Organic maturity of Late Cretaceous and Tertiary coal measures,Canadian Arctic Archipelago

Maastrichtian and Lower Tertiary strata of the Eureka Sound Formation are widespread in the Canadian Arctic Archipelago and include major resources of lignite, subbituminous and high-volatile bituminous coal. The level of organic maturity of the strata for the most part reflects pre-orogenic (pre-Late Eocene-Miocene) depths of burial and thus helps define Early Tertiary depositional patterns. In the Remus Basin, in the eastern Canadian Archipelago, over 90 seams of coal occur ranging in rank from lignite (0.15% R_{0 max}) to high-volatile bituminous (0.70% R_{0 max}). The maturity values at the base of the Eureka Sound Formation, in conjunction with measured maturation gradients, indicate a maximum paleothickness of 4500 m and outline a basin with well defined eastern, western and southern margins. On the bases of numerical modeling, the maturation gradients are interpreted to reflect paleogeothermal gradients up to 55°C/km in the eastern part of the basin and of about 20°C/km in the western part.Elsewhere in the Canadian Arctic Archipelago the level of organic maturity of the Eureka Sound Formation varies from 0.15% R_{0 max} to 0.70% R_{0 max}. Maturation gradients measured from Meighen Island in the Strand Fiord Basin and from Melville Island in the southern part of the West Sverdrup Basin are about 0.10 log R_{0 max/km}, and when compared to numerical models suggest paleogeothermal gradients on the order of 15°C/km. At Meighen Island the paleodepth of burial of the Eureka Sound Formation may have been up to 6000 m. As a first approximation, the Melville Island gradient is considered representative of West Sverdrup and Banks Basin. Using this gradients, a paleodepth of burial of 3000 m is calculated for central West Sverdrup Basin and 4000 m for the southern part. In Banks Basin the paleodepth of burial is estimated to be on the order of 4000 m. Maturity values obtained from the Lake Hazen and Judge Dally Basins, Eclipse Trough and Somerset, Devon and Cornwallis Islands and at Bache Peninsula on eastern Ellesmere Island cannot be readily interpreted in terms of paleodepth of burial. No measured sections are thick or complete enough to establish maturation gradients, and the Tertiary history of these areas is only poorly known.The low paleogeothernal gradients calculated from Meighen Island, Melville Island and from the western part of the Remus Basin (15–20°C/km) are considered to reflect low heat flow or rapid Tertiary sedimentation and uplift such that an equilibrium geothermal gradient may never have existed. The higher maturation gradients and interpreted paleogeothermal gradients in the eastern Remus Basin are considered to be the product of higher heat flow on eastern Ellesmere Island.Anomalously high levels of maturity obtained along the Stolz Fault and adjacent Strand Fiord on Axel Heiberg Island are attributed to the thermal effects of evaporite diapirs.     

Middle Eocene ostracoda from the Tadkeshwar lignite mine, Cambay Basin, Gujarat

Previous work on the fauna and flora of the Cambay shale underlying as well as inter-bedded within the lignite seams of Vastan lignite mine, Gujarat allows the shale to be assigned a Lower Eocene age. However, there is no record of occurrence of any fossil from the sedimentary beds succeeding the shale-lignite sequence that might fix upper age limit of the Cambay shale. We record a characteristic Middle Eocene ostracod assemblage from the Nummulitic marl/limestone, immediately overlying the shale-lignite sequence from the Tadkeshwar lignite mine close to the Vastan lignite mine. The assemblage comprises 22 species, many of which widely occur in the Middle Eocene beds of Kachchh, Rajasthan and adjacent areas of Pakistan.     

