that the zones of the Complex studied represent crystallization of a single magma type some 3600 m thick. Pyroxenites dominate the lower portion of the section studied and their Ni content shows an initial rapid decrease from 850 ppm in the lowermost rocks, to around 500 ppm, with considerable scatter. This distribution is most likely to have resulted from bottom crystallization with superimposed convective overturn near the transient floor of the chamber. Gold abundances are generally higher in chromitites, and correlate positively with Ni, indicating the presence of significant amounts of cumulus immiscible sulphide. In the silicate rocks, Au does not correlate with any of the analysed elements, and it is concluded that Au was trapped in small quantities of immiscible sulphide which precipitated continuously during crystallization. There is an upward increase in the amount of cumulus immiscible sulphide, indicating a progressive increase in sulphur solubility in the magma.     

REE mineralization in the carbonatites of the sung valley ultramafic-alkaline-carbonatite complex,Meghalaya, India

The Early Cretaceous Sung Valley Ultramafic-Alkaline-Carbonatite (SUAC) complex intruded the Proterozoic Shillong Group of rocks and located in the East Khasi Hills and West Jaintia Hills districts of Meghalaya. The SUAC complex is a bowl-shaped depression covering an area of about 26 km² and is comprised serpentinised peridotite forming the core of the complex with pyroxenite rim. Alkaline rocks are dominantly ijolite and nepheline syenite, occur as ring-shaped bodies as well as dykes. Carbonatites are, the youngest intrusive phase in the complex, where they form oval-shaped bodies, small dykes and veins. During the course of large scale mapping in parts of the Sung Valley complex, eleven carbonatite bodies were delineated. These isolated carbonatite bodies have a general NW-SE and E-W trend and vary from 20–125 m long and 10–40 m wide. Calcite carbonatite is the dominant variety and comprises minor dolomite and apatite and accessory olivine, magnetite, pyrochlore and phlogopite. The REE-bearing minerals identified in the Sung Valley carbonatites are bastnäsite-(Ce), ancylite-(Ce), belovite-(Ce), britholite-(Ce) and pyrochlore that are associated with calcite and apatite. The presence of REE carbonates and phosphates associated with REE-Nb bearing pyrochlore enhances the economic potential of the Sung Valley carbonatites. Trace-element geochemistry also reveals an enrichment of LREEs in the carbonatites and average ΣREE value of 0.102% in 26 bed rock samples. Channel samples shows average ΣREE values of 0.103 wt%. Moreover, few samples from carbonatite bodies has indicated relatively higher values for Sn, Hf, Ta and U. Since the present study focuses surface evaluation of REE, therefore, detailed subsurface exploration will be of immense help to determine the REE and other associated mineralization of the Sung Valley carbonatite prospect.     

Geological controls on the sulphur content of coal seams in the Northumberland Coalfield, Northeast England

The sulphur content of coal is an important consideration when developing reserves for exploitation, driven by emission limits from power stations becoming more stringent. Variations in the sulphur content of Westphalian A and B coals from the predominantly freshwater Northumberland Coalfield, Northeast England, were studied according to their regional, stratigraphic and in-seam location. The observed variation in sulphur content spatially increases towards the source area away from more marine influenced areas, with increased sulphur content through time linked to changes in the general depositional environment as conditions became more marine-influenced. A model of basinal surface water and groundwater flow driven by post-depositional source area tectonism is thought to have played only a minor role in contributing secondary sulphur to the coal. However, the isotopic composition of coal pyrite shows a similar range in composition to that of pyrite and other sulphides from the North Pennine Orefield along the southern margin of the coalfield, suggesting an additional potential source of secondary sulphur, as sulphur-rich fluids were expelled northwards through the coal measures during early Permian Variscan transpression from the south. The Westphalian A and B are interpreted as third-order depositional sequences, defined by third-order maximum flooding surfaces. Each sequence is made up of several coal-bearing fourth-order parasequences, which tend to be more brackish to marine in character, on either side of the third-order maximum flooding surfaces when base level was relatively high. The lowest sulphur coals are confined to the lower to middle, relative low stand part of the Westphalian A third-order base level curve and the lowest part of the Westphalian B third-order base level curve. This difference is attributed to a more rapid rise of base level in the Westphalian B. The stratigraphic and spatial distribution of coal sulphur has been used as a guide to prediction of reserve identification for surface mining operations.     

