Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.     

TTGs and adakites: are they both slab melts?

Although both high-Al TTG (tonalite–trondhjemite–granodiorite) and adakite show strongly fractionated REE and incompatible element patterns, TTGs have lower Sr, Mg, Ni, Cr, and Nb/Ta than most adakites. These compositional differences cannot be easily related by shallow fractional crystallization. While adakites are probably slab melts, TTGs may be produced by partial melting of hydrous mafic rocks in the lower crust in arc systems or in the Archean, perhaps in the root zones of oceanic plateaus. It is important to emphasize that geochemical data can be used to help constrain tectonic settings, but it cannot be used alone to reconstruct ancient tectonic settings.

Depletion in heavy REE and low Nb/Ta ratios in high-Al TTGs require both garnet and low-Mg amphibole in the restite, whereas moderate to high Sr values allow little, if any, plagioclase in the restite. To meet these requirements requires melting in the hornblende eclogite stability field between 40- and 80-km deep and between 700 and 800 °C.

Some high-Al TTGs produced at 2.7 Ga and perhaps again at about 1.9 Ga show unusually high La/Yb, Sr, Cr, and Ni. These TTGs may reflect catastrophic mantle overturn events at 2.7 and 1.9 Ga, during which a large number of mantle plumes bombarded the base of the lithosphere, producing thick oceanic plateaus that partially melted at depth.     

北祁连浪力克铜矿镁安山质岩石年代学及地球化学特征

浪力克铜矿床位于北祁连造山带中段的冷龙岭复式背斜内,铜矿体主要赋存于火山通道内的闪长玢岩及其邻近的安山岩中,本文对矿区内赋矿的安山岩和石英闪长玢岩进行岩石学、地球化学研究,对安山岩进行锆石U-Pb年代学研究,以探讨矿区火山岩的岩石成因与形成环境,并对成矿时代进行约束。岩石地球化学数据显示,安山岩和石英闪长玢岩的化学特征十分相似,均具有高镁的特点,以大离子亲石元素(Rb、Ba、Th、U、K)强烈富集和高场强元素相对亏损及出现明显的Nb、Ta、P、Ti谷为特征,Cr和Ni含量较高,稀土元素配分曲线呈平坦型,∑REE较低,轻重稀土元素分馏不明显,略微富集轻稀土,基本无Eu异常,为一套高镁安山质岩石组合,其特点可以和世界某些高镁安山岩相对比,属于岛弧构造环境岩浆作用的产物,很可能为俯冲洋壳脱水熔融产生的熔体与地幔楔反应形成的。LA-ICP-MS锆石U-Pb测年结果表明,浪力克铜矿区安山岩的成岩年龄为479.2±3.4Ma,时代为早奥陶世,代表了浪力克铜矿的成矿下限年龄。     

Footwall mineralization during Late Miocene extension along the West Cycladic Detachment System,Lavrion, Greece

The West Cycladic Detachment System (WCDS) has been mapped from the western Cycladic islands to Lavrion (mainland Greece), where several top‐to‐SSW low‐angle normal faults at different structural levels are observed. Near the detachment horizon, hydrothermal fluid flow originating from Miocene intrusions lead to high‐temperature carbonate strata‐bound Pb–Ag–Zn ore deposits. Zircon (U–Th)/He cooling ages from the mineralized footwall are 7.1 ± 0.6 to 7.9 ± 0.6 Ma. Carbon‐ and O‐isotope analyses of the carbonate host indicate high water‐to‐rock ratios during brittle deformation‐induced metasomatism, and that this interaction, unrelated to proximity of the intrusions, plays the dominant role in the mineralization. The Late Miocene geology of Lavrion is strikingly similar to Serifos island on the SE termination of the WCDS, both characterized by strong localization of detachment faulting and the interaction of brittle deformation with the injection of fluids related to granitoid intrusions.     

