Venus: Mesospheric hazes of ice,dust, and acid aerosols

We speculate on the origin and physical properties of haze in the upper atmosphere of Venus. It is argued that at least four distinct types of particles may be present. The densest and lowest haze, normally seen by spacecraft, probably consists of a submicron sulfuric acid aerosol which extends above the cloud tops (at ～70 km) up to ～80 km; this haze represents an extension of the upper cloud deck. Measurements of the temperature structure between 70 and 120 km indicate that two independent water ice layers may occasionally appear. The lower one can form between 80 and 100 km and is probably the detached haze layer seen in high-contrast limb photography. This ice layer is likely to be nucleated on sulfuric acid aerosols, and is analogous to the nacreous (stratospheric) clouds on Earth. At the Venus “mesopause” near 120 km, temperatures are frequently cold enough to allow ice nucleation on meteoric dust or ambient ions. The resulting haze (which is analogous to noctilucent clouds on Earth) is expected to be extremely tenous, and optically invisible. On both Earth and Venus, meteoric dust is present throughout the upper atmosphere and probably has similar properties.     

Localized structures of nanosize charged dust grains in Earth's middle atmosphere

The Earth's middle atmosphere at altitudes of 80-95 km exhibits layered phenomena known as noctilucent clouds and polar mesosphere summer echoes. These structures are believed to be associated with the presence of large quantities of charged dust or aerosol particles. The sign of the charge depends on the material composition of the latter as well as the environment. The grains are normally composed of ice together with possible metallic impurities. Particles of pure ice are always charged negatively, but if the metal content is sufficiently high, they can become positive. The characteristics of self-organized structures on the dust acoustic time scale depend strongly on the sign of the charge, and the structures can appear as either electron (ion) density humps or dips. Such a physical distinction can be used for the identification and diagnostics of noctilucent clouds and polar mesosphere summer echoes.     

Noctilucent cloud formation and the effects of water vapor variability on temperatures in the middle atmosphere

To investigate the occurrence of low temperatures and the formation of noctilucent clouds in the summer mésosphere a one-dimensional time-dependent photochemical-thermal numerical model of the atmosphere between 50 and 120 km has been constructed. The model includes the important chemistry of the hydrogen and oxygen species and transport by eddy and molecular processes. The thermal balance incorporates: heating by solar ultraviolet radiation; transport of chemical potential energy; eddy diffusion and dissipation; molecular conduction; airglow emissions; and infrared cooling by carbon dioxide. A non- LTE parameterization is used to calculate 15 μm band cooling by carbon dioxide. The model self-consistently solves the coupled photochemical and thermal equations as perturbation equations from a reference state assumed to be in equilibrium and is used to consider the effect of variability in water vapor in the lower mesosphere on the temperature in the region of noctilucent cloud formation. It is found that change in water vapor from an equilibrium value of 5 ppm at 50 km to a value of 10 ppm, a variation consistent with observations, can produce a ~ 15 K drop in temperature at 82 km. It is suggested that this process may produce long periods (weeks) of cold temperatures and influence noctilucent cloud formation.     

Subvisible CO2 ice clouds detected in the mesosphere of Mars

The formation of CO₂ ice clouds in the upper atmosphere of Mars has been suggested in the past on the basis of a few temperature profiles exhibiting portions colder than CO₂ frost point. However, the corresponding clouds were never observed. In this paper, we discuss the detection of the highest clouds ever observed on Mars by the SPICAM ultraviolet spectrometer on board Mars Express spacecraft. Analyzing stellar occultations, we detected several mesospheric detached layers at about 100 km in the southern winter subtropical latitudes, and found that clouds formed where simultaneous temperature measurements indicated that CO₂ was highly supersaturated and probably condensing. Further analysis of the spectra reveals a cloud opacity in the subvisible range and ice crystals smaller than 100 nm in radius. These layers are therefore similar in nature as the noctilucent clouds which appear on Earth in the polar mesosphere. We interpret these phenomena as CO₂ ice clouds forming inside supersaturated pockets of air created by upward propagating thermal waves. This detection of clouds in such an ultrararefied and supercold atmosphere raises important questions about the martian middle-atmosphere dynamics and microphysics. In particular, the presence of condensates at such high altitudes begs the question of the origin of the condensation nuclei.     

