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1.
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.  相似文献   

2.
淮南张集矿区煤中微量元素的含量分布特征分析   总被引:2,自引:0,他引:2       下载免费PDF全文
在采用ICP-AES对张集7个煤层144个样品微量元素含量测试分析的基础上,探讨了元素在不同煤层中的变化规律及其在煤层对比中的应用。结果表明:张集矿区煤中元素B、Se和As含量偏高;不同煤层中微量元素含量变化较大,但具有一定的规律性,其中在9煤层中元素Ba和Cr含量最低,Mn、Zn、As和Se含量相对较高,可以利用这些元素分布特征来区别和划分相邻煤层。  相似文献   

3.
为研究沁水盆地东北部煤层气成藏特征与产出控制因素,基于寺家庄区块煤层气勘探和生产资料,从地质构造、煤厚与煤层结构、埋深和水文地质特征等方面研究了煤层含气性影响因素,并结合压裂排采工艺和煤体结构等因素探讨了煤层气井产能控制因素。结果表明:(1) 研究区煤储层含气性受构造影响较大,在褶皱的轴部及旁侧构造挤压带,多呈现出高含气量,尤其是向斜轴部。在陷落柱和水文地质条件叠加作用下,15号煤层含气量整体较8、9号煤层低,且8、9号煤层含气饱和度也整体高于15号煤层。(2) 8、9和15号煤层含气性均表现出随煤层埋深增加而增大的趋势,但随埋深增加,构造应力和地温场的作用逐渐增强,存在含气量随埋深变化的“临界深度”(700 m左右)。煤层含气性也表现出随煤层厚度增加而增大的趋势,煤层结构越简单,煤层含气性越好。(3) 研究区中部的NNE?NE向褶皱与EW向构造叠加地区,因较大的构造曲率和相对松弛的区域地应力,具备较好渗透率条件和含气性,故成为煤层气高产区。(4) 发育多煤层地区采用分压合采技术可以有效增加产气量,多煤层可以提供煤层气井高产能的充足气源,且多个层位的同时排水降压可使不同煤储层气体产出达到产能叠加,实现长期稳产,含气性较好及游离气可能存在的区域可出现长期持续高产井。   相似文献   

4.
The No. 1 and No. 2 coal seams from the Permian Vryheid Formation in the east Witbank Coalfield, South Africa are described with respect to their distribution, thickness and quality. These two coal seams accumulated in a postglacial climatic environment and peat accumulation was closely associated with and influenced by deposition in a braided river system. The fluvial channels that were syndepositional with peat accumulation have resulted in thinning of coal below and above channel axes and pinch-out of coal adjacent to channel margins. Low-ash coal originated from peat which accumulated in areas away from the influence of clastic sedimentation. In contrast, higher-ash coals are situated adjacent and parallel to channel margins where interbedded channel sand and silt contaminated the peat.The lower No. 1 seam peat originated under near-optimum conditions in a lacustrine swamp which blanketed an underlying platform of glaciofluvial braided river sediment. This peat swamp was not subjected to syndepositional clastic contamination and as a result is of superior quality (lower ash/higher calorific value and volatile matter) than the overlying No. 2 coal seam. The No. 2 seam is split by a clastic parting produced by a braided fluvial channel which transected the swamp midway through peat accumulation. This fluvial clastic parting deleteriously affected coal thickness and quality.A comparison of the Gondwanan Permian peat-forming conditions with those from Carboniferous northern hemisphere counterparts suggests that the differences in coal characteristics between these two regions are probably related to different palaeoclimatic conditions and basin tectonics. Cool-temperate climatic conditions which prevailed over the Permian peat swamps resulted in less species diversification of vegetation at these high-latitude settings than the diverse floral assemblages of the Carboniferous swamps. A stable intracronic basin platform caused lateral dispersion of sedimentary facies rather than the stacking of vertical facies which occurred in rapidly subsiding depositories. Partial exposure of the Permian peat swamps during peat accumulation may account for the relatively higher inertinite content of the coals.  相似文献   

5.
We present new original data on the geochemistry of scandium in the coals of Asian Russia, Mongolia, and Kazakhstan. In general, the studied coals are enriched in Sc as compared with the average coals worldwide. Coal deposits with abnormally high, up to commercial, Sc contents were detected in different parts of the study area. The factors for the accumulation of Sc in coals have been identified. The Sc contents of the coals depend on the petrologic composition of coal basins (composition of rocks in their framing) and the facies conditions of coal accumulation. We have established the redistribution and partial removal of Sc from a coal seam during coal metamorphism. The distribution of Sc in deposits and coal seams indicates the predominantly hydrogenic mechanism of its anomalous concentration in coals and peats. The accumulation of Sc in the coals and peats is attributed to its leaching out of the coal-bearing rocks and redeposition in a coal (peat) layer with groundwater and underground water enriched in organic acids. The enrichment of coals with Sc requires conditions for the formation of Sc-enriched coal-bearing rocks and conditions for its leaching and transport to the coal seam. Such conditions can be found in the present-day peatland systems of West Siberia and, probably, in ancient basins of peat (coal) accumulation.  相似文献   

