Foreslope stromatoporoid-renalcid bioherm with evidence of early cementation, Devonian Ancient Wall reef complex, Rocky Mountains

A small mound, 4 × 23 m in size, on the fore-reef slope of the Ancient Wall reef complex at Mount Haultain, Alberta, consists of fenestral, renalcid micrite and wackestone. Stromatoporoids are the most abundant skeletal component but do not form an organic framework. Renalcids, together with early micrite cementation, performed a supporting and stabilizing role but only rarely directly encrusted skeletal material. Many of the primary shelter voids, interparticle voids and fenestrae were filled with internal sediments and submarine micrite cements. A considerable proportion of the micrite matrix appears to be cement. The location and development of the bioherm was controlled by a local hard substrate and suitable environmental conditions. The mound developed on and around a large block within an underlying megabreccia bed soon after it was deposited in a debris flow on the fore-reef slope. It formed near wave base in about 30–50 m water depth and was subject to gentle current action. Laminar stromatoporoids grew on the flanks and top of the mound, and fenestral, renalcid micrite and wackestone accumulated in the central part. Deepening water and increased rates of mud accumulation terminated further build-up of the bioherm and it was buried by basin mud. Fenestral, renalcid micrite occurs in a number of Devonian and Lower Palaeozoic organic mounds. This study suggests that early, submarine cementation was a significant factor in the development and preservation of this distinctive lithotype.     

Simultaneous production of magnesium carbonate and calcium carbonate from dolomites and dolomitic limestones

By use of a recarbonation process, it is possible to separate magnesium carbonate and calcium carbonate from dolomites/dolomitic limestones. Magnesium carbonate can be used for manufacturing basic refractories and magnesium chemicals; the portion rich in calcium carbonate can be used for cement manufacture if the MgO content is below 3%. In this paper the process developed for the purpose and the results of bench scale tests are reported. The results indicate that, under optimum conditions, both objectives can be fulfilled by the recarbonation process.     

Magnesian calcite cements and their diagenesis: dissolution and dolomitization, Mururoa Atoll

The most ubiquitous syn-sedimentary cements affecting Mururoa atoll are composed of magnesian calcite. Three main types are distinguished: fibrous, bladed and sparitic on the basis of petrography, morphology and MgCO₃ concentration of the constituting crystals, while peloid infills, a particular form of HMC chemical precipitation, also exist. Petrographic evidence and isotopic signatures are compatible with marine precipitation. Mururoa atoll was exposed several times to meteoric diagenesis resulting in varied diagenetic alterations including selective dissolution and partial dolomitization of Mg-calcite cements. These alterations are responsible for substantial modifications of the initial cement fabrics and may introduce unconformities in the diagenetic chronology. The first stage of the partial dissolution of Mg-calcite induces the development of chalky, white friable zones within the initially crystalline, hard cement layers. At ultrascale, this is due to the creation of micro-voids along the elongate cement fibres. Advanced dissolution includes total disappearance of cement portions as attested to by large voids within the cement crust and/or between superposed cement layers. Mg-calcite dissolution is related to meteoric diagenesis during periods of Quaternary exposure. The creation of voids within Mg-calcite layers is due to the mechanical removal of previously altered calcium carbonate, a process suggesting marine or non-marine water flow, probably in the vadose environment. Selective dolomitization of Mururoa cements involves alternations of calcite and dolomite which form successive cement-like rinds within primary cavities. At Mururoa, these alternations are the result of selective dolomitization of the pre-existing Mg-calcite cements rather than successive precipitation of calcite and dolomite. Selective dolomitization of Mg-calcite cements at Mururoa indicates that a given cement succession is not necessarily a simple chronological sequence. Oxygen isotope values of dolomites are enriched in δ¹⁸6 by about 3‰ PDB within calcite-dolomite pseudo-alternations. The dolomitizing fluid at Mururoa seems similar to present marine water although some mixture with meteoric water is probable to favour dissolution associated with dolomitization.     

