Formation and photochemistry of Methylamine in Jupiter's atmosphere

The formation of methylamine (CH₃NH₂) in the upper troposphere and lower stratosphere of Jupiter is investigated. Translationally hot hydrogen atoms are produced in the photolysis of ammonia, phosphine, and acetylene which react with methane to produce methyl (CH₃) radicals; the latter recombine with NH₂ to form CH₃NH₂. Also, methane is catalytically dissociated to CH₃ + H by the species C₂ and C₂H produced in the photolysis of acetylene. It is shown that the combined production of CH₃NH₂ and subsequent photolysis to HCN is unlikely to account for the HCN observed near Jupiter's tropopause. Recombination of NH₂ and C₂H₅N followed by photolysis to HCN is the preferred path. Production of C₂H₆ by these two processes is negligible in comparison to the downward flux of C₂H₆ from the Lyman α photolysis region of CH₄. An upper limit column density on CH₃PH₂ is estimated to be ～10¹³ cm^?2 as compared to 10¹⁵ cm^?2 for CH₃NH₂. Hot H atoms account for a negligible fraction of the total ortho-para conversion by the reaction H + H₂     

Ion chemistry in the cometary atmosphere

Dirty ice of a second kind (major components, H₂O, CO, and N₂; minor components less than several percents, NH₃, CH₄, and other organic substances such as HCN, CH₃CN etc.) is assumed for the composition of volatiles in the cometary nucleus. The consistency with the observations of molecular ions and daughter molecules in the cometary atmosphere is argued by taking into account various ion-molecular reactions and dissociative recombinations. There is a satisfactory agreement for the second kind of dirty-ice model, but the presence of large amounts of CH₄ and NH₃ is found to be rather in contradiction with observational evidence. A velocity of 8 km s^?1 for the hydrogen atoms, derived from analysis of the hydrogen Lyman-alpha corona around comets, is found from the dissociative recombination of H₃O⁺, the dominant constituent of cometary ionosphere, in accordance with H₃O⁺+e ^?→OH+H+H.     

Irradiation of NH3CH4 mixtures as a model of photochemical processes in the Jovian planets and Titan

Photolysis of NH₃ in the presence of CH₄ with a 185-nm light source results in the generation of hot hydrogen atoms that abstract hydrogen from the CH₄ to produce CH₃·. Subsequent reactions of CH₃· and NH₂· give hydrocarbons, CH₃NH₂, and HCN. The extent of reaction of CH₄ was measured by the ratio of the moles of CH₄ reacted per mole of NH₃ decomposed ($\text{Δ}\text{CH}{}_4\text{Δ}\text{NH}{}_3$). This ratio increases with diminishing NH₃ pressure at constant CH₄ pressure but it remains constant if $\text{CH}{}_4\text{NH}{}_3\text{?3}$. The $\text{Δ}\text{CH}{}_4\text{Δ}\text{NH}{}_3$ ratio is independent of temperature in the range 156–298° K, suggesting that hot hydrogen atoms were responsible for the reaction of CH₄. This postulate was confirmed by the observation that this reaction was quenched when H₂ or SF₆ was added to the reaction mixture.     

Nonthermal escape of hydrogen and deuterium from Venus and implications for loss of water

Nonthermal escape processes responsible for the escape of hydrogen and deuterium from Venus are examined for present and past atmospheres. Three mechanisms are important for the escape of hydrogen from the present atmosphere: (a) charge exchange of plasmaspheric H⁺ with exospheric H, (b) impact of exospheric hot O atoms on H, and (c) ion molecule reactions involving O⁺ and H₂. However, in the past when the H abundance was higher, the charge-exchange mechanism would be the strongest. The H escape flux increases rapidly with increasing hydrogen abundance in the upper atmosphere and saturates at a value of 1 × 10¹⁰ cm^?2 sec^?1 emerging primarily from the day side when the H mixing ratio at the homopause is 2 × 10^?3. This corresponds to an H₂O mixing ratio of 1 × 10^?3 at the cold trap and ～15% at the surface. Deuterium would also escape by the charge-exchange mechanism and a D/H enrichment by a factor of ～1000 over the nonthermal escape regime is expected, which could have lasted over the last 3 billion years. Coincidentally, the onset of hydrodynamic flow leading to efficient H escape occurs just at the H₂O mixing ratio at which the charge-exchange escape flux saturates. Thus it is possible that Venus has lost an Earth-equivalent ocean of water over geologic time. If so, either the D/H enrichment has been kept low by modest outgassing of juvenile water or Venus started out with a D/H ratio of ～4.0 × 10^?6.     

The absence of endogenic methane on Titan and its implications for the origin of atmospheric nitrogen

We calculate the D/H ratio of CH₄ from serpentinization on Titan to determine whether Titan’s atmospheric CH₄ was originally produced inside the giant satellite. This is done by performing equilibrium isotopic fractionation calculations in the CH₄-H₂O-H₂ system, with the assumption that the bulk D/H ratio of the system is equivalent to that of the H₂O in the plume of Enceladus. These calculations show that the D/H ratio of hydrothermally produced CH₄ would be markedly higher than that of atmospheric CH₄ on Titan. The implication is that Titan’s CH₄ is a primordial chemical species that was accreted by the moon during its formation. There are two evolutionary scenarios that are consistent with the apparent absence of endogenic CH₄ in Titan’s atmosphere. The first is that hydrothermal systems capable of making CH₄ never existed on Titan because Titan’s interior has always been too cold. The second is that hydrothermal systems on Titan were sufficiently oxidized so that C existed in them predominately in the form of CO₂. The latter scenario naturally predicts the formation of endogenic N₂, providing a new hypothesis for the origin of Titan’s atmospheric N₂: the hydrothermal oxidation of ¹⁵N-enriched NH₃. A primordial origin for CH₄ and an endogenic origin for N₂ are self-consistent, but both hypotheses need to be tested further by acquiring isotopic data, especially the D/H ratio of CH₄ in comets, and the ¹⁵N/¹⁴N ratio of NH₃ in comets and that of N₂ in one of Enceladus’ plumes.     

