Spectrum characteristics of major ion concentrations at Wuhan sectoin of the Changjiang Rriver

Spectrum analyses of water quality time series have been carried out for five hydrometric stations including Wuhan hydrometric station of the Changjiang(Yangtze) River, etc. The fluctuations of Ca²⁺, Mg²⁺ and HCO ₃ ⁻ concentrations in river water under different physical geography conditions have about two-year cycle which is corresponding to hydrometeorological quasi-biannual-oscillation (QBO). Na⁺, Cl⁻ SO ₄ ²⁻ have about two-year cycle in the area lightly affected by human activities while two-year cycle doesn’t exist in the area heavily affected by human activities. All the fluctuations of major ions have about three-month cycle. The river diseharge fluctuation accounts for 43.9%, 45.1%, 54.3%, 33.9%, 30.3% and 42.7% of the variance of Ca²⁺, Mg²⁺, HCO ₃ ⁻ , Na⁺, Cl⁻, SO ₄ ²⁻ , respectively, at Wuhan from 1962 to 1985. According to the spectrum characteristic of major ions, the duration of the time series has to be at least 13 years for trend analysis of monthly water quality data. Foundation item: Under the auspices of the National Natural Science Foundation of China (No. 49671017). Biography: XIA Xing-hui(1971-), female, a native of Hunan Province, Ph. D. Her research interest includes environmental chemistry.     

Soluble species in aerosols collected on the route of the Second Chinese National Arctic Research Expedition

Aerosol samples are collected on the route of the Second Chinese NationalArctic Research Expedition from July 15 to September 28,2003.The concentration ofwater soluble ions(Na~+,NH_4~+,Ca~(2+),Cl~-,MSA,SO_4~(2-)and so on)are ana-lyzed.By correlation analysis,the ions can be divided into three groups:(1)Na~+,Mg~(2+),K~+,Ca~(2+),Cl~-,SO_4~(2-),mainly from sea salt;(2)NH_4~+,NO_3~-,markedlyfrom coastal regions of the continents;(3)Acetate,MSA,C_2O_4~(2-),from othersources.Marine aerosols are the dominant origin,Cl~- and Na~+ are the most domi-nant anion and cation,respectively and these two ions(Na~++Cl~-)account for 55.6% of the total aerosol loading.The mean equivalence ratio of NH_4~+/SO_4~(2-)is 0.45,we suggest that ammonium and sulfate exist mainly as NH_4HSO_4.The concentrationof NO_3~- shows three different patterns on the route of expedition:Japan Sea with me-dian value of 15.2 neq·m~(-3);Sea of Okhostk and Bering Sea of 1.8 neq·m~(-3)andArctic Ocean of 0.4 neq·m~(-3).Bering Sea is a high MSA area.Through the com-parison of the concentration of main water soluble ions between the First and SecondChinese National Arctic Research Expedition,the variation matches each other.     

正交试验法在大骨节病区饮水水质研究中的应用

本文运用正交试验法对陕西永寿等大骨节病区饮水水质及其与病情间的关系进行了研究和试验,取得了如下初步认识:1)饮用缺乏Mg~(2+)、C1~-、SO_4~(2-)、HCO_3~-、Se、Sr等组分的低矿化度水,是导致大骨节病发生的重要原因。2)水中的Na~++K~+、Mg~(2+)、Ca~(2+);C1~-、SO_4~(2-)、HCO_3~-;可溶性SiO_2、有机耗氧量、矿化度;Sr、Se、Zn等含量(或阴、阳离子毫克当量百分数)的任何一组最优组合,均可用来作为优质水的划分标准。在此基础上,确定出了非致病水的水质标准。文章还对所确定出的非致病水水质标准进行了实际验证。     

The concentration variation features of sea salt ions and non sea salt ions in a firn core recovered from Princess Elizabeth Land, East Antarctica

