Discovery of the Plagiogranites in the Diyanmiao Ophiolite,Southeastern Central Asian Orogenic Belt,Inner Mongolia,China and Its Tectonic Significance

In this study, plagiogranites in the Diyanmiao ophiolite of the southeastern Central Asian Orogenic Belt(Altaids) were investigated for the first time. The plagiogranites are composed predominantly of albite and quartz, and occur as irregular intrusive veins in pillow basalts. The plagiogranites have high SiO_2(74.37–76.68 wt%) and low Al_2O_3(11.99–13.30 wt%), and intensively high Na_2O(4.52–5.49 wt%) and low K_2O(0.03–0.40 wt%) resulting in high Na_2O/K_2O ratios(11.3–183). These rocks are classified as part of the low-K tholeiitic series. The plagiogranites have low total rare earth element contents(∑REE)(23.62–39.77 ppm), small negative Eu anomalies(δEu=0.44–0.62), and flat to slightly LREE-depleted chondrite-normalized REE patterns((La/Yb)N=0.68–0.76), similar to N-MORB. The plagiogranites are also characterized by Th, U, Zr, and Hf enrichment, and Nb, P, and Ti depletion, have overall flat primitivemantle-normalized trace element patterns. Field and petrological observations and geochemical data suggest that the plagiogranites in the Diyanmiao ophiolite are similar to fractionation-type plagiogranites. Furthermore, the REE patterns of the plagiogranites are similar to those of the gabbros and pillow basalts in the ophiolite. In plots of SREE–SiO_2, La–SiO_2, and Yb–SiO_2, the plagiogranites, pillow basalts, and gabbros show trends typical of crystal fractionation. As such, the plagiogranites are oceanic in origin, formed by crystal fractionation from basaltic magmas derived from depleted mantle, and are part of the Diyanmiao ophiolite. LA–ICP–MS U–Pb dating of zircons from the plagiogranites yielded ages of 328.6±2.1 and 327.1±2.1 Ma, indicating an early Carboniferous age for the Diyanmiao ophiolite. These results provide petrological and geochronological evidence for the identification of the Erenhot–Hegenshan oceanic basin and Hegenshan suture of the Paleo-Asian Ocean.     

Geochemical and Petrological Studies on the Early Carboniferous Sidingheishan Mafic–Ultramafic Iintrusion in the Southern Margin of the Central Asian Orogenic Belt, NW China

The Sidingheishan mafic-ultramafic intrusion is located in the eastern part of the Northern Tianshan Mountain, along the southern margin of the Central Asian Orogenic Belt in northern Xinjiang autonomous region of China. The Sidingheishan intrusion is mainly composed of wehrlite, olivine websterite, olivine gabbro, gabbro and hornblende gabbro. At least two pulses of magma were involved in the formation of the intrusion. The first pulse of magma produced an olivine-free unit and the second pulse produced an olivine-bearing unit. The magmas intruded the Devonian granites and granodiorites.An age of 351.4±5.8 Ma(Early Carboniferous) for the Sidingheishan intrusion has been determined by U-Pb SHRIMP analysis of zircon grains separated from the olivine gabbro unit. A U-Pb age of 359.2±6.4 Ma from the gabbro unit has been obtained by LA-ICP-MS. Olivine of the Sidingheishan intrusion reaches 82.52 mole% Fo and 1414 ppm Ni. On the basis of olivine-liquid equilibria, it has been calculated that the MgO and FeO included in the parental magma of a wehrlite sample were approximately10.43 wt% and 13.14 wt%, respectively. The Sidingheishan intrusive rocks are characterized by moderate enrichments in Th and Sm, slight enrichments in light REE, and depletions in Nb, Ta, Zr and Hf. The ε_(Nd)(t) values in the rock units vary from +6.70 to +9.64, and initial ~(87)Sr/~(86)Sr ratios range between 0.7035 and0.7042. Initial ~(206)Pb/~(204)Pb, ~(207)Pb/~(204)Pb and ~(208)Pb/~(204)Pb values fall in the ranges of 17.23-17.91,15.45-15.54 and 37.54-38.09 respectively. These characteristics are collectively similar to the Heishan intrusion and the Early Carboniferous subduction related volcanic rocks in the Santanghu Basin, North Tianshan and Beishan area. The low(La/Gd)_(PM) values between 0.26 and 1.77 indicate that the magma of the Sidingheishan intrusion was most likely derived from a depleted spinel-peridotite mantle.(Th/Nb)_(PM)ratios from 0.59 to 20.25 indicate contamination of the parental magma in the upper crust.Crystallization modeling methods suggest that the parental magma of the Sidingheishan intrusion was generated by flush melting of the asthenosphere and subsequently there was about 10 vol%contamination from a granitic melt. This was followed by about 5 vol% assimilation of upper crustal rocks. Thus, the high-Mg basaltic parental magma of Sidingheishan intrusion is interpreted to have formed from partial melting of the asthenosphere during the break-off of a subducted slab.     

