Palaeomagnetic estimates of emplacement temperatures of pyroclastic deposits on Santorini,Greece

Thermal remanent magnetism provides a method of quantitatively determining the emplacement temperature of individual lithic clasts in a volcaniclastic rock. The technique is reviewed and applied to two types of Quaternary pyroclastic deposit on Santorini. Emplacement-temperature estimates for lithic clasts from two co-ignimbrite lithic breccias (Cape Riva and Middle Pumice eruptions) range from 250°C to 580°C, showing unambiguously that the breccias were emplaced hot. Good precision on temperature estimates (about ±20°C) were obtained from the Cape Riva breccias. Lithics in a Plinian airfall deposit from the Middle Pumice eruption give less precise results because the primary magnetisation has been partly overprinted by chemical (and/or viscous) remanence, and some clasts may have rotated during compaction of the deposit. Temperatures from proximal airfall are consistent with welding of the deposit within 1.5 km from vent. Temperature estimates for lithic clasts further from vent scatter, but a falloff of temperature away from vent can be recognised if an average emplacement temperature for the whole deposit is identified at each location. The study highlights some difficulties in interpreting quantitative temperature estimates for prehistoric pyroclastic deposits.     

Emplacement temperature determinations of proximal pyroclastic deposits on Santorini,Greece, and their implications

Received: 14 May 1998 / Accepted: 8 July 1999     

Syn-eruptive chaotic breccia on Kos, Greece, associated with an energetic pyroclastic flow

The climax of the Kos Plateau Tuff (KPT) eruption (eastern Aegean, Greece) generated a highly energetic, coarse-grained, lithic-rich, pyroclastic flow. In most places on Kos, the deposit from this event is an ignimbrite (ignimbrite El) that comprises a basal, coarse-grained, lithic breccia and overlying pumiceous part, above a planar, strongly erosional lower contact. However, along the northern coast of central Kos, "normal" ignimbrite El overlies a hummocky, 6-m-thick layer of chaotic breccia comprising mingled-to-pervasively mixed ignimbrite El and unconsolidated sediment. The surface morphology of the chaotic breccia and its internal texture resemble those of a debris-avalanche deposit, but the breccia is neither proximal nor downcurrent of steep topography. The lower part of the chaotic breccia comprises distinct domains of unconsolidated sediment or lower KPT units that are deformed and/or mingled with pumiceous ignimbrite. The upper part is dominated by a matrix of mingled-to-pervasively mixed ignimbrite and sediment that contains sediment domains as large as 2-10 m in diameter. Such large intact allochthonous domains are best preserved at the top of the chaotic breccia and form the hummocks. The chaotic breccia formed synchronously with the passage of a highly energetic pyroclastic flow where it traversed wet, unconsolidated sediment. Shear-induced liquification, together with possible ground shaking associated with the eruption, probably caused failure. Part of the unconsolidated substrate and basal part of ignimbrite El were dislodged and resedimented a short distance (tens to hundreds of metres) downcurrent. The lower part records deformation and disintegration of the substrate induced by the overriding, shearing flow. Mingling and deformation of the poorly consolidated material occurred as a result of within-flow lateral shear. Attenuated worm burrows within the sediment domains, and pinch-and-swell and flame structures within the mingled domains, preserve evidence of shear in the lower part. The upper part was transported downcurrent above a zone of shear failure. Internal heterogeneities in physical properties resulted in variable strain rates causing some domains to be pervasively mixed while others remained intact. Intact large unconsolidated domains at the top were transported mostly above the zone of shearing.     

