Input of chemical substances with atmospheric precipitation onto the territory of Karelia

The chemical composition of atmospheric precipitation over the entire territory of Karelia is characterized on the basis of snow samples taken during the periods of maximum snow storage in 1996–2000. The concentration of chemical elements and their fallouts are considered within the northern, central, southern, and eastern regions of Karelia. The aero-technogenic effect of industrial centers of Karelia and the Archangelsk Province on the chemical composition of atmospheric precipitation is analyzed. The above material is generalized in the form of average statistical characteristics of the chemical fallouts of mineral, organic, and biogenic substances, heavy metals, and strong acids.     

The importance of energetic particle precipitation on the chemical composition of the middle atmosphere

An assessment is made of the relative contribution of certain classes of energetic particle precipitation to the chemical composition of the middle atmosphere with emphasis placed on the production of odd nitrogen and odd hydrogen species and their subsequent role in the catalytic removal of ozone. Galactic cosmic radiation is an important source of odd nitrogen in the lower stratosphere but since the peak energy deposition occurs below the region where catalytic removal of O₃ is most effective, it is questionable whether this mechanism is important in the overall terrestrial ozone budget. The precipitation of energetic solar protons can periodically produce dramatic enhancement in upper stratospheric NO. The long residence time of NO in this region of the atmosphere, where catalytic interaction with O₃ is also most effective, mandates that this mechanism be included in future modelling of the global distribution of O₃. Throughout the mesosphere the precipitation of energetic electrons from the outer radiation belt (60°70°) can sporadically act as a major local source of odd hydrogen and odd nitrogen leading to observable O₃ depletion. Future satellite studies should be directed at simultaneously measuring the precipitation flux and the concomitant atmosphere modification, and these results should be employed to develop more sophisticated models of this important coupling.     

The effect of variations in rainfall on the chemical composition of vulcano fumaroles (Italy)

Analytical data for samples collected over a period of 17 months at the crater fumaroles of Vulcano are given. Fluids are both condensed and absorbed in KOH solutions, thus providing a complete analysis of acid and condensable species. Variations in H₂O, CO₂, SO₂, H₂S, HCl, B, F, Br, NH₄ concentrations are taken into account. Rainwater represents an important modifying facor of the basic chemical composition of the investigated discharges, which do not seem to have undergone any other significant change during the above mentioned span of time. While acting essentially as a diluting factor for CO₂ and SO₂, the inflow of meteoric water can introduce substantial modifications in concentrations of other constituents. As a consequence, any correct comparison of fumaroles compositions either for different systems or for different samplings at the same system should take into consideration the influence of meteorological conditions.     

A study on the spatial variations in stable isotopic composition of precipitation in a semiarid region of Southern India

The stable isotope analysis of all major rain events from Moinabad (MB), Rajendranagar (RN) and Osmanasagar (OS) reservoir, three closely placed locations in Hyderabad, India, were carried out during the 2005 to 2008 period. The OS station recorded the highest amount of rainfall with an average value of 1000 mm, whereas the MB station recorded the lowest average rainfall of 790 mm. The stable isotope (δ¹⁸O) values of the precipitation samples during these period varied from ?11.43‰ to ?0.03‰ for the MB station, ?8.21‰ to 0.54‰ for the RN station and ?11.47‰ to 0.72‰ for the OS station. The d‐excess of precipitation at the three stations also showed considerable variations and revealed that the precipitation in the region undergoes significant modification through secondary evaporation during its fall. The possible causes for these observed spatial and temporal variations in amount and the isotopic composition of precipitation in a small geographical area within the city were studied. The observed variations may be attributed to the regional scale differences in water budget induced by rapid urbanisation activities in the city coupled with the differences in secondary effects undergone by the falling drops. This study elucidating changes in precipitation patterns in the city and its possible causes may largely help in its water balance calculation. Copyright © 2011 John Wiley & Sons, Ltd.     