中亚造山带北山南部下泥盆统火山—沉积地层的岩相、时代及古地理意义

中亚造山带北山南部的火山—沉积地层对探讨古地理演化有重要意义。本文通过北山南部双鹰山地块5条剖面实测,将该区火山—沉积地层分为4种相组合19种岩相,并通过LA-ICP-MS锆石U-Pb测年获得酸性火山岩夹层年龄(418.9±1.2Ma、417.8±1.2Ma、417.5±1.4Ma),证明各剖面均形成于早泥盆世洛赫科夫期(Lochkovian)。双鹰山地块南缘的下泥盆统由共生火山岩相(coherent facies)和原生火山岩相组合(primary volcanic facies)构成,是熔岩溢流、爆发坠落、火山碎屑流和岩浆侵出的产物,代表陆上隆升的普林尼型(Plinian)古火山作用。双鹰山地块中部墩墩山盆地充填序列自下而上由原生火山岩相组合、含火山碎屑沉积岩相组合(volcanogenic sedimentary facies)和正常沉积的河流相组合构成,代表火山活动逐步减弱和水体深度逐步加深的沉积过程。墩墩山盆地火山—沉积层序指示伸展构造背景,与同造山期磨拉石建造有显著区别。     

Origin of zircon in jadeitite from the Nishisonogi metamorphic rocks,Kyushu, Japan

On the basis of internal structures, laser ablation U–Pb ages and trace element compositions, the origin of zircon in jadeitite in the Nishisonogi metamorphic rocks was examined. The zircon comprises euhedral zoned cores overgrown by euhedral rims. The cores contain inclusions of muscovite, quartz, albite and possibly K‐feldspar, yield ²³⁸U–²⁰⁶Pb ages of 126 ± 6 Ma (±2 SD, n = 45, MSWD = 1.0), and have Th/U ratios of 0.48–1.64. The rims contain inclusions of jadeite, yield ²³⁸U–²⁰⁶Pb ages of 84 ± 6 Ma (±2 SD, n = 14, MSWD = 1.1), and have Th/U ratios of <0.06. The cores are richer in Y, Th, Ti and rare earth elements (REEs), but the rims are richer in Hf and U. Chondrite‐normalized REE patterns of the cores indicate higher Sm_N/La_N ratios, lower Yb_N/Gd_N ratios and larger positive Ce anomalies compared with those of the rims. Thus, the cores and rims have different ²³⁸U–²⁰⁶Pb ages and trace element compositions, suggesting two stages of zircon growth. Although the ²³⁸U–²⁰⁶Pb ages of the rims are consistent with the reported ⁴⁰Ar/³⁹Ar spot‐fusion ages of matrix muscovite in the jadeitite, the ²³⁸U–²⁰⁶Pb ages of the cores are older. The mineral inclusions and high Th/U ratios in the cores are best explained by crystallization from felsic magma. Therefore, the cores are considered relicts from igneous precursor rocks. The rims surrounding the inherited cores possibly precipitated from aqueous fluids during jadeitite formation. The elevated U concentrations in the rims suggest that infiltration of external fluids was responsible for the precipitation. This study provides an example of jadeitite formation by metasomatic replacement of a protolith.     

Petrogenesis of metatexite and diatexite migmatites determined using zircon U–Pb age,trace element and Hf isotope data,Higo metamorphic terrane,central Kyushu,Japan

Metatexite and diatexite migmatites are widely distributed within the upper amphibolite and granulite facies zones of the Higo low‐P/high‐T metamorphic terrane. Here, we report data from an outcrop in the highest grade part of the granulite facies zone, in which diatexite occurs as a 3 m thick layer between 2 m thick layers of stromatic‐structured metatexite within pelitic gneiss. The migmatites and gneiss contain the same peak mineral assemblage of biotite + plagioclase + quartz + garnet + K‐feldspar with retrograde chlorite ± muscovite and some accessory minerals of ilmenite ± rutile ± titanite + apatite + zircon + monazite ± pyrite ± zinc sulphide ± calcite. Calculated metamorphic P–T conditions are 800–900 °C and 9–12 kbar. Zircon in the diatexite forms elongate euhedral crystals with oscillatory zoning, but no core–rim structure. Zircon from the gneiss and metatexite forms euhedral–subhedral grains comprising inherited cores overgrown by thin rims. The overgrowth rims in the metatexite have lower Th/U ratios than zircon in the diatexite and yield a ²⁰⁶Pb/²³⁸U age of 116.0 ± 1.6 Ma, which is older than the 110.1 ± 0.6 Ma ²⁰⁶Pb/²³⁸U age derived from zircon in the diatexite. Zircon from the diatexite has variable REE contents with convex upward patterns and flat normalized HREE, whereas the overgrowth rims in the metatexite and gneiss have steep HREE‐enriched patterns; however, both types have similar positive Ce and negative Eu anomalies. ¹⁷⁶Hf/¹⁷⁷Hf ratios in the overgrowth rims from the metatexite are more variable and generally lower than values from zircon in the diatexite. Based on U–Pb ages, trace element and Hf isotope data, the zircon rims in the metatexite are interpreted to have crystallized from a locally derived melt, following partial dissolution of inherited protolith zircon during anatexis, whereas the zircon in the diatexite is interpreted to have crystallized from a melt that included an externally derived component. By integrating zircon and petrographic data for the migmatites and pelitic gneiss, the metatexite migmatite is interpreted to have formed by in situ partial melting in which the melt did not migrate from the source, whereas the diatexite migmatite included an externally derived juvenile component. The Cretaceous high‐temperature metamorphism of the Higo metamorphic terrane is interpreted to reflect emplacement of mantle‐derived basalts under a volcanic arc along the eastern margin of the Eurasian continent and advection of heat via hybrid silicic melts from the lower crust. Post‐peak crystallization of anatectic melts in a high‐T region at mid‐crustal depths occurred in the interval c. 116–110 Ma, as indicated by the difference in zircon ages from the metatexite and diatexite migmatites.     