Lithic breccias in pyroclastic flow deposits on St. Kitts,West Indies

Lithic-rich breccias are described from within a sequence of young (2000–3000 yrs B.P.) scoria and ash flow deposits erupted from Mount Misery and an older pumice and ash flow deposit (ignimbrite) on St. Kitts. Cross sections constructed through pyroclastic flow fans in well-exposed sea cliffs 4–6 km from the vent show that the lithic breccias are lensoid deposits which seem to occur as channel-shaped accumulations (up to > 20 m thick and > 150 m wide) within flow units. The best-developed example infills a deeply incised channel cut into older flow units. The coarsest lithic breccias are clast supported and fines depleted and grade laterally and vertically through finer-grained, matrix-supported breccias into scoria and ash flow deposits. Coarse scoria-concentration zones mainly occur at the tops of scoria and ash flow units but also at the bases, and gas-segregation pipes are common. The lithic breccias are a type of body-concentration deposit as they pass laterally into normal scoria and ash flow deposits and, where best developed, clearly occur above a reversely graded basal shear zone or layer. Grain-size studies indicate the lithic breccias and parent flows are strongly fines depleted and were highly fluidized. We suggest this may be a feature of many Lesser Antillean pyroclastic flows because of increased turbulence-induced fluidization resulting from a high degree of surface roughness caused by the steep (up to 40 °) irregular slopes, densely vegetated sinuous gullies of the tropical volcanoes, and ingestion and ignition of large amounts of lush vegetation. Accumulation of batches of lithics concentrated in the highly fluidized flows began at the break in slope where flows moved from gullies across hydraulic jumps onto the outer coastal flanks. The accumulations of breccias continued to move and be channelled down the central parts of the flows. Initially, on crossing onto the lower slopes, some of these flows seem to have had very powerfully erosive, nondepositional heads, and in the extreme example a deep channel as long as 1–2 km may have cut through underlying flow units at least as far as the present coastline. Much of the overriding remainder of the flow then drained away laterally. Thin, fine-grained ash flow deposits may form a marginal overbank facies to the pyroclastic flow fans.     

Textural analysis and flow mechanism of the Donzurubo subaqueous pyroclastic flow deposits

The Donzurubo subaqueous pyroclastic flow deposits deposited in subaqueous environments maintaining high temperatures (about 500°C). Each flow unit of these pyroclastic flow deposits shows some characteristic size distributions in its stratigraphic column. The concentration of pumice at the top clearly defines the top facies of a flow unit. Median diameter (Md Ø) and the averages of the largest ten essential dense debris increase gradually starting from both the top and the bottom of the flow unit. The maximum points of Md Ø and the averages of the largest ten essential dense debris are usually found in the middle zone of each flow unit, but the Md Ø maximum points are generally in a lower position than the averages. Mechanical analyses show that the deposits consist of polymodal populations. They show, on the whole, an asymmetrical distribution, which is mainly due to the absence of the coarser fractions of the main population. The size distribution characteristics and the C-M pattern of the deposits suggest that these subaqueous pyroclastic flow deposits were not originated by homogeneously suspended turbulent flows but by incandescent turbulent flows with layered suspension.     

Palaeotemperature estimation of the pyroclastic deposit covering the pre-Minoan palaeosol at Megalochori Quarry, Santorini (Greece): Evidence from magnetic measurements

Thermal remanent magnetization analyses were carried out on ceramic fragments and lithic clasts embedded in the first pumice fall deposits of the Minoan eruption. The aim of this study is to estimate the equilibrium temperature after deposition of these pyroclastic fall deposits and their thermal effect on the pre-Minoan surface. A total of 30 samples from 22 independent ceramic fragments and 20 samples from 14 lithic clasts have been studied. Samples were collected from the Megalochori Quarry, located at the southern part of Santorini island. Stepwise thermal demagnetization reveals that the ceramics were mostly re-heated at temperatures around 140–180°C; in few ceramics a higher temperature component is also present, probably related to the original heating or the use of the ceramics before the eruption. Thermal demagnetization of the lithic clasts shows similar results with slightly higher re-heating temperatures, around 180–240°C. The estimated temperatures represent the equilibrium temperatures obtained after the deposition of the pumice fall and show that the pyroclastic fall deposits at a distance of around 6 km from the eruption vent maintained a temperature high enough to re-heat the buried ceramics at temperatures around 140–180°C.     