Phenocryst complexity in andesites and dacites from the Tequila volcanic field,Mexico: resolving the effects of degassing vs. magma mixing

The petrology of five phenocryst-poor (2–5%) andesites and dacites, all of which were erupted from different short-lived, monogenetic vents, is compared to that of phenocryst-rich (10–25%) andesites erupted from the adjacent stratovolcano, Volcán Tequila, in the Mexican arc. Despite differences in phenocryst abundances, these magmas have comparable phase assemblages (plagioclase + orthopyroxene + titanomagnetite + ilmenite + apatite ± augite ± hornblende), and similarly wide variations in phenocryst compositions, coupled to complex zoning patterns. For the phenocryst-poor lavas, equilibrium pairs of two Fe–Ti oxides lead to a narrow range of calculated temperatures for each sample that range from 934 (±24) to 1,073 (±6)°C and oxygen fugacities that range from +0.1 to +0.7 log units relative to the Ni–NiO buffer. Application of the plagioclase-liquid hygrometer to each sample at these calculated temperatures leads to maximum melt water concentrations of 4.6–3.1 wt% during plagioclase crystallization, indicating that the magmas were fluid saturated at depths ≥6.4–4.5 km. There is a wide, continuous range in the composition of plagioclase (≤44 mol% An) and orthopyroxene (≤16% Mg#) phenocrysts in each sample, which is consistent with a loss of dissolved water (≤2.8 wt%) from the melt phase during degassing as the magmas ascended rapidly to the surface. Evidence is presented that shows the effect of dissolved water is to reduce the activity of MgO relative to FeO in the melt phase, which indicates that degassing will also affect the Mg# of pyroxene phenocrysts, with higher melt water concentrations favoring Fe-rich pyroxene. Both plagioclase and orthopyroxene commonly display diffusion-limited growth textures (e.g., skeletal and hopper crystals, large interior melt hollows, and swallow tails), which are consistent with large undercoolings produced by degassing-induced crystallization. Therefore, degassing is proposed as a possible cause for the phenocryst compositional diversity documented in the phenocryst-poor andesite and dacite lavas erupted from peripheral vents, including the coexistence of normally zoned plagioclase and reversely zoned orthopyroxene. Degassing-induced crystallization may also explain some of the phenocryst complexity in crystal-rich andesites erupted from large stratovolcanoes, including Volcán Tequila.     

North‐eastward subduction followed by slab detachment to explain ophiolite obduction and Early Miocene volcanism in Northland,New Zealand

Oligocene–Miocene models for northern New Zealand, involving south‐westward subduction to explain Early Miocene Northland volcanism, do not fit within the regional Southwest Pacific tectonic framework. A new model is proposed, which comprises a north‐east‐dipping South Loyalty basin slab that retreated south‐westward in the Eocene–earliest Miocene and was continuous with the north‐east‐dipping subduction zone of New Caledonia. In the latest Oligocene, the trench reached the Northland passive margin, which was pulled it into the mantle by the slab, resulting in obduction of the Northland allochthon. During and after obduction, the slab detached from the unsubductable continental lithosphere, inducing widespread calc‐alkaline volcanism in Northland. The new model further explains contemporaneous arc volcanism along the Northland Plateau Seamount Chain and sinking of the Northland basement, followed by uplift and extension in Northland.     

New insights into petrogenesis of Miocene magmatism associated with porphyry copper deposits of the Andean Pampean flat slab,Argentina

The Paramillos de Uspallata mining district located in the backarc region of the Pampean flat-slab segment(28°-33°S) features porphyry-type deposits genetically associated with Middle Miocene volcanics. This mineralizing magmatism comprising hydrothermally altered(sodic-calcic, potassic and phyllic alteration) subvolcanic and pyroclastic rocks of andesite-basaltic andesite and dacite-rhyolite composition with a typical arc signature, represents the eastward broadening of the Farellones arc by ~17 Ma. Its geochemistry also reveals a residual mineralogy of amphibole ± garnet with limited plagioclase fractionation resulting in an adakitic signal; however, according to the isotopic data collected in our study, the contributions of MASH(melting-assimilation-storage-homogenization) processes in the acquisition of this signal cannot be disregarded.Both the broadening of the Farellones arc and its residual mineralogy e typical of relatively deep magmatic chambers e are consistent with a slab shallowing and outcoming crustal thickening setting.This tectonic scenario could be interpreted as a result of an early effect of the Juan Fernandez Ridge collision that was further to the north by ~17 Ma. Our findings suggest that magmas were fertile for porphyry type deposits during the early stages of the slab shallowing.     