Multiple growth of garnet,sillimanite/kyanite and monazite during amphibolite facies metamorphism: implications for the P–T–t and tectonic evolution of the western Altai Range,Mongolia

Four amphibolite facies pelitic gneisses from the western Mongolian Altai Range exhibit multistage aluminosilicate formation and various chemical‐zoning patterns in garnet. Two of them contain kyanite in the matrix and sillimanite inclusions in garnet, and the others have kyanite inclusions in garnet with sillimanite or kyanite in the matrix. The Ca‐zoning patterns of the garnet are different in each rock type. U–Th–Pb monazite geochronology revealed that all rock units experienced a c. 360 Ma event, and three of them were also affected by a c. 260 Ma event. The variations in the microstructures and garnet‐zoning profiles are caused by the differences in the (i) whole‐rock chemistry, (ii) pressure conditions during garnet growth at c. 360 Ma and (iii) equilibrium temperatures at c. 260 Ma. The garnet with sillimanite inclusions records an increase in pressure at low‐P (~5.2–7.2 kbar) and moderate temperature conditions (~620–660 °C) at c. 360 Ma. The garnet with kyanite inclusions in the other rock types was also formed during an increase in pressure but at higher pressure conditions (~7.0–8.9 kbar at ~600–640 °C). The detrital zircon provenance of all the rock types is similar and is consistent with that from the sedimentary rocks in the Altai Range, suggesting that the provenance of all the rock types was a surrounding accretionary wedge. One possible scenario for the different thermal gradient is Devonian ridge subduction beneath the Altai Range, as proposed by several researchers. The subducting ridge could have supplied heat to the accretionary wedge and elevated the geotherm at c. 360 Ma. The differences in the thermal gradients that resulted in varying prograde P–T paths might be due to variations in the thermal regimes in the upper plate that were generated by the subducting ridge. The c. 260 Ma event is characterized by a relatively high‐T/P gradient (~25 °C km^?1) and may be due to collision‐related granitic activity and re‐equilibrium at middle crustal depths, which caused the variations in the aluminosilicates in the matrix between the rock units.     

Multiple partial melting events in the Sulu UHP terrane: zircon U–Pb dating of granitic leucosomes within amphibolite and gneiss

Thin layers and lenses of granitic leucosome are widely distributed within amphibolites, paragneisses and orthogneisses of the Sulu UHP terrane. They are parallel to, or cross‐cut, foliations in the host rocks at different scales and show evidence of coalescence and migration to form centimetre‐ to decimetre‐scale segregations. Variously migmatized rocks extend at least 350 km from SW Sulu (Maobei) to NE Sulu (Weihai), in a band at least 50 km wide. A combined study of mineral inclusions, cathoduluminescence (CL) images, U–Pb LA‐ICP‐MS dates, and in‐situ trace element compositions of zircon provide clear evidence on the nature and timing of partial melting in these UHP rocks. Most zircon from the granitic leucosomes occurs as distinct overgrowths around inherited (igneous or metamorphic) cores or as new, euhedral crystals. The overgrowths and new crystals commonly show perfectly euhedral shapes, have pronounced oscillatory zoning and contain felsic mineral inclusions, such as Kfs + Pl + Qtz ± Ilm ± monazite (Mon). In contrast, the inherited igneous or metamorphic cores are rounded or irregular, contain low‐P or UHP mineral inclusions and show clear dissolution textures. These data suggest that the new zircon is anatectic in origin and that it grew during partial melting of the UHP rocks. The REE patterns of the anatectic zircon show steep slopes from the HREE to LREE with strongly to moderately negative Eu anomalies (Eu/Eu* = 0.31–0.72) and pronounced positive Ce anomalies (Ce/Ce* = 6.8–26.5). Abundant U–Pb spot analyses of the anatectic zircon reveal two discrete and meaningful ages of partial melting within the Sulu UHP terrane. Anatectic zircon from 12 granitic leucosomes within amphibolites, paragneisses, and orthogneisses from Sulu UHP slices II and III yields consistent mean U–Pb ages of 219.0 ± 1.2 to 218.3 ± 1.6 Ma, 218.8 ± 2.0 to 217.3 ± 1.7 Ma and 218.2 ± 1.4 to 215.0 ± 1.5 Ma, respectively. In contrast, anatectic zircon from six granitic leucosomes within paragneisses and orthogneisses from Sulu UHP slice III records younger mean U–Pb ages of 151.9 ± 1.3 to 151.1 ± 1.8 Ma and 155.9 ± 1.8 to 153.7 ± 1.7 Ma, respectively. These data imply that the Sulu UHP terrane experienced two Mesozoic partial melting events. The first partial melting event (219–215 Ma) was probably associated with a Late Triassic granulite facies stage of ‘hot’ exhumation, whereas the second (156–151 Ma) is interpreted as the result of Middle‐Late Jurassic extension and thinning of the previously thickened crust of the Sulu UHP terrane. Both partial melting events induced extensive retrograde metamorphism of the eclogites and their country rocks.     