On the lateral variations in chemical composition and volume of quaternary volcanic rocks across Japanese arcs

The Fe/Mg+Fe) ratios (X_Fe) of the Quaternary basalts (SiO₂ < 53 wt.%) in the Japanese arcs were examined. The X_XFe of relatively magnesian basalts decreases from the volcanic front toward the Japan Sea across the arcs. Based on the partition coefficient of Mg-Fe²⁺ between olivine and liquid, it is suggested that all the basalts near the volcanic front, which are mostly tholeiitic basalts, are significantly fractionated, whereas many basalts near the Japan Sea, which are mostly alkali basalts, are little fractionated. The K₂ O content in the primary basalt magmas increases toward the Japan Sea. Combining the X_Fe and K₂ O data, it is suggested that relatively large amounts of tholeiitic magmas are produced near the volcanic front, but they fractionate during their ascent, whereas smaller amounts of alkali basalt magmas are formed near the Japan Sea, but they can ascend with less fractionation. The density of primary tholeiite magma is significantly larger than that of primary alkali basalt magmas. It is most likely that primary tholeiite magmas cannot ascend beyond the upper crust and would fractionate to produce less dense tholeiitic magmas near the volcanic front, whereas primary alkali basalt magmas can ascend through the upper crust without fractionation, as far as buoyancy is the principal ascending force. In the Japanese arcs, the stress field may be less compressional near the Japan Sea than near the volcanic front, so that magmas can ascend more rapidly in the latter region than in the former. These two factors may be responsible for the above mentioned chemical variations of basalt magmas across the arcs. The variation in volume of the Quaternary volcanic rocks across the arcs can be explained by the presence of a melt-rich zone above but nearly parallel to the subducted slab.     

D/H ratios in speleothem fluid inclusions: A guide to variations in the isotopic composition of meteoric precipitation?

D/H ratios of fluid inclusion waters extracted from²³⁰Th/²³⁴U-dated speleothems that were originally deposited under conditions of isotopic equilibrium should provide a direct estimate of the hydrogen isotopic composition of ancient meteoric waters. We present here D/H ratios for 47 fluid inclusion samples from thirteen speleothems deposited over the past 250,000 years at cave sites in Iowa, West Virginia, Kentucky and Missouri. At each site glacial-age waters are depleted in deuterium relative to those of interglacial age. The average interglacial/glacial shift in the hydrogen isotopic composition of meteoric precipitation over ice-free areas of east-central North America is estimated to be ?12‰. This shift is consistent with the present climatic models and can be explained in terms of the prevailing pattern of atmospheric circulation and an increased ocean-continent temperature gradient during glacial times which more than compensated for the increase in deuterium content of the world ocean.     

On the seasonal variations of the atmospheric electric elements

Summary The air-earth current density in the stratosphere, the columnar resistance derived from the measurements of conductivity, and the ionospheric potential were investigated. The data were obtained by radiosonde ascents during the period of 1957–1967.It was found that the local horizontal visibility at the surface is related to the air-earth current density in the stratosphere, and it is expected that the air-earth current density has a seasonal variation. Statistical results show that indeed the air-earth current has a pronounced seasonal variation, high in winter and low in summer. The columnar resistance has also a seasonal variation, reverse to the variation of the air-earth current.The percentage time variation of the air-earth current (1/i) (di/dt) was found to be twice as much as the percentage time variation of the columnar resistance (1/R) (dR/dt) at the Tateno Observatory.The ionospheric potential, deduced from the measurements of the potential gradient by radiosonde ascents, shows no clear seasonal variation at Syowa-Base (Antarctica). Following Ohm's law, however, the above-mentioned results suggest that the seasonal variation of the ionospheric potential would exist on land.

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Zusammenfassung Die Vertikalstromdichte in der Stratosphäre, der Säulenwiderstand, berechnet aus Leitfähigkeitsmessungen, und das Ionosphärenpotential wurden untersucht. Die Messergebnisse wurden mittels Radiosonden im Jahrzehnt 1957–1967 erlangt.Es wurde festgestellt, dass die örtliche waagrechte Sichtweite am Erdboden mit der Vertikalstromdichte in der Stratosphäre korreliert ist, und dass erwartet werden muss, dass die Vertikalstromdichte einen jahreszeitlichen Gang aufweist. Tatsächlich lässt sich statistisch zeigen, dass ein solcher jahreszeitlicher Gang der Vertikalstromdichte besteht, mit einem Höchstwert im Winter und einem Mindestwert im Sommer. Auch der Säulenwiderstand zeigt einen jahreszeitlichen Gang, umgekehrt zu dem der Vertikalstromdichte.Die prozentuale zeitliche Änderung der Vertikalstromdichte (1/i) (di/dt) stellte sich als zweimal so gross heraus als die des Säulenwiderstandes (1/R) (dR/dt) gemessen am Observatorium zu Tateno.Wird das Ionosphärenpotential aus den Messungen des Potentialgefälles mit Radiosonden hergeleitet, so stellt sich bei den an der Syowa-Station in der Antarktik angestellten Messungen kein klarer Jahresgang heraus. Die hier zuvor erwähnten Ergebnisse, jedoch, führen zu der Annahme eines Jahresgangs des Ionosphärenpotentials über der genannten Station, wenn man das Ohm'sche Gesetz auf sie anwendet.