<Emphasis Type="Italic">Holigarna</Emphasis> (Anacardiaceae) from the early Eocene of Western India and its palaeogeographical and palaeoclimatological significance

Thick lignite deposits on the western margin of India were preserved on account of thick vegetation which got buried underneath due to tectonic activities that occurred in northwestern part of India during the early Palaeogene. Study of the fossil flora preserved in these beds is important to deduce the palaeoclimate of the region. Therefore, a field work was undertaken to collect plant fossils from the Tarkeshwar lignite mine, Surat district, Gujarat (western India) which is still unexplored as far as the plant mega-remains are concerned. A fossil wood is systematically described from the Cambay Shale Formation of the mine considered to be of early Eocene in age. It shows close affinities with Holigarna (Anacardiaceae), particularly with H. beddomei and H. grahamii. This genus is evergreen in nature and grows in the Indo-Malayan region, while both the modern analogues of the fossil are endemic to semi-evergreen to evergreen forests ofWestern Ghats, south India, located at the equator. This not only confirms the palaeolatitudinal position of the Indian subcontinent at the equator during the early Palaeogene, but also indicates the presence of equatorial rain forest in the Indian subcontinent during the period. Based on the timetree, Sapindales started to diverge in the early Palaeocene (62–57 Ma) as its oldest fossil is from the K-Pg boundary. Discovery of the present anacardiaceous fossil (belonging to Sapindales) from the early Eocene strengthens the above phylogenetic view.     

Changes in hydrocarbon maturity indices with coal rank and type,Buller Coalfield,New Zealand

The Buller Coalfield (South Island, New Zealand) is an inverted late Paleogene Basin that contains middle Eocene bituminous coals which exhibit considerable variation in both coal rank (across-basin), and coal type (in-seam). Twenty-two fractionated bitumen extracts of Brunner Coal Measures coal samples from 12 drillholes were analyzed by GC and GC–MS to characterize the effect of coal rank and type on conventional hydrocarbon maturity indices at the beginning and end of the oil window (0.56–1.26% Ro_max).The Carbon Preference Index, pristane/phytane and isoprenoid/n-alkane ratios evolve throughout the high volatile bituminous B rank stage, while other biomarker ratios [18α(H)-22,29,30-trisnorneohopane/17α(H)-22,29,30-trisnorhopane (Ts/Tm), 18α(H),21β(H)-30-norneohopane (C₂₉ Ts)/17α(H),21β(H)-30-norhopane and C₃₀ diahopane/hopane] do not show appreciable change in value until medium volatile bituminous rank. Various aromatic based ratios appear to be more effective in delineating rank throughout the entire oil window; in particular the Methylphenanthrene Index and vitrinite reflectance are positively correlated over the entire bituminous rank range. However, subtle changes in depositional conditions (variable coal type) complicate these rank estimates. Within a given coal seam, variation in CPI, isoprenoid/n-alkane and hopane/sterane ratios appear to be related to the hydrogen content of the coal, while the homohopane index and the oleanane/hopane ratio covary with sulfur content. As with depressed vitrinite reflectance values, MPI is similarly lowered in the perhydrous samples. The mechanisms that control these hydrocarbon parameters during deposition and diagenesis are complex and convoluted, however, changes in bacterial activity and community (with marine incursion) appear to play an important role. Due to these anomalies, none of the hydrocarbon maturity indices calculated can be singularly used to constrain coal rank.     

A fossil coconut fruit from the early Eocene of Gujarat

A fossil fruit resembling extant Cocos nucifera of the family Arecaceae is reported for the first time from the early Eocene sediments of Gujarat. The fossil was collected from the Tarkeshwar lignite mine of the Surat District which belongs to the Cambay Shale Formation. Its occurrence indicates coastal conditions in the region during the depositional period in contrast to arid to semi-arid climate prevailing there at present. The present fossil, along with the previously published palyno-assemblages from the mine supports the equatorial position of the Indian subcontinent at the time of deposition i.e. during the early Eocene.     

The occurrence of anthracites in an area characterized by lower rank coals in the Upper Silesian Coal Basin of Poland