Zircon U–Pb ages and Hf isotope compositions of migmatites from the North Qinling terrane and their geological implications

Migmatites are predominant in the North Qinling (NQ) orogen, but their formation ages are poorly constrained. This paper presents a combined study of cathodoluminescence imaging, U–Pb age, trace element and Hf isotopes of zircon in migmatites from the NQ unit. In the migmatites, most zircon grains occur as new, homogeneous crystals, while some are present as overgrowth rims around inherited cores. Morphological and trace element features suggest that the zircon crystals are metamorphic and formed during partial melting. The inherited cores have oscillatory zoning and yield U–Pb ages of c. 900 Ma, representing their protolith ages. The early Neoproterozoic protoliths probably formed in an active continental margin, being a response to the assembly of the supercontinent Rodinia. The migmatite zircon yields Hf model ages of 1911 ± 20 to 990 ± 22 Ma, indicating that the protoliths were derived from reworking of Palaeoproterozoic to Neoproterozoic crustal materials. The anatexis zircon yields formation ages ranging from 455 ± 5 to 420 ± 4 Ma, with a peak at c. 435 Ma. Combined with previous results, we suggest that the migmatization of the NQ terrane occurred at c. 455–400 Ma. The migmatization was c. 50 Ma later than the c. 490 Ma ultra‐high‐P (UHP) metamorphism, indicating that they occurred in two independent tectonic events. By contrast, the migmatization was coeval with the granulite facies metamorphism and the granitic magmatism in the NQ unit, which collectively argue for their formation due to the northward subduction of the Shangdan Ocean. UHP rocks were distributed mainly along the northern margin and occasionally in the inner part of the NQ unit, indicating that they were exhumed along the northern edge and detached from the basement by the subsequent migmatization process.     

Zircon U–Pb Dating and Geochemistry of the Linong Granitoid and Its Relationship to Cu Mineralization in the Yangla Copper Deposit,Yunnan, China

The Yangla copper deposit (Cu reserves: 1.2 Mt) in the Jinshajiang–Lancangjiang–Nujiang region in China is spatially associated with the Linong granitoid. Zircon U–Pb dating shows the granitoid formed at 234.1 ± 1.2 to 235.6 ± 1.2 Ma, and the KT2 ore body of the deposit yields a molybdenite Re–Os model age of 230.9 ± 3.2 Ma. The ages of mineralization and crystallization of the granitoid are identical within the measurement uncertainties, suggesting the Yangla deposit is genitically related to the Indosinian Linong granitoid.     

Eclogite origin and timings in the North Qinling terrane,and their bearing on the amalgamation of the South and North China Blocks