1　Introduction Thestudyonthefeaturesofatmosphericenvironmentbyglaciochemistryisthemajor contentofsnow iceandglobalchangeresearch.Antarcticicesheetisfarfromtheregions pollutedbyhumanactivities,andsurroundedbyocean,andtheAntarcticCircumpolarCur rentisthewideseawaterandatmospherebarrierbetweenAntarcticaandtheoutsideworld. AlloftheuniquegeographicalfeaturesmaketheimpuritiesinsnowandiceinAntarcticice sheetissimple.Therefore,itissignificanttostudytheorigins,transmissionpathsanddep ositionalst…     

泰安市城区岩溶地下水水化学特征及成因分析

岩溶地下水是泰安市城区重要供水水源,近年来随着气候环境变化和人为活动的影响,岩溶地下水水化学特征日趋复杂,但其水化学特征及成因尚不明晰。为识别研究区地下水水化学特征、成因机制,本文采用数理统计方法、离子比值、水化学图解等方法,研究了该区岩溶地下水的水文地球化学特征。结果表明：研究区内岩溶地下水水化学类型主要为HCO3Ca型、HCO3·SO4Ca 型、HCO3·SO4·ClCa型。地下水水化学成分主要受水岩相互作用控制,以溶滤作用为主,地下水中的Ca2+、Na+、HCO-3、SO2-4主要来源于方解石、白云石的碳酸盐岩及石膏、盐岩等蒸发岩的溶解,且存在逆向的阳离子交替吸附作用,导致Ca2+含量增加,Na+含量减少,人为活动影响导致地下水中Cl-、NO-3浓度增加。研究成果为研究区内岩溶地下水的合理开发与保护提供了依据。     

济南泉水水化学动态特征分析

济南是山东省省会城市,以泉水而闻名,济南泉域位于济南市中部,为掌握济南泉水水质变化情况,根据多年监测的泉水水质资料,采用年度及年内对比方法,分析研究了泉水主要离子多年动态特征及年内变化,研究结果表明,从1984—2013年近30年间,济南泉水主要水质指标呈恶化趋势,主要驱动因素是CO2,SO2-4,Cl-离子含量的增长,其与当地燃煤量持续增长联系密切;而年内主要离子含量动态变化,属短期波动,与泉区排泄点周边的环境影响有关。     

山东省黄河下游地区浅层地下水地球化学特征与环境质量评价

浅层地下水调查是山东省黄河下游流域生态地球化学调查项目中的一项工作内容。调查是按每16 km2采集1件浅层地下水样品的密度,分析测试As,Ba,Be,Ca,Cd,Co,Cu,Fe,Hg,Pb,Se,Zn,F-,Cl-,Cr6 ,NO2-,COD,pH等33项指标;通过对这些指标在浅层地下水中的背景变化规律研究认为:调查区内浅层地下水中各指标含量起伏变化大,局部富集程度高,特别是As,Fe,K,La,Sb,Sn,Zn,Cl-,NO2-等指标的变异系数均>3.0,说明这些指标在浅层地下水中分布极不均匀,虽然背景含量较低,但在局部地段会形成高含量区,影响浅层地下水质量。选择As,Ba,Be,Cd,Co,Cu,Fe,Hg,Mn,Mo,Ni,Pb,Se,Zn,F-,Cl-,Cr6 ,NO2-,COD,pH等20项指标,按《地下水环境质量标准》中的要求,对浅层地下水环境质量进行的单项组分和综合评价结果显示,达到较好级以上者不足9%,而较差和极差级者达90%以上,表明调查区内浅层地下水环境污染状况较为严重。     

陕西谭家沟热水沉积型金矿床地质特征与成因分析

谭家沟金矿产于中泥盆统热水沉积岩中。矿体位于铁白云石硅质岩构造角砾带 ,是以浸染状矿化为主 ,由热水沉积铁白云石硅质岩提供矿质并基本在层内富集成矿的热水沉积改造型金矿床。铅同位素特征表明成矿金属来源于地壳 ;硫同位素组成特征表明硫主要来自海水硫酸盐的还原硫 ;氢氧同位素测试数据表明 ,成矿流体主要为原生建造水。成矿流体为SO4 2 F/Na Ca2 型 ,成矿物理化学条件为弱中等还原环境 ,成矿温度 15 0～ 170℃ ,盐度w(NaCl)为 6 .86 %。     