The results of petrographical-geological and chemical examinations on anthracites, semianthracites and medium-low volatile bituminous coals from Jastrzebie in the Upper Silesian Coal Basin of Poland are presented. The coking coals mined in this region exhibit volatile matter V^daf = 18–26%, free swelling index FSI = 3–8 and reflectance R_m = 1.10–1.35% and are inertiniterich coals (I = 25–63%).Coal Seam 504 of the Anticlinal beds (Namurian B) has been affected by thermal metamorphism and contains both coking coals and coals of higher rank. According to the criterion of Polish Standards this coal seam varies from anthracite (V^daf <10%) to semianthracite (V^daf = 10–14%) in rank. The carbon content is slightly lower and the hydrogen content a little higher than those of typical anthracites and semianthracites. The reflectance values (R_m = 1.56–2.62%) are generally lower than the R_m values proposed by the International Committee for Coal Petrology as boundary values for anthracites and bituminous coal. The magnitude of anisotropy and microhardness were also examined. Examinations of optical properties prove that the metamorphism exhibited by the coals is the result of elevated temperature and variable pressure. The analyses of the maceral composition indicate that there is a decrease in the inertinite content in anthracites. Vitrinite exhibits the features of thermally altered coal. The micrinite content shows a little variation. In coking coals, a strongly fluorescing bituminous substance with the optical features of exsudatinite was found. The constructed geological section of Coal Seam 504 shows distinct regular changes in chemical and physical properties as well as the petrographic composition which may be caused by the heat flux of a magma intrusion, not localized so far.     

Characterization of organic matter and depositional environment of Tertiary mudstones from the Sylhet Basin,Bangladesh

The Sylhet Basin of Bangladesh is a sub-basin of the Bengal Basin. It contains a very thick (up to 22 km) Tertiary stratigraphic succession consisting mainly of sandstones and mudstones. The Sylhet succession is divided into the Jaintia (Paleocene–late Eocene), Barail (late Eocene–early Miocene), Surma (middle–late Miocene), Tipam (late Miocene–Pliocene) and Dupitila Groups (Pliocene–Pleistocene), in ascending order. The origin of the organic matter (OM) and paleoenvironment of deposition have been evaluated on the basis of C, N, S elemental analysis, Rock-Eval pyrolysis and gas chromatography–mass spectrometry (GC–MS) analysis of 60 mudstone samples collected from drill core and surface outcrops. Total organic carbon (TOC) content ranges from 0.11% to 1.56%. Sulfur content is low in most samples. TOC content in the Sylhet succession varies systematically with sedimentation rate, with low TOC caused by clastic dilution produced by high sedimentation rates arising from rapid uplift and erosion of the Himalaya.The OM in the succession is characterized by systematic variations in pristane/phytane (Pr/Ph), oleanane/C₃₀ hopane, n-C₂₉/n-C₁₉ alkane, Tm/Ts [17α(H)-22,29,30-trisnorhopane/18α(H)-22,29,30-trisnorhopane] and sterane C₂₉/(C₂₇ + C₂₈ + C₂₉) ratios during the middle Eocene to Pleistocene. Based on biomarker proxies, the depositional environment of the Sylhet succession can be divided into three phases. In the first (middle Eocene to early Miocene), deposition occurred completely in seawater-dominated oxic conditions, with abundant input of terrestrial higher plants, including angiosperms. The second phase (middle to late Miocene) consisted of mainly freshwater anoxic conditions along with a small seawater influence according to eustasic sea level change, with diluted OM derived from phytoplankton and a lesser influence from terrestrial higher plants. Oxygen-poor freshwater conditions prevailed in the third phase (post-late Miocene). Planktonic OM was relatively abundant in this stage, while a high angiosperm influx prevailed at times. T_max values of ca. 450 °C, vitrinite reflectance (R_o) of ca. 0.66% and methylphenanthrene index (MPI 3) of ca. 1 indicate the OM to be mature. The lower part (middle Eocene to early Miocene) of the succession with moderate TOC content and predominantly terrestrial OM could have generated some condensates and oils in and around the study area.     

Petrologic studies of terrestrial organic matter in Carpathian flysch sediments, southern Poland

In the Carpathian Flysch, coal is present either as exotics of Carboniferous coal deposits or as autochthonous, thin layers of lustrous coal. This paper present the results of the studies of coal-bearing rocks that are coeval with the enclosing flysch sediments. These coals form lenses up to 0.15 m thick. Their morphology precludes an exotic origin. The main petrographic component is collinite with admixtures of poorly fluorescing telinite. Minor components are: exudatinite, sporinite, fusinite, micrinite and sclerotinite. Mineral matter consists of framboidal pyrite clay minerals and quartz.The random reflectance of telocollinite varies from 0.38% to 0.72%, which corresponds to subbituminous and bituminous ranks. Correlation between chemical analysis, coking properties and relfectance measurements, leads to the conclusion that boundary between subbituminous and bituminous coals should be defined by the following values: C=80wt%, VOLATILES=43wt%; calorific VALUE=32.3 MJ/kg; and R^o=0.56–0.57%.Atypical properties, such as: upper C value (75–80wt%); high volatile matter contents (over 43wt%) and low random reflectance (^o about 0.38–0.57%) in subbituminous coals; low C value (about 80–82wt%); low reflectance (0.56–0.72%); and good coking properties, of the bituminous coals are attributed to quick coalification during increasing temperature as a result of tectonic stress.     

