An engineering geological appraisal of the Lakhwar Dam, Garhwal Himalaya, India

A 204 m high solid concrete gravity dam is proposed across the River Yamuna in Garhwal Himalaya, India. It will be located on dolerite rocks which have been intruded into the slates of Chandpur Formation. The present study includes the evaluation of the dam foundation by means of drifts, drill holes, water pressure tests and abutment slope stability studies. The water pressure test indicate the necessity of providing a grout curtain below the dam foundation. The analysis of the dam abutments for stability using the Limit equilibrium method indicates that the right abutment slope is kinematically unstable for plane failure mode. The plane failure analysis of the right abutment slope was carried out by modifying the Hoek and Bray (1981, Rock Slope Engineering, 3rd ed., Institute of Mining and Metallurgy, London) technique of plane failure analysis. The analysis reveals that right abutment slope may become unstable during the stripping operation. Based upon the analysis a safe cut slope design for the abutments have been suggested. Subsurface exploration by means of cross drift and drill holes has indicated a sheared contact of slate and dolerite in the foundation area. To avoid the settlement of the dam along this shear zone precautionary measures are suggested.     

Seismic hazard analysis for critical infrastructures in California

California is in a highly seismically active region, and structures must be designed and constructed to withstand earthquakes. Seismic hazard analysis to estimate realistic earthquake ground motions and surface fault rupture offsets is done for various mitigation measures. The best policy is to avoid constructing structures crossing seismogenic faults. Because earthquake timings are unpredictable within our current understanding, the best method is time-invariant deterministic seismic hazard analysis (DHSA) to assess effects from the largest single earthquake called Maximum Credible Earthquake (MCEs) expected from seismogenic faults. Time-dependent hazard estimates such as those arrived at through probabilistic seismic hazard analysis (PSHA) are inherently unreliable. Hazard analyses based on MCEs have been in continuous use for the design and construction of highways and bridges in California for over 30 years.

This paper presents an alternative to other methods of analysis, e.g., Abrahamson (2000) [Abrahamson, N.A., 2000. State of the practice of seismic hazard evaluation. Melbourne: proceedings of GeoEng, 2000].     

Sea-level changes, geoid and gravity anomalies due to Pleistocene deglaciation by means of multilayered, analytical Earth models

A new class of analytical, multilayered, viscoelastic Earth models based on PREM, with an incompressible, linear, viscoelastic Maxwell rheology, is applied to the modeling of global sea-level changes due to Pleistocene deglaciation. Until now, analytical schemes based on normal mode theory, have dealt with at most five layers, an elastic lithosphere, a three layered mantle including a transition zone, and a core (Spada et al., 1992. Geophys. J. Int. 109, 683–700). The novelty of our approach, used for the first time in sea-level studies, stands on an analytical scheme that can reproduce continuous elastic and rheological stratification when a sufficient number of layers is taken into account. We specifically assess the importance of our results for the Gravity Field and Steady-State Ocean Circulation Explorer (GOCE) satellite mission. GOCE will resolve the gravity field with a spatial resolution (half-wavelength) of 75 km and amplitude of 1.5 mgal, with a uniform coverage over the Earth, including presently unsurveyed, remote areas. Our models lead to post-glacial rebound induced free air gravity anomalies of a few mgals peak-to-peak in the harmonic degree range l=80–200, which will be discernible by GOCE. This finding demonstrates that post-glacial rebound has a high frequency component in the gravity field that can in principle be resolved by high resolution gravity satellite missions. We show that post-glacial rebound can contribute a substantial fraction to present-day sea-level variations and point out that for the Mediterranean Sea they are of the same order of magnitude as those induced by tectonic processes.     