Rhyolitic fallout and pyroclastic density current deposits from a phreatoplinian eruption in the eastern Aegean Sea, Greece

The Kos Plateau Tuff consists of pyroclastic deposits from a major Quaternary explosive rhyolitic eruption, centred about 10 km south of the island of Kos in the eastern Aegean, Greece. Five main units are present, the first two (units A and B) were the product of a phreatoplinian eruption. The eruption style then changed to `dry' explosive style as the eruption intensity increased forming a sequence of ignimbrites and initiating caldera collapse. The final waning phase returned to phreatomagmatic eruptive conditions (unit F). The phreatomagmatic units are fine grained, poorly sorted, and dominated by blocky vitric ash, thickly ash-coated lapilli and accretionary lapilli. They are non-welded and were probably deposited at temperatures below 100°C. All existing exposures occur at distances between 10 km and 40 km from the inferred source. Unit A is a widespread (>42 km from source), thin (upwind on Kos) to very thick (downwind), internally laminated, dominantly ash bed with mantling, sheet-like form. Upwind unit A and the lower and middle part of downwind unit A are ash-rich (ash-rich facies) whereas the upper part of downwind unit A includes thin beds of well sorted fine pumice lapilli (pumice-rich facies). Unit A is interpreted to be a phreatoplinian fall deposit. Although locally the bedforms were influenced by wind, surface water and topography. The nature and position of the pumice-rich facies suggests that the eruption style alternated between `wet' phreatoplinian and `dry' plinian during the final stages of unit A deposition.Unit B is exposed 10–19 km north of the inferred source on Kos, overlying unit A. It is a thick to very thick, internally stratified bed, dominated by ash-coated, medium and fine pumice lapilli in an ash matrix. Unit B shows a decrease in thickness and grain size and variations in bedforms downcurrent that allow definition of several different facies and laterally equivalent facies associations. Unit B ranges from being very thick, coarse and massive or wavy bedded in the closest outcrops to source, to being partly massive and partly diffusely stratified or cross-bedded in medial locations. Pinch and swell, clast-supported pumice layers are also present in medial locations. In the most distal sections, unit B is stratified or massive, and thinner and finer grained than elsewhere and dominated by thickly armoured lapilli. Unit B is interpreted to have been deposited from an unsteady, density stratified, pyroclastic density current which decelerated and progressively decreased its particle load with distance from source. Condensation of steam during outflow of the current promoted the early deposition of ash and resulted in the coarser pyroclasts being thickly ash-coated. The distribution, texture and stratigraphic position of unit B suggest that the pyroclastic density current was generated from collapse of the phreatoplinian column following a period of fluctuating discharge when the eruptive activity alternated between `wet' and `dry'. The pyroclastic density current was transitional in particle concentration between a dilute pyroclastic surge and a high particle concentration pyroclastic flow. Unidirectional bedforms in unit B suggest that the depositional boundary was commonly turbulent and in this respect did not resemble conventional pyroclastic flows. However, unit B is relatively thick and poorly sorted, and was deposited more than 19 km from source, implying that the current comprised a relatively high particle concentration and in this respect, did not resemble a typical pyroclastic surge.     

Young pumice deposits on Nisyros,Greece

The island of Nisyros (Aegean Sea) consists of a silicic volcanic sequence upon a base of mafic-andesitic hyaloclastites, lava flows, and breccias. We distinguish two young silicic eruptive cycles each consisting of an explosive phase followed by effusions, and an older silicic complex with major pyroclastic deposits. The caldera that formed after the last plinian eruption is partially filled with dacitic domes. Each of the two youngest plinian pumice falls has an approximate DRE volume of 2–3 km³ and calculated eruption column heights of about 15–20 km. The youngest pumice unit is a fall-surge-flow-surge sequence. Laterally transitional fall and surge facies, as well as distinct polymodal grainsize distributions in the basal fall layer, indicate coeval deposition from a maintained plume and surges. Planar-bedded pumice units on top of the fall layer were deposited from high-energy, dry-steam propelled surges and grade laterally into cross-bedded, finegrained surge deposits. The change from a fall-to a surge/flow-dominated depositional regime coincided with a trend from low-temperature argillitic lithics to high-temperature, epidote-and diopside-bearing lithic clasts, indicating the break-up of a high-temperature geothermal reservoir after the plinian phase. The transition from a maintained plume to a surge/ash flow depositional regime occurred most likely during break-up of the high-temperature geothermal reservoir during chaotic caldera collapse. The upper surge units were possibly erupted through the newly formed ringfracture.     