On the mean particle size and water content of polar mesospheric clouds

The ultraviolet spectrometer on board the Solar Mesosphere Explorer (SME) satellite has been measuring the scattering of ultraviolet sunlight from optically thin cloud layers in the upper boundary of the mesosphere (85 km) since the launch of the spacecraft in October 1981. These layers are present only at high latitudes during the summer season. During Summer 1983 an observing sequence was undertaken to measure the cloud radiance at two different scattering angles—one in the forward hemisphere at 50°, the other in the backward hemisphere at 130°. The data show a pronounced tendency for the brighter clouds to exhibit greater forward-scattering behavior, indicating that particle size may be the most important factor in determining the cloud brightness. We conclude that if the particles are monodisperse water ice aggregates, their radii do not exceed 70 nm. Estimates are provided for the water content and column particle number of the clouds, depending upon the unknown shape of the particle size distribution. Characterizing the distribution by two parameters, the spherical equivalent particle radius and the width of the distribution, the bulk cloud properties are shown to be dependent upon the limb radiance and the width parameter. For narrow widths the water ice content is less than that expected for the water vapor content at mesopause heights of a few parts per million. This confirms our earlier analysis using a smaller data set and assuming the cloud particles are monodisperse. However if the size dispersion is broad, the implied water ice exceeds the static atmospheric water supply. The calculated column number for the brightest clouds exceeds our estimates for the total supply of condensation nuclei. The alternative is that the brighter clouds are limited to a fairly narrow range of particle sizes from 40 to 60 nm. This conclusion is supported by theoretical time dependent calculations by Turco et al. (1982).     

Water ice cloud formation on Mars is more difficult than presumed: Laboratory studies of ice nucleation on surrogate materials

The role of water ice clouds in the martian water cycle and climate depends on cloud properties such as particle size and number distribution. These properties, in turn, depend on heterogeneous nucleation parameters which are poorly understood. Here we report laboratory experiments performed under martian temperature and water partial pressure conditions (158–185 K, 9 × 10⁻⁷–1 × 10⁻⁴ Torr H₂O) to determine the critical saturation ratio for ice onset, S_crit, as a function of temperature and dust composition. Using infrared spectroscopy to monitor ice nucleation and growth, we find a significant barrier to ice formation, with a pronounced temperature dependence. Even on clay minerals which show uptake of non-crystalline water before ice nucleation, we find a saturation ratio of 2.5 or more (RH_ice > 250%) is needed to begin ice growth at temperatures near 160 K. These results could lead to changes of four orders of magnitude in the nucleation rate relative to the presumptions used currently in Mars microphysical models, which commonly set the contact parameter, m, to a single value of 0.95. Our results range from m = 0.84 to m = 0.98. For ice nucleation on Arizona Test Dust, the temperature dependence is described by m = 0.0046 * T_nucl + 0.1085, while m = 0.0055 * T_nucl + 0.0003 on a smectite-rich clay sample. Our findings suggest that cloud formation will be more difficult than previously thought, potentially leading to areas of increased near-surface humidity but generally drier conditions in the atmosphere of Mars, overall.     

