Microaerobic iron oxidation and carbon assimilation and associated microbial community in paddy soil

Iron oxidation is a prevalent and important biogeochemical process in paddy soil,but little is known about whether and how microbially mediated iron oxidation is coupled with carbon assimilation,particularly under microaerobic conditions.Here,we investigated kinetics of CO_2 assimilation and Fe(Ⅱ)oxidation in an incubation experiment with paddy soil under suboxic conditions,and profiled the associated microbial community using DNA-stable isotope probing and 16S r RNA gene-based sequencing.The results showed that CO_2 assimilation and Fe(II)oxidation in the gradient tubes were predominantly mediated by the microbes enriched in the paddy soil,primarily Azospirillum and Magnetospirillum,as their relative abundances were higher in the~( 13)C heavy fractions compared to~( 12)C heavy fractions.This study provided direct evidence of chemoautotrophic microaerophiles linking iron oxidation and carbon assimilation at the oxic–anoxic interface in the paddy soil ecosystem.     

Net ecosystem CO_2 exchange and controlling factors in a steppe——Kobresia meadow on the Tibetan Plateau

Knowledge of seasonal variation of net ecosystem CO2 exchange (NEE) and its biotic and abiotic controllers will further our understanding of carbon cycling process, mechanism and large-scale modelling. Eddy covariance technique was used to measure NEE, biotic and abiotic factors for nearly 3 years in the hinterland alpine steppe--Korbresia meadow grassland on the Tibetan Plateau, the present highest fluxnet station in the world. The main objectives are to investigate dynamics of NEE and its components and to determine the major controlling factors. Maximum carbon assimilation took place in August and maximum carbon loss occurred in November. In June, rainfall amount due to monsoon climate played a great role in grass greening and consequently influenced interannual variation of ecosystem carbon gain. From July through September, monthly NEE presented net carbon assimilation. In other months, ecosystem exhibited carbon loss. In growing season, daytime NEE was mainly controlled by photosynthetically active radiation (PAR). In addition, leaf area index (LAI) interacted with PAR and together modulated NEE rates. Ecosystem respiration was controlled mainly by soil temperature and simultaneously by soil moisture. Q10 was negatively correlated with soil temperature but positively correlated with soil moisture. Large daily range of air temperature is not necessary to enhance carbon gain. Standard respiration rate at referenced 10℃(R10) was positively correlated with soil moisture, soil temperature, LAI and aboveground biomass. Rainfall patterns in growing season markedly influenced soil moisture and therefore soil moisture controlled seasonal change of ecosystem respiration. Pulse rainfall in the beginning and at the end of growing season induced great ecosystem respiration and consequently a great amount of carbon was lost. Short growing season and relative low temperature restrained alpine grass vegetation development. The results suggested that LAI be usually in a low level and carbon uptake be relatively low. Rainfall patterns in the growing season and pulse rainfall in the beginning and at end of growing season control ecosystem respiration and consequently influence carbon balance of ecosystem.     

Carbon isotope fractionation during CH4 transport in paddy fields

In this study,to further promote the application of the stable carbon isotope natural abundance(SCINA)method to the study of CH4in paddy fields in China,field experiments were carried out to investigate carbon isotope fractionation during CH4transport in both rice-and non-rice-growing seasons.More importantly,two new methods for the measurement of the CH4transport fractionation factor(εtransport)in paddy fields were introduced.The results indicated that the closed chamber+syringe method was much better for the determination ofεtransport during the non-rice-growing season.Presently,εtransport was calculated using theδ13C value of the CH4emitted from a rice field minus that of the CH4in the floodwater(–6.7‰to–3.0‰).In addition,there were three methods available for estimatingεtransport during the rice-growing season:deduction of theδ13C value of the CH4in the floodwater from that of the CH4emitted from the field(–16.6‰to–15.2‰);deduction of theδ13C value of the CH4in the soil pore water from that of the CH4emitted from the field(–13.2‰to–1.1‰);and deduction of theδ13C value of the CH4in the aerenchyma of plants from that of the CH4emitted from plants(–16.3‰to–10.9‰).Unfortunately,the first two methods showed relatively large uncertainties.Only the last one,the dividing+cutting method,was not only scientific and reliable but also provided accurate measurements.     