A vesicularity index for pyroclastic deposits

The vesicularity of juvenile clasts in pyroclastic deposits gives information on the relative timing of vesiculation and fragmentation, and on the role of magmatic volatiles versus external water in driving explosive eruptions. The vesicularity index and range are defined as the arithmetic mean and total spread of vesicularity values, respectively. Clast densities are measured for the 16–32 mm size fraction by water immersion techniques and converted to vesicularities using measured dense-rock equivalent densities. The techniques used are applied to four case studies involving magmas of widely varying viscosities and discharge rates: Kilauea Iki 1959 (basalt), Eifel tuff rings (basanite), Mayor Island cone-forming deposits (peralkaline rhyolite) and Taupo 1800 B.P. (calc-alkaline rhyolite). Previous theoretical studies suggested that a spectrum of clast vesicularities should be seen, depending on the magma viscosity, eruption rate, and the presence and timing of magma: water interaction. The new data are consistent with these predictions. In magmatic dry eruptions the vesicularity index lies uniformly in the range 70%–80% regardless of magma viscosity. For high viscosities and eruption rates the vesicularity ranges are narrow (< 25%), but broaden to between 30% and 50% as the viscosity and eruption rates are lowered and the volatiles and magma can de-couple. In phreatomagmatic wet eruptions, widely varying clast vesicularities reflect complex variations in the relative timing of vesiculation and water-induced fragmentation. Magma:water interaction at an early stage greatly reduces the vesicularity indices (< 40%) and broadens the ranges (as high as 80%), whereas late-stage interaction has only a minor effect on the index and broadens the range to a limited extent. Clast vesicularity represents a useful third parameter in addition to dispersal and fragmentation to characterise pyroclastic deposits.     

Ranking welding intensity in pyroclastic deposits

Welding of pyroclastic deposits involves flattening of glassy pyroclasts under a compactional load at temperatures above the glass transition temperature. Progressive welding is recorded by changes in the petrographic (e.g., fabric) and physical (e.g., density) properties of the deposits. Mapping the intensity of welding can be integral to studies of pyroclastic deposits, but making systematic comparisons between deposits can be problematical. Here we develop a scheme for ranking welding intensity in pyroclastic deposits on the basis of petrographic textural observations (e.g., oblateness of pumice lapilli and micro-fabric orientation) and measurements of physical properties, including density, porosity, point load strength and uniaxial compressive strength. Our dataset comprises measurements on 100 samples collected from a single cooling unit of the Bandelier Tuff and parallel measurements on 8 samples of more densely welded deposits. The proposed classification comprises six ranks of welding intensity ranging from unconsolidated (Rank I) to obsidian-like vitrophyre (Rank VI) and should allow for reproducible mapping of subtle variations in welding intensity between different deposits. The application of the ranking scheme is demonstrated by using published physical property data on welded pyroclastic deposits to map the total accumulated strain and to reconstruct their pre-welding thicknesses.Editorial Responsibility: T. Druitt     

Mixed-magma pyroclastic surge deposits associated with debris avalanche deposits at Colima volcanoes,Mexico