Nature and composition of interbedded marine basaltic pumice in the ∼52–50 Ma Vastan lignite sequence,western India: Implication for Early Eocene MORB volcanism offshore Arabian Sea

The recognition of pyroclasts preserved in sedimentary environments far from its source is uncommon. We here describe occurrences of several centimetres-thick discontinuous basaltic pumice lenses occurring within the Early Eocene Vastan lignite mine sedimentary sequence, western India at two different levels – one at ～5 m and the other at 10 m above a biostratigraphically constrained 52 Ma old marker level postdating the Deccan Volcanism. These sections have received global attention as they record mammalian and plant radiations. We infer the repetitive occurrence of pumice have been sourced from a ～52–50 Ma MORB related to sea-floor spreading in the western Arabian Sea, most plausibly along the Carlsberg Ridge. Pyroclasts have skeletal plagioclase with horsetail morphologies ± pyroxene ± Fe–Ti oxide euhedral crystals, and typically comprise of circular polymodal (radii ≤10 to ≥30 μm), non-coalescing microvesicles (>40–60%). The pumice have undergone considerable syngenetic alteration during oceanic transport and post-burial digenesis, and are a composite mixture of Fe–Mn-rich clay and hydrated altered basaltic glass (palagonite). The Fe–Mn-rich clay is extremely low in SiO ₂, Al ₂ O ₃, TiO ₂, MgO, alkalies and REE, but very high in Fe ₂ O ₃, MnO, P, Ba, Sr contents, and palagonitization involved significant loss of SiO ₂, Al ₂ O ₃, MgO and variable gain in Fe ₂ O ₃, TiO ₂, Ni, V, Zr, Zn and REE. Bubble initiation to growth in the ascending basaltic magma (liquidus ～1200–1250 ^°C) may have occured in ～3 hr. Short-distance transport, non-connected vesicles, deposition in inner shelf to more confined lagoonal condition in the Early Eocene and quick burial helped preservation of the pumice in Vastan. Early Eocene Arabian Sea volcanism thus might have been an additional source to marginal sediments along the passive margin of western India.     

Organo-petrographic and geochemical characteristics of Gurha lignite deposits,Rajasthan,India:Insights into the palaeovegetation,palaeoenvironment and hydrocarbon source rock potential

The sedimentary sequence containing lignite deposits in Gurha quarry of the Bikaner-Nagaur Basin(Rajasthan)has been investigated.The samples from lignite and allied shale horizons were evaluated for petrographical,palynological,palynofacies and organic geochemical inferences,to depict the source flora and to reconstruct the palaeodepositional conditions prevailed during the sedimentation.An assessment for the hydrocarbon generation potential of these deposits has also been made.The results revealed the dominance of huminite macerals and phytoclasts organic matter(OM) indicating the existence of forested vegetation in the vicinity of the depositional site.A relatively high terrigenous/aquatic ratio(TAR) and the carbon preference index(CPI) are also suggesting the contribution of higher plants in the peat formation.However,the n-alkane distributions,maximizing at n-C17 and n-C29,showed inputs from the algal communities along with the higher plant derived organic matters.Recovered palynomorphs of the families Onagraceae,Meliaceae,Arecaceae,Rhizophoraceae,Rubiaceae,Ctenolophonaceae, etc.together with oleanene and ursane types of triterpenoids suggest the contribution from angiosperms source vegetation.Interestingly,the presence of Araucareaceae and Podocarpaceae pollen grains shows the existence of gymnosperms vegetation.Further,the presence of tetracyclic diterpanes;demethylated entbeyerane,sandaracopimarane,pimarane,and Kaurane type of compounds confirms the contribution of conifers.The variation in the values of the coefficient of non-equality(H:0.68%-7.56%),the standard deviation(8:0.04%-0.16%) and the coefficient of variability(V:16.10%-46.47%),also shows the heterogeneity in the source organic matter.The various petrographical indices,palynological entities,and geochemical parameters indicate that the peatforming vegetation was accumulated under a mixed environment and fluctuating hydrological settings.The interpretation of palynofacies data on APP(Amorphous organic matter-Phytoclast-Palynomorphs) diagram suggests that the accumulation of organic matter occurred in a dysoxic-suboxic condition in a proximal(to land)setting with the shift to an anoxic condition in distal setting towards the termination of sedimentation.The huminite(ulminite) reflectance(R_r) values(av.0.28%) showed a good relationship with average T_(max) value(414℃),suggesting the immaturity.The TOC content ranges of 13-59 wt.%,and HI values vary between 101 and 546 mg HC/g TOC in the studied samples.Collectively,the studied lignite and shale samples have the admixed kerogens(Type Ⅲ-Ⅱ) and exhibit the ability to generate the gaseous to oil hydrocarbons upon maturation.     