INVESTIGATION ON FUNDAMENTAL CHARACTERISTICS OF HYDROCHEMISTRY IN HEAD AREA OF THE CANGJIANG RIVER

The results of water sample analyses and investigation in the head area of the Changjiang River reveal that the characteristics of hydrochemistry of the river vary with drainage basins. In the drainage basin of the Tuotuo River, the mineral concentration of water is generally high, ions of Cl and Na are obviously dominant. The water tends to be salty, and the type of hydrochemistry is rather complex. In the drainage basin of the Dam River, the mineral concentration is mainly in a low and middle level, ions of HCO3- and Ca2 are higher than others, and the type of hydrochemistry is relatively simple. The ground water in deep layers plays an important role in recharging surface water, and the stable recharging results in little change in chemical composition of surface water.     

EFFECTS OF COMPOSITION AND STRUCTURE OF ALGINATES ON ADSORPTION OF DIVALENT METALS

Results of a series of experiments(on the adsorption of divalent metal ions by dried alginic acid, Na and Ca alginates of different composition and block structure) conducted in this systematic study of the effects of the composition and structure of alginates on the static adsorption equilibrium of divalent metal ions indicate that the properties of alginate adsorption to divalent metal ions are highly different, depending not only on the cations used, but also on the form and structure of the alginates. There is close correlation between the adsorption properties and the structure of the alginates. The selectivity coefficient of Na alginate for Cd-Sr ion exchange tends to increase with the increase of the M/G ratio in alginate, whereas the adsorption capacity of Ca alginate for Cu~(2+) ion decrease with the increase of the G-block or the average length of the G-block ((?)_G) and the total adsorption capacity of alginic acid is found to vary in the same order as the F_(MM)(diad frequency) in alginate in     

Study on changes of plasmalemma permeability and some primary inorganic ions of Antarctic ice microalgae （Chlamydomonas sp. ICE-L） in the low-temperature stress

The changes of plasmalemma permeability and some primary inorganic ions of Antarctic ice microalgae （ Chlamydomonas sp. ICE-L） in the low-temperature stress were examined. The plasmalemma of 1CE-L could maintain the stability at the freezing condition of -6 ℃. That signifies that it could maintain the proper function of plasmalemma and stability of the intracellular environment during sea ice formation. The function of inorganic ions on low-temperature adaptation of ICE-L was investigated by using the X-ray microanalysis method. Low temperature （0 - -6 ℃ ） induces Ca^2 ＋ concentration increment of cytoplasm, but after 24 h the content decrease quickly to normal value. As a matter of fact, Ca^2 ＋ plays an important role as the second messenger in the low temperature adaptation of ICE-L. In addition, low temperature also influences on the other primary inorganic ions transfer and the cell maintains activity by keeping ratio balance among different ions. Above all, it is necessary for Antarctic ice microalgae to survive and breed by maintaining the stability of K^ ＋ content and the balance of Na^ ＋/Cl^ -.     

Isotopic and chemical analyses of a temperate firn core from a Chinese alpine glacier and its regional climatic significance