Rare earth elements in seep carbonates as tracers of variable redox conditions at ancient hydrocarbon seeps

Marine hydrocarbon seeps are dynamic systems, which are typically reflected in complex lithologies of limestones forming at these sites. In order to test if seep limestones with their multiple generations of carbonate phases reflect variable redox conditions, the rare earth element (REE) patterns of limestones from five ancient hydrocarbon-seep localities, Hollard Mound (Middle Devonian), Iberg (Mississippian), Beauvoisin (Oxfordian), Canyon and Satsop River (Oligocene), and Marmorito (Miocene) have been investigated. The total REE contents vary widely (0.3–43.7 p.p.m.). Early microcrystalline phases tend to show higher contents than spatially associated later phases (microspar, sparite, and blocky cement). The shale-normalized REE patterns of the carbonates show both negative and positive Ce anomalies even for individual deposits, suggesting that the redox conditions varied significantly. It is apparent that in addition to anoxic conditions, oxic conditions were common in some ancient seep environments. Intermittent oxygenation is presumed to have resulted from abrupt changes in fluid flow.     

Marine cements in mid-Tertiary cool-water shelf limestones of New Zealand and southern Australia

Large areas of southern Australia and New Zealand are covered by mid‐Tertiary limestones formed in cool‐water, shelf environments. The generally destructive character of sea‐floor diagenesis in such settings precludes ubiquitous inorganic precipitation of carbonates, yet these limestones include occasional units with marine cements: (1) within rare in situ biomounds; (2) within some stacked, cross‐bedded sand bodies; (3) at the top of metre‐scale, subtidal, carbonate cycles; and (4) most commonly, associated with certain unconformities. The marine cements are dominated by isopachous rinds of fibrous to bladed spar, interstitial homogeneous micrite and interstitial micropeloidal micrite, often precipitated sequentially in that order. Internal sedimentation of microbioclastic micrite may occur at any stage. The paradox of marine‐cemented limestone units in an overall destructive cool‐water diagenetic regime may be explained by the precipitation of cement as intermediate Mg‐calcite from marine waters undersaturated with respect to aragonite. In some of the marine‐cemented limestones, aragonite biomoulds may include marine cement/sediment internally, suggesting that dissolution of aragonite can at times be wholly marine and not always involve meteoric influences. We suggest that marine cementation occurred preferentially, but not exclusively, during periods of relatively lowered sea level, probably glacio‐eustatically driven in the mid‐Tertiary. At times of reduced sea level, there was a relative increase in both the temperature and the carbonate saturation state of the shelf waters, and the locus of carbonate sedimentation shifted towards formerly deeper shelf sites, which now experienced increased swell wave and/or tidal energy levels, fostering sediment abrasion and reworking, reduced sedimentation rates and freer exchange of sediment pore‐waters. Energy levels were probably also enhanced by increased upwelling of cold, deep waters onto the Southern Ocean margins of the Australasian carbonate platforms, where water‐mass mixing, warming and loss of CO₂ locally maintained critical levels of carbonate saturation for sea‐floor cement precipitation and promoted the phosphate‐glauconite mineralization associated with some of the marine‐cemented limestone units.     

Insight into the development of a carbonate platform through a multi-disciplinary approach: a case study from the Upper Devonian slope deposits of Mount Freikofel (Carnic Alps,Austria/Italy)