Problems in the application of the SSHAC probability method for assessing earthquake hazards at Swiss nuclear power plants

From 2000 to 2004 a large scale probabilistic seismic hazard analysis (PEGASOS) was created and performed as a research project, sponsored by the Swiss NPP utilities to improve the assessment methodology for seismic risk in support of the plant-specific seismic PRAs. The project followed the methodology of the SSHAC [Senior Seismic Hazard Analysis Committee (SSHAC), 1997. Recommendations for Probabilistic Seismic Hazard Analysis: Guidance on Uncertainty and Use of Experts. NU-REG/CR-6372] procedures at its most elaborate way—level 4. Before practical implementation was to occur, a detailed review was performed including validation tests and analysis of uncertainty propagation. This paper presents the main results of the review. The review revealed that current PSHA (Probabilistic Seismic Hazard Analysis) methodology as based on logic trees, in conjunction with the SSHAC procedures, potentially leads to a significant overestimation of the seismic hazard in areas with low seismic activity due to the inherent possibilities of unconstrained accumulation of uncertainties. The preliminary results of the project did not pass any of our logical geological–scientific benchmark tests used in our attempts to perform a validation process of the PEGASOS analysis method. Some of the problems encountered are of generic nature and shall be studied carefully before making the decision of whether or not the Swiss nuclear power industry will adopt the recommended use of SSHAC-procedures as a basis for the evaluation of the seismic hazard for individual nuclear power plant seismic PRA without correction.     

Sm–Nd geochronology and petrography of garnet pyroxene granulites in the northern Sulu region of China and their geotectonic implication

Abundant garnet-bearing granulite lenses are widely distributed in the northern part of the Sulu region and adjacent areas. They are possibly re-metamorphosed high-pressure metamorphic rocks. On the basis of detailed petrographic study, samples WD01, WD04 and ML06 from Laixi and Wendeng were identified as high-pressure granulites, and WH1 from Weihai as an original coesite-bearing eclogite. Three high-pressure granulite samples give mineral-WR isochron ages of 1846±76, 1743±79 and 1752±30 Ma. TDM ages are 3.3, 3.0 and 2.8 Ga. The Sm–Nd mineral-WR isochron ages are interpreted to date as the metamorphic resetting within the medium-pressure granulite facies, representing an isotopic re-homogeneity during uplifting of the high-pressure granulites from deep continent crust. It is important that Sm–Nd chronological characteristics are the same as Archaean high-pressure granulites in the North China craton. However, sample WH1 from Weihai demonstrates abnormal Sm–Nd characteristics. Its whole rock _Nd (0) value is +129. TDM age is 1.3 Ga, and constrains the minimum age of re-metamorphosed eclogite protolith formation to the mid-Proterozoic. This result is identical to those reported by Jahn (1994), showing complicated processes of metamorphism and metasomatism. The data in this paper provide further evidence to define the boundary between the North China craton and UHPM belt in eastern Shandong and to understand the geotectonic nature of the boundary.     

Origin of micro-layering in a deep magma chamber: Evidence from two ultramafic–mafic layered xenoliths from Puy Beaunit (French Massif Central)

The origin of magmatic layering is still hotly debated. To try to shed some light on this problem, two ultramafic–mafic layered xenoliths from Puy Beaunit (French Massif Central) were investigated in detail. The nodules belong to a stratiform intrusion emplaced in the deep crust during the Permian (257 ± 6 Ma; Féménias, O., Coussaert, N., Bingen, B., Whitehouse, M., Mercier, J.-C., Demaiffe, D., 2003. A Permian underplating event in late- to post-orogenic tectonic setting. Evidence from the mafic–ultramafic layered xenoliths from Beaunit (French Massif Central). Chem. Geol. 199 293–315.). The 3 to 5 cm thick nodules have, in common, a central orthopyroxenite layer; the succession of layers is, respectively, norite–orthopyroxenite–norite (PBN 00-01) and norite–orthopyroxenite–harzburgite (PBN 00-03). The variations of both major (by electron microprobe) and trace, essentially the RE, elements (by LA-ICP-MS) were measured in major mineral phases (orthopyroxene, clinopyroxene, plagioclase, spinel) along cross-section perpendicular to the layering. Strong grain size, chemical and textural variations occur along these sections: they can be continuous or discontinuous, symmetrical or asymmetrical. Such complex variations cannot be solely related to a single magmatic history (fractional crystallisation, mineral sorting). Other processes such as element enrichment by residual liquid channelling along layer boundaries and/or sub-solidus recrystallisation and element redistribution must be invoked. It appears, in particular, that element distribution in the central orthopyroxenite layer could result from the injection of micro-sills of orthopyroxene-rich liquid between previously consolidated layers.     