The amalgamation of South (SCB) and North China Blocks (NCB) along the Qinling‐Dabie orogenic belt involved several stages of high pressure (HP)‐ultra high pressure (UHP) metamorphism. The new discovery of UHP metamorphic rocks in the North Qinling (NQ) terrane can provide valuable information on this process. However, no precise age for the UHP metamorphism in the NQ terrane has been documented yet, and thus hinders deciphering of the evolution of the whole Qinling‐Dabie‐Sulu orogenic belt. This article reports an integrated study of U–Pb age, trace element, mineral inclusion and Hf isotope composition of zircon from an eclogite, a quartz vein and a schist in the NQ terrane. The zircon cores in the eclogite are characterized by oscillatory zoning or weak zoning, high Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, pronounced Eu anomalies and steep heavy rare earth element (HREE) patterns. The zircon cores yield an age of 796 ± 13 Ma, which is taken as the protolith formation age of the eclogite, and implies that the NQ terrane may belong to the SCB before it collided with the NCB. The ?_Hf(t) values vary from ?11.3 to 3.2 and corresponding two‐stage Hf model ages are 2402 to 1495 Ma, suggesting the protolith was derived from an enriched mantle. In contrast, the metamorphic zircon rims show no zoning or weak zoning, very low Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, insignificant Eu anomalies and flat HREE patterns. They contain inclusions of garnet, omphacite and phengite, suggesting that the metamorphic zircon formed under eclogite facies metamorphic conditions, and their weighted mean ²⁰⁶Pb/²³⁸U age of 485.9 ± 3.8 Ma was interpreted to date the timing of the eclogite facies metamorphism. Zircon in the quartz vein is characterized by perfect euhedral habit, some oscillatory zoning, low Th/U ratios and variable HREE contents. It yields a weighted mean U–Pb age of 480.5 ± 2.5 Ma, which registers the age of fluid activity during exhumation. Zircon in the schist is mostly detrital and U–Pb age peaks at c. 1950 to 1850, 1800 to 1600, 1560 to 1460 and 1400 to 1260 Ma with an oldest grain of 2517 Ma, also suggesting that the NQ terrane may have an affinity to the SCB. Accordingly, the amalgamation between the SCB and the NCB is a multistage process that spans c. 300 Myr, which includes: the formation of the Erlangping intra‐oceanic arc zone onto the NCB before c. 490 Ma, the c. 485 Ma crustal subduction and UHP metamorphism of the NQ terrane, the c. 430 Ma arc‐continent collision and granulite facies metamorphism, the 420 to 400 Ma extension and rifting in relation to the opening of the Palaeo‐Tethyan ocean, the c. 310 Ma HP eclogite facies metamorphism of oceanic crust and associated continental basement, and the final 250 to 220 Ma continental subduction and HP–UHP metamorphism.     

Metamorphic evolution of a newly identified Mesoproterozoic oceanic slice in the Yuka terrane and its implications for a multi‐cyclic orogenic history of the North Qaidam UHPM belt

The North Qaidam Orogenic Belt (NQOB), lying at the northern margin of the Tibet Plateau, records two orogenic cycles: A Proterozoic cycle related to the amalgamation and breakup of the supercontinent Rodinia, and an Early Palaeozoic cycle including oceanic subduction and continental deep subduction. At present, the only information about the Proterozoic cycle is the concurrent c. 1,000–900 Ma magmatic and metamorphic events, which limited the understanding of the Proterozoic evolution of NQOB and the relationship between the Qaidam Block and other Rodinia fragments. In this study, a kyanite‐bearing eclogite was identified in Yuka terrane. It has positive‐slope chondrite‐normalized rare earth element distribution patterns, similar to present‐day N‐MORB. LA–ICP–MS zircon U–Pb dating obtained a protolith age of 1,273 Ma and an eclogite facies metamorphic age of 437 Ma, which is similar to the continental deep subduction age of the Yuka terrane. Zircon Lu–Hf analysis show that the magmatic zircon cores have high εHf(t) of 8.36–15.98 and T_DM1 of 1,450–1,131 Ma (M = 1,303 ± 55 Ma, consistent with its protolith age within error), indicating a juvenile crust protolith of the eclogite. The MORB‐like whole‐rock composition and zircon U–Pb and Lu–Hf analysis indicate that the protolith of the kyanite‐bearing eclogite was a Mesoproterozoic oceanic slice. P–T pseudosection analysis shows that the kyanite‐bearing eclogite experienced four metamorphic stages: (1) a prograde stage with the assemblage garnet+omphacite+talc+lawsonite+phengite+quartz at 22.4–23.2 kbar and 585°C; (2) a peak stage with the assemblage garnet+omphacite+lawsonite+phengite+coesite at 32.5 kbar and 670°C; (3) an early retrograde stage with the assemblage garnet+omphacite+kyanite+phengite+coesite/quartz±lawsonite at 27.1–30.0 kbar and 670–690°C; and (4) a late retrograde stage with the assemblage garnet+omphacite+epidote+hornblende+phengite+quartz at <18.0 kbar. The established clockwise P–T path is similar with other continental‐type eclogites in this area. On the basis of the geochemical and geochronological data, as well as the P–T path, we suggest that the protolith of the kyanite‐bearing eclogite was emplaced in the active margin of the Qaidam Block during the assembly of Rodinia and underwent continental deep subduction in the Early Palaeozoic. We conclude that (1) the Qaidam Block participated in the assembly of the Rodinia supercontinent. It was situated at or proximal to the margin of the supercontinent and probably close to India, east Antarctica and Tarim; and (2) both Mesoproterozoic and Early Palaeozoic oceanic crust slices occur in the NQOB. Thus, special caution is needed when using the metamorphic ages of oceanic affinity eclogites without protolith ages to constrain the evolution history of the North Qaidam UHPM belt.     