Volatile displacement of Meghalaya coals — A pointer to explore low sulphur coals

Volatile displacement, which measures the difference between calculated and experimental volatile matter, is indicative of abnormality in coals which may be related to petrological or chemical parameters. The volatile displacement (δυ) values of Meghalaya coals were calculated from their chemical analyses. Correlations of volatile displacement (δυ) with parameters such as carbon, hydrogen, moisture, oxygen, oxygen plus sulphate sulphur, oxygen plus pyritic sulphur, oxygen plus organic sulphur and total sulphur were studied. An approximately linear relationship exists only between δυ and moisture, and δυ and total sulphur, and not between other parameters. Plots on Seyler’s chart indicate the coals as perhydrous to orthohydrous. The linear relationship with total sulphur indicates that the coals may have become abnormal mainly due to the marine environment of deposition and weathering.     

Reconnaissance of quaternary sediments from Khasi Hills,Meghalaya

Khasi Hills area of Meghalaya, one of the highest rainfall zones of the world has been explored to understand the spatial and temporal extent of Quaternary sediments. In general such deposits are restricted to shallow depths in most of the sites except in one site where it is 600 cm thick. AMS C-14 dates of these deposits suggest that sediments deposited are mostly of Holocene or in rare cases belong to later part of Pleistocene. Early Quaternary deposit is either missing or yet to be explored from this region. Natural hazards combined with human activity effecting degradation of vegetation and sediment cover are probably the main cause for poor Quaternary exposure at the region.     

利用测井资料解释炼焦煤中硫含量初探

煤层中含有硫化物（特别是硫铁矿）,代表一种强的还原环境。测井中自然电位参数对氧化和还原环境的反映比较明显。根据这种关系,我们将自然电位测井数据和实验室分析原煤全硫含量进行回归,建立回归方程,进而推广了自然电位测井资料在实际工作中的应用。     

Organic carbon and sulphur compounds in wetland soils: insights on structure and transformation processes using K-edge XANES and NMR spectroscopy

X-ray absorption near-edge structure (XANES) and nuclear magnetic resonance (NMR) spectroscopy were used in combination to characterize organic carbon structures in a series of wetland soils in Saskatchewan, and XANES spectroscopy was also used to examine sulphur speciation in the soils. The organic C contents of most of the wetland soils are consistently higher by a factor of two to five times compared to adjacent well-drained soils. NMR analyses indicate that the organic matter in the wetland soils consists of predominantly aliphatic structures such as carbohydrates and long chain poly(methylene) units which are refractory structures found in plant waxes. The poly(methylene) structures have a significant capacity to sorb nonpolar organic molecules. The phenolic OH and carboxyl group content of the wetland soils studied is an additional significant factor in their sequestering ability for heavy metals or pesticides. Carbon XANES spectroscopy shows that the surface (∼10 nm) layer of particulate organic matter has a structure dominated by aromatic, carbohydrate and carboxylic acid-like material apparently derived from partially degraded lignin and cellulose polymers which are adsorbed onto clay minerals. The aliphatic structures remaining in this surface layer are probably recalcitrant (poly)methylene units. At a depth of ∼100 nm, the aliphatic content significantly increases suggesting the presence of more labile structures. The presence of these more labile aliphatic compounds may be due to slow decomposition rates in the wet, often cool environments present and to the protective action of the more refractory components in the surface ∼10 nm of the organic matter. Drying of the wetlands, either by draining or as a result of climate change, is likely to result in the rapid decomposition of these labile organic structures releasing carbon dioxide. Our data indicate that the preservation of the organic carbon compounds in these soils is a result of their presence as surface adsorbed layers on the soil mineral particles. The soils contain three different classes of sulphur compounds: reduced organic sulphur such as sulphides, low valent oxidized sulphur such as sulphoxides, and high valent oxidized sulphur such as sulphonate and sulphate. Of these, reduced sulphur species constitute between one-third and two-thirds of the total. Sulphonate structures comprise between a fifth and a third of the total. Sulphates exhibit a wide variation in content, and sulphoxides are either not detected or are present to a lesser extent (<5%). Drying of the wetlands would cause oxidation of sulphides to sulphates.     