Geochemistry of cumulates from the Bjerkreim–Sokndal layered intrusion (S. Norway) Part II. REE and the trapped liquid fraction

Rare earth elements in bulk cumulates and in separated minerals (plagioclase, apatite, Ca-poor and Ca-rich pyroxenes, ilmenite and magnetite) from the Bjerkreim–Sokndal layered intrusion (Rogaland Anorthosite Province, SW Norway) are investigated to better define the proportion of trapped liquid and its influence on bulk cumulate composition. In leuconoritic rocks (made up of plagioclase, Ca-poor pyroxene, ilmenite, ±magnetite, ±olivine), where apatite is an intercumulus phase, even a small fraction of trapped liquid significantly affects the REE pattern of the bulk cumulate, together with cumulus minerals proportion and composition. Contrastingly, in gabbronoritic cumulates characterized by the presence of cumulus Ca-rich pyroxene and apatite, cumulus apatite buffers the REE content. La/Sm and Eu/Eu* vs. P₂O₅ variations in leuconorites display mixing trends between a pure adcumulate and the composition of the trapped liquid, assumed to be similar to the parental magma. Assessment of the trapped liquid fraction in leuconorites ranges from 2 to 25% and is systematically higher in the north-eastern part of the intrusion. The likely reason for this wide range of TLF is different cooling rates in different parts of the intrusion depending on the distance to the gneissic margins. The REE patterns of liquids in equilibrium with primitive cumulates are calculated with mass balance equations. Major elements modelling (Duchesne, J.C., Charlier, B., 2005. Geochemistry of cumulates from the Bjerkreim–Sokndal layered intrusion (S. Norway): Part I. Constraints from major elements on the mechanism of cumulate formation and on the jotunite liquid line of descent. Lithos. 83, 299–254) permits calculation of the REE content of melt in equilibrium with gabbronorites. Partition coefficients for REE between cumulus minerals and a jotunitic liquid are then calculated. Calculated liquids from the most primitive cumulates are similar to a primitive jotunite representing the parental magma of the intrusion, taking into account the trapped liquid fraction calculated from the P₂O₅ content. Consistent results demonstrate the reliability of liquid compositions calculated from bulk cumulates and confirm the hypothesis that the trapped liquid has crystallized as a closed-system without subsequent mobility of REE in a migrating interstitial liquid.     

Flow rule effects in the Tresca model

The Tresca failure criterion is used regularly in geotechnical engineering to compute the failure loads of clay soils deforming under undrained conditions. When this criterion is used together with the finite element method a plastic flow rule must also be incorporated in the elasto-plastic soil model.

The effects of the flow rule on the performance of a non-linear analysis using an elastic perfectly plastic soil model obeying the Tresca failure criteria are discussed in this note. Application of this model in a three-dimensional analysis causes computational difficulties, due to the gradient discontinuities that exist at the corner of the Tresca yield surface. Such discontinuities can be removed from the yield (or failure) surface using different methods. Two of the most widely used methods in removing singularities from the yield surface and their overall performances in a three-dimensional finite element analysis are discussed.