秦岭造山带中部两河口岩体花岗岩锆石U-Pb年代学、地球化学及地质意义

北秦岭两河口岩体位于太白地区,侵位于秦岭群杂岩中,主要岩性为眼球状花岗岩、片麻状花岗岩和二长花岗岩。 本文研究的眼球状花岗岩和片麻状花岗岩的结晶年龄分别为928±19 Ma 和940±12 Ma,岩石中还保留古元古代至中元古代的 继承锆石。眼球状花岗岩含有富铝矿物石榴子石和白云母。岩石的A/CNK 多大于1.1,具有高Si、富铝的特征,属于高钾钙 碱性系列。岩石轻、重稀土分馏明显,具有中等负Eu 异常。岩石富集大离子亲石元素（Rb, Ba, K 等）、亏损高场强元素 （Nb, Ta, Ti 等）,具有明显的Ba, P, Sr 负异常。矿物学和地球化学特征显示眼球状花岗岩和片麻状花岗岩为S 型花岗岩。两河 口岩体初始Sr 同位素组成变化大,87Sr/86Sr(t)=0.701067~0.739451,具有较低的εNd(t)=-5.7~-3.3, 两阶段Nd 模式年龄为TDM2= 1.9~2.1 Ga。样品具有高的放射成因Pb 同位素组成,指示两河口岩体是壳源成因岩石,其源岩可能为秦岭群斜长角闪岩和 片麻岩。结合区域地质背景,认为两河口岩体源于新元古代陆壳碰撞晚期的构造转换阶段古老中下地壳的熔融作用,是对 Rodinia 超大陆汇聚事件的响应。     

Petrography, geochemistry, and geochronology of granitoid rocks in the Neoproterozoic-Paleozoic Lufilian–Zambezi belt, Zambia: Implications for tectonic setting and regional correlation

There are several pre-orogenic Neoproterozoic granitoid and metavolcanic rocks in the Lufilian–Zambezi belt in Zambia and Zimbabwe that are interpreted to have been emplaced in a continental-rift setting that is linked to the break-up of the Rodinia supercontinent. However, no geochemical data were previously available for these rocks in the Zambian part of the belt to support this model. We conducted petrographic and whole-rock chemical analyses of the Neoproterozoic Nchanga Granite, Lusaka Granite, Ngoma Gneiss and felsic metavolcanic rocks from the Lufilian–Zambezi belt in Zambian, in order to evaluate their chemical characteristics and tectonic settings. Other magmatic rocks of importance for understanding the evolution of the belt in Zambia, included in this study, are the Mesoproterozoic Munali Hills Granite and associated amphibolites and the Mpande Gneiss. The Neoproterozoic rocks have monzogranitic compositions, aluminum-saturation indices (ASI) < 1.1, and high contents of high field strength elements (HFSE) and rare earth elements (REE). The chondrite-normalised spider diagrams are similar to those of A-type granites from the Lachlan fold belt and show negative Sr, P, and Ti anomalies. On various tectonic discrimination diagrams the Neoproterozoic rocks plot mainly in A-type granite fields. These petrographic and trace element compositions indicate that these rocks are A-type felsic rocks, but they do not have features of granites and rhyolites emplaced in true continental-rift settings, as previously suggested. On the basis of the A-type features and independent regional geological and geochronological data, we suggest that the Neoproterozoic granitoid and felsic metavolcanic rocks were emplaced during the earliest extensional stages of continental rifting in the Lufilian–Zambezi belt. The apparent continental-arc like chemistry of the granitoid and felsic metavolcanic rocks is thus inferred to be inherited from calcalkaline sources. The Mesoproterozoic Munali Hills Granite and Mpande Gneiss have trace element features e.g., Nb–Ta depletions, which indicate that that these gneisses were emplaced in a convergent-margin setting. The MORB-normalised spider diagram of co-magmatic amphibolites exhibit a fractionated LILE/HFSE pattern recognized in subduction zones. This inference is consistent with remnants of ocean crust, juvenile Island arcs and ophiolites elsewhere in the Mesoproterozoic Irumide belt in Zambia and Zimbabwe. In addition, we report the first U–Pb zircon age of 1090.1 ± 1.3 Ma for the Munali Hills Granite. The age for the Munali Hills Granite provides new constraints on correlation and tectono-thermal activity in the Lufilian–Zambezi belt. The age of the Munali Hills Granite indicates that some supracrustal rocks in the Zambezi belt of Zambia, which were previously thought to be Neoproterozoic and correlated with the Katanga Supergroup in the Lufilian belt, are Mesoproterozoic or older. Consequently, previous regional lithostratigraphic correlations in the Lufilian–Zambezi belt would require revision.     