     

Review of Chinese atmospheric science research over the past 70 years: Synoptic meteorology

Synoptic meteorology is a branch of meteorology that uses synoptic weather observations and charts for the diagnosis,study,and forecasting of weather.Weather refers to the specific state of the atmosphere near the Earth's surface during a short period of time.The spatial distribution of meteorological elements in the atmosphere can be represented by a variety of transient weather phenomena,which are caused by weather systems of different spatial and temporal scales.Weather is closely related to people's life,and its development and evolution have always been the focus of atmospheric scientific research and operation.The development of synoptic meteorology is closely related to the development of observation systems,dynamical theories and numerical models.In China,observation networks have been built since the early 1950 s.Up to now,a comprehensive meteorological observation systembased on ground,air and space has been established.In particular,the development of a new generation of dense radar networks,the development of the Fengyun satellite series and the implementation of a series of large field experiments have brought our understanding of weather from large-scale environment to thermal dynamics,cloud microphysical structure and evolution characteristics of meso and micro-scale weather systems.The development of observation has also promoted the development of theory,numerical model and simulation.In the early days,China mainly used foreign numerical models.Lately,China has developed numerical model systems with independent intellectual property rights.Based on the results of high-resolution numerical simulations,in-depth understanding of the initiation and evolution mechanism and predictability of weather at different scales has been obtained.Synoptic meteorology has gradually changed from an initially independent development to a multidisciplinary approach,and the interaction between weather and the change of climate and environment has become a hot and frontier topic in atmospheric science.This paper reviews the important scientific and technological achievements made in China over the past 70 years in the fields of synoptic meteorology based on the literatures in China and abroad,from six aspects respectively including atmospheric dynamics,synoptic-scale weather,typhoon and tropical weather,severe convective weather,numerical weather prediction and data assimilation,weather and climate,atmospheric physics and atmospheric environment.     

Morning polar substorms and variations in the atmospheric electric field

The effects of morning magnetospheric substorms in the variations in near-Earth atmospheric electricity according to the observations of the electric field vertical component (E _z ), at Hornsund polar observatory (Spitsbergen). The E _z, data, obtained under the conditions of fair weather (i.e., in the absence of a strong wind, precipitation, and fog), are analyzed. An analysis of the observations indicated that the development of a magnetospheric substorm in the Earth’s morning sector is as a rule accompanied by positive deviations in E _z, independently of the Hornsund location: in the polar cap or at its boundary. In all considered events, Hornsund was located near the center of the morning convection vortex. In the evening sector, when Hornsund fell in the region of evening convection vortex, the development of a geomagnetic substorm was accompanied by negative deviations in E _z., It has been concluded that the variations in the atmospheric electric field E _z), at polar latitudes, observed during the development of magnetospheric substorms, result from the penetration of electric fields of polar ionospheric convection (which are intensified during a substorm) to the Earth’s surface.     

Correlation of atmospheric occurences over the United States with some physical and chemical parameters. Part III: Frequencies of precipitation

Summary Correlation between some physical and chemical variables, measured at 28 stations of the United States Weather Bureau Network, and seasonal and annual frequencies of precipitation, has been attempted with the aim of gaining insight into the bearing of such variables, on occurrence of precipitation. — Concurrent trends of frequencies with local temperature functions, altitude parameters, precipitable water vapour increments, and some chemical species have been found.Contribution of the «Centro Nucleazione Aerosoli» of the National Research Council of Italy, Via Vettore 4 (Monte Sacro),Roma.     