The development and behavior of million year-scaled depositional sequences recorded within Palaeozoic carbonate platform has remained poorly examined. Therefore, the understanding of palaeoenvironmental changes that occur in geological past is still limited. We herein undertake a multi-disciplinary approach (sedimentology, conodont biostratigraphy, magnetic susceptibility (MS), and geochemistry) of a long-term succession in the Carnic Alps, which offers new insights into the peculiar evolution of one of the best example of Palaeozoic carbonate platform in Europe. The Freikofel section, located in the central part of the Carnic Alps, represents an outstanding succession in a fore-reef setting, extending from the Latest Givetian (indet. falsiovalis conodont zones) to the Early Famennian (Lower crepida conodont zone). Sedimentological analysis allowed to propose a sedimentary model dominated by distal slope and fore-reef-slope deposits. The most distal setting is characterized by an autochthonous pelagic sedimentation showing local occurrence of thin-bedded turbiditic deposits. In the fore-reef slope, in a more proximal setting, there is an accumulation of various autochthonous and allochthonous fine- to coarse-grained sediments originated from the interplay of gravity-flow currents derived from the shallow-water and deepwater area. The temporal evolution of microfacies in the Freikofel section evolves in two main steps corresponding to the Freikofel (Unit 1) and the Pal (Unit 2) limestones. Distal slope to fore-reef lithologies and associate changes are from base to top of the section: (U1) thick bedded litho- and bioclastic breccia beds with local fining upward sequence and fine-grained mudstone intercalations corresponding, in the fore-reef setting, to the dismantlement of the Eifelian–Frasnian carbonate platform during the Early to Late Frasnian time (falsiovalis to rhenana superzones) with one of the causes being the Late Givetian major rift pulse; (U2) occurrence of thin-bedded red nodular and cephalopod-bearing limestones with local lithoclastic grainstone intercalations corresponding to a significant deepening of the area and the progressive withdrawal of sedimentary influxes toward the basin, in relation with Late Frasnian sea-level rise. MS and geochemical analyses were also performed along the Freikofel section and demonstrate the inherent parallel link existing between variation in MS values and proxy for terrestrial input. Interpretation of MS in terms of palaeoenvironmental processes reflects that even though distality remains the major parameter influencing MS values, carbonate production and water agitation also play an important role.     

Considerations about Hercynian thrusting in the Marimanya massif (central Pyrenees)

We can distinguish four main units within the Marimanya massif: the Cambro-Ordovician detrital series; a carbonate unit, mainly made up of massive limestones dated as Silurian-Devonian; dark slates and limestones dated as Middle-Upper Devonian; and the late Hercynian Marimanya intrusive, mainly composed of granites and granodiorites. Mapping has shown that the carbonate units lie on different levels of the Cambro-Ordovician series and even on the dark slates and limestones. This abnormal contact is demonstrated to be a thrust. The thrusting surface is affected by Hercynian folds with vertical axial planes, a fold axis trending E-W and an associated cleavage. Moreover, it is cut by the late Hercynian intrusive. Consequently, considering paleontological and structural data as well as the regional context, the most reasonable interpretation is that this structure represents a Hercynian thrust, probably with southward displacement.     

中韩第五次《东北亚地壳演化》学术研讨会在北京举行

新疆天山东部广泛发育晚石炭世碳酸盐岩隆。这些岩隆主要为生物丘,少数为生物滩及与岩隆有关的生物层,其中生物丘含大量灰泥和内碎屑。基本岩石类型为泥粒状灰岩、粒泥状灰岩、粒泥状－泥粒状灰岩,少量岩石类型包括颗粒岩、骨架岩和障积岩。成岩作用是碳酸盐岩隆发展演化的重要阶段和过程,在生物丘内,已经识别出四种重要的胶结物,即球粒泥晶、纤状方解石、放射轴状方解石和粒状方解石。尽管缺失典型的造礁生物,但通过岩石类型研究和微相分析,认为碳酸盐岩隆的形成主要取决于生物作用及古环境格局。本区碳酸盐岩隆可以同欧洲瓦尔索坦的岩隆对比     

Rare earth element geochemistry of Late Devonian reefal carbonates, Canning Basin, Western Australia: confirmation of a seawater REE proxy in ancient limestones

