Emission line shapes produced by dissociative excitation of atmospheric gases

Special line shapes are derived fro the λ 1356 Å (${}^5\text{S}{}^0\text{-}{}^3\text{P}$) transition of atomic oxygen from metastable (${}^5\text{S}{}^0\text{-}{}^3\text{P}$) time-of-flight spectra produced by electron impact dissociative excitation of O₂, CO₂, CO, and NO, and they are compared with the broadened λ 1304 A resonance line shapes deduced by Poland and Lawrence (1973) from atomic oxygen absorption studies. The non-thermal line shapes for both airglow emission features are shown to have an effective width comparable to a 60,000 K thermal doppler line shape for an electron impact energy of 100eV. The variation of the effective line width with electron-impact energy from threshold to 300 eV is given. Since the effective line width of the resonance radiation produced by dissociative excitation is very large compared with the doppler absorption widths of the ambient O atoms at normal exospheric temperatures, the anomalously broadened resonance lines will propagate through a planetary atmosphere as though they were optically thin. Thus, electron-impact dissociation of CO and CO₂ will contribute to the observed optically thin component of the λ 1304 Å emission in the upper atmospheres of Venus and Mars. However, the process cannot account for more than 10% of the observed optically thin emission because of the small magnitude of the excitation cross-section and the comparatively high-energy threshold for the process. The possibility that the source of the kinetically energetic $\text{O}\text{(}{}^3\text{S}$) atoms is the dissociative recombination of vibrationally excited CO₂⁺ ions is discussed.     

The excitation of the infrared atmospheric oxygen bands in the nightglow

Simultaneous observations of the nightgiow emission profiles of $\text{O}{}_2\text{(}{}^1\text{Δ)}$ and the OH Meinel bands have been used to show that the excitation mechanism for $\text{O}{}_2\text{(}{}^1\text{Δ)}$ in the night-time is through the reaction between OH¹ and atomic oxygen and the recombination of atomic oxygen. These reactions, and the proposed rate constants, have been used to derive the atomic oxygen profile appropriate to the observations. It is suggested that the atomic oxygen profile may exhibit significant structure near the mesopause at high latitude. It is also suggested that the extent of this structure may be influenced by transport effects related to stratospheric warming events.     

Airglow from the inner comas of comets

The intensities of radiation from the inner comas of comets which are composed primarily of water and carbon monoxide have been calculated. Only “airglow” emissions initiated by the absorption of extreme ultraviolet radiation have been considered. The photoionizations of H₂O, CO, CO₂, and N₂ are the most important emission sources, although photoelectron excitation is also considered. Among the emission features for which intensities were calculated are H₂O⁺ ($\text{A}\text{?}{}^2\text{A}{}_{\mathrm{1?}}\text{X}\text{?}{}^2\text{B}{}_1$), CO⁺ (first negative), CO (fourth positive), CO (Cameron), CO₂⁺ ($\text{B}\text{?}{}^2\text{?}{}_{\mathrm{u}}\text{?}\text{X}\text{?}{}^2\text{II}{}_{\mathrm{g}}$), N₂ (Vegard-Kaplan), N₂⁺ (first negative), and OI (1304 Å). In the inner coma (collision region) these airglow mechanisms are shown to be possible competitors with the usually assumed resonance scattering and flourescence excitation mechanisms which are appropriate for the outer coma and tail.     

Direct measurement of conjugate photoelectrons and predawn 630 nm airglow

A sounding rocket was flown during the predawn on 17 January, 1976 from Uchinoura, Japan, to measure directly the behaviour of the conjugate photoelectrons at magnetically low latitudes. On board the rocket were an electron energy analyzer, 630 nm airglow photometer, and plasma probes to measure electron density and temperature. The incoming flux of the photoelectrons was measured in the altitude range between 210 and 340 km. The differential flux at the top of the atmosphere was determined to be $\text{F = (1.3 ± 0.4) × 10}{}^{11}\text{exp}\text{[?}\text{E(}\text{eV}\text{)}\text{12}\text{]}$ electron · m^?2 · sr^?1 · s^?1 in the energy range 10 ? E ? 50 eV. The emission rate of the 630 nm airglow was observed in the altitude range between 90 and 360 km. The apparent emission rate observed at 80 km was 32 ± 5 R. From a theoretical calculation of the optical excitation rate using the observed electron flux data along with a model distribution of atomic oxygen, it was estimated that more than 65% of the emission could be produced by direct impact of the photoelectrons with atomic oxygen in the thermosphere between 200 and 360 km. Using the observed electron density and the model distribution of oxygen molecules the residual of the emission was ascribed to the excitation of O(¹D) through dissociative recombination, $\text{O}{}_2{}^{\mathrm{+}}\text{+}\text{e}\text{→}\text{O}{}^1\text{+}\text{O}{}^7$. The direct collisional excitation by ambient electrons is estimated to be negligibly small at the level of observed electron temperature.     