The transition between the terminal cones and the ancestral edifices of Nevado de Colima and Fuego de Colima volcanoes is marked by the deposits of gigantic volcanic debris avalanches of the Mount St. Helens (MSH) or Bezymianny type. Unusual mafic juvenile fragments and cauliflower bombs as well as juvenile fragments of mixed and more evolved composition are abundant in dune-bedded pyroclastic-surge deposits directly associated with these catastrophic events at both volcanoes. At Nevado, these mafic juvenile fragments represent the most primitive magma ever erupted by the volcano (SiO₂52.50%). The lavas directly preceding and following the debris-avalanche event are silicic andesites (SiO₂59%). At Fuego these juvenile fregments have 56% SiO₂. The lavas from the upper parts of the caldera wall are dacites (65% SiO₂), whereas the terminal cone is composed of andesites (57% to 62% SiO₂). At Nevado, petrologic evidence for interaction of mafic magma with andesitic or dacitic magma in a high-level magma chamber, just before the eruption of pyroclastic surge deposits, consists of: (1) banded juvenile bombs of intermediate composition; (2) the range of composition of these bombs from SiO₂52% to 58%; (3) the presence of highly magnesian olivine with reaction rims; (4) inverse zoning in clinopyroxene with strong Mg enrichment towards the rim; (5) resorption of plagioclase; and (6) significant compositional heterogeneity in the vitric phase. Volcanic debris-avalanche events at Nevado and Fuego de Colima may thus correspond with major breaks in the petrological evolution of the volcanoes and the start of a new magmatic cycle. Injection of mafic magma into the presently perched viscous surface dome of the active Fuego cone, as occurred in 1818 and 1913, could enhance the likelihood of southward collapse of the flank of an already unstable edifice, and it must be considered in future hazard assessment of this active volcano. Risk to life and property for the entire Colima region associated with such catastrophic phenomena would be immeasurably greater in comparison with hazards related to the last explosive outburst in 1913, which resulted in emplacement of pyroclastic flows over uninhabited areas of the upper flanks of the volcano.     

Complex spatter- and pumice-rich pyroclastic deposits from an andesitic caldera-forming eruption: the Siwi pyroclastic sequence,Tanna, Vanuatu

The small- to moderate-volume, Quaternary, Siwi pyroclastic sequence was erupted during formation of a 4 km-wide caldera on the eastern margin of Tanna, an island arc volcano in southern Vanuatu. This high-potassium, andesitic eruption followed a period of effusive basaltic andesite volcanism and represents the most felsic magma erupted from the volcano. The sequence is up to 13 m thick and can be traced in near-continuous outcrop over 11 km. Facies grade laterally from lithic-rich, partly welded spatter agglomerate along the caldera rim to two medial, pumiceous, non-welded ignimbrites that are separated by a layer of lithic-rich, spatter agglomerate. Juvenile clasts comprise a wide range of densities and grain sizes. They vary between black, incipiently vesicular, highly elongate spatter clasts that have breadcrusted pumiceous rinds and reach several metres across to silky, grey pumice lapilli. The pumice lapilli range from highly vesicular clasts with tube or coalesced spherical vesicles to denser finely vesicular clasts that include lithic fragments.Textural and lithofacies characteristics of the Siwi pyroclastic sequence suggest that the first phase of the eruption produced a base surge deposit and spatter-poor pumiceous ignimbrite. A voluminous eruption of spatter and lithic pyroclasts coincided with a relatively deep withdrawal of magma presumably driven by a catastrophic collapse of the magma chamber roof. During this phase, spatter clasts rapidly accumulated in the proximal zone largely as fallout, creating a variably welded and lithic-rich agglomerate. This phase was followed by the eruption of moderately to highly vesiculated magma that generated the most widespread, upper pumiceous ignimbrite. The combination of spatter and pumice in pyroclastic deposits from a single eruption appears to be related to highly explosive, magmatic eruptions involving low-viscosity magmas. The combination also indicates the coexistence of a spatter fountain and explosive eruption plume for much of the eruption.Editorial responsibility: R. Cioni     

Sedimentology of the Krakatau 1883 submarine pyroclastic deposits

The majority of tephra generated during the paroxysmal 1883 eruption of Krakatau volcano, Indonesia, was deposited in the sea within a 15-km radius of the caldera. Two syneruptive pyroclastic facies have been recovered in SCUBA cores which sampled the 1883 subaqueous pyroclastic deposit. The most commonly recovered facies is a massive textured, poorly sorted mixture of pumice and lithic lapilli-to-block-sized fragments set in a silty to sandy ash matrix. This facies is indistinguishable from the 1883 subaerial pyroclastic flow deposits preserved on the Krakatau islands on the basis of grain size and component abundances. A less common facies consists of well-sorted, planarlaminated to low-angle cross-bedded, vitric-enriched silty ash. Entrance of subaerial pyroclastic flows into the sea resulted in subaqueous deposition of the massive facies primarily by deceleration and sinking of highly concentrated, deflated components of pyroclastic flows as they traveled over water. The basal component of the deposit suggests no mixing with seawater as inferred from retention of the fine ash fraction, high temperature of emplacement, and lack of traction structures, and no significant hydraulic sorting of components. The laminated facies was most likely deposited from low-concentration pyroclastic density currents generated by shear along the boundary between the submarine pyroclastic flows and seawater. The Krakatau deposits are the first well-documented example of true submarine pyroclastic flow deposition from a modern eruption, and thus constitute an important analog for the interpretation of ancient sequences where subaqueous deposition has been inferred based on the facies characteristics of encapsulating sedimentary sequences.     