Rare earth element and yttrium (REE+Y) concentrations were determined in 49 Late Devonian reefal carbonates from the Lennard Shelf, Canning Basin, Western Australia. Shale-normalized (SN) REE+Y patterns of the Late Devonian samples display features consistent with the geochemistry of well-oxygenated, shallow seawater. A variety of different ancient limestone components, including microbialites, some skeletal carbonates (stromatoporoids), and cements, record seawater-like REE+Y signatures. Contamination associated with phosphate, Fe-oxides and shale was tested quantitatively, and can be discounted as the source of the REE+Y patterns. Co-occurring carbonate components that presumably precipitated from the same seawater have different relative REE concentrations, but consistent REE+Y patterns. Clean Devonian early marine cements (n = 3) display REE+Y signatures most like that of modern open ocean seawater and the highest Y/Ho ratios (e.g., 59) and greatest light REE (LREE) depletion (average Nd_SN/Yb_SN = 0.413, SD = 0.076). However, synsedimentary cements have the lowest REE concentrations (e.g., 405 ppb). Non-contaminated Devonian microbialite samples containing a mixture of the calcimicrobe Renalcis and micritic thrombolite aggregates in early marine cement (n = 11) have the highest relative REE concentrations of tested carbonates (average total REE = 11.3 ppm). Stromatoporoid skeletons, unlike modern corals, algae and molluscs, also contain well-developed, seawater-like REE patterns. Samples from an estuarine fringing reef have very different REE+Y patterns with LREE enrichment (Nd_SN/Yb_SN > 1), possibly reflecting inclusion of estuarine colloidal material that contained preferentially scavenged LREE from a nearby riverine input source. Hence, Devonian limestones provide a proxy for marine REE geochemistry and allow the differentiation of co-occurring water masses on the ancient Lennard Shelf. Although appropriate partition coefficients for quantification of Devonian seawater REE concentrations from out data are unknown, hypothetical Devonian Canning Basin seawater REE patterns were obtained with coefficients derived from modern natural proxies and experimental values. Resulting Devonian seawater patterns are slightly enriched in LREE compared to most modern seawaters and suggest higher overall REE concentrations, but are very similar to seawaters from regions with high terrigenous inputs. Our results suggest that most limestones should record important aspects of the REE geochemistry of the waters in which they precipitated, provided they are relatively free of terrigenous contamination and major diagenetic alteration from fluids with high, non-seawater-like REE contents. Hence, we expect that many other ancient limestones will serve as seawater REE proxies, and thereby provide information on paleoceanography, paleogeography and geochemical evolution of the oceans.     

Radiaxial fibrous calcite: a replacement after acicular carbonate

Radiaxial fibrous calcite, a common cavity fill in ancient limestones, is characterized by curved twin lamellae, optic axes that converge away from the substrate and subcrystals which diverge in this same direction. The optic axes radiate about three or four axes located in positions between adjacent crystals and orientated parallel with the crystal elongation. The crystals are commonly turbid with inclusions, which may be concentrated along twin lamellae and subcrystal and inter-crystalline boundaries, or form zones parallel to the substrate. Some inclusion patterns reveal the position of former crystal faces. From a consideration of the occurrences, gross morphological characters, the fabrics of the crystals and the inclusion patterns, radiaxial fibrous calcite is interpreted as a replacement of an early diagenetic acicular cement, composed of interfering bundles of radiating crystals. It is suggested that replacement takes place by a solution-precipitation process and the migration of a fluid film through the acicular host, with replacement occurring most rapidly between bundles of acicular carbonate. The optic axis pattern of the fibrous calcite is considered to be inherited from the c-axis orientations of the host acicular crystals. Fibrous calcite intercrystalline boundaries form as fractures after replacement. Some inclusion patterns record the characters of the replaced acicular cement; others, formed of impurities reorganized during the replacement, reveal the form of the replacement front.     

Lithofacies and sequence development on an Upper Devonian mixed carbonate-siliciclastic fore-reef slope, Canning Basin, Western Australia

Detailed sedimentological and stratigraphical analysis coupled with conodont biostratigraphy of a fore-reef slope succession in the Napier Range (Napier Formation) is used to develop a depositional model and relative sea-level history for late Frasnian to late Famennian reef evolution in the Canning Basin of north-western Australia. Changes in sedimentary style on the slope, reflecting differing rates of carbonate production on the platform, are linked to third- and higher order relative sea-level fluctuations. Overlapping slope aprons accumulated along the base of a steep-walled platform margin. Coarse carbonate debris was deposited adjacent to the margin as talus breccias (via rockfall) and debris-flow breccias. Depositional slopes up to 45°, and locally steeper, are demonstrated using rotated geopetal cavity fills. The predominance of channel-filling lithofacies throughout the slope succession indicates the highly channelized nature of the aprons. The middle slope is dominated by sandy oolitic-peloidal turbiditic grainstones interpreted as sediment exported from an active platform. The turbidites and associated debris-flow breccias contrast with condensed carbonate intervals and deep-water, non-fenestral stromatolites that record times of very low platform production. Lower slope turbidites and associated intraclastic breccias indicate widespread redeposition of sediment eroded from lithified and semi-lithified limestones higher up the slope. Several third-order sequences are recognized in the fore-reef succession and these are composed primarily of transgressive and highstand deposits. Carbonate production was severely restricted in the early Famennian coinciding with development of onlapping siliciclastic aprons during a relative sea-level lowstand. Evidence for a subaerial exposure event is also preserved within the siliciclastic strata. Controls on sequence development are difficult to constrain. Although two sequence boundaries can be correlated with falls on the global sea-level curve, the reef complexes evolved in an active extensional regime and it is highly likely that tectonism, in conjunction with eustasy, controlled accommodation on the platform and therefore carbonate productivity.     