Linewidth studies on the NI(4S−4P) resonance multiplet

We have measured the linewidths of the NI multiplets $\text{[2p}{}^2\text{3p}{}^4\text{D}{}^0\text{?2p}{}^2\text{3s}{}^4\text{P, λ8691}\text{A}\text{?}\text{; 2p}{}^2\text{3p}{}^4\text{P}{}^0\text{?2p}{}^2\text{3s}{}^4\text{P, λ8212}\text{A}\text{?}\text{; 2p}{}^2\text{3s}{}^4\text{P?2p}{}^3{}^4\text{S}{}^0\text{, λ1200}\text{A}\text{?}\text{]}$ produced in the dissociative excitation of N₂ by energy electrons. The infrared transitions excite the N(⁴P) resonance state by cascade and they account for > 50% of the total N(⁴P) cross section at 100 eV. Both the i.r. and v.u.v. lines are found to be highly Doppler broadened ( ～ 25 times the thermal Doppler line width). These results indicate that dissociative excitation of N₂ produces N (⁴P) atoms with sufficient kinetic energy so that the $\text{λ1200}\text{A}\text{?}$ resonance radiation $\text{[2p}{}^2\text{3s}{}^4\text{P ?2p}{}^3{}^4\text{S}{}^0\text{]}$ emitted by these excited atoms would be optically thin in the Earth's upper atmosphere. We also found that the line strength ratios for the resolved components of the $\text{λ1200}\text{A}\text{?}$ triplet excited by dissociative excitation differ from those predicted by the multiplicities of the states involved and used in current entrapment models; the intensity ratios also vary with the energy of the incident electron. These developments introduce new complications into the analysis of the terrestrial ultraviolet dayglow.     

Photoelectron fluxes in cometary atmospheres

The photoelectron fluxes in cometary atmospheres are calculated by a Monte Carlo method. This is the first quantitative model calculation of this kind. A pure H₂O atmosphere is assumed with a sublimation rate of 10³⁰ molecules sec^?1 at 1 AU. Discussions of the energetics of electron gas and of the elementary collisional processes in determining the fluxes largely concern this water atmosphere. Influences on the photoelectron fluxes are also investigated for CO, another possible constituent. The excitation rate of the ${}^1\text{D}$ level of atomic oxygen in electron impacts is evaluated. It is highly improbable that the photoelectrons are responsible for the observed 6300 Å emission of the order of 1 kR at a heliocentric distance of 1 AU. The structure of the heat equation for thermal electrons is analyzed and a drastic change of the plasma behavior within the coma region is expected.     

A new interpretation of the 1304 Å triplet airglow intensity ratio with the fine structure levels O3Pj) in local thermodynamic equilibrium

The intensity ratios of the 1304 Å triplet airglow of atomic oxygen observed by Fastie and Crosswhite (1964) are interpreted on the basis of the radiative transfer formulation for a model with complete frequency redistribution in a Voigt line profile. A model for the fine structure levels $\text{O(}{}^3\text{P}{}_{\mathrm{j}}\text{)}$ in local thermodynamic equilibrium is favorable to the observed intensity ratios, as far as a Voigt profile is applicable. In view of large cross sections as calculated theoretically by Allison and Burke (1969), the mutual relaxation among the ³P_j levels should occur rapidly enough to allow the population in the ³P_j levels to be in thermodynamic equilibrium with the ambient neutral gases.     