地下水气体组分的潮汐变化

我们观察了日本中部Omaezaki地区地下水气体组分时间序列数据的周期性变化,Omaezaki是日本地震预报目录中即将到来的Tokai地震前兆信号观察的重要地区.我们已经开始在一口100 m深的井中对地下水中气体组分进行持续监测.     

临近空间大气扰动变化特性的定量研究

本文利用TIMED/SABER 2002年1月至2013年1月共11年的卫星温度探测数据,通过全球网格化及在网格内作数学统计的方法,得到了20~100 km高度上全球网格点上温度的平均值和标准差,实现了对临近空间全球大气扰动进行定量刻画的目的.通过定量分析温度标准差的分布特性,文中得到了临近空间大气扰动的全球分布规律,并讨论了与这些分布规律相关的物理过程.结果表明,在20~70 km高度上,温度标准差为1~10 K,有显著的冬季/夏季的差异,冬季的温度标准差比夏季大;大气重力波扰动是最主要来源,同时大气传播性行星波引起的扰动也是来源之一.在70~100 km高度上,温度标准差常年较强,量值为10~30 K,冬季/夏季的差异小,低纬地区的温度标准差高于中高纬度地区,呈现许多局地化的小结构.大气重力波是引起该区域大气总扰动量的主要扰动来源,大气潮汐波、传播性行星波(准2天、准6.5天)也有重要贡献.     

Water transport over Western Europe and its correlation with climate variations based on data on precipitation isotopic composition

Space and time variations in the isotopic composition of precipitation on the IAEA/WMO network in Western Europe over 1961–1991 are analyzed. The authors came to the conclusion that climate becomes warmer and the western water transfer intensifies since the 1970s. Correlation between the observed climate changes and variations in the Caspian Sea level is detected. The effect of warming on changes in the normal annual air temperatures and the amount of precipitation in various latitudinal zones of Western Europe is assessed. The supposed periodicity of climate conditions enables their prediction.     

Effect of magnetic storms in variations in the atmospheric electric field at midlatitudes

The observations of the variations in the vertical component of the atmospheric electric field (E _z ) at Swider midlatitude Poland observatory (geomagnetic latitude 47.8°) under the conditions of fair weather during 14 magnetic storms have been analyzed. The effect of the magnetic storm main phase in the daytime midlatitude variations in E _z in the absence of local geomagnetic disturbances has been detected for the first time. Considerable (～100–300 V m^?1) decreases in the electric field strength (E _z ) at Swider observatory were observed in daytime simultaneously with the substorm onset in the nighttime sector of auroral latitudes (College observatory). The detected effects indicate that an intensification of the interplanetary electric field during the magnetic storm main phase, the development of magnetospheric substorms, and precipitation of energetic electrons into the nighttime auroral ionosphere can result in considerable disturbances in the midlatitude atmospheric electric field.     

Isotopic variations in precipitation at Bangkok and their climatological significance

The stable isotopic composition of precipitation from low to mid latitudes contains information about changes of some climatic factors, such as temperature, precipitation and atmospheric circulation patterns. However, the isotopic variations in the area are very complicated because of the combined influences of these factors. Proper interpretation of the patterns of isotopic variations for palaeoclimate reconstructions in this area requires a detailed understanding of these complex stable isotope controls. The isotopic data (δ¹⁸O and δ²D) in precipitation at the International Atomic Energy Agency–World Meteorological Organization Bangkok station were collected and analysed because of the relatively long and unbroken isotopic records and the particular geographical location. The isotopic variations at Bangkok have strong seasonal patterns owing to distinct source regions in different seasons. In summer, the remote sources of water there can influence the δ¹⁸O values significantly, which is verified by the simple Rayleigh model. In winter, the mixing of isotopically distinct air masses with different origins, i.e. the continental and oceanic air masses, accounts for the isotopic variations. In the transition periods of the Asia–Australia monsoon, namely in May and October, the local vapour contribution may play a role in the isotopic ratios. On the interannual time‐scale, the influences of El Niño–southern oscillation (ENSO) and the Indian Ocean dipole (IOD) on isotopic composition are examined. The indications are that both the ENSO and IOD indices have a significant correlation with the δ¹⁸O ratios, and that the δ¹⁸O ratio in summer rains is significantly more enriched (depleted) during the warm (cold) phase of ENSO/IOD events. All the results suggest that it is useful for us in understanding the water cycling process and may be helpful in palaeoclimate reconstruction in this monsoon region. Copyright © 2006 John Wiley & Sons, Ltd.     