The motivation for this study comes from a concern raised by Randolph and Puzrin [Randolph MF and Puzrin AM Upper bound limit analysis of circular foundations on clay under general loading. Geotechnique, (2003);53(9):785–796, [5]] about reported instances of under predictions of the collapse loads by finite element analysis [Taiebat HA and Carter JP Numerical studies of the bearing capacity of shallow foundations on cohesive soil subjected to combined loading. Geotechnique, (2000);50(4):409–418, [7]] and [Taiebat HA and Carter JP Bearing capacity of strip and circular foundations on undrained clay subjected to eccentric loads. Geotechnique, (2002);52(1):61–64, [8]], [Gourvenec S and Randolph M Effect of strength non-homogeneity on the shape of failure envelopes for combined loading of strip and circular foundations on clay, Geotechnique, (2003);53(6):575–586, [4]], when it is usually expected that finite element results should overestimate the true collapse loads. The intent of this study is to demonstrate and reiterate that although the finite element method is an extremely powerful analytical tool for solution of engineering problems, it is nevertheless subjected to approximation errors due to simplifications that are necessarily made to prevent other numerical difficulties.     

Two Neoarchean supercontinents? Evidence from the Paleoproterozoic

An unresolved question in Precambrian geology is the relationship between Archean crustal fragments that are now separated by younger orogens: were they once contiguous? Williams et al. (1991) proposed the name ‘Kenorland' for a speculative Neoarchean supercontinent comprising the Archean provinces in North America. Recently, a large number of ca. 2.5–2.0 Ga magmatic, metamorphic, detrital and xenocrystic ages have been reported from North America. We interpret that the wide geographic distribution and temporal spread of these ages may signify long-lived, regional-scale mantle upwelling, and anorogenic magmatic and metamorphic processes related to the protracted breakup of Kenorland. Breakup may have extended from ca. 2.5 to 2.1 Ga, culminating with dispersion of continental fragments at ca. 2.1–2.0 Ga. In North America, ca. 2.5–2.1 Ga intracratonic basin successions (e.g. Hurwitz Group) formed in the interior of Kenorland before dispersion, and passive margin sequences flanking the Superior Province (e.g. Huronian Supergroup) and the Wyoming Province (e.g. Snowy Pass Supergroup) defined the edges of Kenorland. Earliest Paleoproterozoic magmatic and sedimentary rocks, which include voluminous quartz arenites and glacigenic deposits, are consistent with a high-standing supercontinent and a mantle superplume. The Paleoproterozoic record from the Baltic and Siberian shields is similar to that of North America, suggesting inclusion in Kenorland. A slightly different record from the southern continents suggests a second, coexisting supercontinent that included the Zimbabwe, Kaapvaal, and Pilbara cratons, (‘Zimvaalbara' of I.G. Stanistreet), the São Francisco Craton, and possibly, cratonic blocks in India. Attenuation of this second supercontinent started earlier than in Kenorland (ca. 2.65 Ga) and was accompanied by high sea level and deposition of vast Lake Superior-type iron formations. Immediately thereafter, both supercontinents became emergent and were subject to global cooling and glaciation.     

Comparative study of the kinetics and mechanisms of dissolution of carbonate minerals

The influence of pH on the rate of dissolution of various carbonates (calcite, aragonite, witherite, magnesite and dolomite) has been investigated at 25°C using a continuous fluidized bed reactor. The general rate dependence on pH observed for the simple carbonates is very similar and is in agreement with the results observed for calcite and aragonite by L.N. Plummer and coworkers. However, the rate of dissolution of magnesite is approximately four orders of magnitude lower than calcite.

For simple carbonates, the elementary steps involved in the dissolution reaction are:

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where M represents the metal ion which can be Ca, Mg and Ba. According to the stoichiometry of the three reaction steps and the thermodynamic constraints, the total forward and backward rates can be expressed as:

R_f=k₁a_H+k₂a_H2CO3^*+K₃

r_b=k_-1^aM²+^aHCO₃^-+k_-2^aHCO3^-+k_{-3^aM²+^aCO3^2-}

The rate constants (k₁, k₂, k₃ and k₋₃) determined with our experimental results for calcite, aragonite and witherite show that the dissolution rates are similar for these three minerals and that the nature of the cations does not play a significant role. The good agreement between the K_sp calculated from the measured k₃/k₋₃ ratio and the theromodynamic value suggests that our dissolution mechanism is coherent.