Zircon U–Pb Geochronology and Petrogenesis of Early–Midlle Permian Arc–Related Volcanic Rocks in Central Jilin: Implications for the Tectonic Evolution of the Eastern Segment of Central Asian Orogenic Belt

This paper presents age and geochemical data of a recently identified Late Paleozoic volcanic sequence in central Jilin Province, with aims to discuss the petrogenesis and to constrain the tectonic evolution of the Central Asian Orogenic Belt in this area. Firstly, the volcanic rocks have zircon U-Pb ages of 290–270 Ma. Secondly, they are characterized by(a) ranging in composition from the low-K tholeiite series to high-K calc-alkaline series;(b) enrichment in light rare earth elements and deple...     

西昆仑甜水海地体早寒武世花岗岩浆作用及其构造意义

瓦仍孜拉甫岩体和阿依里西岩体出露于西昆仑造山带的甜水海地体中。LA-ICP-MS锆石U-Pb定年表明,阿依里西岩体的花岗质斑岩的侵位年龄为（530±6）Ma,瓦仍孜拉甫岩体的黑云母二长花岗质片麻岩的侵位年龄为（515±2）Ma,都形成于早寒武世。岩石地球化学特征表明,阿依里西岩体中花岗质斑岩的SiO2含量为67.7%~69.4%,具有较高的Mg#值（44~46）,A/CNK值为0.81~0.93;K2O含量为2.15%~3.02%,呈钙碱性至高钾钙碱性特征;其εHf（t）值为-3.3~-0.8;以轻重稀土分异较为明显,富集Cs、Rb、K、Th、Zr、Hf、Y等元素,而亏损Ba、Nb、Ta、Sr、P和Ti等元素为特点,是由幔源岩浆与壳源岩浆发生混合作用而成。瓦仍孜拉甫岩体黑云母二长花岗质片麻岩的SiO2含量高其变化范围为75.0%~76.3%,Mg#值比较低,为18~26;A/CNK值为1.01~1.30,K2O含量为4.31~4.98,表现为高钾钙碱性、过铝质特征,其εHf（t） 值为+2.5~+4.3;属于高分异I型花岗岩,源于高钾钙碱性的安山岩和玄武质安山岩的部分熔融。根据这些地球化学特征,结合西昆仑不同地质单元中早古生代花岗岩体的分布特征、地质年代学和岩石成因特征,研究认为这2个花岗质岩体形成于岛弧环境,其为进一步深入研究西昆仑造山带早古生代的构造演化过程提供了新的地质资料。     

西拉木伦构造带克德河砂砾岩的时代及构造意义

西拉木伦构造带北部双井地区发育一套巨厚的、成熟度低的快速堆积的粗碎屑沉积建造,为同造山磨拉石沉积,前人称其为克德河砂砾岩带并将其时代分别划为中二叠世(哲斯组)、晚二叠世(林西组)。本次工作对该套地层进行了大比例尺剖面测量,对取自剖面第下、中、上(1、25、86层)三个部分的砂岩样品进行LA-ICP-MS U-Pb年代学研究,结果显示：3个样品具有相似的主要年龄区间,依次为405-485Ma、401-463Ma、363-520Ma,其峰值年龄分别为427Ma、445Ma、440Ma,锆石数量分别占总量的48％、52.5％和38.75％;其次为大于1000Ma的年龄,锆石数量分别占30.7%、22.5%、45%,且均具有1800Ma和2500Ma左右的峰值年龄,明显具有华北板块基底年龄信息;自下而上3个测年样品最年轻峰值年龄分别为312Ma、376Ma,282Ma,最年轻的锆石年龄分别为304Ma、244Ma和245Ma。在第85层杂色复成分砾岩的灰岩砾石中发现晚石炭－早二叠世阿木山组的蜓和珊瑚化石,在41及43层发现中生代孢粉化石。综合碎屑锆石测年及生物化石研究结果,克德河砂砾岩带的时代应为中三叠世。推测西拉木伦构造带经历了一个较长的演化过程,中二叠世开始华北板块和西伯利亚板块进入碰撞造山阶段, 同造山磨拉石建造(克德河砂砾岩带)标志着中亚造山带演化的终止,华北板块和西伯利亚板块的碰撞拼合造山一直延续到中三叠世才结束。     

Geochronology of metarhyolites from the Kangbutiebao Formation in the Kelang basin, Altay Mountains, Xinjiang: Implications for the tectonic evolution and metallogeny

The Altay orogenic belt (AOB), situated in the middle part of the Central Asian Orogenic Belt (CAOB), is one of the most important metallogenic belts in China. The Kangbutiebao Formation is a Late Paleozoic stratigraphic unit that hosts many important iron and Pb–Zn deposits. The Kangbutiebao Formation consists of intercalated volcanic and sedimentary rocks that have undergone regional greenschist to lower amphibolite facies metamorphism, and mainly outcrops in three NW-trending fault-bounded volcano–sedimentary basins, including the Maizi, Kelang, and Chonghuer basins. SHRIMP analyses of zircons from three metarhyolites of the Kangbutiebao Fm. in the Kelang Basin yield weighted mean ²⁰⁶Pb/²³⁸U ages of 412.6 ± 3.5 Ma, 408.7 ± 5.3 Ma and 406.7 ± 4.3 Ma, respectively, which can be interpreted as the eruption age of the Kangbutiebao silicic volcanic rocks in the Kelang Basin. These ages indicate that the Kangbutiebao Formation was formed during the Late Silurian to Early Devonian. They also demonstrate that the deposits hosted in the Kangbutiebao Formation were formed after 412–407 Ma. They play a key role in understanding the Paleozoic tectonic evolution and metallogenesis of the southern margin of the Chinese AOB.     