Global atomic oxygen density derived from OGO-6 1304 Å airglow measurements

The OGO-6 UV photometer experiment measured the atomic oxygen OI 1304 Å triplet in the Earth's dayglow between 400 and 1100 km. We have analyzed the data for the period 15 September–25 October 1969 by obtaining best-fit models in which the 1304 Å emission is excited by solar resonance scattering and photoelectron excitation. Provided the excitation processes are specified, we find a unique relationship between the vertical column density of atomic oxygen and the zenith 1304 Å intensity. This is essentially independent of the atmospheric temperature. Because of the large numerical uncertainties, the excitation sources are determined from the 1304 Å data and quiet-time in situ measurements of atomic oxygen density. They are found to be in good agreement with recent solar measurements of the 1304 Å lines and with calculations of the photoelectron excitation source. The deduced variations of atomic oxygen column densities over the daytime atmosphere are found to agree well with the Jacchia 1971 models. During the geomagnetic storm, the column density generally increased above a fixed altitude. However, the latitudinal dependence is complex. Following the strong geomagnetic activity between 15 September and 1 October, depletions in atomic oxygen are observed. At times, there is evidence of high-altitude transport of atomic oxygen from high latitude to low latitude.     

Changes in the concentration of mesospheric ozone during the total solar eclipse

Measurements of dayglow radiance of $\text{O}{}_2\text{(}{}^1\text{Δ}{}_{\mathrm{g}}\text{)}$ and OH(7,2) bands are reported. Ground based photometers were used to monitor zenith radiance of 1270 and 694 nm emissions during the total solar eclipse of 16 February 1980. Altitude distribution of 1270 nm intensity was derived from ground based observations. A set of altitude distributions of $\text{O}{}_2\text{(}{}^1\text{Δ}{}_{\mathrm{g}}\text{)}$ were thus obtained throughout the eclipse. These altitude distributions were converted into ozone distributions using the rate equations for formation and loss of ozone and $\text{O}{}_2\text{(}{}^1\text{Δ}{}_{\mathrm{g}}\text{)}$ molecules. Results indicate an increase in the ozone concentration at mid-eclipse. OH(7,2) emission did not show enhancement during totality. This may mean that there was no increase in OH concentration during the eclipse.     

The O(1S) quantum yield from O2+ dissociative recombination

Recent laboratory studies show that the $\text{O}\text{(}{}^1\text{S}\text{)}$ quantum yield, $\text{f}\text{(}{}^1\text{S}\text{)}$, from O₂⁺ dissociative recombination varies considerably with the degree r of vibrational excitation. However, the suggestion that the high values for $\text{f}\text{(}{}^1\text{S}\text{)}$ deduced from airglow and auroral observations can be explained by invoking vibrational excitation, creates a number of problems. Firstly, the rapid vibrational deactivation of O₂⁺ ions by collisions with O atoms will keep r too low to account for the magnitude of $\text{f}\text{(}{}^1\text{S}\text{)}$; secondly, r varies considerably from one atmospheric source to another but its relative values (which should be reliable) do not co-vary with those of $\text{f}\text{(}{}^1\text{S}\text{)}$; thirdly, because r increases markedly above the peak of the $\text{X5577}\text{A}\text{?}$ dissociative recombination layer, the fits which theorists have obtained to the observed volume emission rate profiles would have to be regarded as fortuitious. It is tentatively suggested that $\text{f}\text{(}{}^1\text{S}\text{)}$ is higher in the airglow and aurora than in the laboratory plasma studied by Zipf (1980) because of the electron temperature dependence of the $\text{O}\text{(}{}^1\text{S}\text{)}$ specific recombination coefficient for O₂⁺(v^' ? 3) ions.The repulsive ${}^1\text{Σ}{}_{\mathrm{<mtext>u</mtext>}}\text{[}{}^1\text{D}\text{+}{}^1\text{s}\text{]}$ state of O₂ does not provide a suitable channel for the dissociative recombination. A possible alternative is the bound ${}^3\text{Π}{}_{\mathrm{<mtext>u</mtext>}}\text{[}{}^5\text{S}\text{+}{}^3\text{s}\text{]}$ state with predissociation to the repulsive ${}^3\text{Π}{}_{\mathrm{<mtext>u</mtext>}}\text{[}{}^3\text{P}\text{+}{}^1\text{s}\text{]}$ state.     