The rate dependence on pH of the dissolution of dolomite obeys a fractional order at low pH's and confirms previously published observations therein. However, the two-step reaction mechanism proposed does not explain the fractional reaction order observed, which is likely due to a more complex surface reaction.     

Permeability of compacted granule–clay mixtures

Achieving a sufficiently low permeability for the aggregate-clay mixtures, whether used as the core of embankment dam or soil liner, is essential. The study illustrates the role of granule (bead or aggregate) content and size, confining stress and fabric anisotropy on the permeability of ceramic bead–lean clay and aggregate-fat clay mixtures. It is shown that depending on the plasticity of the clay, the permeability may decrease or increase with bead/aggregate content. The permeability also decreases when either granule size or confining stress increases. It is found that the permeability is affected by fabric anisotropy in such a manner that its value in the horizontal direction (k_h) is more than that in the vertical direction (k_v), however, k_h/k_v decreases towards 1 for bead contents equal to or below 40%. In high bead content mixtures (i.e., 60% beads) k_h/k_v reaches as high as 3 with an increase in the confining stress. The concept of the development of heterogeneous field of density in the clay is also used to demonstrate the impact of granule size and fabric anisotropy on the permeability.     

东疆白石头泉含黄玉天河石花岗岩体的地球化学：分带和岩浆演化

白石头泉含黄玉的天河石花岗岩体Rb-Sr等时线年龄209.6±9.6 Ma，从下至上可分为5个连续过渡的岩相带，即淡色花岗岩（a带），含天河石花岗岩（b带），天河石花岗岩（c带），含黄玉天河石花岗岩（d带）以及黄玉钠长花岗岩（e带）。岩体的岩石地球化学特征是高F（> 2 %）、高 Rb (500×10-6～1 087×10-6)，低 P2O5 (≤0.06%)，Na2O>K2O，弱过铝 (A/NKC=1.00~1.11)、翼型稀土元素配分曲线 (ΣREE=28.6×10-6~231.9×10-6)、低(La/Lu)N值 (0.11~0.68)、强烈Eu负异常(Eu/Eu* = 0.0005~0.0110)、Nd同位素富集（εNd (t )= -4.4~-4.9）。该岩体的岩浆是中地壳云母片麻岩部分熔融的产物。从a带到e带的地球化学变化是：（1）F，A2O3和Na2O含量逐渐增加，而SiO2，（Fe2O3+FeO+MgO+MnO）、FeO和K2O含量逐渐减少，在标准矿物的Qz-Ab-Or图上总体向Ab角顶移动；（2）总体而言，Cr，Ni，Co，V，W，Nb，Zr，U，Th和Y含量逐渐减少，而F，Li，Rb，Hf，Ta，Sn，Sc，Ga和Zn含量逐渐增加，但d带到e带间存在Li，Rb，Sn，Sc和Zn含量的突降；（3）K/Rb，Al/Ga，Nb/Ta和Zr/Hf值下降， 但K/Cs，Th/U，(La/Lu)N值上升；（4）全岩的δ18O 值从a带的9.25 ‰~9.75 ‰降低到e带的7.32 ‰，d带与e带间存在2.1‰的δ18O值突降。岩浆从a带到e带的垂向分带是分离结晶和流体输运的共同结果。岩体的d带与e带存在明显的成分间断。在矿物成分上表现为黄玉、钠长石和白云母的剧增，钾长石和天河石的剧减。在主量元素上表现为 Na2O和CaO含量的剧增，SiO2和K2O含量的剧减。在微量元素上表现为F，Ga，Sr和Ba含量的剧增，Li，Rb，Sc，Zn和Sn含量的剧减。在稀土元素上，Eu/Eu*和(La/Lu)N值增加，而ΣREE值降低。在氧同位素特征上，δ18O值显著降低。这种间断不仅受分离结晶和流体输运的制约，也与天水加入、围岩混染和亚固相线淋滤有关。     

