Cadmium distribution in coastal sediments and mollusks of the US

Cadmium (Cd) concentrations in the coastal United States were assessed using the National Status and Trends (NS&T) Mussel Watch dataset, which is based on the analysis of sediments and bivalves collected from 280 sites since 1986. Using the 1997 sediment data, Pearson correlation (r = 0.44, p < 0.0001) suggested that Cd distributions in sediment can, be to some extent, explained by the proximity of sites to population centers. The 2003 tissue data indicated that “high” Cd concentrations (greater than 5.6 μg/g dry weights [dw] for mussel and 5.4 μg/g dw for oysters) were related to salinity along the East and Gulf coasts. Along the West coast, however, these “high” sites appeared to be related to upwelling phenomenon. Additionally, sedimentary diagenesis was found to be the most likely explanation of why sediment and mollusk Cd content were not well correlated.     

Organic micropollutants in marine plastics debris from the open ocean and remote and urban beaches

To understand the spatial variation in concentrations and compositions of organic micropollutants in marine plastic debris and their sources, we analyzed plastic fragments (∼10 mm) from the open ocean and from remote and urban beaches. Polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), dichloro-diphenyl-trichloroethane and its metabolites (DDTs), polybrominated diphenyl ethers (PBDEs), alkylphenols and bisphenol A were detected in the fragments at concentrations from 1 to 10,000 ng/g. Concentrations showed large piece-to-piece variability. Hydrophobic organic compounds such as PCBs and PAHs were sorbed from seawater to the plastic fragments. PCBs are most probably derived from legacy pollution. PAHs showed a petrogenic signature, suggesting the sorption of PAHs from oil slicks. Nonylphenol, bisphenol A, and PBDEs came mainly from additives and were detected at high concentrations in some fragments both from remote and urban beaches and the open ocean.     

Chemical contamination assessment of the Hudson-Raritan Estuary as a result of the attacks on the World Trade Center: analysis of trace elements

The attack on the World Trade Center (WTC) resulted in the destruction of buildings, and the release of tons of dust and debris into the environment. As part of the effort to characterize the environmental impact of the WTC collapse, Mussel Watch Program trace element measurements from the Hudson–Raritan Estuary (HRE) were assessed for the years before (1986–2001) and after (2001–2005) the attack. Trace element measurements in the HRE were significantly higher than Mussel Watch measurements taken elsewhere in the Nation. Post-attack trace element measurements were not significantly different from pre-attack measurements. The impacts of WTC collapse may have been obscured by high ambient levels of trace elements in the HRE.     

A historical assessment of coastal contamination in Birch Harbor, Maine based on the analysis of mussels collected in the 1940s and the Mussel Watch Program

Coastal contamination in the 1940s was assessed based on analysis of canned blue mussels presumably collected from Birch Harbor, Maine, USA. Analytical results on legacy organic contaminants were compared to long-term National Oceanic and Atmospheric Administration (NOAA) Mussel Watch (MW) monitoring data to estimate the degree of coastal contamination before World War II (WWII) when many synthetic organic compounds were first introduced into the environment. While dieldrin and chlordane were not detected in the canned mussels, dichloro-diphenyl-trichloroethane (DDT) and hexachlorocyclohexanes (HCHs) were present at lower concentrations relative to the more recent MW data. Polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) were detected, and the later were significantly higher in canned mussels relative to the MW data (p < 0.05). Furthermore, moving average analysis applied to the MW data depicted three-phased temporal trend patterns (increase-decrease-steady state) for virtually all contaminants indicating an overall increased coastal contamination in post WWII era.     

Towards a long-term monitoring of Central European water mite faunas (Acari: Hydrachnidia and Halacaridae) – considerations on the background of data from 1900 to 2000

The state of knowledge of the Central European water mite fauna and the research history are briefly surveyed. Several areas for which we are provided with rich data sets are of high value for the monitoring of faunistic trends on the background of local and global environmental change. The need for a database combining historical and actual faunistic information is stressed. It should facilitate the access to all data from former times, give a survey on actual activities by regular updates, and help for a better organization of future research activities. On the base of an update of the Limnofauna Europaea (K.O. Viets 1978, Gerecke in www.watermite.org) a first attempt is made to (1) recognize changes in the Central European fauna during the past 100 years; (2) emphasize species which may be endangered or have disappeared during the past 100 years. At the present state of knowledge, the degree of threat to water mite species in this area is best calculated from their preference for particular habitat types which are rare and in danger to disappear in cultivated landscapes. Our knowledge concerning neozoic water mites in the study area is discussed.     