Formation of basins and mountain ranges in Attica (Greece): The role of Miocene to Recent low-angle normal detachment faults

In seismically active regions, active low-angle detachment faults are probably more frequent as is commonly thought and may play an important but still underestimated role in the evolution of landforms and basins. We investigate the tectonically active region of Attica (Greece) in the Aegean back arc as a model region to show how basins and mountain ranges commonly thought to be formed by movements on high-angle normal faults in fact reflect the surface expression of displacements on yet undetected, deep-seated, active low-angle normal detachment faults. Inferences are made based on an integrated study of Attica linking the petrology of clastic sediments with geomorphology and structures, and including few new palynological data. From the Miocene to Recent, three sets of normal detachment fault systems were successively active. Shear zones of the 1st (Early Miocene) stage emplaced rocks of the Attic Cycladic high-P metamorphic belt (AC-HP-belt) from depth corresponding to greeschist facies conditions in the brittle, upper crust. In the 2nd stage the WNW dipping Attica low-angle normal detachment fault system between the AC-HP-belt and the un- or weakly metamorphosed rocks of the sub-Pelagonian Zone (SPZ) was active. Clastic sedimentation started in the Late Miocene, during the 2nd stage. Late Miocene and Early Pliocene clastic sediments reveal that during the 2nd stage many areas that presently expose the AC-HP-belt were still covered by the overlying SPZ. Also, now uplifted areas such as the Parnitha mountain range that currently undergo strong erosion were then the sites of sedimentary sinks. The 3rd stage (Late Pliocene through Recent) is associated with dramatic changes in the morphology and recurring steepening of the relief. Reversal of the Parnitha area from the site of deposition into the site of erosion is associated with deposition of coarse conglomerates to the SE of the Parnitha Mt. and S of the Penteli Mt. Sediments of the 3rd stage reflect activity of the here newly described, SSE-dipping Penteli—Athens low-angle detachment fault (PADF) system formed at a high angle to the Attica detachment fault. The outcome of this study is that the present-day geomorphology is to a high degree related to the operation of the PADF system. Steep fault bounding the Athens and Mesogea basins as well as the mountain ranges (Parnitha, Penteli, Hymittos mounts) belongs to its breakaway zone or root into the PADF. Ongoing tectonic movements related to this fault system were responsible for the 1999 Athens (Mw = 6.0) earthquake. We particularly discuss how the PADF may continue into greater depth, the translation magnitude, and how the PADF fits into the wider kinematic framework of the Aegean region.     

Triassic shoshonites and andesites,Lakmon Mountains,western continental Greece: Differences in primary geochemistry and sheet silicate alteration products

Shallow marine lavas and pyroclastic rocks, several tens of metres thick, outcrop at the base of thrust slices in the Pindos nappe in the Lakmon Mountains of western continental Greece. These volcanic rocks are basalts and andesites formed during mid-Triassic subduction. Geochemically, on the basis of the potassium content, shoshonitic and calc-alkalic groups are distinguished. Principally the shoshonitic rocks contain primary K-feldspar. The calc-alkalic rocks contain complexly zoned feldspars and are depleted in intermediate REE: this depletion could reflect a small degree of partial melting of amphibole, or possibly phlogopite, during petrogenesis. These two characteristics are found in other examples of minor calc-alkalic rocks associated with shoshonites described in the literature. A petrogenetic model is developed involving deeper mantle enrichment in LILE and partial melting of this enriched mantle rock containing amphibole. Calc-alkalic rocks are the result of initial partial melting and may be mixed with small amounts of magma of deeper origin; further partial melting produces the more voluminous shoshonites. Celadonite developed as a secondary mineral during burial beneath about 1 km of Mesozoic to early Tertiary sediments. During nappe emplacement, vermiculite formed in the calc-alkalic rocks; in contrast, smectite developed in the shoshonites, because the potassium was sufficient to immobilize all available Fe in celadonite.     