6.
根据地质勘探资料和煤心煤样的分析结果,对贵州金沙安洛区北段煤中硫的时空分布以及煤中硫与沉积环境的关系进行了研究。结果表明,该区形成于以潮坪为主的过渡相环境,由于沉积过程中受海水影响,煤中硫的质量分数总体偏高;但由于海水对煤层作用的强度不一,使不同煤层或同一煤层不同部位硫的质量分数差异很大,而且煤中硫的质量分数变化与煤层顶底板的古地理环境有关。   相似文献   

7.
古交邢家社勘探区煤中镓的分布及其地质影响因素   总被引:1,自引:0,他引:1  
依据煤炭资源勘探资料,探讨了山西古交矿区邢家社勘探区石炭-二叠系煤中镓的分布状况及其地质影响因素。结果显示:研究区煤中镓的加权平均质量分数为15.87×10-6,比全球平均值要高0.5~3倍;煤层层位降低,镓含量呈明显的递减趋势。同时,煤中镓含量与灰分产率、灰分组成、硫含量及煤层厚度之间也有明显的相关关系。这些特征表明,区内煤中镓的矿物载体主要为粘土矿物,水动力较强和还原性较弱的泥炭沼泽条件可能有利于镓在煤中富集,且成煤期地壳的稳定程度也可通过一定方式影响到煤中镓的富集。   相似文献   

8.
The Gunnedah Basin, NSW, Australia, contains more than 500 Gt of coal, and has been the subject of recent coalbed methane exploration. Large areas of the basin contain igneous intrusions and large areas of coal have been heat-affected as a consequence. A detailed study has been undertaken of coal seams intersected in a cored coalbed methane exploration drillhole in which two sill-form igneous intrusions are present. Comparisons are made between coals that are unaltered and coals that have been heat-affected, using petrographic and chemical data, coal seam gas desorption data, and gas chemical analysis data.Results demonstrate that the two igneous intrusions have had a very positive effect on coalbed methane development. The gas content in a number of heat-affected coal seams within thermal aureoles above and below the sills is substantially higher than in adjacent unaffected coal seams. In addition, the intrusions have had little effect on gas quality. The coals in the heat-affected zone were found to contain gas with approximately 95% methane. The coals in the thermal aureoles were found, under the microscope, to contain characteristic micropores and slits, which collectively may serve to enhance gas adsorption capacity, permeability, and gas desorption. Gas contents below each of the sills is substantially higher than above the sill, confirming earlier results that the sills appear to have acted as a reservoir seal, during and for some time after intrusion. The background coal rank in ACM Yannergee DDH 1 is in the high-volatile bituminous range. The igneous intrusions have resulted in an increase in rank such that large areas of coal have moved into the optimal thermogenic gas generation window. This rank increase has affected a major part of the coal-bearing sequence.  相似文献   

9.
云南省宣威市是我国肺癌最严重的地区,该区肺癌发病率和死亡率均居世界首位。对宣威肺癌患者的基因组学研究发现,宣威肺癌具有与众不同的基因特征,是一种与环境相关的独特发病模式。通过综述宣威肺癌的流行特征以及燃煤排放物的污染水平和毒理学特征,并结合二叠纪末期C1煤层的地球化学特征探讨宣威肺癌的地质起因。宣威肺癌主要流行特征表现在,肺癌死亡率男女比接近1.22,女性肺癌死亡率明显偏高。前人研究表明,室内燃煤排放颗粒物的长期、高浓度暴露,是宣威肺癌的主要诱因。综述毒理学研究结果可知,宣威室内燃煤排放颗粒物中的重金属、多环芳烃和微晶石英矿物浓度均高于其他地区,且被证实可能会引起更严重的DNA损伤和细胞破坏。通过对比宣威肺癌死亡率的空间分布和不同煤矿的煤层分布发现,可采煤层包含C1煤的来宾和龙场地区同时也是宣威肺癌的高发地区,推断C1煤的燃烧可能与宣威肺癌高发有关。C1煤作为晚二叠世最后一层煤,成煤期间受二叠纪-三叠纪生物大灭绝事件影响,形成了独特的地球化学特征。高含量的重金属、多环芳烃和微晶石英矿物等潜在致癌物不仅存在于C1煤中,也随着室内燃煤被释放到空气中,并通过呼吸系统进入人体体内,破坏细胞及D...  相似文献   