Sequence stratigraphic analysis and the origins of Tertiary brown coal lithotypes, Latrobe Valley, Gippsland Basin, Australia

The methods of sequence analysis have been applied to the onshore Gippsland Basin and in particular to the Latrobe Valley Group coal measures which include up to five coal seams each exceeding 100 m in thickness. The methods appear to provide new depositional concepts to the evolution of these seams, and the development of coal lithotypes. In the eastern half of the Latrobe Valley evidence for marine transgressions into the coal measures are recorded in most of the interseam sediment splits by the presence of contained foraminifera and dinoflagellates. To the west (inland) these splits pinch out into continuous coal. However, they can be followed westwards as enhanced organic sulphur levels along sharply defined boundaries between light coal lithotypes below and dark coal lithotypes above. The dark lithotype immediately overlying each of these boundaries contains the highest sulphur value and warmer climate pollen assemblages (Sluiter et al., 1995, this volume).Colorimeter and lithotype logging strongly supports an upwards lightening cyclicity to coal colour at 12–20 m intervals through the approx. 100 m thick seams, with cycle boundaries defined at sharp planar to undulating surfaces. The lightening upward lithotype cycles together with their unique boundary conditions (i.e. enhanced organic sulphur levels, warm climatic indicators and laterally equivalent marine clay splits) are interpreted as parasequences and parasequence boundaries respectively. Each major coal seam can comprise up to five parasequences and is interpreted to represent deposition during an outbuilding high stand systems tract at one of several maximum periods of Tertiary coastal onlap. The top of each major seam shows evidence of truncation (erosion?) on a regional scale and these surfaces are interpreted to represent the sequence boundaries. The major seams are usually conformably underlain by marine clays and extensive aquifer sands, being deposits of the late transgressive systems tracts. The low stands and early parts of the transgressive systems tracts appear not to be represented in the Latrobe Valley due to its (more) basin margin location, but are probably present down-dip in the equivalent marine facies of the Seaspray Group.Stratigraphic correlation of the sequence boundaries identified in the coal measures to the adjacent, internationally dated marine Seaspray Group, provides a basis for chronostratigraphic correlation of the coal successions to the coastal onlap charts of Haq et al. (Exon Mesozoic-Cenozoic chronostratigraphic chart, version January 1988, and August 1989). From this dating it appears that each major seam is confined to high stands of third order eustatic cycles. It therefore follows that the lithotype cycles (parasequences) that comprise each seam are related to fourth order eustatic cycles. By analogy all the coal cycles may have developed under subtropical conditions as ombrogenous forested peat swamps in a similar manner to the Holocene, though tropical, swamps of Indonesia.     

Mercury in Western Canadian subbituminous coal—a weighted average study to evaluate potential mercury reduction by selective mining

Western Canadian subbituminous coal is mined using strip-mining methods. The coal is used to feed coal-fired power plants for electricity generation. Parameters that influence the mercury content of these coals include the occurrence and frequency of partings in the seam, weathering, and epigenetic mineralization. Most partings have higher mercury content than the coal layers in the same seam, with the single bentonite bed having the highest Hg content. However, some high ash components, such as sandy siltstone, do not follow this trend. The incorporation of the high mercury partings into the as-mined coal may increase the Hg content in the feed coal. Epigenetic mineralization may also increase the mercury content of coal, depending on the nature of the mineralization.Calculation of the weighted mean of mercury content for various combination of lithological components of a seam illustrates how these components influence the total mercury content of the seam. This approach also suggests how selective mining might be used to reduce mercury in “as-mined” coal.Results of weighted average calculations of mercury indicate that the thin lithological units with moderate mercury may not necessarily influence that overall weighted average of Hg for a seam. However, there can be exception, such as presence of thin (3.5 cm) bentonite parting with high mercury in a 94.5 cm seam that increased the mercury content of seam by 83.4%.     

Identifying spatial heterogeneity of coal resource quality in a multilayer coal deposit by multivariate geostatistics

This study presents a new geostatistical approach to characterization of the geometry and quality of a multilayer coal deposit using the data of seam thickness as a geometric property and the contents of ash, sodium, total sulphur, and the heating value as quality properties. A coal deposit in East Kalimantan (Borneo), Indonesia, which has a synclinal geological structure, was chosen as the study site. Semivariogram analysis clarified the strong dependence of heating value on ash content in the top and bottom parts of each seam and the existence of a strong correlation with sodium content over the sub-seams in the same location. The correlations between the geometry and quality of the seams were generally weak. A linear coregionalization model was used to derive the spatial correlation coefficients of two variables at each scale component from the single- and cross-semivariogram matrices. Because the data were correlated spatially in the same seam or over different seams, multivariate techniques (ordinary cokriging and factorial cokriging) were mainly used and the resultant spatial estimates were compared to those derived using a univariate technique (ordinary kriging). A factorial cokriging was effective to decompose the spatial correlation structures with different scales. Another important characteristic was that the sodium content shows distinct segregation: the low zones are concentrated near the boundary of the sedimentary basin, while the high zones are concentrated in the central part. The main component of sodium originates from the abundance of saline water. Therefore, it can be inferred that seawater had stronger effects on the coal depositional process in the central basin than in the border part. The geostatistical modeling results suggest that the thicknesses of all the major seams were controlled by the syncline structure, while the coal qualities chiefly were originated from the coal depositional and diagenetic processes.     