Do the Austrian blackfly fauna (Diptera: Simuliidae) support the typological approach of the EU water framework directive?

The Austrian blackfly fauna were analysed with regard to spatial (ecoregions, bioregions), vertical (altitude classes) and longitudinal zonation characteristics [stream order, biocoenotic (= fish) regions] on the basis of 2600 investigation sites. Of a total of 45 species recorded, Simulium ornatum, S. variegatum, S. argyreatum and S. reptans are the most common and most frequently distributed species, occurring in 60% of the investigated sites. Although the Austrian blackfly fauna seem to be quite well documented (on average one investigation site per 32 km²) the jackknife analyses indicates that there are still some fauna deficits. Whereas the species diversity of the main ecoregions is quite similar, the number of species differs clearly between the bioregions. Within the typological context of the Water Framework Directive, the Austrian Simuliidae confirm the bioregions as the most useful spatial units for river typology. A further optimisation in predicting a target list of blackfly species of a site can be achieved by subdividing the bioregions into either catchment area and altitude classes or into longitudinal zonation types (biocoenotic regions).     

Palaeoecology, reference conditions and classification of ecological status: the EU Water Framework Directive in practice

The European Union's Water Framework Directive (WFD) requires that all Member States within the European Union determine reference conditions for aquatic ecosystems to provide a baseline against which to measure the effects of past and present activities. Reference conditions are subsequently used to classify the ecological status of European waters. The decisions regarding environmental status will be important future elements in the management of European coastal waters. We have developed a number of classification scenarios for total nitrogen (TN) in the overlying waters of the southern part of Roskilde Fjord, Denmark, taking as our basis a palaeoecological reconstruction of fluctuations in TN between 1850 and 1995. We present a provisional classification scheme for the ecological status of Roskilde Fjord, sensu the WFD. Decision(s) regarding the deviation from reference conditions will give a wide range of apparent ecological status from good, through moderate and poor, to bad depending upon the definition of an acceptable deviation from reference conditions. The determination of an acceptable deviation will ultimately be a political decision, and will result in a wide range in the protection of coastal waters in Europe. There is still, however, an urgent need for a sound scientific documentation of the various scenarios for the implementation of the WFD.     

Catchment-scale vulnerability assessment of groundwater pollution from diffuse sources using the DRASTIC method: a case study

Abstract

The catchment-scale groundwater vulnerability assessment that delineates zones representing different levels of groundwater susceptibility to contaminants from diffuse agricultural sources has become an important element in groundwater pollution prevention for the implementation of the EU Water Framework Directive (WFD). This paper evaluates the DRASTIC method using an ArcGIS platform for assessing groundwater vulnerability in the Upper Bann catchment, Northern Ireland. Groundwater vulnerability maps of both general pollutants and pesticides in the study area were generated by using data on the factors depth to water, net recharge, aquifer media, soil media, topography, impact of vadose zone, and hydraulic conductivity, as defined in DRASTIC. The mountain areas in the study area have “high” (in 4.5% of the study area) or “moderate” (in 25.5%) vulnerability for general pollutants due to high rainfall, net recharge and soil permeability. However, by considering the diffuse agricultural sources, the mountain areas are actually at low groundwater pollution risk. The results of overlaying the maps of land use and the groundwater vulnerability are closer to the reality. This study shows that the DRASTIC method is helpful for guiding the prevention practices of groundwater pollution at the catchment scale in the UK.

Citation Yang, Y. S. & Wang, L. (2010 Yang, Y. S. and Wang, L. 2010. A review of modelling tools for implementation of the EU Water Framework Directive in handling diffuse water pollution. Water Resour. Manage., 24: 1819–1843.  [Google Scholar]) Catchment scale vulnerability assessment of groundwater pollution from diffuse sources using the DRASTIC method: a case study. Hydrol. Sci. J. 55(7), 1206–1216.     