Factors governing the flow lineation of a large-scale pyroclastic flow — An example in the ata pyroclastic flow deposit,Japan

Schmincke andSwanson (1967) explained laminar flowage structures as indicators for flow direction of pyroclastic flows that show a radial flow pattern away from the source. Several other authors have reported similar examples, but the influence of pre-flow topographic relief has not been analyzed. Flow lineations were measured for the Ata pyroclastic flow deposit, southwestern Japan. This deposit has covered an undulating basement topography. Preferred orientation of crystals and lithic fragments were measured on thin sections cut parallel to sedimentary layering. The following three factors which control the flow lineation have been recognized. 1) Flow lineations oriented radially away from the source, as described by previous authors, were obtained only for samples collected from the surface of the pyroclastic flow plateau where the basement valleys were nearly filled by earlier flow units. 2) Lineations near the floor of narrow valleys were parallel to the strike of the valley. 3) Flow lineations near the wall of valleys tend to be parallel to the dip of the valley walls. These data suggest that the initial radial movement of pyroclastic flows from the source gradually changes direction to parallel the strike of deep valleys due to confining effect of valley wall. Flows which are trapped within a valley, tends to move towards the bottom of the valley just prior to the final settlement. After the basement topographic relief has been filled up with earlier flow units, the later flows maintain their original radial movement until final settlement.     

Characterization of pyroclastic fall and flow deposits from the 1815 eruption of Tambora volcano,Indonesia using ground-penetrating radar

Ground-penetrating radar (GPR) is used to image and characterize fall and pyroclastic flow deposits from the 1815 eruption of Tambora volcano in Indonesia. Analysis of GPR common-mid-point (CMP) data indicate that the velocity of radar in the sub-surface is 0.1 m/ns, and this is used to establish a preliminary traveltime to-depth conversion for common-offset reflection profiles. Common-offset radar profiles were collected along the edge of an erosional gully that exposed approximately 1–2 m of volcanic stratigraphy. Additional trenching at select locations in the gully exposed the contact between the pre-1815 eruption surface and overlying pyroclastic deposit from the 1815 eruption. The deepest continuous, prominent reflection is shown to correspond to the interface between pre-eruption clay-rich soil and pyroclastics that reach a maximum thickness of 4 m along our profiles. This soil surface is distinctly terraced and is interpreted as the ground surface augmented for agriculture and buildings by people from the kingdom of Tambora. The correlation of volcanic stratigraphy and radar data at this location indicates that reflections are produced by the soil-pyroclastic deposit interface and the interface between pyroclastic flows (including pyroclastic surge) and the pumice-rich fall deposits. In the thickest deposits an additional reflection marks the interface between two pyroclastic flow units.     