10.
五凤井田龙潭组含煤层数多,厚度变化较大,根据井田钻孔地质资料,采用标志层法、古生物法,结合物性特征及煤质特征等对井田主要可采煤层进行对比。该井田6号煤位于龙潭组顶部,上距龙潭组顶部灰岩标志层6m,±常分叉为6上、6中、6下三层,6中煤层平均厚度〉2m,为全区最厚,且唯一可采煤层,对比可靠;26号煤位于龙潭组中段底部,结构简单,无夹石,其直接顶板为高伽马异常,与上下相邻煤层区别明显;33号煤位于龙潭组下段,是井田内唯一一层大可部分可采的高硫煤,易于对比。  相似文献   

11.
采用沉积学、煤地质学、古生物学、地层学及地球化学等多技术手段,结合比较分析法的思路,分析了事件型海侵的特点和海侵事件沉积组合特征,研究发现:海侵事件沉积组合为区域对比性强、具沉积时间连续性与相序间断性的暴露沉积-煤层-灰岩组合,其关键沉积学特征是煤层底板的暴露沉积.海侵事件组合灰岩的古生化石个体小、破碎强烈等特征表现为高能量水体运动等环境,孢粉表现为低含量的单缝孢和裸子植物及高含量的三缝孢.地球化学分析表明暴露沉积为陆相环境,煤层中的微量元素表现为海相主要原因是由于泥炭沼泽覆于深水后受海水影响所致.海侵事件成煤与海侵过程成煤差异体现在两个方面:第一,盆地属性差异,即海侵事件成煤形成于陆表海盆地之中,而海侵过程成煤则形成于具有缓坡的边缘海盆地,第二,成煤原理存在着差异,海侵事件成煤强调的是成煤前海侵未发生前的碎屑体系废弃而发育大量泥炭沼泽且被后期突发性海侵终止,而海侵过程成煤则强调的是泥炭沼泽发育于滨海的活动碎屑体系并终止于后期的缓慢海平面上升.  相似文献   

12.
The quantitative maceral study of the Queen seam from Mailaram coalfield of Godavari valley has displayed alternate coal bands rich in vitrinite/liptinite or inertinite. The random vitrinite reflectance (Ro max. %) of these coals, from top part ranges from 0.50 to 0.64%. However, the bottom part of the seam has indicated lower reflectance, between 0.49 and 0.52%. Thus, the Queen seam, in general, has attained high volatile bituminous C rank. The study indicates that the depositional site has been a slowly sinking basin that witnessed alternate dry (oxidizing) and wet (reducing) spells. This subsequently caused fluctuation in water table of the basin and the formation of oxic and anaoxic moor condition, where accumulated vegetal resource transformed into mixed and fusic coal types in due course of time. Being high in liptinite and vitrinite contents and low mineral matter, the Queen seam of Mailaram coalfield has high economic potential.  相似文献   

13.
Trace-element data are presented for the first time for any coal seam in India, across a full working section, based on systematically collected channel samples of coal, together with their maceral composition. The trace-element variation curves along the seam profile are presented together with group maceral compositions of Kargali Bottom, Kargali Top, Kargali, Kathara, Uchitdih, Jarangdih Bottom, Jarangdih, and Jarangdih Top seams, East Bokaro coalfield. The Kathara and Uchitdih seams have also been sampled at two other localities and lateral variation in data in their trace-element and maceral compositions is also evaluated.The East Bokaro coals have: Ba and Sr > 1000 ppm; Mn < 450 ppm; Zr < 400 ppm; Ni and V < 250 ppm; Cr < 185 ppm; La < 165 ppm; Cu, Nb, and B < 125 ppm; Pb, Co and Y < 75 ppm; Ga, Sn, Mo, In and Yb < 15 ppm; Ag 2 ppm; and Ge 7 ppm. Petrographically, the coals are dominant in vitrinite (33–97%), rare in exinite (<15%), and semifusinite (0.8–49%) is the dominant inertinite maceral, with variable mineral and shaly matter (11–30%), graphic representation of trace elements versus vitrinite, inertinite, and coal ash indicates the affinity of (a) vitrinite with Cu, Ni, Co, V, Ga and B; (b) inertinite with Nb and B; and (c) coal ash (mineral matter) with Pb, Cu, Ni, La, Mn and Y; Ba, Cr, Sr, Zr, Cu and Ni are of organic as well as inorganic origins.The trend of the variation patterns and average compositions of the different seams are shown to be distinct and different. The variation along the same profile is inferred to be different for different seams of the coalfield.Trace-element data for certain coals of seams from different coalfields in the Gondwana basins of India are presented. There is a wide difference for each of these basins with respect to certain elements. This is suggestive of the proportions of Cu, Ni, V, Y, Ba, Sr, Cr, B, Zr and Ag, characterizing the different Gondwana Basins.  相似文献   