Coal rank variation in the Intrasudetic Basin,SW Poland

The Upper Carboniferous, coal-bearing sequence of the Intrasudetic Basin (SW Poland) includes coals ranging from high-volatile bituminous to anthracitic rank. The lowest values of reflectance are recorded around the basin margins (0.6% R₀ max), the highest ones appear in the center of the basin (exceeding 4% R₀ max). Reflectance gradients are very high, reaching 0.6%/100 m in the centre of the basin.A comparison of the isoreflectance maps for three lithostratigraphical units—the Walbrzych, Bialy Kamien and Zacler Formations, with the present-day burial depth and the depth of burial during the Westphalian B/C—indicates that there is a strong relationship between reflectance and the sediment cover during the Westphalian B/C, particularly in the vicinity of Walbrzych and Lubawka. This suggests that the increase in coal rank is related to the increase in cover which permitted the temperature to build-up to high values.In the eastern and central parts of the basin and the Nowa Ruda area, higher reflectance than that derived from burial depth is observed which is believed to result from higher heat flow from the basement. The volcanic rocks of the Intrasudetic Basin appear to have little effect on coal rank and are not considered to be a significant contributor to the heat flow of the region.During coalification, the oldest Westphalian coal seams were buried to about 700 m and the youngest seams of the Walbrzych Formation to 900 m. Around the basin margins the coals had reached their present-day rank by the Westphalian B/C and in the central part probably by the end of the Stephanian. Most effective coalification took place during the Westphalian A,B occupying a period of less than 20 million years. The coalification temperature is calculated to be 160–170°C with a geothermal gradient of 8–10°C/100 m. These geothermal conditions support the suggestion of a volcanic origin for the Intrasudetic Basin.     

Petrology and geochemistry of the Juzzak Sill,western Chagai arc (Pakistan): implications for petrogenesis and emplacement

The Juzzak Sill occurs in the western part of the east-west trending, subduction-related magmatic belt known as the Chagai arc. The sill is concordantly emplaced in the Paleocene Juzzak Formation and locally cross-cuts the Early to Middle Eocene Robat Limestone and Eocene Saindak Formation. The sill is a porphyritic pyroxene diorite that grades into a porphyritic andesite (60.12–61.57 wt% SiO₂) along the chilled margins. It comprises phenocrysts of hypersthene and plagioclase (An_32–45) in a medium- to fine-grained groundmass of these minerals, opaque oxide, and apatite. The rocks are high-K (2.37–2.86 wt% K₂O) calc-alkaline with low Mg# (42–55), Cr (51–80 ppm), and Ni (22–30 ppm) contents. Mantle-normalized trace element patterns, exhibited by marked negative Nb anomalies and positive spikes for Sr, Rb, and Zr and are akin to island arc signatures. The relatively higher ratios of Zr/Y (3.57–6.58), Ti/V (46.05–54.36), Ta/Yb (0.14–0.15), and Th/Yb (2.56–2.65) and high ⁸⁷Sr/⁸⁶Sr ratio (0.70524) suggest the role of continental crust materials, thus implying continental margin-type arc affinity. The source diagnostic ratios including K/Ba, P/Zr, and La/Ce of Juzzak Sill andesite and Eocene andesite from the Chagai arc are more or less similar, but the former has a much higher K/Y and Ba/Y ratios, which suggests assimilations of the host sediments during intrusion.     