Stratified flow in pyroclastic surges

Stratified flow theory is applied to pyroclatic surges in an effort to gain insight into transport dynamics during explosive eruptions. Particle transport is assumed to be by turbulent suspension, and calculations contained herein show that this is likely for many cases including the 18 May 1980 blast at mount St. Helens. The discussion centers on the Rouse number (Pn), which represents a ratio of particle settling velocity to scale of turbulence; the Brunt-Väisälä frequency (N), which is the maximum possible frequency of internal waves; the Froude number (Fr), representing the ratio of inertial forces to gravitational forces; and the Richardson number (Ri), a ratio of buoyant restoring forces to turbulent mixing forces. The velocity or flow power dependence of bed-form wavelength in surge deposits is related to a velocity dependence of wavelength of internal waves in the turbulent surge. This produces a decrease in dune wavelength with increasing distance from vent. Migration direction of bed forms is related toFr as it is defined for a continuously stratified flow. Proximal to distal facies variations in surge deposits reflect increasingPn andRi as the flows move away from their sources. This produces the progression from sandwave to massive to planar facies with increasing distance from vent. Where the long axis of topography is at low angles to the flow direction, massive facies in topographic lows may from concurrently with sandwave facies on highs, due to the higher particle concentration in the lows. Where long axis of topography is at high angles to flow direction, denser lower parts of the surge may be dammed or blocked. Blocked material tends to form massive flows that may move down slope independent of the overriding surge. A model incorporating turbulent transport, stratified flow, and time evolution of pyroclastic surges is proposed for deposits which have been attributed to both pyroclastic flow and pyroclastic surge transport by various workers. During the initial high energy (waxing) phase of the eruptive event,Pn is sufficiently low that only coarse, but poorly sorted, material is deposited to form relatively coarse bottom layers. As the event wanes, remaining finer material is deposited through a thin bed load to produce overlying bedded and cross-bedded veneer deposits. Throughout most of the event, blocking occurs to produce relatively thick and massive deposits in valley bottoms.     

Welded tuffs and related pyroclastic deposits in northeastern Japan

Welded tuffs and related pyroclastic deposits are distributed at many localities in northeastern Japan, especially around the volcanoes of the Nasu volcanic zone running from north to south, but they are absent from the region along the Japan Sea. Their geological age varies from the Miocene to the Holocene, those of the Pleistocene being predominant in amount. Petrographically they cover rather a wide range from andesite to rhyolite, among which dacite is most common. The welded tuffs are always compact and hard, with well-developed columnar jointing, carrying parallel-layered obsidian lenticules; and various stages are observed from loose pyroclastic deposits to lava-like welded tuffs. Petrological, petrochemical, and physical properties of these deposits are studied in some detail. From these data some genetic consideration is given for the mechanism of welding, and also for the relation between the nature of parental magma and the formation of such pyroclastic deposits.     

Helium and CO2 soil gas emission from Santorini (Greece)

Soil gas investigation is a useful tool to detect active faults. The sudden appearance of soil gas anomalies in zones of deep-reaching faults represents a promising potential precursor of earthquakes and volcanic eruptions. In volcanic areas the development of soil gas monitoring techniques is particularly important, as they can represent, together with remote sensing techniques, the only geochemical methods that can be safely applied during volcanic unrest, when it becomes impossible or too dangerous to sample crater fumaroles. A soil gas survey was carried out in June 1993 at the main island of Thera, in the Santorini volcanic complex. CO₂ flux and CO₂ and helium concentrations were measured at 50 cm depth for 76 points covering the entire island, with a spacing of 500 m or less. Several anomalous soil degassing sites have been detected. The main anomalies correspond to the Kolumbos line and to the Kameni line, two volcano-tectonic fault systems that controlled all the historic volcanic activity of Santorini. A third anomaly is related to a gas-leaking fault cutting the geothermal field of southern Thera. Soil gas data, together with geovolcanological and seismological evidence, indicate that the Kolumbos and Kameni lines are the most probable sites for future volcanic or seismic reactivation, and provide the basis for the establishment of a new geochemical monitoring technique at Thera.     

The effect of explosive eruption processes on geochemical patterns within pyroclastic deposits

The effects of magma fragmentation and atmospheric transport of pyroclasts in modifying tephra chemistry are quantitatively examined in order to assist in devising geochemical sampling strategies for young pyroclastic deposits, with particular regard to air-fall tephra. Magma fragmentation during explosive eruption results in crystal fractionation, the extent of which increases with decreasing tephra particle size. Among the products of a single sustained plinian eruption, variable atmospheric flight times of pyroclasts may cause simultaneous deposition of earlier-erupted and later-erupted material. Both of these processes will affect the degree and nature of chemical variations found in individual pyroclastic deposits. Their effects may be largely overcome by sampling coarse tephra within a narrow grain-size range.