14.
淮北煤田二叠纪煤中稀土元素地球化学研究   总被引:9,自引:0,他引:9  
从淮北煤田二叠系10,7,5,4和3煤层中采集34个样品,采用等离子体质谱(ICP-MS)、中子活化(INNA)、等离子体发射光谱(ICP-AES)等方法对样品中主量元素和稀土元素进行了测试,利用X射线衍射等方法对煤中矿物质及其煤质参数进行了测定。在各种测试的基础上,全面分析了稀土元素含量特征、空间分布规律、地球化学参数和分布模式,探讨了淮北煤田二叠纪煤中稀土元素的主要来源及其在煤中的主要赋存方式。研究表明:与华北和国内外其他地区相比,本区煤层中稀土元素相对富集;产于石盒子组煤中的稀土元素含量高于山两组的,在同一煤层中自下而下稀土元素含量有增高趋势,在顶底板中可能出现富集。Ce呈正异常,Eu明显负异常,不同煤层稀土元素的分布模式相似,稀土元素和灰分具有较好的正相关,∑REE与灰分、灰分中的主要元素以及典型陆源灰分中的微量元素正相关,与反映海相的低灰组分相关性较差。结合煤中矿物质的X射线衍射结果,分析获知,淮北煤田二叠纪成煤环境基本不受海水影响,稀土元素主要由陆源供给,而且主要赋存在以高岭石、伊利石为主的粘土矿物中。  相似文献   

15.
The coals of the upper part of the Mansfield, Brazil, and the lower part of the Staunton Formations (Atokan and Desmoinesian, Pennsylvanian) in Indiana (Illinois Basin) are characteristically thin and discontinuous. As a result, problems with correlation and identification of the seams have persisted for both researchers and industry. These discrepancies affect coal exploration, mine planning, and subsequently coal-fired utilities. This study presents exploration and operational examples demonstrating some of the correlation problems associated with the coals of the Brazil Formation, and the Upper Block and Lower Block, in particular, and the surrounding upper part of the Mansfield Formation and lower part of the Staunton Formations. Based on exploration boreholes, mine scale observations, and coal quality and petrographic data, this study suggests that (1) the coal mapped as the Upper Block Coal Member of Clay County may, in fact, be the same seam as the Lower Block Coal Member of Daviess County; and (2) the Lower Block coal of Clay County is not present south of the Switz City area of central Greene County, IN.  相似文献   

16.
The Carboniferous succession in the Donets Basin hosts about 130 seams, each with a thickness over 0.45 m. Nine economically important seams from the (south)western Donets Basin are studied using organic petrographical, inorganic geochemical, and organic geochemical techniques. The main aim of the study is the reconstruction of peat facies of Serpukhovian (Mississippian) and Moscovian (Middle Pennsylvanian) coals.Formation of major coal seams commenced during Serpukhovian times. Early Serpukhovian coal accumulated in a relatively narrow shore-zone and is rich in inertinite and liptinite. Very low ash yields, low to moderate sulphur contents, and upward increasing inertinite contents suggest coal deposition in raised mires.Moscovian coal has a significantly wider lateral extension and is generally rich in vitrinite. Coal properties vary widely in response to different peat facies. Low-sulphur, low-ash k7 coal was formed in a raised mire or in a low-lying mire without detrital input. l1 and l3 seams containing several fluvial partings were formed in low-lying mires. Both seams are more than 2 m thick. Seams m2 and m3 contain high-sulphur coal, a consequence of deposition in a peat with marine influence. In contrast, syngenetic sulphur content is low in the m51 upper seam, which was formed in a lacustrine setting. The late Moscovian n1 seam, up to 2.4 m thick, accumulated in a swamp with a vegetation rich in bryophytes and pteridophytes. The properties of the n1 seam are transitional between those of Serpukhovian and other Moscovian seams. Differences in maceral composition between Serpukhovian and Moscovian coals probably reflect changes in climate and vegetation type.Tuff layers are observed in the l1, l3, and m3 seams. The l3 and m3 seams contain abundant authigenic quartz. Trace element contents are high in many seams. As contents are especially high in seams c102, k7, l3 and m3. Ash in the l3 seam contains up to 8000 ppm As. Co is enriched near the base of several seams. Maxima up to 2400 ppm occur in the ash of the k7 and l3 seams. Cd contents in ash are frequently as high as 30 or 40 ppm.  相似文献   