Climate‐modulated sequence development in a tropical rift basin during the Late Palaeocene to Early Eocene super greenhouse Earth

Sequence developments in rift basins are considered to be influenced largely by tectonics and to a lesser extent by eustatic sea‐level and climate. Studies indicate that in passive margin basins, climate can mask the effects of tectonics and eustasy by modulating the sediment supply. It is, however, less understood how the sedimentary sequence in rift basins might respond to strong climatic fluctuations where tectonic pulses generate rapid accommodation space. Here a case study has been provided to assess the effect of climate vis à vis sea‐level and tectonics on sequence development in the Cambay rift basin, western India, during the Early Palaeogene (Late Palaeocene to Early Eocene) super greenhouse globe. Facies analysis of this shale–lignite sequence suggests deposition in a lagoon/bay, developed over the Deccan Trap basement. Detailed sequence stratigraphic analysis using basin‐wide representative composite sections, marker lignite seam, event bed and high‐resolution carbon isotope (δ¹³C) chemostratigraphy suggest an overall transgressive motif. Among the three prominent Early Eocene eustatic highstands, only the one at ca 53·7 Ma is expressed by the thickest coal accumulation throughout the basin. Expression of the other sequence stratigraphic surfaces is subdued and can be due to the overall finer grain size of the sediment or local variation in the subsidence rate at different fault‐controlled mini‐basins. Enigmatic presence of a maximum flooding surface coinciding with the 53·7 Ma climate event (Eocene Thermal Maximum 2), manifested by negative carbon isotope excursion, indicates possible influence of climate over and above tectonics in developing the rift sequence. Qualitative rainfall variation assessed using the magnitude of the carbon isotope excursion and pollen abundance show that a relatively dry/low precipitation climatic phase during the Eocene Thermal Maximum 2 hindered the siliclastic supply to the basin. Thus, it has been inferred that climate‐induced high siliciclastic supply possibly enhanced the autocyclic reorganization and hindered the development of the key sequence stratigraphic surfaces across the basin during climate extremes.     

Paleostress reconstructions of Jabal Hafit structures,Southeast of Al Ain City,United Arab Emirates (UAE)

This paper presents the first paleostress results obtained from displacement and fracture systems within the Lower Eocene sediments at Jabal Hafit, Abu Dhabi Emirate, UAE. Detailed investigation of Paleogene structures at Jabal Hafit reveal the existence of both extensional structures (normal faults) and compressional structures (strike-slip and reverse faults). Structural analysis and paleostress reconstructions show that the Paleogene kinematic history is characterized by the succession of four paleostress stages. Orientation of principal stresses was found from fault-slip data using an improved right-dihedra method, followed by rotational optimisation (TENSOR program).The paleostress results confirm four transtensional tectonic stages (T1–T4) which affected the study area. The first tectonic stage (T1) is characterized by S_Hmax NW–SE σ₂-orientation. This stage produced NW–SE striking joints (tension veins) and E–W to ENE–WSW striking dextral strike-slip faults. The proposed age of this stage is Early Eocene. The second stage (T2) had S_Hmax N–S σ₂-orientation. N–S striking joints and NNE–SSW striking sinistral strike-slip faults, E–W striking reverse faults and N–S striking normal faults were created during this stage. The T2 stage is interpreted to be post-Early Eocene in age. The third stage (T3) is characterized by S_Hmax E–W σ₂-orientation. This stage reactivated the E–W reverse faults as sinistral strike-slip faults and created E–W striking joints and NE–SW reverse faults. The proposed age for T3 is post-Middle Eocene. During the T3 (S_Hmax E–W σ₂-orientation) stage the NNW-plunging Hafit anticline was formed. The last tectonic stage that affected the study area (T4) is characterized by S_Hmax NE–SW σ₂-orientation. During this stage, the ENE–WSW faults were reactivated as sinistral strike-slip and reverse faults. NE–SW oriented joints were also created during the T4 (S_Hmax NE–SW σ₂-orientation) stage. The interpreted age of this stage is post-Middle Miocene time but younger than T3 (S_Hmax E–W σ₂-orientation) stage.     