A petrological study of the younger Tongan andesites and dacites,and the olivine tholeiites of Niua Fo'ou Island,S. W. Pacific

Basaltic andesites are the dominant Tongan magma type, and are characterized by phenocrysts of augite, orthopyroxene (or rarely pigeonite), and calcic plagioclase (modally most abundant phase, and interpreted as the liquidus phase). The plagioclase phenocrysts exhibit slight oscillatory reverse zoning except for abrupt and thin more sodic rims, which are interpreted to develop during eruptive quenching. These rim compositions overlap those of the groundmass plagioclase. The pyroxene phenocrysts also exhibit only slight compositional zoning except for the outermost rim zones; the compositions of these rims, together with the groundmass pyroxenes, vary throughout the compositional range of subcalcic augite to ferroaugite through pigeonite to ferropigeonite, and are interpreted in terms of quench-controlled crystallization. This is supported, for example, by the random distribution of Al solid solution in the groundmass pyroxenes, compared to the more regular behaviour of Al in the phenocryst pyroxenes. The analysed Niua Fo'ou olivine tholeiites are aphyric; groundmass phases are plagioclase (An_17–88), olivine (Fa_18–63), titanomagnetite (usp. _59–73), and augite-ferroaugite which does not extend to subcalcic compositions; this is interpreted to be due to higher quenching temperatures and lower viscosities of these tholeiites compared to the basaltic andesites.Application of various geothermometers to the basaltic andesites suggest initial eruptive quenching temperatures of 1,008–1,124 ° C, plagioclase liquidus temperatures (1 bar) of 1,210–1,277 ° C, and orthopyroxene-clinopyroxene equilibration of 990–1,150 ° C. These calculated temperatures, together with supporting evidence (e.g. absence of olivine and amphibole, liquidus plagioclase, and plagioclase zoning patterns) are interpreted in terms of phenocryst crystallization from magmas that were either strongly water undersaturated, nearly anhydrous, or at best, water saturated at very low pressures (< 0.5 kb). This interpretation implies that these Tongan basaltic andesites did not originate by any of the currently proposed mechanisms involving hydrous melting within or above the Benioff zone.     

Magnesian andesites, Nb-enriched basalt-andesites, and adakites from late-Archean 2.7 Ga Wawa greenstone belts, Superior Province, Canada: implications for late Archean subduction zone petrogenetic processes

Magnesian andesites (MA) occur with 'normal' tholeiitic to calc-alkaline basalt-andesite suites in four greenstone belts of the 2.7 Ga Wawa subprovince, Canada. Collectively, the magnesian andesites span ranges of SiO₂=56-64 wt%, Mg-number=0.64-0.50, with Cr and Ni contents of 531-106 and 230-21 ppm, respectively. Relative to 'normal' andesites, the magnesian andesites form distinct trends on variation diagrams, with relatively high Th and LREE contents, uniform Yb over a range of MgO, more fractionated HREE, and lower Nb/Th_pm and Nb/La_pm ratios. Niobium-enriched basalts and andesites (NEBA; Nb=7-16 ppm), and an Al-enriched rhyolite (adakite) suite are associated in space and time with the magnesian andesites. Nb-enriched basalts and andesites are characterized by high TiO₂, P₂O₅, Th, and Zr contents, variably high Zr/Hf (36-44) ratios, and more fractionated HREE (Gd/Yb_cn=1.3-4.1) compared to the 'normal' tholeiitic to calc-alkaline basalt-andesite suites. The adakite suite has the high Al (Al₂O₃=16-18 wt%), high La/Yb_cn (21-43), and low Yb (0.4-1.2 ppm) of Archean tonalite-trondhjemite-granodiorite (TTG) suites and Cenozoic adakites, indicative of liquids derived mainly from slab melting. The basalt-andesite suites are not characterized by normal tholeiitic or calc-alkaline fractionation trends of major or trace elements. Rather, compositional trends can be accounted for by some combination of fractional crystallization and variable degrees of metasomatism of the source of basalt and/or andesites by adakitic liquids. The occurrence of magnesian andesites, Nb-enriched basalts/andesites, and adakites has been described from certain Phanerozoic arcs featuring shallow subduction of young and/or hot oceanic lithosphere. Adakites likely represent slab melts, magnesian andesites the product of hybridization of adakite liquids with mantle peridotite, and Nb-enriched basalts/andesites melts of the residue from hybridization. Geological similarities between the late-Archean Wawa greenstone belts and certain Cenozoic transpressional orogens with the MA-NEBA-adakite association suggest that subduction of young, hot oceanic lithosphere may have played an important role in the production of this arc-related association in the late Archean.     