Microphysical modeling of ethane ice clouds in titan’s atmosphere

A time-dependent microphysical model is used to study the evolution of ethane ice clouds in Titan’s atmosphere. The model simulates nucleation, condensational growth, evaporation, coagulation, and transport of particles. For a critical saturation of 1.15 (a lower limit, determined by laboratory experiments), we find that ethane clouds can be sustained between altitudes of 8 and 50 km. Growth due to coalescence is inefficient, limiting the peak in the size distribution (by number) to 10 μm. These clouds vary with a period of about 20 days. This periodicity disappears for higher critical saturation values where clouds remain subvisible. Rainout of ethane due to methane cloud formation raises the altitude of the ethane cloud bottom to near the tropopause and may eliminate ethane clouds entirely if methane cloud formation occurs up to 30 km. However, clouds formed above the troposphere from other gases in Titan’s atmosphere could be sustained even with rainout up to 30 km. Although the optical depth of ethane clouds above 20 km is typically low, short-lived clouds with optical depths of order 0.1-1 can be created sporadically by dynamically driven atmospheric cooling. Ethane cloud particles larger than 25 μm can fall to the surface before total evaporation. However, ethane clouds remain only a small sink for tholin particles. At the peak of their cycle, the optical depth of ethane clouds could be comparable to that of tholin in the near-infrared, resulting in a 5% increase in Titan’s albedo for wavelengths between 1 and 2 μm. A number of factors limit our ablility to predict the ethane cloud properties. These factors include the mixing time in the troposphere, the critical saturation ratio for ethane ice, the existence of a surface reservoir of ethane, the magnitude and timing of dynamically driven temperature perturbations, and the abundance and life cycle of methane clouds.     

Lidar atmospheric measurements on Mars and Earth

The LIDAR instrument operating from the surface of Mars on the Phoenix Mission measured vertical profiles of atmospheric dust and water ice clouds at temperatures around −65 °C. An equivalent lidar system was utilized for measurements in the atmosphere of Earth where dust and cloud conditions are similar to Mars. Coordinated aircraft in situ sampling provided a verification of lidar measurement and analysis methods and also insight for interpretation of lidar derived optical parameters in terms of the dust and cloud microphysical properties. It was found that the vertical distribution of airborne dust above the Australian desert is quite similar to what is observed in the planetary boundary layer above Mars. Comparison with the in situ sampling is used to demonstrate how the lidar derived optical extinction coefficient is related to the dust particle size distribution. The lidar measurement placed a constraint on the model size distribution that has been used for Mars. Airborne lidar measurements were also conducted to study cirrus clouds that form in the Earth’s atmosphere at a similar temperature and humidity as the clouds observed with the lidar on Mars. Comparison with the in situ sampling provides a method to derive the cloud ice water content (IWC) from the Mars lidar measurements.     

Light scattering by nonspherical ice grains: An application to noctilucent cloud particles

The light scattered by noctilucent cloud particles is nearly fully polarized at scattering angles in the vicinity of 90 . This was one of the reasons to conclude that the upper limit of their sizes is not larger than about 0.12 m. Nevertheless, this estimate was made on the basis of the Mie scattering theory for spherical particles, whereas many investigators noted usefulness of highly aspherical shapes of noctilucent cloud particles. In this paper, we used rigorous light scattering theory for randomly oriented nonspherical particles to calculate the degree of linear polarization of the scattered light for ice grains of different shape. By comparing these calculations with rocket polarization measurements of noctilucent clouds, we show that, as for spherical particles, the upper limit of particle equal-volume radii for slightly flattened and elongated grains is of about 0.12 m, while for highly aspherical plate-like and needle-like particles this upper limit is substantially larger and is of about 0.18–0.20 m. We also report calculations of the volumetric scattering cross-section for particles of different shape and show that randomly oriented spheroids have (slightly) smaller scattering cross section per unit particle mass than equal-volume spherical grains. Nevertheless, if in noctilucent clouds plate-like and needle-like grains grow to much larger sizes than spherical particles, their scattering efficiency may be much greater.     

Small scale structures of a mesospheric dusty plasma

A dusty plasma model is presented to study the small scale structures of plasma densities in mesopause region associated with polar mesosphere summer echoes (PMSE). The heavy dust grains (ice particles) are treated as a flowing background of negative charge. Numerical results show that the electron and ion densities drop rapidly while the electric field increases dramatically within a short distance of several meters. The scalelengths of the electron density are comparable to the typical wavelength of the PMSE radars, which may be responsible for strong radar backscatter. Furthermore, the increase of the ice particle concentration results in the reduction of the density gradient and electric field.     