Effect on greenhouse gas balance of converting rice paddies to vegetable production

Rice paddies are increasingly being converted to vegetable production due to economic benefits related,in part,to changes in demand during recent decades.Here,we implemented a parallel field experiment to simultaneously measure annual emissions of CH_4and N_2O,and soil organic carbon(SOC)stock changes,in rice paddies(RP),rice paddy–converted conventional vegetable fields(CV),and rice paddy–converted greenhouse vegetable fields(GV).Changing from rice to vegetable production reduced CH_4emissions by nearly 100%,and also triggered substantial N_2O emissions.Furthermore,annual N_2O emissions from GV significantly exceeded those from CV due to lower soil p H and higher soil temperature.Marginal SOC losses occurred after one year of cultivation of RP,CV,and GV,contributing an important share(3.4%,32.2%,and 10.3%,respectively)of the overall global warming potential(GWP)balance.The decline in CH_4emissions outweighed the increased N_2O emissions and SOC losses in CV and GV,leading to a 13%–30%reduction in annual GWP as compared to RP.These results suggest that large-scale expansion of vegetable production at the expense of rice paddies is beneficial for mitigating climate change in terms of the overall GWP.     

Quantifying the carbon source of pedogenic calcite veins in weathered limestone: implications for the terrestrial carbon cycle

The continent is the second largest carbon sink on Earth’s surface.With the diversification of vascular land plants in the late Paleozoic,terrestrial organic carbon burial is represented by massive coal formation,while the development of soil profiles would account for both organic and inorganic carbon burial.As compared with soil organic carbon,inorganic carbon burial,collectively known as the soil carbonate,would have a greater impact on the long-term carbon cycle.Soil carbonate would have multiple carbon sources,including dissolution of host calcareous rocks,dissolved inorganic carbon from freshwater,and oxidation of organic matter,but the host calcareous rock dissolution would not cause atmospheric CO2drawdown.Thus,to evaluate the potential effect of soil carbonate formation on the atmospheric p CO2level,different carbon sources of soil carbonate should be quantitatively differentiated.In this study,we analyzed the carbon and magnesium isotopes of pedogenic calcite veins developed in a heavily weathered outcrop,consisting of limestone of the early Paleogene Guanzhuang Group in North China.Based on the C and Mg isotope data,we developed a numerical model to quantify the carbon source of calcite veins.The modeling results indicate that4–37 wt%of carbon in these calcite veins was derived from atmospheric CO2.The low contribution from atmospheric CO2might be attributed to the host limestone that might have diluted the atmospheric CO2sink.Nevertheless,taking this value into consideration,it is estimated that soil carbonate formation would lower 1 ppm atmospheric CO2within 2000 years,i.e.,soil carbonate alone would sequester all atmospheric CO2within 1 million years.Finally,our study suggests the C–Mg isotope system might be a better tool in quantifying the carbon source of soil carbonate.     

Migration and enrichment of trace elements of Lower Palaeozoic carbonate rock strata in Beijing

Analyses of trace elements of the Lower Palaeozoic carbonate rock strata in Beijing show that the contents of As, Hg, F increase from primary carbonate rocks to weathered carbonate rocks and from primary carbonate rocks to the soil coexisting with carbonate rocks, but the distribution regularity of S is not obvious. In the whole weathered stages, the sorption of As is mainly affected by Fe2O3. In soil Fe2O3 is also the main affecting factor of Hg enrichment. The main existing forms of Hg in primary carbonate rocks should simply be physical adsorption, coprecipitation and false isomorphous form between surface of carbonate rock and Hg. In soil the enrichment of F has little relationship with sul-fides and Fe2O3. In primary carbonate rocks, F is mainly absorbed by sulfides and clay minerals, etc. Weathered samples have closer genetic relationships with primary carbonate rocks. This also implies that weathered carbonate rocks have the close existing forms to that of primary carbonate rocks. In primary carbonate rocks FeS2 and FeS are the main forms of S, and sulfides have fixation effect on some heavy metals, whereas in weathered carbonate rocks and soil the fixation effect is weakened.     

Study of oxygen fugacity during magma evolution and ore genesis in the Hongge mafic–ultramafic intrusion,the Panxi region,SW China