The role of slab melting in the petrogenesis of high-Mg andesites: evidence from Simbo Volcano,Solomon Islands

The petrogenesis of high-Mg andesites (HMA) in subduction zones involves shallow melting of refractory mantle sources or, alternatively, the interaction of ascending slab-derived melts with mantle peridotite. To unravel the petrogenesis of HMA, we report major, trace element and Sr–Nd–Hf–Pb isotope data for a newly found occurrence of HMA in the New Georgia group, Solomon Islands, SW-Pacific. Volcanism in the Solomon Islands was initiated by subduction of the Pacific plate beneath the Indian–Australian plate until a reversal of subduction polarity occurred ca. 10 Ma ago. Currently, the Indian–Australian plate is subducted northeastwards along the San Cristobál trench, forming the younger and still active southwestern Solomon island arc. However, a fossil slab of Pacific crust is still present beneath the arc. The edifice of the active volcano Simbo is located directly in the San Cristobál trench on top of the subducting Indian–Australian plate. Simbo Island lies on top of a strike-slip fault of the adjacent Woodlark spreading centre that is subducted beneath the Pacific plate. Geochemical and petrological compositions of volcanic rocks from Simbo are in marked contrast to those of volcanic rocks from islands north of the trench (mostly arc basalts). Simbo-type rocks are opx-bearing HMA, displaying 60–62 wt% SiO₂ but rather primitive Mg–Ni–Cr characteristics with 4–6 wt% MgO, up to 65 ppm Ni, up to 264 ppm Cr and Mg# from 67 to 75. The compositions of the Simbo andesites are explained by a binary mixture of silicic and basaltic melts. Relict olivine phenocrysts with Fo_88–90 and reaction-rims of opx also support a mixing model. The basaltic endmember is similar to back-arc basalts from the Woodlark Ridge. A slab melt affinity of the silicic mixing component is indicated by Gd_(N)/Yb_(N) of up to 2.2 that is higher if compared to MORB and other arc basalts from the Solomon Islands. ⁸⁷Sr/⁸⁶Sr, ɛNd and ɛHf values in the analysed rocks range from 0.7035 to 0.7040, +6.4 to +7.9 and +12 to +14.4, respectively. These values reveal the presence of the Indian–Australian mantle domain beneath Simbo (i.e. the Indian–Australian plate) and also beneath all other volcanic islands of the New Georgia group, which are located north of the San Cristobál trench. ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb values (18.43–18.52, 15.49–15.55 and 18.13–18.34, respectively) confirm the presence of slab melts from the subducted Pacific plate beneath southern Simbo where the highest Gd_(N)/Yb_(N) ratios are reported. A spatial shift towards an Indian–Australian slab signature is observed when approaching the active San Cristobál trench on northern Simbo, reflecting the decreasing influence of slab melts from the old subducted Pacific plate.     

1: Subduction,slab detachment and mineralization: The Neogene in the Apuseni Mountains and Carpathians