The near infrared nightglow continuum

A review is given of observations of the nightglow continuum extending from about 7000 Å to longer wavelengths. It is suggested that the source of this emission is radiative association of atomic oxygen via the repulsive ${}^3\text{Π}{}_{\mathrm{u}}$ state to vibrationally excited O₂(³Σ_g^?). Predicted spectra are compared with nightglow and laboratory observations. Other implications for the physics of the thermosphere and upper mesosphere are discussed.     

The possible effects of translationally excited nitrogen atoms on lower thermospheric odd nitrogen

In the quiet lower thermosphere, photolysis of N₂ produces translationally excited $\text{N}\text{(}{}^4\text{S}\text{)}$ and $\text{N}\text{(}{}^2\text{D}\text{)}$ atoms. A fraction of these $\text{N}\text{(}{}^4\text{S}\text{)}$ atoms may react rapidly with O₂ while still translationally hot. This results in substantially larger calculated NO densities than those obtained if translational excitation is not considered. The sensitivity of the calculated NO density in the lower thermosphere to this process is examined.     

The 63 μm radiation field in the earth's thermosphere and its influence on the atomic hydrogen temperature

The thermal escape of hydrogen from the Earth's atmosphere is strongly affected by its temperature at the exobase. It has been suggested recently that the hydrogen temperature might be significantly lower than the thermospheric temperature as a result of a collisional exchange of energy with atomic oxygen. The tendency is to cool the hydrogen since the energy of the excited ${}^3\text{P}{}_1$ level of oxygen can be lost from the atmosphere via magnetic dipole emission of the 63 μm line (${}^3\text{P}{}_2\text{?}{}^3\text{P}{}_1$). We present here a detailed calculation of the net cooling effect as a function of altitude throughout the thermosphere. The calculations have been performed for both day and night conditions and for periods of maximum and minimum solar activity conditions. It is found that its effect on ΔT/T varies from a very small value to a maximum of ～3%. We also provide the theoretical framework for describing deviations of the 63 μm emission from local thermodynamic equilibrium and show that these effects can cause the emission to be reduced by as much as 40% near 500 km.     

Origin of 30 ∼ 100 kev protons observed in the upstream region of the Earth's bow shock

a Fermi-type acceleration model is constructed to explain the origin of energetic protons (30 ～ 100 keV) which have been observed upstream of the bow shock. It is shown that the suprathermal protons (with energy of several keV) can be accelerated up to several tens of keV through the Fermi-type process in which the reflection at the shock front and the scattering in the upstream region are coupled. The efficiency of the scattering process is estimated by using the result of Barnes' quasilinear treatment of the wave excitation. The resultant energy spectrum and flux intensity ($\text{10}{}^3\text{～ 10}{}^4\text{protons}\text{(}\text{cm}{}^2\text{s ster keV}$) in 32 ～ 45.3keV) are consistent with the observation, and the softening of the energy spectrum observed in the dawn region can be explained by the decrease in the efficiency of the acceleration process in the dawn region due to the curvature of the bow shock and the reduction of shock strength. The spatial distribution of the flux predicted by the model is also consistent with the observation. In view of these consistencies the Fermi-type acceleration process is suggested as a possible candidate mechanism to explain the upstream protons although we do not intend to exclude other possibilities.     

Further quantification of the sources and sinks of thermospheric O1D) atoms

In this paper we confirm an earlier finding that the reaction

constitutes a major source of OI 6300 Å dayglow. The rate coefficient for this reaction is found to be consistent with an auroral result, namely k₁ ≈ 6 × 10^?12cm³s^?1. We correct an error in an earlier publication and demonstrate that reaction (1) is consistent with the laboratory determined quenching rate for the reaction

where $\text{k}{}_2\text{= 2.3 × 10}{}^{\mathrm{?11}}\text{cm}{}^3\text{s}{}^{\mathrm{?1}}$. Dissociative recombination of O⁺₂ with electrons is found to be a major daytime source in summer above ～220 km.     