Ore Genesis of the Lunwei Granite‐Related Scheelite Deposit in the Wuyi Metallogenic Belt,Southeast China: Constraints from Geochronology,Fluid Inclusions,and H–O–S Isotopes

A granite‐related scheelite deposit has been recently discovered in the Wuyi metallogenic belt of southeast China. The veinlet–disseminated scheelite occurs mainly in the inner and outer contact zones of the porphyritic biotite granite, spatially associated with potassic feldspathization and silicification. Re–Os dating of molybdenite intergrowths with scheelite yield a well‐constrained isochron age of 170.4 ± 1.2 Ma, coeval with the LA–MC–ICP–MS concordant zircon age of porphyritic biotite granite (167.6 ± 2.2 Ma), indicating that the Lunwei W deposit was formed in the Middle Jurassic (~170 Ma). We identify three stages of ore formation (from early to late): (I) the quartz–K‐feldspar–scheelite stage; (II) the quartz–polymetallic sulfide stage; and (III) the quartz–carbonate stage. Based on petrographic observations and microthermometric criteria, the fluid inclusions in the scheelite and quartz are determined to be mainly aqueous two‐phase (liquid‐rich and gas‐rich) fluid inclusions, with minor gas‐pure and CO₂‐bearing fluid inclusions. Ore‐forming fluids in the Lunwei W deposit show a successive decrease in temperature and salinity from Stage I to Stage III. The homogenization temperature decreases from an average of 299 °C in Stage I, through 251 °C in Stage II, to 212 °C in Stage III, with a corresponding change in salinity from an average of 5.8 wt.%, through 5.2 wt.%, to 3.4 wt.%. The ore‐forming fluids have intermediate to low temperatures and low salinities, belonging to the H₂O–NaCl ± CO₂ system. The δ¹⁸O_H2O values vary from 1.8‰ to 3.3‰, and the δD_V‐SMOW values vary from –66‰ to –76‰, suggesting that the ore‐forming fluid was primarily of magmatic water mixed with various amounts of meteoric water. Sulfur isotope compositions of sulfides (δ³⁴S ranging from –1.1‰ to +2.4‰) and Re contents in molybdenite (1.45–19.25 µg/g, mean of 8.97 µg/g) indicate that the ore‐forming materials originated mainly in the crust. The primary mechanism for mineral deposition in the Lunwei W deposit was a decrease in temperature and the mixing of magmatic and meteoric water. The Lunwei deposit can be classified as a porphyry‐type scheelite deposit and is a product of widespread tungsten mineralization in South China. We summarize the geological characteristics of typical W deposits (the Xingluokeng, Shangfang, and Lunwei deposits) in the Wuyi metallogenic belt and suggest that porphyry and skarn scheelite deposits should be considered the principal exploration targets in this area.     

Structure and U–Pb zircon geochronology in the Variscan foreland of SW Sardinia,Italy

New field mapping, U–Pb zircon geochronology and structural analysis of the southernmost Sardinia metamorphic basement, considered a branch of the Variscan foreland, indicate that it is, in part, allochthonous and was structurally emplaced within the foreland area, rather than being older depositional basement beneath the foreland succession. The Bithia Formation, classically considered part of the ‘Southern Sulcis metamorphic Complex’ (and here termed the Bithia tectonic unit, or BTU), is a greenschist facies metamorphic unit commonly interpreted as Precambrian in age. New geochronology of felsic volcanic rocks in the BTU, however, yield a U–Pb zircon age of 457.01 ± 0.17 Ma (Upper Ordovician). Thus, the depositional age of the unit is younger than the weakly metamorphosed Lower Cambrian rocks of the adjacent foreland succession. New detailed mapping and analysis of the field relationships between the BTU and foreland succession indicates that their contact is a mylonitic shear zone. The metamorphic character, general lithology, and deformational history of the BTU are similar to those of units in the Variscan Nappe Zone located northeast of the foreland area. We reinterpret the BTU as a synformal klippe of material related tectonically to the Variscan Nappe Zone. We infer that it was thrust over and became infolded into the foreland during late stages of the Variscan contractional deformation. Copyright © 2012 John Wiley & Sons, Ltd.