Coal deposits of the United States

The coal fields of the Unites States can be divided into six major provinces. The Appalachian and Interior Provinces contain dominantly bituminous coal in strata of Pennsylvanian age. The coal seams are relatively thin and are mined both by surface and underground methods. Sulfyur content is low to moderate in the Appalachian Province, generally high in the Interior province. The Gulf Coastal Plain Province, in Texas and neighboring states, contains lignite of Eocene age. The seams are 3–25 ft (0.9–7.5 m) thick and are minded in large open pits. The Northern Great Plains Province has lignite and subbituminous coal of Cretaceous, Paleocene and Eocene age. The coal, largely very low in sulfur, occurs in beds up to 100 ft (30 m) thick and is strip-mined. The Rocky Mountain Province contains a great variety of coal deposits in numerous separate intermontane basins. Most of it is low-sulfur subbituminous to bituminous coal iof Creatceous and early Tertiary age. The seams range from a few feet to over 100 ft (30 m) thick. Strip-mining dominates but underground mines are important in Utah and Colorado. The Pacific Coast Province, which includes Alaska, contains enormous cola resources but has seen little mining. The coal is highly diverse in physical character and geologic setting.     

Coalification levels and their significance in the groundhog coalfield,North-Central British Columbia

The only significant deposits of anthracite and meta-anthracite in Canada occur in Upper Jurassic-Lower Cretaceous strata of the Groundhog coalfield in northcentral British Columbia. The coal rank in the coalfield varies from low volatile bituminous (1.70% R_{0 max}) to meta-anthracite (5.8% R_{0 max}). The main coal bearing unit, the Currier, includes up to 17 seams of anthracite and meta-anthracite most of which are less than 1 m thick. In the McEvoy unit, which overlies the Currier, up to 9 coal seams, mainly of semi-anthracite, occur that are up to 0.8 m thick. The coals are variably argillaceous, locally sheared and cut by quartz and less commonly, by carbonate veins. Coalification gradients in the coalfield vary from 0.8% to 3.0% R_{0 max} km^?1. The rank of coal within both the McEvoy and Currier units appears to increase towards the eastern edge of the coalfield.The level of coalification and the coalification gradients in the coalfield are anomalously high considering an indicated maximum depth of burial of 3500 m. From comparison with coalification models it appears that geothermal gradients in the order of 50° to 70°C/km must have existed for a period of time measured in millions of years. Studies to date suggest the coalification is pre-tectonic and thus pre-Late Cretaceous although there is some evidence for high heat flow in the Tertiary. The origin of the high heat flow may be related to intrusion accompanying collision of the Stikine terrain with the early Mesozoic margin of North America and/or high heat flux over an easterly dipping subduction zone below the Coastal volcanic-plutonic arc to the west.     

Organic geochemistry and depositional environment of the Aptian bituminous limestone in the Kale Gümüşhane area (NE-Turkey): An example of lacustrine deposits on the platform carbonate sequence

The Jurassic–Lower Cretaceous aged carbonate sequence is widely exposed in the southern zone of Eastern Pontides. Aptian black bituminous limestone is found in the upper part of this sequence in the Kale area (Gümüşhane). This limestone contains faunal remains (e.g., gastropod, ostracod, characean stems and miliolid type benthic foraminifera) that indicate a freshwater, lacustrine depositional environment.The total organic carbon (TOC) values of the bituminous limestone samples range from 0.11–1.30% with an average TOC value of 0.54%. The hydrogen index (HI) varies from 119–448 mg HC/g TOC (average HI 298 mg HC/g TOC) indicating that the limestone contains gas prone as well as oil prone organic matter. Pyrolysis data prove that the organic matter content in the bituminous limestone consists of Type II kerogen. The average T_max value for bituminous limestone samples is 438 °C (434–448 °C). Bitumen/TOC ratios for bituminous limestone are 0.05 and 0.04. The T_max values and the ratios indicate that the bituminous limestone samples contain early mature to mature organic matter.Analysis of solvent extracts from the two richest bituminous limestones show a predominance of high carbon number (C₂₆–C₃₀) n-alkanes. The Pr/Ph ratio and CPI value are 1.34 and 0.96, respectively. C₂₉ is the dominant sterane, with C₂₉ > C₂₇ > C₂₈. The bituminous limestone samples have low C₂₂/C₂₁ ratios, high C₂₄/C₂₃ tricyclic terpane ratios and very low C₃₁R/C₃₀ hopane ratios (<0.25). These data are consistent with the bituminous limestones being deposited in a lacustrine environment.     