Economic concentrations of Fe–Ti oxides occurring as massive layers in the middle and upper parts of the Hongge intrusion are different from other layered intrusions(Panzhihua and Baima) in the Emeishan large igneous province, SW China. This paper reports on the new mineral compositions of magnetite and ilmenite for selected cumulate rocks and clinopyroxene and plagioclase for basalts. We use these data to estimate the oxidation state of parental magmas and during ore formation to constrain the factors leading to the abundant accumulation of Fe–Ti oxides involved with the Hongge layered intrusion. The results show that the oxygen fugacities of parental magma are in the range of FMQ-1.56 to FMQ+0.14, and the oxygen fugacities during the ore formation of the Fe–Ti oxides located in the lower olivine clinopyroxenite zone(LOZ) and the middle clinopyroxenite zone(MCZ) of the Hongge intrusion are in the range of FMQ-1.29 to FMQ-0.2 and FMQ-0.49 to FMQ+0.82, respectively.The MELTS model demonstrates that, as the oxygen fugacity increases from the FMQ-1 to FMQ+1, the proportion of crystallization magnetite increases from 11 % to 16 % and the crystallization temperature of the Fe–Ti oxides advances from 1134 to 1164 °C. The moderate oxygen fugacities for the Hongge MCZ indicate that the oxygen fugacity was not the only factor affecting the crystallization of Fe–Ti oxides. We speculated that theinitial anhydrous magma that arrived at the Hongge shallow magma chamber became hydrous by attracting the H_2O of the strata. In combination with increasing oxygen fugacities from the LOZ(FMQ-1.29 to FMQ-0.2) to the MCZ(FMQ-0.49 to FMQ+0.82), these two factors probably account for the large-scale Fe–Ti oxide ore layers in the MCZ of the Hongge intrusion.     

Spatiotemporal dynamic simulation of grassland carbon storage in China

Based on the Terrestrial Ecosystem Model(TEM 5.0), together with the data of climate(temperature, precipitation and solar radiation) and environment(grassland vegetation types, soil texture, altitude, longitude and latitude, and atmospheric CO2 concentration data), the spatiotemporal variations of carbon storage and density, and their controlling factors were discussed in this paper. The results indicated that:(1) the total carbon storage of China's grasslands with a total area of 394.93×104 km2 was 59.47 Pg C. Among them, there were 3.15 Pg C in vegetation and 56.32 Pg C in soil carbon. China's grasslands covering 7.0–11.3% of the total world's grassland area had 1.3–11.3% of the vegetation carbon and 9.7–22.5% of the soil carbon in the world grasslands. The total carbon storage increased from 59.13 to 60.16 Pg C during 1961–2013 with an increasing rate of 19.4 Tg C yr~(-1).(2) The grasslands in the Qinghai-Tibetan Plateau contributed most to the total carbon storage during 1961–2013, accounting for 63.2% of the total grassland carbon storage, followed by Xinjiang grasslands(15.8%) and Inner Mongolia grasslands(11.1%).(3) The vegetation carbon storage showed an increasing trend, with the average annual growth rate of 9.62 Tg C yr~(-1) during 1961–2013, and temperature was the main determinant factor, explaining approximately 85% of its variation. The vegetation carbon storage showed an increasing trend in most grassland regions, however, a decreasing trend in the central grassland in the southern China, the western and central parts of the Inner Mongolian grasslands as well as some parts on the Qinghai-Tibetan Plateau. The soil carbon storage showed a significantly increasing trend with a rate of 7.96 Tg C yr~(-1), which resulted from the interaction of more precipitation and low temperature in the 1980 s and 1990 s. Among them, precipitation was the main determinant factor of increasing soil carbon increases of China's grasslands.     

Characterizing the dynamics of soil organic carbon in grasslands on the Qinghai-Tibetan Plateau

Carbon dynamics of grasslands on the Qinghai-Tibetan Plateau may play an important role in regional and global carbon cycles. The CENTURY model (Version 4.5) is used to examine temporal and spatial variations of soil organic carbon (SOC) in grasslands on the Plateau for the period from 1960 to 2002. The model successfully simulates the dynamics of aboveground carbon and soil surface SOC at the soil depth of 0-20 cm and the simulated results agree well to the measurements. Examination of SOC for eight typical grasslands shows different patterns of temporal variation in different ecosystems in 1960-2002. The extent of temporal variation increases with the increase of SOC of ecosystem. SOC increases first and decreases quickly then during the period from 1990 to 2000. Spatially, SOC density obtained for the equilibrium condition declines gradually from the southeast to the northwest on the plateau and showed a high heterogeneity in the eastern plateau. The results suggest that (i) SOC den-sity in the alpine grasslands shows remarkable response to climate change during the 42 years, and (ii) the net carbon exchange rate between the alpine grassland ecosystems and the atmosphere increases from 1990 to 2000 as compared with that before 1990.     