Laboratory studies of methane and ethane adsorption and nucleation onto organic particles: Application to Titan's clouds

Titan, Saturn's largest moon, has a thick nitrogen/methane atmosphere. The temperature and pressure conditions in Titan's atmosphere are such that the methane vapor should condense near the tropopause to form clouds. Several ground-based measurements have observed sparse cloud-like features in Titan's atmosphere, while the Cassini mission to Saturn has provided large scale images of the clouds. However, Titan's cloud formation conditions remain poorly constrained. Heterogeneous nucleation (from the vapor phase onto a solid or liquid aerosol surface) greatly enhances cloud formation relative to homogeneous nucleation. In order to elucidate the cloud formation mechanism near the tropopause, we have performed laboratory measurements of the adsorption of methane and ethane onto solid organic particles (tholins) representative of Titan's photochemical haze. We find that monolayers of methane adsorb onto tholin particles at saturation ratios less than unity. We also find that solid methane nucleates onto the adsorbed methane at a saturation ratio of S=1.07±0.008. This implies that Titan's methane clouds should form easily. This is consistent with recent measurements of the column of methane ruling out excessive methane supersaturation. In addition, we find ethane adsorbs onto tholin particles in a metastable phase prior to nucleation. However, ethane nucleation onto the adsorbed ethane occurs at a relatively high saturation ratio of S=1.36±0.08. These findings are consistent with the recent report of polar ethane clouds in Titan's lower stratosphere.     

The effect of ammonia ice on the outgoing thermal radiance from the atmosphere of Jupiter

We examine the effects of NH₃ ice particle clouds in the atmosphere of Jupiter on outgoing thermal radiances. The cloud models are characterized by a number density at the cloud base, by the ratio of the scale height of the vertical distribution of particles (H_p) to the gas scale height (H_g), and by an effective particle radius. NH₃ ice particle-scattering properties are scaled from laboratory measurements. The number density for the various particle radius and scale height models is inferred from the observed disk average radiance at 246 cm^?1, and preliminary lower limits on particle sizes are inferred from the lack of apparent NH₃ absorption features in the observed spectral radiances as well as the observed minimum flux near 2100 cm^?1. We find lower limits on the particle size of 3 μm if H_p/H_g = 0.15, or 10μmif H_p/H_g = 0.50 or 0.05. NH₃ ice particles are relatively dark near the far-infrared and 8.5-μm atmospheric windows, and the outgoing thermal radiances are not very sensitive to various assumptions about the particle-scattering function as opposed to radiances at 5 μm, where particles are relatively brighter. We examined observations in these three different spectral window regions which provide, in principle, complementary constraints on cloud parameters. Characterization of the cloud scale height is difficult, but a promising approach is the examination of radiances and their center-to-limb variation in spectral regions where there is significant opacity provided by gases of known vertical distribution. A blackbody cloud top model can reduce systematic errors due to clouds in temperature sounding to the level of 1K or less. The NH₃ clouds provide a substantial influence on the internal infrared flux field near the 600-mbar level.     

Water clouds and dust aerosols observations with PFS MEX at Mars

Observations of water ice clouds and dust are among the main scientific goals of the Planetary Fourier Spectrometer (PFS), a payload instrument of the European Mars Express mission. We report some results, obtained in three orbits: 37, 41 and 68. The temperature profile, and dust and water ice cloud opacities are retrieved from the thermal infrared (long-wavelength channel of PFS) in a self-consistent way using the same spectrum. Orographic ice clouds are identified above Olympus (orbit 37) and Ascraeus Mons (orbit 68). Both volcanoes were observed near noon at Ls=337° and 342°, respectively. The effective radius of ice particles is preliminary estimated as 1-3 μm, changing along the flanks. The corresponding visual opacity changes in the interval 0.2-0.4 above Olympus and 0.1-0.6 above Ascraeus Mons. In the case of Ascraeus Mons, the ice clouds were observed mainly above the Southern flank of the volcano with maximum opacity near the summit. In the case of Olympus, the clouds were found above both sides of the top. A different type of ice cloud is observed at latitudes above 50°N (orbit 68) in the polar hood: the effective particle radius is estimated to be 4 μm. Below the 1 mb level an inversion in the temperature profiles is found with maximum temperature at around 0.6 mb. Along orbit 68 it appears above Alba Patera, then it increases to the north and decreases above the CO₂ polar cap. Beginning from latitude 20°S above Tharsis (orbit 68), the ice clouds and dust contribute equally to the spectral shape. Further on, the ice clouds are found everywhere along orbit 68 up to the Northern polar cap, except the areas between the Northern flank of Ascraeus Mons (below 10 km) and the edge of Alba Patera. Orbit 41 is shifted from the orbit 68 by roughly 180° longitude and passes through Hellas. Ice clouds are not visible in this orbit at latitudes below 80°S. The dust opacity is anticorrelated with the surface altitude. From 70°S to 25°N latitude the vertical dust distribution follows an exponential law with a scale height of 11.5±0.5 km, which corresponds to the gaseous scale height near noon and indicates a well-mixed condition. The 9 μm dust opacity, reduced to zero surface altitude, is found to be 0.25±0.05, which corresponds to a visual opacity of 0.5-0.7 (depending on the particle size).     