Geochemical Charactristics and Genesis of Topaz—Bearing Porphyries in Yangbin Area of Taishun County,Zhejiang Province

The host rocks of the porphyry tin deposits in the Yangbin area are principally topaz-bearing porphyry dikes about 2 km long and 2–20m wide. Three lithologie types are identified for the dikes: topaz-bearing potassium feldspar granitic porphyry, topaz-bearing monzonitic granitic porphyry and topaz-bearing quartz porphyry. The content of topaz in the rocks ranges from 10 to 20 vol.%. Porphyritic texture is characteristic, with quartz, potassium feldspar and albite as main phenocryst minerals. The phenocryst occupies 10–20 vol% of the rocks. The rock groundmass consists of subhedral topaz, quartz and protolithionite. Topaz has a unit-cell parameter b=8.797 (Å), and F:OH=1.92:0.18, indicating a F-rich variety formed at high temperature. The topaz-bearing porphyries occurring in this area are strongly peraluminous (A/NKC=1.574–12.94), with high ratios of F/Cl (146–303) and Rb/Sr (5–122). They are rich in incompatible elements (Sn, 313 × 10^?6–1042 × 10^?6; W, 6 × 10^?6–218 × 10^?6; Nb, 27 × 10^?6–54 × 10^?6), but poor in compatible elements (Sr, 10 × 10^?6–28 × 10^?6; Ba, 58 × 10^?6–73 × 10^?6; V, 3 × 10^?6–12 × 10^?6, Cl, 150 × 10^?6–226 × 10^?6). The rocks are also characterized by high total REE amount (281.69 × 10^?6–319.76 × 10^?6), with strong Eu depletion (δEu=0.01–0.03) and low ratio of LREE/HREE (0.78–0.84). In summary, the authors propose an idea of S-type genesis for the topaz-bearing porphyries with tin mineralization, instead of I-type.     

Provenance analysis and tectonic setting of the Ordovician clastic deposits in the southern Puna Basin, NW Argentina

Provenance studies on Early to Middle Ordovician clastic formations of the southern Puna basin in north-western Argentina indicate that the sedimentary detritus is generally composed of reworked crustal material. Tremadoc quartz-rich turbidites (Tolar Chico Formation, mean composition Q_t89 F7 L4) are followed by volcaniclastic rocks and greywackes (Tolillar Formation, mean Q_t33 F42 L25). These are in turn overlain by volcaniclastic deposits (mean Q_t24 F30 L46) of the Diablo Formation (late Arenig–early Llanvirn) that are intercalated by lava flows. All units were deformed in the Oclóyic Orogeny during the Middle and Late Ordovician. Sandstones of the Tolar Chico Formation are characterized by Th/Sc ratios > 1, La/Sc ratios ≈ 10, whereas associated fine-grained wackes show slightly lower values for both ratios. LREE (light rare earth elements) enrichment of the arenites is ≈ 50× chondrite, Eu/Eu* values are between 0·72 and 0·92, and flat HREE (heavy rare earth elements) patterns indicate a derivation from mostly felsic rocks of typical upper crustal composition. The ε_{Nd(t = sed)} values scatter around −11 to −9. The calculated Nd-T_DM residence ages vary between 1·8 and 2·0 Ga indicating contribution by a Palaeoproterozoic crustal component. The Th/Sc and La/Sc ratios of the Tolillar Formation are lower than those of the Tolar Chico Formation. Normalized REE (rare earth elements) patterns display a similar shape to PAAS (post-Archaean average Australian shale) but with higher abundances of HREEs. Eu/Eu* values range between 0·44 and 1·17, where the higher values reflect the abundance of plagioclase and feldspar-bearing volcanic lithoclasts. Average ε_{Nd(t = sed)} values are less negative at −5·1, and Nd-T_DM are lower at 1·6 Ga. This is consistent with characteristics of regional rocks of upper continental crust composition, which most probably represent the sources of the studied detritus. The rocks of the Diablo Formation have the lowest Th/Sc and La/Sc ratios, lower LREE abundances than the average continental crust and are slightly enriched in HREEs. Eu/Eu* values are between 0·63 and 1·17. The Nd isotopes (ε_{Nd(t = sed)} = −3 to −1; T_DM = 1·2 Ga) indicate that one source component was less fractionated than both the underlying Early Ordovician and the overlying Middle Ordovician units. Synsedimentary vulcanites in the Diablo Formation show the same isotopic composition. Our data indicate that the sedimentary detritus is generally composed of reworked crustal material, but that the Diablo Formation appears to contain ≈ 80% of a less fractionated component, derived from a contemporaneous continental volcanic arc. There are no data indicating an exotic detrital source or the accretion of an exotic block at this part of the Gondwana margin during the Ordovician.     