东南极拉斯曼丘陵地区变质杂岩的层序与构造变形过程

东南极拉斯曼丘陵地区位于兰伯特裂谷东缘普里兹湾东岸,该地区主要出露一套麻粒岩相变质岩,前期对原岩时代、变质过程等进行了详细研究,但是对于变质杂岩的层序和变形过程研究相对薄弱。文章通过大比例尺地质填图,发现拉斯曼丘陵地区变质杂岩总体成层有序,在此基础上建立拉斯曼岩群,并将其划分成6个岩组,原岩形成时代为中元古代。拉斯曼岩群经历了格林维尔期和泛非期变质作用的叠加,变质程度均达到高角闪岩相-麻粒岩相。拉斯曼丘陵地区主体构造线方向为北东东—南西西方向,总体上构成往北东东方向翘起的复式向斜构造,几个岩组的分布也显示由东向西逐渐变新。东部米洛半岛一带明显叠加了北北西—南南东向的构造变形。研究表明,拉斯曼岩群经历了6次重要的构造变形,包括新元古代格林维尔期(D1)、新元古代—早古生代泛非期变质变形作用(D2,D3,D4,D5)以及中新生代伸展作用(D6)。目前岩石中保存的主变形面理是格林维尔期和泛非期两次构造热事件的复合型面理,主要是泛非事件形成,格林维尔期变形面理呈残留状。综合拉斯曼岩群变质年龄及早古生代进步花岗岩体形成时代,认为D2~D5变形时代为550~500 Ma左右。因此,拉斯曼丘陵地区变质变形特征显示,中元古代拉斯曼岩群经历了格林维尔期和泛非期两次重要的造山作用,以及冈瓦纳大陆的裂解。      

滇黔北探区煤层气储层特征及多层合采有利区优选

滇黔北探区赋煤向斜众多,多薄煤层发育,含气量较高,煤层气资源丰富,是筠连外围重要的拓展区块。基于大量煤田孔及煤层气试验井,分析煤层气地质条件,建立多层合采有利区优选评价方法:多层次模糊数学+关键指标法。首先,基于层次递阶优选构建评价模型并确定关键指标,明确关键指标为合采系数、煤体结构、含气量,其中,合采系数由最优合采跨度及合采累计煤厚构成,并给出关键指标的定量评价表,然后,运用模糊数学计算公式,得到储层评分结果,最终获得多层合采有利区优选结果。结果显示:研究区晚二叠世龙潭组/宣威组煤层最多可达到20层以上,可采煤层一般3层左右,煤层总厚度一般在6 m以上,煤层层数及煤层厚度由东南向西北逐渐减少或减薄。大部分区域主力煤层为C5(M11)煤层,厚度一般在2 m以上,其灰分质量分数平均为27.73%,为中灰煤,煤级主要为贫煤–无烟煤。各向斜主力煤层含气性差异性较大,含气量最大可达到30.53 m3/t。研究区煤体结构以原生结构煤和碎裂结构煤为主。以C5(M11)煤层分别向上或向下合采计算合采系数,由此形成了两个合采层段,多层合采Ⅰ类有利区主要位于研究区可乐向斜中西部,牛场–以古向斜南部,镇雄向斜南部,庙坝向斜东南部,洛旺向斜中西部,石坎向斜中西部。      