Depositional characteristics and constraints on the mid-Valanginian demise of a carbonate platform in the intra-Tethyan domain,Circum-Rhodope Belt,northern Greece

Two platform-type carbonate successions of Berriasian to early Valanginian age are exposed in the eastern Circum-Rhodope belt which extends from the Chalkidiki Peninsula to the Thrace region in northern Greece. On the basis of new sedimentological and biostratigraphic results and analysis of published palaeomagnetic data, the Porto Koufos Limestones and Aliki Limestones are interpreted as deposits of a formerly unknown earliest Cretaceous carbonate platform in the Western Tethys realm. This Circum-Rhodope carbonate platform existed in tropical latitudes of the intra-Tethyan domain on the northern shelf area of the small Vardar oceanic basin. It was characterized by limited regional extent, remoteness from land, and short lateral transitions into deeper basin areas. Predominantly skeletal sediments with various microencrusters were produced along with variable amounts of lime mud, marine cements, peloids, intraclasts, aggregate grains, ooids and microbialites. The microfacies analysis of limestones formed around the Berriasian–Valanginian boundary indicates the configuration of a rimmed shelf with restricted lagoon, open lagoon, reef margin, fore-reef and upper slope depositional environments. During the early Valanginian a change from photozoan to heterozoan mode of carbonate production occurred mainly as a result of climate cooling. Deposition continued in protected lagoon, shoal and near-shoal settings implying a ramp-like morphology of the platform. Finally, a shift from skeletal to non-skeletal carbonate deposition took place as a consequence of high seawater carbonate saturation and possibly coeval increase of the marine trophic levels. A major sea level fall and climate cooling were the prime palaeoenvironmental controls that caused decline of the shallow-water carbonate factory and subsequent demise of the Circum-Rhodope carbonate platform in mid-Valanginian time that was followed by a long-term subaerial exposure and karstification which continued at least until the middle Eocene. The new results can be used for correlation with other shallow marine carbonates deposited in the intra-Tethyan domain during the earliest Cretaceous. Also, they appear to be of critical significance to decipher the Mesozoic geodynamic evolution of the Circum-Rhodope belt and adjacent tectonic zones.     

论古代海洋碳酸盐沉积环境基本模式

我国碳酸盐地层分布广泛,厚度巨大,类型复杂,从而为我国碳酸盐研究提供广阔前景。解放以后,我国首先在四川盆地的二、三叠系碳酸盐岩中获得高产气田,推动了碳酸盐岩的研究。     

Triassic carbonate buildup flanks in the Dolomites, northern Italy: breccias, boulder fabric and the importance of early diagenesis