Composition and age of tertiary sills and dykes, Jameson Land Basin, East Greenland: relation to regional flood volcanism

The Paleozoic–Mesozoic Jameson Land Basin (East Greenland) is intruded by a sill complex and by a swarm of ESE trending dykes. Together with dykes of the inner Scoresby Sund fjord, they form a regional Early Tertiary intrusive complex located 200–400 km inland of the East Greenland rifted continental margin. Most of the intrusive rocks in the Jameson Land Basin are geochemically coherent and consist of evolved plagioclase–augite–olivine saturated, uncontaminated high-Ti basalt with 48.5–50.2 wt.% SiO₂, 2.2–3.2 wt.% TiO₂, 5.1–7.4 wt.% MgO, 9–17 ppm Nb and La/Yb_N=2.8–3.6. Minor tholeiitic rock types are: (a) low-Ti basalt (49.7 wt.% SiO₂, 1.7 wt.% TiO₂, 6.8 wt.% MgO, 2.6 ppm Nb and La/Yb_N=0.5) akin to oceanic basalts; (b) very-high-Ti basalt (48.6 wt.% SiO₂, 4.1 wt.% TiO₂, 5.1 wt.% MgO and 21 ppm Nb); and (c) plagioclase ultraphyric basalt. The tholeiitic dolerites are cut by alkali basalt (43.7–47.3 wt.% SiO₂, 4.1–5.1 wt.% TiO₂, 4.9–6.2 wt.% MgO, 29–46 ppm Nb and La/Yb_N=16–17) sills and dykes.Modelling of high-field-strength and rare-earth elements indicate that the high-Ti basalts formed from 6–10% melting of approximately equal proportions of garnet- and spinel-bearing mantle of slightly depleted composition beneath thick continental lithosphere. Conversely, dolerite intrusions and flood basalts of similar compositional kindred from adjacent but more rift-proximal occurrences in Northeast Greenland formed from shallower melting of dominantly spinel-bearing mantle beneath extended and thinned continental lithosphere. These variations in lithospheric thickness suggest the continent–ocean transition of the East Greenland rifted volcanic margin is sharp and narrow.⁴⁰Ar–³⁹Ar dating and paleomagnetism show that the high-Ti dolerites were emplaced at 53–52 Ma (most likely during C23r) and hence surprisingly postdate the main flood volcanism by 2–5 Ma and the inception of seafloor spreading between Greenland and Europe by 1–2 Ma. The formation of tholeiitic and alkaline magmas emplaced into the Jameson Land Basin corroborates to the importance of post-breakup magmatism along the East Greenland volcanic rifted margin. Upwelling of the ancestral Iceland mantle plume under central Greenland at 53–52 Ma (rather than under the active rift), perhaps accompanied by a failed attempt to shift the rift zone westward towards the plume axis, may have triggered post-breakup continental magmatism of the Jameson Land Basin and the inner Scoresby Sund region, along preexisting structural lineaments.