Ion deficit restricts the distribution of brown trout (Salmo trutta) in very dilute mountain lakes

The current study is, according to our knowledge, the first study indicating that ion deficit is an important restrictor to the distribution of brown trout populations in very dilute mountain lakes. The brown trout populations in the study lakes may be able to survive solely due to traces of air borne sea salt spray.     

Application of the new multimetric MMI_PL index for biological water quality assessment in reference and human-impacted streams (Poland,the Slovak Republic)

A new multimetric MMI_PL index, which is based on the macroinvertebrate composition and combines six single key metrics, has already been implemented in Poland according to the requirements of the EU Water Framework Directive. The objectives of our survey were to assess the biological water quality using the new multimetric MMI_PL index in both reference and human-impacted streams, to analyze whether the values of the new multimetric index properly reflect the ecological status of the water in upland and mountain streams as well as to determine which environmental factors influence the distribution of benthic macroinvertebrates and the values of the metrics. The study was carried out from 2007 to 2010 in three Ecoregions that were established by the EU WFD. A total of 60 sampling sites: 36 reference sites that were situated in the headwaters of mountain streams at mid- and high-altitudes and 24, human-impacted sampling sites were selected. The benthic macroinvertebrate surveys were supported by both a hydromorphological and macrophyte assessment according to the River Habitat Survey (RHS) and to the Macrophyte Methods for Rivers. Canonical correspondence analysis (CCA) showed that the values of the Habitat Quality Assessment (HQA) index, conductivity, pH and altitude were the parameters most associated (statistically significant) with the distribution of benthic macroinvertebrate taxa and the values of the metrics in both the reference and human-impacted (impaired) sections of the streams in Ecoregions 9, 10 and 14. The new MMI_PL index was useful for biological water quality assessment and was also important for separating both the reference and impaired sections of streams. The MMI_PL index and some key metrics performed contrary to what was expected in relation to the reference high-altitude siliceous streams (the High Tatra Mts., Ecoregion 10). Low values of multimetric index and key metrics did not properly reflect their high ecological status and pristine character as reflected by the hydromorphological (RHS) and macrophyte surveys or the physical and chemical parameters of the water.     

The indication of morphological degradation of streams and rivers using Simuliidae

Blackfly communities from five German stream types out of two ecoregions (small and mid-sized siliceous gravel-bed mountain streams of the Central mountains, ecoregion 9, and organic type brooks, small and mid-sized sand-bottomed Central lowland streams of ecoregion 14) are compared. Ecoregional, as well as stream type-specific biocoenotic differences are discussed. The presence of Prosimulium sp. was restricted to mountain streams, whereas Simulium lineatum seemed to prefer mid-sized sand-bottomed Central lowland streams, and S. vernum showed a clear preference for Central lowland streams. An Index of Morphological Stress (IMS), derived from 22 geo-hydromorphological parameters recorded during sampling in the field, is presented. According to the IMS values, sites are divided into morphologically ‘unstressed’ sites (high or good morphological quality) and ‘stressed’ sites (moderate, poor or bad morphological quality), and biocoenotic differences of the two categories are discussed. Two stream types and the entire data set showed significantly higher numbers of taxa at ‘unstressed’ sites. Linear Multiple Regression (LMR) was used to identify geo-hydromorphological parameters that significantly explain the variance of the three most constant taxa, Prosimulium sp., P. hirtipes and Simulium sp. in the LMR model.     

Influence of macrofauna long-term natural variability on benthic indices used in ecological quality assessment

An essential prerequisite for the assessment of the ecological quality of marine ecosystems is the understanding of the natural variability and its effect on the performance of quality indices. This study is focused on the long-term natural variability of diversity, biotic and multimetric indices by using long-term macrofauna data of a coastal area in the southern North Sea (1978-2005). The univariate and most biotic and multimetric indices respond significantly on specific natural disturbance events such as cold winters, but the strength of response varied between indices as well as between events. As a result, the ecological quality status can decrease over a range of 3 (out of 5) classification units. The overall ecological quality was good to high, but an increase of indices occurred from the mid 1980s onwards due to changes in the climate regime. This long-term variability has to be considered within ecological quality assessment schemes.     