Properties of the clouds of Venus,as inferred from airborne observations of its near-infrared reflectivity spectrum

We have measured the shape and absolute value of Venus' reflectivity spectrum in the 1.2-to 4.0-μm spectral region with a circular variable filter wheel spectrometer having a spectral resolution of 1.5%. The instrument package was mounted on the 91-cm telescope of NASA Ames Kuiper Airborne Observatory, and the measurements were obtained at an altitude of about 41,000 feet, when Venus had a phase angle of 86°. Comparing these spectra with synthetic spectra generated with a multiple-scattering computer code, we infer a number of properties of the Venus clouds. We obtain strong confirmatory evidence that the clouds are made of a water solution of sulfuric acid in their top unit optical depth and find that the clouds are made of this material down to an optical depth of at least 25. In addition, we determine that the acid concentration is 84 ± 2% H_2SO4 by weight in the top unit optical depth, that the total optical depth of the clouds is 37.5 ± 12.5, and that the cross-sectional weighted mean particle radius lies between 0.5 and 1.4 μm in the top unit optical depth of the clouds. These results have been combined with a recent determination of the location of the clouds' bottom boundary [Marov et al., Cosmic Res.14, 637–642 (1976)] to infer additional properties about Venus' atmosphere. We find that the average volume mixing ratio of H₂SO₄ and H₂O contained in the cloud material both equal approximately 2× 10^?6. Employing vapor pressure arguments, we show that the acid concentration equals 84 ± 6% at the cloud bottom and that the water vapor mixing ratio beneath the clouds lies between 6 × 10^?4 and 10^?2.     

Climatology and first-order composition estimates of mesospheric clouds from Mars Climate Sounder limb spectra

Mesospheric clouds have been previously observed on Mars in a variety of datasets. However, because the clouds are optically thin and most missions have performed surface-focussed nadir sounding, geographic and seasonal coverage is sparse. We present new detections of mesospheric clouds using a limb spectra dataset with global coverage acquired by NASA’s Mars Climate Sounder (MCS) aboard Mars Reconnaissance Orbiter. Mesospheric aerosol layers, which can be CO₂ ice, water ice or dust clouds, cause high radiances in limb spectra, either by thermal emission or scattering of sunlight. We employ an object recognition and classification algorithm to identify and map aerosol layers in limb spectra acquired between December 2006 and April 2011, covering more than two Mars years. We use data from MCS band A4, to show thermal signatures of day and nightside features, and A6, which is sensitive to short wave IR and visible daytime features only. This large dataset provides several thousand detections of mesospheric clouds, more than an order of magnitude more than in previous studies.Our results show that aerosol layers tend to occur in two distinct regimes. They form in equatorial regions (30°S–30°N) during the aphelion season/northern hemisphere summer (L_s < 150°), which is in agreement with previous published observations of mesospheric clouds. During perihelion/dust storm season (L_s > 150°) a greater number of features are observed and are distributed in two mid-latitude bands, with a southern hemisphere bias. We observe temporal and longitudinal clustering of cloud occurrence, which we suggest is consistent with a formation mechanism dictated by interaction of broad temperature regimes imposed by global circulation and the propagation to the mesosphere of small-scale dynamics such as gravity waves and thermal tides.Using calculated frost point temperatures and a parameterization based on synthetic spectra we find that aphelion clouds are present in generally cooler conditions and are spectrally more consistent with H₂O or CO₂ ice. A significant fraction has nearby temperature retrievals that are within a few degrees of the CO₂ frost point, indicating a CO₂ composition for those clouds. Perihelion season clouds are spectrally most similar to H₂O ice and dust aerosols, consistent with temperature retrievals near to the clouds that are 30–80 K above the CO₂ frost point.     