The Inner Carpathians comprise several distinct Neogene late-stage orogenic Pb–Zn–Cu–Ag–Au ore districts. The mineral deposits in these districts are closely related to volcanic and subvolcanic rocks, and represent mainly porphyry and epithermal vein deposits, which formed within short periods of time in each district. Here, we discuss possible geodynamic and structural controls that suggest why some of the Neogene volcanic districts within the Carpathians comprise abundant mineralization, while others are barren. The Neogene period has been characterized by an overall geodynamic regime of subduction, where primary roll-back of the subducted slab and secondary phenomena, like slab break-off and the development of slab windows, could have contributed to the evolution, location and type of volcanic activity. Structural features developing in the overlying lithosphere and visible in the Carpathian crust, such as transtensional wrench corridors, block rotation and relay structures due to extrusion tectonics, have probably acted in focusing hydrothermal activity. As a result of particular events in the geodynamic evolution and the development of specific structural features, mineralization formed during fluid channelling within transtensional wrench settings and during periods of extension related to block rotation.In the Slovakian ore district of the Western Carpathians, Neogene volcanism and associated mineralization were localized by sinistral, NE-trending wrench corridors, which formed part of the extruding Alcapa block. The Baia Mare ore district, in the Eastern Carpathians, reflects a transtensional wrench setting on distributed oversteps close to the termination of the Dragos Voda fault. There, mineralization was spatially controlled by the transtensional Dragos Voda master fault and associated cross-fault systems. The Golden Quadrangle Cu–Au ore district of the Southern Apuseni Mountains reflects an unusual rotated transtensional/extensional setting close to the termination of a graben system. There, fluid flow was probably localized by fault propagation at the inner tip of the graben system.The spatial and temporal evolution of the magmatism and its changing geochemical signature from (N)W to (S)E strongly suggests a link with the contemporaneous northeastward roll-back of the subducted slab and a progressive southeastward detachment during accelerating roll-back. This geodynamic evolution is further supported by the present-day overall and detailed mantle lithospheric density images, the present-day heat flow patterns, the crustal architecture and its interpreted evolution, and the spatial and temporal evolution of depocentres around the Carpathian arc. In contrast to all these features, the mineral deposits in the West Carpathians, East Carpathians and Apuseni Mountains are too synchronous with respect to their individual volcanic history and contrast too much with younger volcanics of similar style, but barren, in southeastern parts of the Carpathians to simply link them directly to the slab evolution. In all three districts, the presence of magmatic fluids released from shallow plutons and their mixing with meteoric water were critical for mineralization, requiring transtensional or extensional local regimes at the time of mineralization, possibly following initial compressional regimes.These three systems show that mineralization was probably controlled by the superposition of favourable mantle lithospheric conditions and partly independent, evolving upper crustal deformation conditions.In the 13 to 11 Ma period the dominant mineralization formed all across the Carpathians, and was superimposed on structurally favourable crustal areas with, at that time, volcanic–hydrothermal activity. The period may reflect the moment when the (upper part of the) crust failed under lithospheric extension imposed by the slab evolution. This crustal failure would have fragmented the overriding plate, possibly breaking up the thermal lid, to provoke intensive fluid flow in specific areas, and allowed subsequent accelerated tectonic development, block rotation and extrusion of a “family of sub-blocks” that are arbitrarily regarded as the Tisia–Dacia or Alcapa blocks, even though they have lost their internal entity.     

1: Subduction, slab detachment and mineralization: The Neogene in the Apuseni Mountains and Carpathians

The Inner Carpathians comprise several distinct Neogene late-stage orogenic Pb–Zn–Cu–Ag–Au ore districts. The mineral deposits in these districts are closely related to volcanic and subvolcanic rocks, and represent mainly porphyry and epithermal vein deposits, which formed within short periods of time in each district. Here, we discuss possible geodynamic and structural controls that suggest why some of the Neogene volcanic districts within the Carpathians comprise abundant mineralization, while others are barren. The Neogene period has been characterized by an overall geodynamic regime of subduction, where primary roll-back of the subducted slab and secondary phenomena, like slab break-off and the development of slab windows, could have contributed to the evolution, location and type of volcanic activity. Structural features developing in the overlying lithosphere and visible in the Carpathian crust, such as transtensional wrench corridors, block rotation and relay structures due to extrusion tectonics, have probably acted in focusing hydrothermal activity. As a result of particular events in the geodynamic evolution and the development of specific structural features, mineralization formed during fluid channelling within transtensional wrench settings and during periods of extension related to block rotation.In the Slovakian ore district of the Western Carpathians, Neogene volcanism and associated mineralization were localized by sinistral, NE-trending wrench corridors, which formed part of the extruding Alcapa block. The Baia Mare ore district, in the Eastern Carpathians, reflects a transtensional wrench setting on distributed oversteps close to the termination of the Dragos Voda fault. There, mineralization was spatially controlled by the transtensional Dragos Voda master fault and associated cross-fault systems. The Golden Quadrangle Cu–Au ore district of the Southern Apuseni Mountains reflects an unusual rotated transtensional/extensional setting close to the termination of a graben system. There, fluid flow was probably localized by fault propagation at the inner tip of the graben system.The spatial and temporal evolution of the magmatism and its changing geochemical signature from (N)W to (S)E strongly suggests a link with the contemporaneous northeastward roll-back of the subducted slab and a progressive southeastward detachment during accelerating roll-back. This geodynamic evolution is further supported by the present-day overall and detailed mantle lithospheric density images, the present-day heat flow patterns, the crustal architecture and its interpreted evolution, and the spatial and temporal evolution of depocentres around the Carpathian arc. In contrast to all these features, the mineral deposits in the West Carpathians, East Carpathians and Apuseni Mountains are too synchronous with respect to their individual volcanic history and contrast too much with younger volcanics of similar style, but barren, in southeastern parts of the Carpathians to simply link them directly to the slab evolution. In all three districts, the presence of magmatic fluids released from shallow plutons and their mixing with meteoric water were critical for mineralization, requiring transtensional or extensional local regimes at the time of mineralization, possibly following initial compressional regimes.These three systems show that mineralization was probably controlled by the superposition of favourable mantle lithospheric conditions and partly independent, evolving upper crustal deformation conditions.In the 13 to 11 Ma period the dominant mineralization formed all across the Carpathians, and was superimposed on structurally favourable crustal areas with, at that time, volcanic–hydrothermal activity. The period may reflect the moment when the (upper part of the) crust failed under lithospheric extension imposed by the slab evolution. This crustal failure would have fragmented the overriding plate, possibly breaking up the thermal lid, to provoke intensive fluid flow in specific areas, and allowed subsequent accelerated tectonic development, block rotation and extrusion of a “family of sub-blocks” that are arbitrarily regarded as the Tisia–Dacia or Alcapa blocks, even though they have lost their internal entity.     