Development of a daily soil moisture product for the period of2002–2011 in Chinese mainland

Soil moisture is an essential climate variable(ECV) concerned widely. Due to its high spatial variability, it is costly to measure soil moisture at tens of kilometers scale. In this study, a ten-year(2002–2011) daily soil moisture dataset at 0.25° spatial resolution for Chinese mainland was produced through assimilating the Advanced Microwave Scanning Radiometer for Earth Observing System(AMSR-E) brightness temperature(TB) data into a land surface model(LSM). The obtained soil moisture data was evaluated against soil moisture-measuring networks deployed in two wet areas and one dry area of the Tibetan Plateau.The results show that for the wet areas the accuracy of the soil moisture product obtained from the assimilation is considerably higher than that of both AMSR-E official soil moisture products and land surface simulation results, and for the dry area their accuracy is comparable to each other. The spatial pattern of the soil moisture from the new product is consistent with that of soil porosity from an independent survey-based dataset, further confirming the credibility of the new product. According to this product, the transition regions in China show stronger seasonal variation of soil moisture than dry and wet regions, and drier regions have stronger inter-annual variability of soil moisture than wetter regions, particularly during transitional seasons(spring and autumn). The soil moisture product is accessible at the National Tibetan Plateau Data Center.     

头颈部CTA对茎突解剖的应用研究

目的:运用头颈部CTA对茎突的解剖进行研究。资料与方法:随机选取我院200例进行头颈部CTA检查的受试者,年龄范围21~82岁,平均年龄(57.38±9.99)岁。根据受试者年龄进行分组,A组<60岁,B组≥60岁。将原始数据传入GE AW 4.5工作站进行容积再现(VR),多平面重组(MPR)等后处理,观察颞骨茎突的形态,并分型;测量茎突的长度、内倾角、前倾角及茎突尖端与颈内外动脉之间的最短距离。结果:197例受试者茎突平均长度约为26.79 mm,内倾角约为21.07°,前倾角约为25.03°,茎突尖端与颈内动脉最短距离均值约为6.26 mm,与颈外动脉最短距离均值约为4.15 mm;茎突尖端与颈外动脉最短距离为0的有44个,占总数的11.2%。双侧茎突长度、内倾角、茎突尖端与颈外动脉最短距离及右侧前倾角性别差异具有统计学意义(P<0.05);内倾角、茎突尖端与颈外动脉最短距离左右侧差异具有统计学意义(P<0.05)。茎突分为4型,各型的比例分别为:完整型(71.75%),发育不良型(22.75%),分节型(4.25%)及未发育型(1.25%)。结论:头颈部CTA不仅能显示茎突的形态、测量茎突的长度、内倾角及前倾角,更能清晰显示茎突与颈内外动脉之间的关系,测量茎突尖端与动脉之间的最短距离,对临床诊断及治疗茎突相关疾病有一定指导及参考意义。      

Estimation for partially observed Markov processes

Many stochastic process models for environmental data sets assume a process of relatively simple structure which is in some sense partially observed. That is, there is an underlying process (X_n, n 0) or (X_t, t 0) for which the parameters are of interest and physically meaningful, and an observable process (Y_n, n 0) or (Y_t, t 0) which depends on the X process but not otherwise on those parameters. Examples are wide ranging: the Y process may be the X process with missing observations; the Y process may be the X process observed with a noise component; the X process might constitute a random environment for the Y process, as with hidden Markov models; the Y process might be a lower dimensional function or reduction of the X process. In principle, maximum likelihood estimation for the X process parameters can be carried out by some form of the EM algorithm applied to the Y process data. In the paper we review some current methods for exact and approximate maximum likelihood estimation. We illustrate some of the issues by considering how to estimate the parameters of a stochastic Nash cascade model for runoff. In the case of k reservoirs, the outputs of these reservoirs form a k dimensional vector Markov process, of which only the kth coordinate process is observed, usually at a discrete sample of time points.     

Estimation for partially observed Markov processes

Many stochastic process models for environmental data sets assume a process of relatively simple structure which is in some sense partially observed. That is, there is an underlying process (X_n, n 0) or (X_t, t 0) for which the parameters are of interest and physically meaningful, and an observable process (Y_n, n 0) or (Y_t, t 0) which depends on the X process but not otherwise on those parameters. Examples are wide ranging: the Y process may be the X process with missing observations; the Y process may be the X process observed with a noise component; the X process might constitute a random environment for the Y process, as with hidden Markov models; the Y process might be a lower dimensional function or reduction of the X process. In principle, maximum likelihood estimation for the X process parameters can be carried out by some form of the EM algorithm applied to the Y process data. In the paper we review some current methods for exact and approximate maximum likelihood estimation. We illustrate some of the issues by considering how to estimate the parameters of a stochastic Nash cascade model for runoff. In the case of k reservoirs, the outputs of these reservoirs form a k dimensional vector Markov process, of which only the kth coordinate process is observed, usually at a discrete sample of time points.     