CO2 Snow on Mars and Early Earth: Experimental Constraints

Greenhouse warming due to carbon dioxide atmospheres may be responsible for maintaining the early Earth's surface temperature above freezing and may even have allowed for liquid water on early Mars. However, the high levels of CO₂ required for such warming should have also resulted in the formation of CO₂ clouds. These clouds, depending on their particle size, could lead to either warming or cooling. The particle size in turn is determined by the nucleation and growth conditions. Here we present laboratory studies of the nucleation and growth of carbon dioxide on water ice under martian atmospheric conditions. We find that a critical saturation, S=1.34, is required for nucleation, corresponding to a contact parameter between solid water and solid carbon dioxide of m=0.95. We also find that after nucleation occurs, growth of CO₂ is very rapid, and we report the growth rates at a number of supersaturations. Because growth would be expected to continue until the CO₂ pressure is lowered to its vapor pressure, we expect particles larger than those being currently suggested for the present and past martian atmospheres. Using this information in a microphysical model described in a companion paper, we find that CO₂ clouds are best described as “snow,” having a relatively small number of large particles.     

Das dynamische Verhalten interstellarer Staubteilchen beim Wolkenstoß Teil I. Ohne Berücksichtigung von Masseänderungen

During the collision of interstellar clouds a partial separation between gas and dust occurs. It can be expected that also a separation between heavier and lighter dust particles takes place. To determine the ratio of this dynamical effect the way of dust particles with different values of the product a · ϱ_p (a radius; ϱ_p density of the particles) during the three successive cooling periods is numerically calculated. It is shown that the heavier particles (a · ϱ_p ⪊ 5 · 10⁻⁵ g/cm²) at the end of the collision and the expansion period are gathered in a thin sheet in the inner parts of the new-built cloud whereas the lighter ones (a · ϱ_p 1 · 10⁻⁵ g/cm²) are distributed more or less uniformly among the gas of the cloud. The growth or destruction of the dust particles are not taken into account in this paper.     

Jupiter: An inhomogeneous atmospheric model analysis of spatial variations of the H2 4-0 S(1) line

An analysis of the structure of the Jovian atmosphere, primarily based on center-to-limb variations (CTLV) of the equivalent width of the hydrogen quadrupole 4-0 S(1) line, is presented. These data require that the atmosphere have regions of both long- and short- scattering mean free paths. Two alternative cloud structures which fit the data are developed. The first is a two-cloud model (TCM) consisting of a thin upper cloud and a lower semi-infinite cloud, with absorbing gas between the clouds and above the upper cloud. The second model is a reflecting-scattering model (RSM), in which a gas layer lies above a haze consisting of scattering particles and absorbing gas. The cloud-scattering phase function in both models must have a strong forward peak. The CTLV data require, however, the presence of a backscattering lobe on the phase function, with the backscattering intensity about 4% of the forward scattering. The decrease in reflectivity of all regions from the visible to the ultraviolet is explained by the presence of dust particles mixed with the gas. Most of the ultraviolet absorption in the atmosphere must occur above the upper cloud layer. Particles with a uniform distribution of radii from 0.0 to 0.1 μm with a complex index of refraction varying as λ^?2.5 are used. The contrast in reflectivity between belts and zones may be explained by the larger concentration of dust in the belts than in the zones. Spatially resolved ultraviolet limb-darkening curves will help to determine the dust distribution of the Jovian atmosphere. The visible methane bands at λλ 6190, 5430, and 4860 Å are analyzed in terms of these models. We derive a methane-to-hydrogen mixing ratio of 2.8 × 10^?3, which is about 4.5 times the value for solar composition.     

