Significance of processes in the near‐stream zone on stream water acidity in a small acidified forested catchment

The near‐stream zone has received increasing attention owing to its influence on stream water chemistry in general and acidity in particular. Possible processes in this zone include cation exchange, leaching of organic matter and redox reactions of sulphur compounds. In this study the influences of processes in the near‐stream zone on the acidity in runoff from a small, acidified catchment in central southern Sweden were investigated. The study included sampling of groundwater, soil water and stream water along with hydrological measurements. An input–output budget for the catchment was established based on data from the International Co‐operative Programme on Integrated Monitoring at this site. The catchment was heavily acidified by deposition of anthropogenic sulphur, with pH in stream water between 4·4 and 4·6. There was also no relationship between stream flow and pH, which is indicative of chronic acidification. Indications of microbial reduction of sulphate were found in some places near the stream, but the near‐stream zone did not have a general impact on the sulphate concentration in discharging groundwater. The near‐stream zone was a source of dissolved organic carbon (DOC) in the stream, which had a median DOC of 6·8 mg L¹. The influence on stream acidity from organic anions was overshadowed by the effect of sulphate, however, except during a spring flow episode, when additional organic matter was flushed out and the sulphate‐rich ground water was mixed with more diluted event water. Ion exchange was not an important process in the near‐stream zone of the Kindla catchment. Different functions of the near‐stream zone relating to discharge acidity are reported in the literature. In this study there was even a variation within the site. There is therefore a need for more case studies to provide a more detailed understanding of the net effects that the near‐stream zone can have on stream chemistry under different circumstances. Copyright © 2001 John Wiley & Sons, Ltd.     

Field investigation and modelling of coupled stream discharge and shallow water‐table dynamics in a small Mediterranean catchment (Sardinia)

In the semi‐arid Mediterranean environment, the rainfall–runoff relationships are complex because of the markedly irregular patterns in rainfall, the seasonal mismatch between evaporation and rainfall, and the spatial heterogeneity in landscape properties. Watersheds often display considerable non‐linear threshold behavior, which still make runoff generation an open research question. Our objectives in this context were: to identify the primary processes of runoff generation in a small natural catchment; to test whether a physically based model, which takes into consideration only the primary processes, is able to predict spatially distributed water‐table and stream discharge dynamics; and to use the hydrological model to increase our understanding of runoff generation mechanisms. The observed seasonal dynamics of soil moisture, water‐table depth, and stream discharge indicated that Hortonian overland‐flow was negligible and the main mechanism of runoff generation was saturated subsurface‐flow. This gives rise to base‐flow, controls the formation of the saturated areas, and contributes to storm‐flow together with saturation overland‐flow. The distributed model, with a 1D scheme for the kinematic surface‐flow, a 2D sub‐horizontal scheme for the saturated subsurface‐flow, and ignoring the unsaturated flow, performed efficiently in years when runoff volume was high and medium, although there was a smoothing effect on the observed water‐table. In dry years, small errors greatly reduced the efficiency of the model. The hydrological model has allowed to relate the runoff generation mechanisms with the land‐use. The forested hillslopes, where the calibrated soil conductivity was high, were never saturated, except at the foot of the slopes, where exfiltration of saturated subsurface‐flow contributed to storm‐flow. Saturation overland‐flow was only found near the streams, except when there were storm‐flow peaks, when it also occurred on hillslopes used for pasture, where soil conductivity was low. The bedrock–soil percolation, simulated by a threshold mechanism, further increased the non‐linearity of the rainfall–runoff processes. Copyright © 2013 John Wiley & Sons, Ltd.     

Stream and bed temperature variability in a coastal headwater catchment: influences of surface‐subsurface interactions and partial‐retention forest harvesting

Stream temperature was recorded between 2002 and 2005 at four sites in a coastal headwater catchment in British Columbia, Canada. Shallow groundwater temperatures, along with bed temperature profiles at depths of 1 to 30 cm, were recorded at 10‐min intervals in two hydrologically distinct reaches beginning in 2003 or 2004, depending on the site. The lower reach had smaller discharge contributions via lateral inflow from the hillslopes and fewer areas with upwelling (UW) and/or neutral flow across the stream bed compared to the middle reach. Bed temperatures were greater than those of shallow groundwater during summer, with higher temperatures in areas of downwelling (DW) flow compared to areas of neutral and UW flow. A paired‐catchment analysis revealed that partial‐retention forest harvesting in autumn 2004 resulted in higher daily maximum stream and bed temperatures but smaller changes in daily minima. Changes in daily maximum stream temperature, averaged over July and August of the post‐harvest year, ranged from 1.6 to 3 °C at different locations within the cut block. Post‐harvest changes in bed temperature in the lower reach were smaller than the changes in stream temperature, greater at sites with DW flow, and decreased with depth at both UW and DW sites, dropping to about 1 °C at a depth of 30 cm. In the middle reach, changes in daily maximum bed temperature, averaged over July and August, were generally about 1 °C and did not vary significantly with depth. The pre‐harvest regression models for shallow groundwater were not suitable for applying the paired‐catchment analysis to estimate the effects of harvesting. However, shallow groundwater was warmer at the lower reach following harvesting, despite generally cooler weather compared to the pre‐harvest year. Copyright © 2012 John Wiley & Sons, Ltd.     