Salmonella: The forgotten pathogen: Health hazards of compliance with European Bathing Water Legislation

The increasing demands on recreational waters have made microbial contamination a matter of public and scientific concern. This study aimed to search for Salmonella spp. in waters classified according EU Directive 2006/7/EC, in order to assess associations between its prevalence and the concentration of the non-pathogenic new faecal indicators: Escherichia coli and intestinal enterococci. Although a statistically significant association was observed Salmonella was detected on beaches classified as “Good” (9.3%) and “Excellent” (14.4%) which compromises the idea that faecal indicators can be predictors of pathogens.Attending the high prevalence of Salmonella found (23.1%) it seemed important to improve the efficiency of the conventional analytical method (ISO 6340:1995), comparing its draft with SML-VIDAS Salmonella and two new chromogenic media: AES Salmonella Agar Plate (ASAP) and Simple Method Salmonella (SMS). ASAP showed the higher efficiency and can be recommended for a faster detection and presumptive identification of salmonellae in bathing waters.     

中国和欧盟阻尼器检测标准比较

国内阻尼器工程应用越来越多,阻尼器生产和应用时需要进行型式检验和出厂检验。中国和欧盟均制定了阻尼器产品检验标准,但在检测参数、检测方法和数据处理等方面存在一些差异,有些参数的检测还存在一些困难和争议,通过比较研究,指出中欧阻尼器检测标准的异同点,并分析各自的特点。以应用量较大的位移型软钢阻尼器和速度型黏滞流体阻尼器为例,比较中国和欧盟检测标准的异同点,内容包括检测方法、检测设备和数据处理方法等,提出一些对现有检测标准的改进建议,供同行参考。     

Fish assemblages in forest drainage ditches: Degraded small streams or novel habitats?

Artificial drainage of forested wetlands to increase timber production has profoundly altered the hydrology of North-European landscapes during the 20th century. Nowadays, drainage ditches and small dredged streams can comprise most fluvial water bodies there, but the resulting ecological effects are poorly documented. In the current study, we explored, using fish as an indicator group, consequences of the transformation of natural stream networks to a mixture of natural and artificial watercourses. We asked whether the transformation results in impoverishment, enrichment or re-assembling of the communities both at watercourse and the landscape scales. We sampled fish in 98 sites in five well-forested regions in Estonia where ditches formed 83–92%, dredged streams 4–7%, and natural streams 3–10% of the total length of small watercourses. Based on a total of 6370 individual fish of 20 species, we found that, compared to natural streams, ditches had an impoverished fauna at both scales and both in terms of species richness and assemblage composition. Only natural streams hosted characteristic species (with Barbatula barbatula, Lampetra planeri and Lota lota emerging as significant indicators), while dredged streams had intermediate assemblages. The habitat factors explaining those drainage-related differences included a reduced flow velocity, loss of stream channel variability, less transparent water, and abundant aquatic vegetation. Hence, for stream-dwelling fish, drained forest landscapes represent degraded habitats rather than novel ecosystems, which contrasts with the transformation of terrestrial assemblages. Future studies should address whether that reflects the situation for whole aquatic assemblages, and how is the functioning of the hydrological systems affected. We suggest that the critical management issues for environmental mitigation of ditching effects on fish include basin scale spatial planning, protecting of the remaining natural streams, and rehabilitation of ditch channels in flat landscapes lacking beavers.     

Modelling indicators of water security,water pollution and aquatic biodiversity in Europe