A physical model of Titan's clouds

We have constructed a model of the physical processes controlling Titan's clouds. Our model produces clouds that qualitatively match the present observational constraints in a wide variety of model atmospheres, including those with low atmospheric pressures (25 mbar) and high atmospheric pressures. We find the following: (1) high atmospheric temperatures (160°K) are important so that there is a large scale height in the first few optical depths of cloud; (2) the aerosol mass production occurs at very low aerosol optical depth so that the cloud particles do not directly affect the photochemistry producing them; (3) the production rate of aerosol mass by chemical processes is probably greater than 3.5 × 10^?14 g cm^?2 sec^?1; (4) and the eddy diffusion coefficient is less than 5 × 10⁶ cm² sec^?1 except perhaps in the top optical depth of the cloud. Our model is not extremely sensitive to particle shape, but it is sensitive to particle density. Higher particle densities require larger aerosol mass production rates to produce satisfactory clouds. Particle densities of unity require a mass production rate on the order of 3.5 × 10^?13 g cm^?2 sec^?1. We also show that an increase in mass input causes a decrease in the mean particle size, as required by J. B. Pollack et al. (1980, Geophys. Res. Lett. 7, 829–832), to explain the observed correlation between the solar cycle and Titan's albedo; that coagulation need not be extremely inefficient in order to obtain realistic clouds as proposed by M. Podolak and E. Podolak (1980, Icarus43, 73–83); that coagulation could be inefficient due to photoelectric charging of the particles; and, that the lifetime of particles near the altitude of unit optical depth is a few months, as required to explain the temporal variability observed by S. T. Suess and G. W. Lockwood and D. P. Cruikshank and J. S. Morgan (1979, Bull. Amer. Astron. Soc.11, 564). Although Titan's aerosols are ottically thick in the vertical direction, the atmosphere is so extended that the horizontal visibility is greater than that found anywhere at Earth's surface.     

Methane, ethane, and mixed clouds in Titan's atmosphere: Properties derived from microphysical modeling

Theoretical arguments point to and recent observations confirm the existence of clouds in Titan's atmosphere, yet we possess very little data on their particle size, composition and formation mechanism. A time-dependent microphysical model is used to study the evolution of ice clouds in Titan's atmosphere. The model simulates nucleation, condensational growth, evaporation, coagulation, and transport of particles in a column of atmosphere. A variety of cloud compositions are studied, including pure ethane clouds, pure methane clouds, and mixed methane-ethane clouds (all with tholin cores). The abundance of methane cloud particles may be limited by the number of ethane coated tholin nuclei rather than the number of tholins with hydrocarbon coatings. However, even the condensation of methane onto these relatively sparse ethane/tholin cloud particles is sufficient to keep the methane close to saturation. Typical methane supersaturations are of order 0.06 on the average. For simulations which take into account recent lab measurements indicating it is relatively easy for methane to nucleate onto tholin particles without an ethane-layer present, the three types of clouds (methane, ethane, and mixed) exist simultaneously. Pure methane clouds are the most abundant cloud type and serve to lower the supersaturation to about 0.04. Cloud production does not require a continuous surface source of methane. However, clouds produced by mean motions are not the visible methane clouds seen in recent Cassini and ground-based observations. Ethane clouds in the troposphere almost instantaneously nucleate methane to form mixed clouds. However, a thin ethane ‘haze’ remains just above the tropopause for some scenarios and the mixed clouds at the tropopause remain ?50% ethane by mass. Also, evaporation of methane from the mixed cloud particles near the surface leaves a thicker layer of ethane cloud particles at ∼10 km. Nevertheless, the precipitation rate of methane to Titan's surface is between 0.001 and 0.5 cm/terrestrial-year, depending on various initial conditions such as critical saturation, size and abundance of cloud condensation nuclei, surface sources and eddy diffusion.