沁水盆地寺家庄区块煤储层含气性及产能控制因素

为研究沁水盆地东北部煤层气成藏特征与产出控制因素,基于寺家庄区块煤层气勘探和生产资料,从地质构造、煤厚与煤层结构、埋深和水文地质特征等方面研究了煤层含气性影响因素,并结合压裂排采工艺和煤体结构等因素探讨了煤层气井产能控制因素。结果表明:(1) 研究区煤储层含气性受构造影响较大,在褶皱的轴部及旁侧构造挤压带,多呈现出高含气量,尤其是向斜轴部。在陷落柱和水文地质条件叠加作用下,15号煤层含气量整体较8、9号煤层低,且8、9号煤层含气饱和度也整体高于15号煤层。(2) 8、9和15号煤层含气性均表现出随煤层埋深增加而增大的趋势,但随埋深增加,构造应力和地温场的作用逐渐增强,存在含气量随埋深变化的“临界深度”(700 m左右)。煤层含气性也表现出随煤层厚度增加而增大的趋势,煤层结构越简单,煤层含气性越好。(3) 研究区中部的NNE?NE向褶皱与EW向构造叠加地区,因较大的构造曲率和相对松弛的区域地应力,具备较好渗透率条件和含气性,故成为煤层气高产区。(4) 发育多煤层地区采用分压合采技术可以有效增加产气量,多煤层可以提供煤层气井高产能的充足气源,且多个层位的同时排水降压可使不同煤储层气体产出达到产能叠加,实现长期稳产,含气性较好及游离气可能存在的区域可出现长期持续高产井。      

Contrasting sulphide contents of the Bushveld and Sudbury Igneous Complexes

The Sudbury Igneous Complex (SIC) contains abundant sulphides, especially near the base, and hosts one of the worlds largest nickel and copper deposits. The Bushveld Complex (BC) contains relatively little sulphide, but hosts the worlds largest platinum-group element deposits. The most recent calculations of the sulphur solubility in magmas that produced the BC are based on the sulphur solubility of mid-ocean ridge basalts that have less SiO₂ than Bushveld magmas. Such a difference may lead to an overestimation of sulphur solubility by as much as 25%. The revised sulphur solubility curve presented here for Bushveld magmas may also have relevance to the SIC in view of its siliceous nature. Sulphur solubility curves can be used to determine the proportion of sulphide expected in cumulate rocks once sulphur saturation is attained. These models are tested using observed sulphide contents in both intrusions. The observed decreasing sulphur contents (>0.3–0.05% S) from the base of the SIC upward are broadly consistent with these sulphur solubility curves, and are consistent with sulphide saturation through the entire mafic portion. In contrast, the lower half of the BC contains extremely little sulphur (generally <0.02% S), except for two thin layers, which is not consistent with sustained sulphide saturation at any level. Previous interpretations of the sulphur content of Bushveld rocks have suggested that the Lower and Critical Zones were sulphide saturated, but that they had then lost some of the sulphide due to various processes. The present sulphide content of the cumulates of the BC is so low that, if they had once been saturated, over 90% of all the sulphide must have been removed. Mass balance calculations indicate that these large amounts of displaced sulphur remain unaccounted for in such models. Instead, the observed sulphur contents are in reasonable agreement with that expected in a cumulate sequence forming from a sulphur-undersaturated magma. Whereas the Merensky Reef and Bastard pyroxenite contain minor sulphides, the compositions of the immediate hanging wall rocks indicate sulphide undersaturation. Such an abrupt return to sulphide undersaturation is not consistent with models involving sulphide formation from large volumes of magma. One possible explanation for these two observations is that intermittent sulphur degassing occurred through a fractured roof of the BC, so that the magma was never continuously sulphur-saturated with respect to an immiscible sulphide liquid.     

Interpolation study on ambient gamma levels in parts of Khasi Hills,Meghalaya (India): Preliminary findings for U exploration

This paper discusses an experimental approach to examine uranium exploration avenue over the geologically extended parts of Mahadek basin in Meghalaya, amid some of the environmental constraints. Study comprises periodic measurements of prevailing ambient gamma levels across 320 georeference points, in relation to the major litho units of Mahadek basin, covering 673 line km of Khasi Hills. Acquired sample data points were then analysed in geostatistical software (Surfer^TM) to develop analytical model of sample variogram having bearing on the uranium exploration in the area. Study findings have given encouraging surface indicators with mostly elevated gamma levels over the parts of West Khasi Hills. Delineated gamma anomalous zones are lithologically well correlated including to that of existing uranium occurrences in the basin. Identified anomalous zones over the parts of West Khasi Hills by this study work, are mainly associated with the Mahadek sandstone (Upper and Lower Mahadek) and Precambrian basement granites. Lower Mahadek sandstone is host rock for uranium mineralisation in the basin. Initial findings suggest with the closer spatial resolution (～1 km) of sample data points, the approach adopted by the study work holds promising application in locating potential uranium exploration targets especially to the extended and inaccessible parts of the basin.