Charge exchange of metastable D oxygen ions with N2 in the thermosphere

Measurements of N₂⁺ and supporting data made on the Atmosphere Explorer-C satellite in the ionosphere are used to study the charge exchange process

$\text{O}{}^{\mathrm{+}}\text{(}{}^2\text{D}\text{)+}\text{N}{}_2\text{→}\text{k}\text{N}{}^{\mathrm{+}}{}_2\text{+}\text{O}$

The equality k = (5 ± 1.7) × 10^?10cm³s^?1. This value lies close to the lower limit of experimental uncertainty of the rate coefficient determined in the laboratory. We have also investigated atomic oxygen quenching of O⁺(²D) and find that the rate coefficient is 2 × 10^?11 cm³s^?1 to within approximately a factor of two.     

On the simultaneous ionization-excitation of the OII(λ834 Å) resonance transition by electron impact on atomic oxygen

Laboratory cross-section data on the excitation of the OII(2s 2p⁴⁴P → 2s² 2p³⁴S; λ834 Å) resonance transition and on the production of O⁺ and O²⁺ ions by electron impact on atomic oxygen are used to show that the ratio $\text{σ(λ834}\text{A}\text{?}\text{)}\text{σ(O}{}^{\mathrm{+}}\text{+ O}{}^{\mathrm{2+}}\text{)}$ is nearly constant for incident electron energies > 50 eV. Under auroral conditions, the total electron-ion pair production rate from electron impact on O can be inferred from λ834 Å volume emission rate measurements using the result that $\text{η(O}{}^{\mathrm{+}}\text{+ O}{}^{\mathrm{2+}}\text{)}\text{\$}\text{?}\text{8.4η(λ834}\text{A}\text{?}\text{)}$. These findings, along with earlier work on the simultaneous ionization-excitation of the 1 Neg (0,0) band of N₂⁺ and the 1 Neg (1, 0) band of O⁺₂, allow the specific ionization rates for the principal atmospheric constituents (O⁺, O⁺₂, N⁺₂), for the multiply-ionized species (O²⁺, O²⁺₂, N²⁺₂), and for the dissociatively produced atomic ions to be inferred in aurora from remote satellite observations.     

Distribution functions for energetic oxygen atoms in the earth's lower atmosphere

Direct photolysis of O₃ and quenching of $\text{O}\text{(}{}^1\text{D}\text{)}$ by N₂ provide abundant sources of fast oxygen atoms for the Earth's lower atmosphere. The concentration of atoms with energy above 0.7 eV may exceed the concentration of $\text{O}\text{(}{}^1\text{D}\text{)}$ for all altitudes below 18 km and these atoms may play an important role in lower atmospheric chemistry. Distribution functions for $\text{O}\text{(}{}^3\text{P}\text{)}$ are given for the energy interval 0.1-1.3 eV, for a range of altitudes from 0 to 62 km.     

Resonant electron scattering by metastable nitrogen

The resonant electron impact quenching of metastable molecules might be important for understanding the phenomena in the upper atmosphere. In order to obtain information about the relative importance of this scattering event the resonant cross sections for electron scattering by metastable nitrogen in the $\text{A}{}^3\text{∑}\text{u}\text{+}$ state were calculated using the “boomerang” model and quenching rates for this state were evaluated for the altitudes of 130,170 and 210km. The obtained quenching rates are small (?5 × 10^?3 s^?1), even with respect to the radiative transition rate showing that under the considered conditions this process is unimportant for population of nitrogen $\text{A}{}^3\text{∑}\text{u}\text{+}$ state in the Earth's thermosphere.     

A self-consistent evaluation of the rate constants for the production of the OI 6300 Å airglow

The quenching rate k_N2 of $\text{O(}{}^1\text{D)}$ by N₂ and the specific recombination rate α_1D of O₂⁺ leading to $\text{O(}{}^1\text{D)}$ are re-examined in light of available laboratory and satellite data. Use of recent experimental values for the $\text{O(}{}^1\text{D)}$ transition probabilities in a re-analysis of AE-C satellite 6300 Å airglow data results in a value for k_N2 of 2.3 × 10^?11 cm³s^?1 at thermospheric temperatures, in excellent agreement with the laboratory measurements. This implies a value of J_O2 = 1.5 × 10^?6s^?1 for the O₂ photodissociation rate in the Schumann-Runge continuum. The specific recombination coefficient α_1D = 2.1 × 10^?7cm³s^?1 is also in agreement with the laboratory value. Implications for the suggested $\text{N}\text{(}{}^2\text{D) + O}{}_2\text{→ O(}{}^1\text{D) + NO}$ reaction are discussed.