Mt. Yulong is the southernmost currently glacier-covered area in Eurasia, including China. There are 19 sub-tropical temperate glaciers on the mountain, controlled by the south-western monsoon climate. In the summer of 1999, a firn core, 10. 10 m long, extending down to glacier ice, was recovered in the accumulation area of the largest glacier, Baishui No. 1. Periodic variations of climatic signals above 7. 8 m depth were apparent, and net accumulation of four years was identified by the annual oscillations of isotopic and ionic composition. The boundaries of annual accumulation were confirmed by higher values of electrical conductivity and pH, and by dirty refreezing ice layers at the levels of summer surfaces. Calculated mean annual net accumulation from 1994/1995 to 1997/1998 was about 900 mm water equivalent. The amplitude of isotopic variations in the profile decreased with increasing depth, and isotopic homogenization occurred below 7. 8 m as a result of meltwater percolation. Variations of δ18O above 7. 8 m showed an approximate correlation with the winter climatic trend at Li Jiang Station, 25 km away. Concentrations of Ca2+ and Mg2+ were much higher than those of Na+ and K+ , indicating that the air masses for precipitation were mainly from a continental source, and that the core material accumulated during the winter period. The close correspondence of C1- and Na+ indicated their common origin. Very low concentrations of SO2-4 and NO3- suggest that pollution caused by human activities is quite low in the area. The mean annual net accumulation in the core and the estimated ablation indicate that the average annual precipitation above the glacier's equilibrium line is 2400 - 3150 mm, but this needs to be confirmed by long term observation of mass balance.     

基于水文地球化学特征的黄河流域(济阳段)地热水成因机制研究

黄河流域(济阳段)地热资源丰富,阐明地热田的成因机制对区域地热水资源的开发利用和黄河流域高质量发展具有重要意义。以黄河流域(济阳段)齐广断裂以南灰岩热储为研究对象,进行水化学分析和同位素分析,结果表明研究区地热水水化学类型主要为SO₄·Cl-Ca·Na型、SO₄-Ca·Na型、HCO₃·SO₄-Ca·Mg型、SO₄-Ca型,地热水总体上受大气降水的入渗补给,地热水补给区高程范围为497.81～2117.97m,地热水属于亚现代与近期补给的混合水和现代水。     

A study on element-stratigraphy of Okinawa Trough

Regular distribution patterns of elements Ca, Sr, K, Na, Mg, Fe, Mn, Ti, Cu, Co, Ni, Zn, Pb, Cr, Rb, Ba, Cd, and U in Late Quaternary strata have been studied in detail. The regional variation patterns of elements in these strata are similar to those in recent surface sediments, showing that the sedimentary environment has been relatively stable since Late Quaternary. Element distribution changes with the variations of lithological characters. Contents of Ca and Sr increase in coarse sediments, while those of other elements decrease. Na content increases in the pumice layer. Mn, content tends to increase sharply towards the surface layer. Ca content decreases sharply in strata where water depth is more than 2,000 m. The strata can be divided based on the distribution curves of element assemblages. The variations in contents of most elements in Holocene Series are smaller than those in Late Pleistocene Series, which might be related to the factors of glacial and interglacial changes, sea level fluctuations and material source differences. Contribution No. 1488 from Institute of Oceanology, Academia Sinica     

Characteristics of metals in the aerosols of Zhongshan Station, Antarctica

Instrumental neutron activation analysis (INAA) was applied to analyze the bulk, high-volume aerosol samples, collected at Zhongshan Station in the Eastern Antarctica, during 1998-2001, to study the chemical species. .A graphical technique was applied to the INAA data. Results showed that Na, Cl, Mg, Ca, Sr, Br, I, Sr and Rb were marine elements while Al, Sc, Fe and Mn were crustal elements. Compared to marine and crustal elements, five elements (Se、Co、Sb、Zn、Cr) were highly abundant in the aerosols collected at Zhongshan station, which indicated that they might come from the petroleum burning, heating and equipment operation. The presence of pollutant elements suggested that human activities have affected the local environments in Antarctica.     