地球化学动力学方法及其在地下流体地震前兆机理研究中的意义

地球化学动力学是继地球化学热力学之后发展起来的一门新兴地球化学分支学科。地球化学动力学包括两个方面的研究内容:一是地球化学反应动力学,如化学反应速度、各种条件对化学反应速率的影响及其化学反应机制;二是物理方面的运动学,如流体动力学、扩散、弥散及热传导等。其中在地球化学反应动力学方面,主要是水—岩反应化学动力学和同位素交换动力学,即对各种物质转换过程的研究。在流体动力学方面,主要是多孔介质中流体的运移及断裂对流体运移的控制作用,即对物质与能量的运输过程及其影响条件的研究。但自然界地球化学作用是转变过程和运输过程的耦合,化学反应是最主要的转变过程,流体流动是最主要的运输过程,所以把各种转变过程和运输过程结合起来,建立相互间的耦合关系,并通过数值计算模拟地下流体的真实行为,这就是研究地下流体的流—固耦合理论。地球化学动力学方法在地震前兆成因机理解释研究方面具有重要的理论指导意义。     

深源地震处理软件开发

为解决东北深震区的深震定位问题开发了相应软件,通过对东北地区以往深震处理的结果来看。效果较好。本文对该软件的开发和使用情况进行了介绍。     

用高台宽频带数字资料研究气流扰动对地脉动的干扰影响

通过对高台宽频带数字资料在数次冷空气过程时段地脉动幅度及频谱变化的分析,在时间域和频率域上研究冷空气过程的干扰特征,发现冷空气过程时段,地脉动记录曲线会出现大周期扰动或抖动式畸变;随着冷空气过程开始到结束,0.001~0.005 Hz的频幅最大值出现较大变化,进程上具有上升、达到最大值、逐渐回复的特征,降温幅度最大则扰动幅度达到最高值。     

Theory and application of nonlinear river dynamics

A theoretical model for river evolution including riverbed formation and meandering pattern formation is presented in this paper.Based on nonlinear mathematic theory,the nonlinear river dynamic theory is set up for river dynamic process.Its core content includes the stability and tropism characteristics of flow motion in river and river selves＇ evolution.The stability of river dynamic process depends on the response of river selves to the external disturbance,if the disturbance and the resulting response will eventually attenuate,and the river dynamics process can be restored to new equilibrium state,the river dynamic process is known as stable;otherwise,the river dynamic process is unstable.The river dynamic process tropism refers to that the evolution tendency of river morphology after the disturbance.As an application of this theory,the dynamical stability of the constant curvature river bend is calculated for its coherent vortex disturbance and response.In addition,this paper discusses the nonlinear evolution of the river peristaltic process under a large-scale disturbance,showing the nonlinear tendency of river dynamic processes,such as river filtering and butterfly effect.     

沉积盆地波动过程分析研究现状与发展趋势

沉积盆地波动过程分析方法是一种较新的盆地分析方法,该方法以物理学中有关波的理论为基础,以波动的观点来分析地壳运动,本文介绍了沉积盆地波动过程分析的基本概念、发展过程、方法原理、研究步骤,从含油气盆地分析的四个主要研究内容论述了波动过程分析法研究现状,并探讨了它的发展趋势.     

Estimation for rainfall-runoff modeled as a partially observed Markov process

Abstract: Linear continuous time stochastic Nash cascade conceptual models for runoff are developed. The runoff is modeled as a simple system of linear stochastic differential equations driven by white Gaussian and marked point process noises. In the case of d reservoirs, the outputs of these reservoirs form a d dimensional vector Markov process, of which only the dth coordinate process is observed, usually at a discrete sample of time points. The dth coordinate process is not Markovian. Thus runoff is a partially observed Markov process if it is modeled using the stochastic Nash cascade model. We consider how to estimate the parameters in such models. In principle, maximum likelihood estimation for the complete process parameters can be carried out directly or through some form of the EM (estimation and maximization) algorithm or variation thereof, applied to the observed process data. In this research we consider a direct approximate likelihood approach and a filtering approach to an algorithm of EM type, as developed in Thompson and Kaseke (1994). These two methods are applied to some real life runoff data from a catchment in Wales, England. We also consider a special case of the martingale estimating function approach on the runoff model in the presence of rainfall. Finally, some simulations of the runoff process are given based on the estimated parameters.     

Bio-reef-chert suite and superlarge ore deposits

The bio-reef-chert suite is an important ore-bearing rock assemblage and one of the metallogenic rock suites of superlarge ore deposits. It is formed as a fixed and ordered suite in space and time, and composed of different rocks formed by different geological processes. It is the product of basin evolution at special stage in a special geological setting. It is also the comprehensive product of normal sedimentary process, biological process in basin, hydrothermal sedimentary process under basin base and magmatic process in the deep lithosphere.