Abstract

The GWAVA (Global Water AVailability Assessment) model for indicating human water security has been extended with a newly developed module for calculating pollutant concentrations. This module is first described and then illustrated by being used to model nitrogen, phosphorus and organic matter concentrations. The module uses solely input variables that are likely to be available for future scenarios, making it possible to apply the module to such scenarios. The module first calculates pollutant loading from land to rivers, lakes and wetlands by considering drivers such as agriculture, industry and sewage treatment. Calculated loadings are subsequently converted to concentrations by considering aquatic processes, such as dilution, downstream transport, evaporation, human water abstraction and biophysical loss processes. Aquatic biodiversity is indicated to be at risk if modelled pollutant concentrations exceed certain water quality standards. This is indicated to be the case in about 35% of the European area, especially where lakes and wetlands are abundant. Human water security is indicated to be at risk where human water demands cannot be fulfilled during drought events. This is found to be the case in about 10% of the European area, especially in Mediterranean, arid and densely-populated areas. Modelled spatial variation in concentrations matches well with existing knowledge, and the temporal variability of concentrations is modelled reasonably well in some river basins. Therefore, we conclude that the updated GWAVA model can be used for indicating changes in human water security and aquatic biodiversity across Europe.

Editor Z.W. Kundzewicz

Citation Dumont, E., Williams, R., Keller, V., Voss, A., and Tattari, S., 2012. Modelling indicators of water security, water pollution and aquatic biodiversity in Europe. Hydrological Sciences Journal, 57 (7), 1378–1403.     

Bestimmung polarer Phosphorsäureester in Trink‐ und Oberflächenwasser mittels HPLC‐MS‐MS

Determination of Organophosphorus Pesticides in Water by HPLC‐MS‐MS In the EC Water Framework Directive 2000/60/EG and in CEC 76/464/EEC there are 16 organophosphorus pesticides (insecticides and acaricides) listed which belong to so‐called priority substances. The committed quality aims of these substances frequently require maximum concentrations below 0.1 μg/L. In this paper a HPLC‐MS‐method is described. The reported limits of determination of organophosphorus pesticides are lower than the demanded limits. High analytical sensitivity is reached by solid‐phase extraction (SPE) and by injecting large volumes. For some of these substances no sample enrichment is needed and low detection limits are obtained by direct injection of the original water sample.     

On the synchronism in the events within the core and on the surface of the earth: the changes in the organic world and in the polarity of the geomagnetic field in the phanerozoic

The data on geomagnetic reversals are compared with the changes in the organic world and with the lower-mantle plumes. The times of the formation of plumes and the times of their appearance on the Earth’s surface relate to the intervals characterized by the different frequencies of geomagnetic reversals, i.e., there is no interrelation between the formation of plumes and the frequency of the changes in the geomagnetic field polarity. At the same time, a certain synchronism is observed between the frequency of the geomagnetic reversals and the boundaries of the biostratigraphic ages, i.e., the changes in the organic world in the long-period range. A hypothesis is proposed, which explains the change in the sign of the geomagnetic field by the combined effect of the irregular rotation of the internal core relative to the mantle and the changes in the slope angle of the axis of the Earth’s rotation, which, in turn, results in synchronous events on the Earth’s surface: the rates of changes in the organic world.     

Comparison Between the Nutations of the Planet Mars and the Nutations of the Earth

The nutations of the planets Mars andEarth are investigated and compared. Alarge number of interior structureparameters are involved in the nutationcomputations. The comparison between the observations and the computationsprovides several constraints on these parmeters andtherefore allows a better understanding of the physics of the interior of theplanet. For the Earth, the high precision of the observations of the nutationshas led to a very good determination of interior properties of the planet. ForMars, observations of nutations are not yet available, and we review how theamplitude of the Martian nutations depends on the hypotheses consideredfor its interior. Although Mars is very similar to the Earth, its interior is not well known;for example, we don't knowif its core is liquid or solid. Only if the core is liquid,the Free Core Nutation (FCN) normal mode exists and can alter the nutationswhich are close to the resonance. From the observed geoids, it is known thatboth planets are not in hydrostatic equilibrium. The departure is larger forMars than for the Earth, and consequently, the implication of considering a convective mantle instead of a mantle in hydrostatic equilibrium described byClairaut's equation for the initial equilibrium state of the planet is largeron the Martian nutations than on the Earth nutations. The consequences of theuncertainty in the core dimensions are also examined and shown to be of a veryhigh influence for Mars if the core is liquid, due to the potential changes inthe FCN resonance. The influence of the presence of an inner core, which isknown to exist for the Earth, could be more important for Mars than for theEarth if the inner core is large. Due to the presence of Tharsis on Mars, thetriaxiality of this planet has, additionally, larger effects than on Earth.