Origin, HP/LT metamorphism and cooling of ophiolitic mélanges in southern Evia (NW Cyclades), Greece

Basic and ultrabasic blocks within ophiolitic mélanges of the Cycladic Blueschist Unit in southern Evia provide a detailed insight into its ocean floor igneous and hydrothermal evolution, as well as the regional poly‐metamorphism occurring during Alpine orogenesis. The upper structural levels (Mt. Ochi exposures) are dominated by metamorphosed wehrlites, gabbros and highly light rare earth element (LREE)‐enriched pillow basalts, whereas the underlying Tsaki mélange consists of basic protoliths with much less fractionated REE patterns as well as mantle harzburgites. Most of the metabasites show Nb anomalies, indicative of derivation from a subduction‐affected mantle. The igneous bodies were juxtaposed and incorporated into the enclosing sedimentary sequences prior to high‐pressure/low‐temperature (HP/LT) metamorphism (M1). Glaucophane, epidote, sodic clinopyroxene and high‐Si phengite constitute the Eocene M1 assemblage, which is estimated to have formed at >11 kbar and 400–450 °C. High δ¹⁸O values of M1 minerals in Ochi metagabbros indicate that the formation of the high‐pressure assemblage was controlled by infiltration of fluids from the dehydrating host sediments. Cooling during decompression is indicated by an overprinting (M2, Early Miocene) pumpellyite–actinolite facies assemblage in metabasic rocks, calculated to have developed at P<8 kbar and T <350 °C. Possible mechanisms for such cooling include: exhumation from shallower burial levels relative to the eclogites of the NW Cyclades, accretion of colder rocks from below and extensional unroofing by low‐angle normal faults and detachments. The occurrence of sodic augite in the M2 assemblage of Tsaki metagabbros indicates that rocks at the base of the Blueschist Unit cooled faster or longer than their higher level Ochi counterparts. This suggests that differential cooling of the blueschists was enhanced by the underthrusting of colder rock units.     

Magnetostratigraphy and revised chronology of the late Miocene mammal localities of Samos,Greece

The late Miocene mammalian record in Samos Island, Greece, is extremely important for the Eurasian Neogene mammalian history and chronology. However, due to the mixed nature of old fossil collections and controversies on the stratigraphic position of fossil quarries, great confusion has arisen concerning the recognition of distinct faunal assemblages, their age(s) and biostratigraphic significance. This paper presents the magnetostratigraphy of the late Miocene continental deposits of the fossiliferous Mytilinii Basin, Samos Island, Greece. Old and new sites are stratigraphically controlled with accuracy and correlated with each other. The magnetostratigraphy of seven individual sections, covering the entire Mytilinii Formation, provides good correlation with the Geomagnetic Polarity Time Scale (GPTS). These results, as well as the relocation and precise litho- and magnetostratigraphic correlation of the old and new mammal localities, combined with new and reviewed paleontological data and thorough studying of the numerous radiometric dates, allowed us to define five biostratigraphic horizons. Their correlation with, and implications to the European Neogene mammal chronology ages and zones make up the following discussion and provides a modified determination of the middle Turolian (MN 12) boundaries.Abbreviations GPTS Geomagnetic Polarity Time Scale - IPGP Institute de Physic du Globe de Paris - MGL Musée Cantonal de Géologie, Lausanne - MNHA Museum of Natural History of the Aegean, Samos - BMNH Natural History Museum of London - Q quarries - Fm Formation     