Water quality evaluation in Tidal River reaches of Liaohe River Estuary, China using a revised QUAL2K model

Rivers in the Liaohe River Estuary area have been seriously polluted by discharges of wastewater containing petroleum pollutants and nutrients. In this paper, The Enhanced Stream Water Quality Model (QUAL2K) and its revised model as well as One-dimensional Tide Mean Model (1D model) were applied to predict and assess the water quality of the tidal river reach of the Liaohe River Estuary. Dissolved oxygen (DO), biochemical oxygen demand (BOD₅), ammonia nitrogen (NH₃-N) and total phosphorus (TP) were chosen as water quality indices in the two model simulations. The modelled results show that the major reasons for degraded rivers remain petroleum and non-point source pollution. Tidal water also has a critical effect on the variation of water quality. The sensitivity analysis identifies that flow rate, point load and diffuse load are the most sensitive parameters for the four water quality indices in the revised QUAL2K simulation. Uncertainty analysis based on a Monte Carlo simulation gives the probability distribution of the four water quality indices at two locations (6.50 km and 44.84 km from the river mouth). The statistical outcomes indicate that the observed data fall within the 90% confidence intervals at all sites measured, and show that the revised QUAL2K gives better results in simulating the water quality of a tidal river.     

新疆阿克苏典型山前洪积扇内高氟地下水的化学特征及氟富集机制

在内陆干旱区,作为重要饮用水源的地下水常面临氟含量超标问题。查明内陆干旱区高氟地下水的分布规律,了解氟在地下水中的富集过程及其影响因素,既可丰富高氟地下水的研究体系,也是保证内陆干旱区饮水安全的重要基础。以新疆阿克苏地区典型山前洪积扇——依格齐艾肯河-喀拉玉尔滚河河间地带为研究区,基于水文地球化学调查结果,刻画了高氟地下水的分布区;结合氟离子含量与特征性水化学指标间的关系,揭示了高氟地下水的成因机制。结果表明:①地下水中氟含量的变化范围为0.8~6.1 mg/L,83%的水样氟含量超过《生活饮用水卫生标准》（GB 5749-2006）规定的上限（1.0 mg/L）;②总体上,氟含量沿地下水流动路径逐渐增大,低氟地下水（ρ（F-）≤1.0 mg/L）分布在国道314以北的补给区,高氟地下水（ρ（F-）>1.0 mg/L）分布在国道314以南的径流区和排泄区;③高氟地下水的水化学类型以Cl·HCO₃-Na型为主,而低氟地下水则以Cl·SO₄-Na型为主,高氟地下水相比于低氟地下水优势阴离子偏向于HCO₃-;④地下水的pH值范围为7.9~8.9（均值为8.4）,表明其处于弱碱环境中。地下水中ρ（F-）与pH值呈正相关,此外构成浅层含水层的上更新统沉积物中含有黑云母、氟磷灰石等矿物,其表面存在一定数量的可交换F-,这表明水中OH-与矿物表面F-间的阴离子交换可能对氟的富集有一定贡献;⑤地下水的F-含量与Ca2+含量呈负相关,即高氟地下水中ρ（Ca2+）小于低氟地下水。考虑到氟化钙（CaF₂）是自然界中的主要含氟矿物,也是地下水中氟的主要来源,ρ（F-）与ρ（Ca2+）间的这种负相关指示着高氟地下水中可能存在去Ca2+、Mg2+作用,如阳离子交替吸附或碳酸盐岩沉淀等。研究区地下水样中ρ（F-）与ρ（Mg2+）间也呈负相关关系,且和ρ（F-）与ρ（Ca2+）间的关系高度相似,也佐证了高氟地下水中去Ca2+、Mg2+作用的存在;⑥绝大部分地下水样品都位于氯碱性指数图的负值区域,且ρ（F-）与CAI-1和CAI-2均呈较好负相关,CAI-1和CAI-2都随ρ（F-）的增大而减小,这表明高氟地下水中存在Ca2+、Mg2+与Na+间更强的交换作用,对氟富集起着重要作用。地下水中ρ（F-）与SAR间呈较好正相关关系,且高氟地下水样的SAR均值（5.71）远大于低氟地下水SAR均值（1.67）,这也进一步证明高氟地下水中的Ca2+、Mg2+与含水介质的Na+间存在强烈的交替作用,对氟的富集起着重要作用;⑦所有地下水样中的萤石均处于未饱和状态,且萤石的饱和指数（SI）与F-含量间呈现较好的正相关,这表明地下水对含氟矿物（主要是萤石）的持续溶解应是导致研究区地下水中氟富集的主要原因。与之相反,研究区所有地下水样中的方解石均处于过饱和状态（SI>0）。这表明CaCO₃的沉淀可能促进了CaF₂的溶解,导致地下水中氟离子质量浓度增高;⑧研究区低氟地下水的δ18O值介于-11.20‰~-10.67‰间,平均值为-10.94‰,而高氟地下水的δ18O值介于-11.65‰~-11.21‰间,平均值为-11.49‰,即低氟地下水较高氟地下水富集δ18O。此外,F-质量浓度较低（ρ（F-）≤3.0 mg/L）的地下水样中δ18O值与F-质量浓度呈负相关,即低氟地下水具有更正的δ18O值;F-质量浓度较高（ρ（F-）≥4.8 mg/L）的地下水样中δ18O值与F-质量浓度的相关性不显著,随F-质量浓度的增高,δ18O值基本维持不变。以上表明蒸发浓缩作用对地下水中氟的富集贡献较小;⑨研究区地下水中ρ（F-）/ρ（Cl-）比值与ρ（F-）间呈现正相关,即ρ（F-）/ρ（Cl-）比值随ρ（F-）增高呈增大趋势,这也说明地下水中氟富集的主要原因是含氟矿物的溶解,而不是蒸发浓缩作用。此外,Gibbs图也提供了证据:研究区地下水样基本处于水岩作用主导区域,表明地下水化学特征（包括氟的富集）主要受水岩作用控制,蒸发浓缩影响很小。总之,地下水中氟的富集主要由溶解作用引起,OH-与矿物表面F-间的交换也有贡献,但蒸发浓缩作用影响微弱。含氟矿物持续溶解的驱动机制是阳离子交替吸附（地下水中Ca2+与岩土颗粒表面Na+之间）及方解石沉淀所引起的地下水中Ca2+的衰减。      