17.
宁武煤田朔南矿区5号、6号煤层位于太原组上段,5号煤厚0~3.20m,6号煤厚0~2.94m,均属局部可采煤层,在实际工作中往往难以区分对比。通过对矿区含煤地层及煤层顶板砂岩K2、K3、K4沉积环境的研究,认为5号煤层形成于三角洲水下分流河道之间的泛滥盆地,6号煤层形成于三角洲前缘河口砂坝基础上发育的潮坪环境,属于三角洲平原水下沉积体系的两个不同旋回。运用岩性标志,物性参数及煤质特征可有效区分5、6号煤层,并进行追踪对比,为进一步勘探和煤矿开采提供了资料。  相似文献   

18.
Coal seams preserve high-resolution records of ancient terrestrial water table (base level) fluctuations in ancient peat accumulations, but little is known about base level change in anomalously thick coal seams. Using the Early Cretaceous 91 m anomalously thick No. 6 coal (lignite) seam in the Erlian Basin (north-east China) as a case study, the origin and evolution of peat accumulation in a continental faulted basin is revealed by sedimentological, sequence stratigraphic and coal petrological analyses. The lignite is dominated by huminite, indicating oxygen-deficient and waterlogged conditions in the precursor mire. Four types of key sequence stratigraphic surfaces are recognized, including paludification, terrestrialization, accommodation-reversal and give-up transgressive surfaces. Vertically, the No. 6 coal seam consists of fourteen superimposed wetting-up and drying-up cycles separated by key sequence stratigraphic surfaces, with each of these cycles having a mean duration of about 156 to 173 kyr. In a high accommodation peat swamp system, the wetting-up cycles are generally characterized by an upward increase in mineral matter and inertodetrinite and an upward decrease in huminite with the paludification surface as their base and the give-up transgressive surface or accommodation-reversal surface as their top, representing a trend of upward-increasing accommodation. In contrast, the drying-up cycles are generally characterized by an upward decrease in mineral matter and inertodetrinite and an upward increase in huminite, with the terrestrialization surface as their base and the accommodation-reversal surface as their top, representing a trend of upward-decreasing accommodation. A multi-phase mire stacking model for accumulation of the coal seam is proposed based on high-frequency accommodation cycles and the stratigraphic relationships between coal and clastic sediments. High-frequency accommodation cycles in the coal are closely related to water table fluctuations in the precursor mires and are driven by high-frequency climate via changes in the intensity and seasonality of precipitation in a relatively stable subsidence regime. Recognition that the No. 6 coal seam is composed of multiple stacked mires has implications for studies addressing palaeoclimatic inferences and genesis of anomalously thick coals seams.  相似文献   

19.
Twenty-nine low sulfur coal samples were selected to determine the magnitude and variability of mercury (Hg) content in a well-documented stratigraphy system including ten continuous coal seams in Zhuji Coal Mine, Huainan Coalfield, Anhui Province, North China. Mercury content of samples was measured on a direct mercury analyzer and confident results were obtained as evaluated by standard references, sample replicates and procedural blanks. The calculated overall mine average Hg content is 71.19?±?9.28 ng/g based on seam averages and weighting by the estimated reserve of each coal seam. The estimated Hg emission potential for Huainan coalfield is obviously lower than that calculated from coal emission factor in industrial use. An increasing trend of Hg content with the evolution of depositional environment was observed from Nos. 3 to 11-2 coal seams. Combining the evidence of sedimentology and paleontology, a better understanding was gained of the mechanism of Hg sequestration in specific coal benches. A large portion of Hg residing in the low sulfur coals presumably integrated to the functional groups of organic constitution, whereas pyrite was generally abundant in the high sulfur coals.  相似文献   

20.
陆相成煤环境及断陷构造特点,致使二连盆地内煤层具有层数多、间距小、厚度横向变化大、标志层少等特点,利用钻探资料进行煤层对比难度大,其结果将直接影响对煤层、煤质评价及煤炭资源量估算。考虑到研究区煤层赋存特点,利用三维地震成果,对该区进行了煤层辅助对比,其结果与原有7个钻孔煤层对比成果存在差异。通过三维地震层位对比与构造解释方案的核查,结合波阻抗反演结果和测井资料重新解释,认为三维地震的煤层对比是合理的。该实例表明,综合利用测井资料、三维地震解释和波阻抗反演等,可有效提高煤层对比的可靠性,提高煤炭资源地质勘探阶段的控制精度。  相似文献   

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