Tectono‐sedimentary evolution of lower to middle Miocene half‐graben basins related to an extensional detachment fault (western Crete,Greece)

Crustal extension in the overriding plate at the Aegean subduction zone, related to the rollback of the subducting African slab in the Miocene, resulted in a detachment fault separating high‐pressure/low‐temperature (HP‐LT) metamorphic lower from non‐metamorphic upper tectonic units on Crete. In western Crete, detachment faulting at deeper crustal levels was accompanied by structural disintegration of the hangingwall leading to the formation of half‐graben‐type sedimentary basins filled by alluvial fan and fan‐delta deposits. The coarse‐grained clastic sediments in these half‐grabens are exclusively derived from the non‐metamorphic units atop the detachment fault. Being in direct tectonic contact with HP‐LT metamorphic rocks of the lower tectonic units today, the basins must have formed in the period between c. 20 and 15 Ma, prior to the exposure of the HP‐LT metamorphic rocks at the surface, and juxtaposed with the latter during ongoing deformation.     

Chloritoid-bearing metapelites associated with glaucophane rocks in western Crete,Greece

In western Crete, Greece, a widespread occurrence of chloritoid-bearing metapelites with the main mineral assemblage chloritoid-phengitic white mica-Fe-rich chlorite-quartz was recorded to form the country rock of glaucophane-bearing metabasalts. Six bulk rock analyses of the metapelites conform to the compositional restrictions evaluated by Hoschek (1967) for the formation of chloritoid. Three microprobe analyses revealed chloritoid compositions low in Mg and Mn, and, consequently, high in Fe. The metamorphic grade documented in the metapelites is obviously related to a subsequent prograde metamorphism by which, in the adjacent meta-basalts, epidote is formed at the expense of lawsonite. No relict of a high-P, low-T assemblage, in part well preserved in the meta-basalts, was recognized in the chloritoid schists. The significance of the metamorphic history is briefly discussed.     

Chloritoid-bearing metapelites associated with glaucophane rocks in western Crete,Greece

Problems related to the formation of chloritoid in metapelites, associated with lawsonite-glaucophane bearing metabasalts, in the quartzitephyllite series of western Crete (Greece) are discussed. It is supposed that chloritoid was formed, during prograde metamorphism, according to a gliding-equilibrium reaction of the type (Fe,Mg)-carpholite₁+chlorite₁ (Fe,Mg)-carpholite_{1 2}+(Fe,Mg)-chloritoid_{1 2} +chlorite_1→2+quartz+H₂O ? (Fe,Mg)-chloritoid₂+chlorite₂+quartz+H₂O. This view is stipulated by the occurrence of ferrocarpholite-chloritoid schists in the southeastern part of central Crete. The assemblage chloritoid+ lawsonite recently recognized in western Crete provides evidence that the formation of chloritoid started well within the stability field of lawsonite.     

Configuration of the subducting Philippine Sea slab in the eastern part of southwestern Japan with seismic array and Hi-net data

It is important to know the shape of a subducting slab in order to understand the mechanisms of inter-plate earthquakes and the process of subduction. Seismicity data and converted phases have been used to detect plate boundaries. The configuration of the Philippine Sea slab has been obtained at the western part of southwestern Japan. At the eastern part of southwestern Japan, however, the configuration of the Philippine Sea slab has not yet been confirmed. A spatially high-density seismic network makes it possible to detect the boundaries of the Philippine Sea slab. We used a spatially high-density temporal seismic array in the area. The configuration of the Philippine Sea plate is obtained at the eastern part of southwestern Japan using the temporal seismic array and permanent seismic network data and comparing the seismic structure obtained from the results of refraction surveys. The configuration of the Philippine Sea plate obtained by this study does not bend sharply compared to previous models obtained from receiver function analyses. We delineated the upper boundary of the slab to a depth of about 45 km. The weak image of the boundary, which corresponds to the upper mantle reflector beneath the source area of the 2000 Western Tottori earthquake, was detected using the spatially dense array.