Spatial and temporal variations in summer precipitation in Japanese mountain areas

We examined spatial and temporal variations in precipitation measured during summer season between 1976 and 2007 for 28 stations located in mountain areas across Japan using the amount of precipitation (Pr), the mean depth of precipitation events (η), and the inverse of the mean interval times (λ). We obtained positive correlations between the period mean Pr (Pr ) and the period mean η ( ) and between Pr and the period mean λ ( ) for the 28 stations. Pr was more strongly related to than to , indicating the spatial variations in Pr that are primarily related to the variations in . In addition, Pr was more strongly related to η than to λ for most stations on the basis of data for 1976–2007, indicating that the year‐to‐year variations in Pr are primarily related to η. We also examined temporal trends in Pr, η and λ for 1976–2007 and found no systematic trends for 23 of the 28 stations, suggesting long‐term trends that are not common in mountain areas of Japan. The relationships between Pr and and between Pr and η presented in this study enable us to generate a temporal precipitation distribution pattern based on only Pr and Pr data, respectively. Furthermore, probabilistic stochastic hydrological models require precipitation characteristics as input; thus, this study contributes to the determination of hydrological cycles and their possible future changes in Japanese mountain areas and therefore to water resource management. Copyright © 2010 John Wiley & Sons, Ltd.     

Isotopic composition of precipitation in a topographically steep,seasonally snow‐dominated watershed and implications of variations from the global meteoric water line

The local meteoric water line (LMWL), the functional relationship between locally measured values of δ¹⁸O and δ²H in precipitation, represents the isotopic composition of water entering hydrologic systems. The degree to which the LMWL departs from the global meteoric water line (GMWL), moreover, can reveal important information about meteoric sources of water (e.g. oceanic or terrestrial) and atmospheric conditions during transport. Here we characterize the isotopic composition of precipitation within an experimental watershed in the Western US that is subject to large topographic and seasonal gradients in precipitation. Interpreting the hydrometeorologic and spatial controls on precipitation, we constructed a seasonally weighted LMWL for southwestern Idaho that is expressed by the equation δ²H = 7.40 × δ¹⁸O ? 2.17. A seasonally weighted LMWL that is based on weighting isotopic concentrations by climatic precipitation volumes is novel, and we argue better represents the significant seasonality of precipitation in the region. The developed LMWL is considerably influenced by the semiarid climate experienced in southwest Idaho, yielding a slope and y‐intercept lower than the GMWL (δ²H = 8 × δ¹⁸O + 10). Moderate to strong correlations exist between the isotopic composition of precipitation from individual events and surface meteorologic variables, specifically surface air temperature, relative humidity, and precipitation amount. A strong negative correlation exists between the annual average isotopic composition of precipitation and elevation at individual collection sites, with a lapse rate of ?0.22‰/100 m. Copyright © 2016 John Wiley & Sons, Ltd.     

Chemical composition of precipitation in the southern part of the Russian Far East

Distribution of macro-and microelements, found in precipitation in dissolved and suspended forms (solid material) is considered. Contribution of the main sources of substance input in the precipitation on the investigated area is assessed.     

Modeling variations in salt composition components of river water

The balance of a component contained in river water is considered taking into account its input with lateral inflow and decay in the aquatic environment. Random changes in lateral inflow causes fluctuations in the parameters of component input and decay. A stochastic equation of component balance is derived and used as the basis for the construction of an equation for the probability density of component concentration. The solution of this equation shows that the probability density follows lognormal law. This theoretical result is applicable to the analysis of time series of water salt composition components, including pH, alkalinity, chlorides, ammonia, iron, and aluminum. The applicability of the lognormal law is proved and distribution parameters are evaluated. The distributions of three components (pH, alkalinity, and chlorides) are found to split into two lognormal branches, describing high and low component concentrations. In the case of pH and alkalinity, this splitting is due to seasonal effects, while in the case of chlorides, it is caused by the difference between concentrations in the surface runoff at the early and final stages of snow melting and rainfalls. The application of the statistical distributions for probabilistic forecasting of extreme component concentrations is considered. The exceedance probability of standard limits of the components is considered. The use of exceedance probability in hydrochemical standardization is demonstrated.