The flanks of Middle Triassic carbonate buildups in the Dolomites show well‐developed clinostratification, with typical angles of 30–40°. This paper focuses on the metre‐scale fabric of these clinoforms and sets these within the context of their large‐scale and microscopic features. Clinoform stratification is caused by fibrous cement crusts, by stylolites paralleling a vague stratification and by pelagic limestone interbedded with the lower portions of the clinoforms. These parts of the clinoforms locally exhibit a boulder fabric. A fracture system, subvertical to clinostratification, is filled by fibrous cements and marine internal sediment. The analysis of clinoform fabric indicates that parts consist of in situ automicrite. Other parts of the clinoforms are made up of breccia. The breccias occur as isolated pockets and lenses with random orientation and dimensions ranging from a few square decimetres to hundreds of square metres. The breccias have gradual contacts with the unbrecciated host rock. Breccia components are mostly angular, show a microfacies similar to that of the unbrecciated host rock and are composed of millimetre‐ to decimetre‐sized particles that generally float in radiaxial‐fibrous cement. Matching grain boundaries are common. Calcite cement typically makes up 20 and 40 vol.% of the brecciated areas. Clinostratification, the fracture system, brecciation and boulder fabric point to gravity induced deformation of in situ flank deposits rather than gravity induced depositional processes. Brecciation appears to result from translational sliding (millimetres to metres) on the steep buildup flanks, which caused fracturing of the vaguely stratified automicrite, followed by displacive growth of fibrous cement. Cementation occurred in a (shallow) burial, marine phreatic environment, because cement clasts are virtually absent from the flank‐derived gravity flows in the adjoining basinal sediments. Displacive cement growth indicates a volume increase of the clinoforms during diagenesis of up to 20–40 vol.% and can account for the local drag of buildup interior limestones. Similarly, the boulder fabric appears to be a diagenetic feature, which resulted from differential settling of incompletely lithified boundstone and grainstone, and the interbedded pelagic limestone.     

晚白垩世中国东南沿岸山系与中南地区的沙漠和盐湖化

晚白垩世在中国东南沿古太平洋西岸地区形成了一条巨大的沿岸山系，其山峰高度在３５００—４０００ｍ之间，东西宽度近５００ｋｍ，挡住了东来的暖湿气流，使中南地区云梦泽内陆水域的广大平原和丘陵地变成了一个热带—亚热带干旱、炎热的半沙漠和盐湖地区，这一古地理和古气候格局一直持续到早第三纪末才开始改变。     

Lower and Middle Carboniferous oil-bearing limestones of southeastern Tatarstan and reconstruction of the paleoenvironment of their formation

The study of Lower and Middle Carboniferous limestones within the eastern flank of the Melekess Depression and the South Tatar Arch allowed us to reconstruct their formation environment. Bioclastic phyto-and zoomorphic limestones occur as wide zones parallel to the shoreline. Therefore, lithogenetic typification of limestones was used for the stratification of Tournaisian and Visean deposits. Serpukhovian and Bashkirian zoogenic, clastic, and pelitomorphic limestones formed away from the shoreline. Such deposits are represented by biogenic buildups (possibly, biostromes), fan limestones, synsedimentary crushing (clastic) limestones, and interbiostrome deposits (pelitomorphic limestones). Therefore, their horizon-scale stratification is impossible.Commercial oil pools in the carbonate part of the section are confined to bioclastic zoomorphic limestones subjected to secondary leaching. The confinement of leaching to the lithogenetic limestone types mentioned above is related to their composition (shell remains and calcite cement). Shell remains making up the rock skeleton are protected against leaching by the organic material that prevents rocks from compaction.     

Petrography and geochemistry of Paleocene–Eocene limestones in the Ching-dar syncline, eastern Iran

The Ching-dar syncline is located to the west of the city of Birjand, in the east of han. The ca. 500 m thick studied section at the eastern flank of the syncline contains a sequence of almost continuous shallow- marine limestones that exhibit no major sedimentary breaks or evidence for volcanic activity. Skeletal grains consist of large benthic foraminifera and green algae whereas non-skeletal grains are mostly peloids and intraclasts. They were deposited on a shallow-marine carbonate ramp. The limestones have undergone extensive diagenetic processes with varying intensities, the most important of which are micritization, cementation, compaction （chemical and mechanical）, internal filling and stylolitization. Chemical analysis of the limestone samples revealed high calcium and low magnesium content. Major and minor element values were used to determine the original carbonate mineralogy of these lime- stones. Petrographic evidence and elemental values indicate that calcite was the original carbonate mineral in the limestones of the Ching-dar syncline. The elemental composition of the Ching-dar car- bonates also demonstrates that they have stabilized in a meteoric phreatic environment. Variation of Sr/ Ca vs. Mn values suggests that diagenetic alteration occurred in an open geochemical system.     