Modelling and experimental study of coupled exchange of p,p′‐DDE and colloids in a flume simulated stream–streambed system

Stream–subsurface exchange plays a significant role in the fate and transport of contaminants in streams. It has been modelled explicitly by considering fundamental processes such as hydraulic exchange, colloid filtration, and contaminant interactions with streambed sediments and colloids. The models have been successfully applied to simulate the transport of inorganic metals and nutrients. In this study, laboratory experiments were conducted in a recirculating flume to investigate the exchange of a hydrophobic organic contaminant, p,p′‐dichloro‐diphenyl‐dichloroethane (DDE), between a stream and a quartz sand bed. A previously developed process‐based multiphase exchange model was modified by accounting for the p,p′‐DDE kinetic adsorption to and desorption from the bed sediments/colloids and was applied to interpret the experimental results. Model input parameters were obtained by conducting independent small‐scale batch experiments. Results indicate that the immobilization of p,p′‐DDE in the quartz sand bed can occur under representative natural stream conditions. The observed p,p′‐DDE exchange was successfully simulated by the process‐based model. The model sensitivity analysis results show that the exchange of p,p′‐DDE can be sensitive to either the sediment sorption/desorption parameters or colloidal parameters depending on the experimental conditions tested. For the experimental conditions employed here, the effect of colloids on contaminant transport is expected to be minimal, and the stream–subsurface exchange of p,p′‐DDE is dominated by the interaction of p,p′‐DDE with bed sediment. The work presented here contributes to a better mechanistic understanding of the complex transport process that hydrophobic organic contaminants undergo in natural streams and to the development of reliable, predictive models for the assessment of impacted streams. Copyright © 2015 John Wiley & Sons, Ltd.     

Design of store‐release covers to minimize deep drainage in the mining and waste‐disposal industries: results from a modelling analyses based on ecophysiological principles

Sustainable long‐term storage of municipal waste and waste rock from mining activities in waste dumps (either above or below the land surface) requires minimization of percolation of rainwater into and then through stored waste material. There has been increasing attention given to the use of store‐release covers (transpirational covers) to achieve this. However, the design of such covers remains problematic because of the unique combinations of weather, vegetation composition, soils and their interactions that determine the efficacy of each design that could be available for the construction of the covers. The aim of the work described here was to use ecophysiological knowledge of soil‐plant‐atmosphere (SPA) interactions through the application of a detailed mechanistic model of the SPA continuum. We examined the relative influence of soil depth, soil texture, leaf area index and rainfall as determinants of rates of evapotranspiration and water budget for several different theoretical cover designs. We show that minimizing deep drainage requires a cover that has the following attributes: (i) a water storage capacity that is large enough to store the volume of water that is received as rainfall in above‐average wet months/seasons; (ii) a root distribution that explores the entire depth of the cover; (iii) a leaf area index that is present all year sufficient to evapotranspire monthly rainfall; and (iv) takes into account the intra‐annual and inter‐annual variability in rainfall and other climatic variables that drive ET. Copyright © 2012 John Wiley & Sons, Ltd.     

Trends in timing of low stream flows in Canada: impact of autocorrelation and long‐term persistence

The annual timing of river flows might indicate changes that are climate related. In this study, trends in timing of low flows for the Reference Hydrometric Basin Network were investigated under three different hypotheses namely: independence, short‐term persistence (STP) and long‐term persistence (LTP). Both summer and winter time series were characterized with scaling behaviour providing strong evidence of LTP. The Mann–Kendall trend test was modified to account for STP and LTP, and used to detect trends in timing of low flows. It was found that considering STP and LTP resulted in a significant decrease in the number of detected trends. Numerical analysis showed that the timing of summer 7‐day low flows exhibited significant trends in 16, 9 and 7% of stations under independence, STP and LTP assumptions, respectively. Timing of summer low flow shifted toward later dates in western Canada, whereas the majority of stations in the east half of the country (except Atlantic Provinces) experienced a shift toward earlier dates. Timing of winter low flow experienced significant trends in 20, 12, and 6% of stations under independence, STP and LTP assumptions, respectively. Shift in timing of winter low flow toward earlier dates was dominant all over the country where it shifted toward earlier dates in up to 3/4 of time series with significant trends. There are local patterns of upward significant/insignificant trends in southeast, southwest and northern Canada. This study shows that timing of low flows in Canada is time dependent; however, addressing the full complexity of memory properties (i.e. short term vs long term) of a natural process is beyond the scope of this study. Copyright © 2009 John Wiley & Sons, Ltd.