潍坊市城区地下水水化学特征及质量评价

为详细了解和掌握潍坊市城区地下水化学特征及质量状况,该文在潍坊市城市地质调查的基础上,共采集地下水样品400件,并进行了样品分析测试。基于检测结果,选用单因子评价法和综合评价法对地下水质量进行了综合评价研究。结果表明,研究区北部为海(咸)水入侵区,水质极差,面积827.04 km~2,中部为主城区,受人类工农业活动影响,水质较差,面积911.52 km~2,南部水质较好,面积670.46 km~2,良好区和优良区在区内零星分布,面积52.64 km~2;研究区地下水化学类型自北向南呈带状分布,北部为Cl-Na型水,向南过渡为Cl·HCO_3-Ca·Mg型水,最后变为HCO_3-Ca型水。     

THE HYDROLOGICAL EFFECT UNDER HUMAN ACTIVITIESIN THE INLAND WATERSHEDS OF XINJIANG, CHINA

I INTRODUCTIONNatllral environment and water transform in theworld have changed faster and faster under the effect ofhuman activities. The study on effect of human activities to hydrological processes, and its extent and tendency has been more and more important as one of theresearch projects of hydrology in the world (RAI et al.,1998, BASS et al., 1998, WANGet al.,, 1998; HILLet al., 1998; LIU, 1997). It became one of the mainresearch program of international Hydrological Decade(…     

威海市环翠区地下水环境质量评价

在威海市环翠区地下水调查研究的基础上,选取10项因子,采用单项组分评价和综合评价相结合的方法对区内浅层地下水进行分析评价。结果显示,区内大部分地区水质较好,部分地区由于受人类活动等的影响,导致水质变差,其主要超标因子有硫酸盐、硝酸盐、氯化物、总硬度等。