新疆库车坳陷中、新生界碳酸盐岩及其成因意义?

新疆库车坳陷古近系库姆格列木群为与广海连通不畅的半封闭局限海湾-蒸发潟湖环境沉积，它应是新特提斯洋向北的延伸部分，其中的碳酸盐岩主要为海相蒸发潮坪环境的潮上带膏云坪，潮间带生屑滩、砂屑滩、鲕滩和潮下带泥晶灰岩、泥岩、泥晶云岩等。白垩系巴什基奇克组底部的灰黑色泥灰岩为深湖环境的沉积，分布较局限，仅见于克拉201井；白垩系巴什基奇克组中部的浅灰色透镜状泥灰岩结核是典型干旱陆上暴露环境的产物，仅在库车河剖面见零星分布。侏罗系湖相碳酸盐岩主要分布在恰克马克组，其次是阳霞组和克孜勒努尔组，在卡普沙良河剖面的恰克马克组上部，可见到大量的叠层石灰岩，它们主要形成于能量较强的浅湖环境；深灰色泥晶灰岩常与灰黑色泥岩伴生，是深湖-半深湖环境产物。以上这些不同时期不同沉积环境的碳酸盐岩具有不同规律的微量元素和碳、氧同位素特征，它们对于研究库车坳陷的沉积环境变迁和盆地演化具有重要意义。个别样品地球化学数据的偏差不能代表对整体沉积环境的判别，所以碳酸盐岩沉积环境的判别需要结合共生岩石沉积构造、沉积组合序列、古生物和沉积地球化学等资料进行综合分析。     

安徽巢湖凤凰山石炭纪岩石特征及沉积环境分析

巢湖市北郊石炭纪地层发育齐全,沉积环境多样,海平面升降频繁。根据岩性、生物与沉积构造等相标志,将其划分为开放海湾、潮坪、潮下浅滩、开阔台地等沉积相。对和州组顶部炉渣状灰岩的形成机制提出不同见解。     

Physico-chemical environment of pedogenic carbonate formation in Devonian vertic palaeosols, central Appalachians, USA

The morphology and geochemistry of pedogenic carbonate found in vertic claystone palaeosols in the Devonian Catskill Formation in central Pennsylvania preserve a record of the physical and chemical environment of carbonate precipitation. The carbonate is characterized by three distinct petrographic generations. Pedogenic rhizoliths and nodules are the earliest precipitated generation, and typically consist of dull red-brown luminescent micrite. Clear, equant calcite spar cement fills voids in the centres of rhizoliths, as well as circumgranular cracks and septarian voids in nodules. Early spar cements are non-luminescent to dull luminescent, whereas later spar cements exhibit bright yellow-orange luminescence. Late stage pedogenic fractures are always occluded with very bright yellow-orange luminescent spar cements. The incorporation of progressively higher concentrations of Mn (up to 34000 ppm) into successively younger calcite spar cements, without concomitant increases in Fe, suggests carbonate precipitation from an evolving meteoric water in which Mn²⁺ became increasingly mobile over time. The increased mobility is possibly due to decreasing Eh, resulting from oxidation of organic matter after rapid soil burial on the floodplain. The amount of Fe²⁺ available for incorporation into calcite was limited because most iron was immobile, having been earlier oxidized and bound to the palaeosol clay matrix as a poorly crystallized ferric oxide or oxyhydroxide mineral. Carbon isotope compositions of pedogenic carbonate correlate with the inferred depth of carbonate precipitation. Rhizoliths preserved below the lowest stratigraphic occurrences of pedogenic slickensides are consistently depleted in ¹³C relative to nodules, which formed stratigraphically higher, within the zone of active soil shrink and swell processes. Nodular carbonate, precipitated in proximity to deep cracks in the soil, is enriched due to increased gas exchange with isotopically heavy atmospheric CO₂. Accordingly, rhizolith compositions will most accurately estimate palaeoatmospheric levels of CO₂; the use of nodule compositions may result in overestimation of P_CO2 by as much as 30%.