Geochemical and isotopic approach to maturity/source/mixing estimations for natural gas and associated condensates in the Thrace Basin,NW Turkey

The Tertiary Thrace Basin located in NW Turkey comprises 9 km of clastic-sedimentary column ranging in age from Early Eocene to Recent in age. Fifteen natural gas and 10 associated condensate samples collected from the 11 different gas fields along the NW–SE extending zone of the northern portion of the basin were evaluated on the basis of their chemical and individual C isotopic compositions. For the purpose of the study, the genesis of CH₄, thermogenic C₂₊ gases, and associated condensates were evaluated separately.Methane appears to have 3 origins: Group-1 CH₄ is bacteriogenic (Calculated δ¹³C_C1–C = −61.48‰; Silivri Field) and found in Oligocene reservoirs and mixed with the thermogenic Group-2 CH₄. They probably formed in the Upper Oligocene coal and shales deposited in a marshy-swamp environment of fluvio-deltaic settings. Group-2 (δ¹³C_C1–C = −35.80‰; Hamitabat Field) and Group-3 (δ¹³C_1–C = −49.10‰; Değirmenköy Field) methanes are thermogenic and share the same origin with the Group-2 and Group-3 C₂₊ gases. The Group-2 C₂₊ gases include 63% of the gas fields. They are produced from both Eocene (overwhelmingly) and Oligocene reservoirs. These gases were almost certainly generated from isotopically heavy terrestrial kerogen (δ¹³C = −21‰) present in the Eocene deltaic Hamitabat shales. The Group-3 C₂₊ gases, produced from one field, were generated from isotopically light marine kerogen (δ¹³C = −29‰). Lower Oligoce ne Mezardere shales deposited in pro-deltaic settings are believed to be the source of these gases.The bulk and individual n-alkane isotopic relationships between the rock extracts, gases, condensates and oils from the basin differentiated two Groups of condensates, which can be genetically linked to the Group-2 and -3 thermogenic C₂₊ gases. However, it is crucial to note that condensates do not necessarily correlate to their associated gases.Maturity assessments on the Group-1 and -2 thermogenic gases based on their estimated initial kerogen isotope values (δ¹³C = −21‰; −29‰) and on the biomarkers present in the associated condensates reveal that all the hydrocarbons including gases, condensates and oils are the products of primary cracking at the early mature st age (R_eq = 0.55–0.81%). It is demonstrated that the open-system source conditions required for such an early-mature hydrocarbon expulsion exist and are supported by fault systems of the basin.     

Petrological and geochemical considerations to predict oil potential of Rajpardi and Vastan lignite deposits of Gujarat, western India

This paper entails the results of the investigations undertaken to assess the oil potential of two lignite deposits, Rajpardi and Vastan, from Gujarat, western India. They are ‘Low rank B’ type lignite. Petrographically, they are enriched in huminite and are low in liptinite and inertinite. Their elevated hydrogen content, in relation to carbon, has probably made them perhydrous in nature and oil prone. The reactivity of these coals during liquefaction has also been discussed in the light of petrofactor. Good correlation has been noticed between oil yield and conversion (r² = 0.999) in both the lignite deposits. The VRr (0.24–0.35% in both lignites), H/C atomic ratio (0.11–1.39 in Rajpardi and 1.09–1.88 in Vastan), reactive maceral content (91.6–99.8 vol % mmf in Rajpardi lignite and 75.5–99.7 vol % in Vastan lignite) and VM_daf (64.8–67.9 wt % in Rajpardi lignite and 42.1–80.0 wt % in Vastan lignite) of these lignites have a favourable range required for a coal to generate oil. Huminite is seen to play a vital role in conversion and maintains a good correlation with it. The calculations show that these lignites have a high conversion (> 95%) and oil yield (> 65%).