Evolution of CO on Titan

The early evolution of Titan's atmosphere is expected to produce enrichment in the heavy isotopomers of CO, ¹³CO and C¹⁸O, relative to ¹²C¹⁶O. However, the original isotopic signatures may be altered by photochemical reactions. This paper explains why there is no isotopic enrichment in C in Titan's atmosphere, despite significant enrichment of heavy H, N, and O isotopes. We show that there is a rapid exchange of C atoms between the CH₄ and CO reservoirs, mediated by the reaction ¹CH₂+*CO→¹*CH₂+CO, where *C is ¹³C. Based on recent laboratory measurements, we estimate the rate coefficient for this reaction to be 3.2×10⁻¹² cm³ s⁻¹ at the temperature appropriate for the upper atmosphere of Titan. We investigate the isotopic dilution of CO using the Caltech/JPL one-dimensional photochemical model of Titan. Our model suggests that the time constant for isotopic exchange through the above reaction is about 800 Myr, which is significantly shorter than the age of Titan, and therefore any original isotopic enhancement of ¹³C in CO may have been diluted by the exchange process. In addition, a plausible model for the evolution history of CO on Titan after the initial escape is proposed.     

Ion composition and chemistry in the coma of Comet 1P/Halley—A comparison between Giotto's Ion Mass Spectrometer and our ion-chemical network

In order to understand the cometary plasma environment it is important to track the closely linked chemical reactions that dominate ion evolution. We used a coupled MHD ion-chemistry model to analyze previously unpublished Giotto High Intensity Ion Mass Spectrometer (HIS-IMS) data. In this way we study the major species, but we also try to match some minor species like the CH_x and the NH_x groups. Crucial for this match is the model used for the electrons since they are important for ion-electron recombination. To further improve our results we included an enhanced density of supersonic electrons in the ion pile-up region which increases the local electron impact ionization. In this paper we discuss the results for the following important ions: C⁺, CH⁺, CH⁺₂, CH⁺₃, N⁺, NH⁺, NH⁺₂, NH⁺₃, NH⁺₄, O⁺, OH⁺, H₂O⁺, H₃O⁺, CO⁺, HCO⁺, H₃CO⁺, and CH₃OH⁺₂. We also address the inner shock which is very distinctive in our MHD model as well as in the IMS data. It is located just inside the contact surface at approximately 4550 km. Comparisons of the ion bulk flow directions and velocities from our MHD model with the data measured by the HIS-IMS give indication for a solar wind magnetic field direction different from the standard Parker angle at Halley's position. Our ion-chemical network model results are in a good agreement with the experimental data. In order to achieve the presented results we included an additional short lived inner source for the C⁺, CH⁺, and CH⁺₂ ions. Furthermore we performed our simulations with two different production rates to better match the measurements which is an indication for a change and/or an asymmetric pattern (e.g. jets) in the production rate during Giotto's fly-by at Halley's comet.     

H and Cl isotope systematics of apatite in brecciated lunar meteorites Northwest Africa 4472, Northwest Africa 773, Sayh al Uhaymir 169, and Kalahari 009

We have investigated the H and Cl systematics in apatite from four brecciated lunar meteorites. In Northwest Africa (NWA) 4472, most of the apatites contain ～2000–6000 ppm H₂O with δD between ?200 and 0‰, except for one grain isolated in the matrix, which contains ～6000 ppm H₂O with δD of ～500–900‰. This low‐δD apatite contains ～2500–7500 ppm Cl associated with δ³⁷Cl of ～15–20‰, while the high‐δD grain contains ～2500 ppm Cl with δ³⁷Cl of ～7–15‰. In NWA 773, apatites in a first group contain ～700–2500 ppm H₂O with δD values averaging around ～0 ± 100‰, while apatites in a second group contain ～5500–16500 ppm H₂O with δD ～250 ± 50‰. In Sayh al Uhaymir (SaU) 169 and Kalahari (Kal) 009, apatites are similar in terms of their H₂O contents (～600–3000 ppm) and δD values (?100 to 200‰). In SaU 169, apatites contain ～6000–10,000 ppm Cl, characterized by δ³⁷Cl of ～5–12‰. Overall, most of the analyzed apatite grains have δD within the range reported for carbonaceous chondrites, similar to apatite analyzed in ancient (>3.9 Ga) lunar magmatic. One grain in NWA 4472 has H and Cl isotope compositions similar to apatite from mare basalts. With an age of 4.35 Ga, this grain could be a representative of the oldest known lunar volcanic activity. Finally, since numerous evolved clasts in NWA 773 formed through silicate liquid immiscibility, the apatite grains with extremely high H₂O contents, reaching pure hydroxylapatite composition, could provide insights into the effects of such process on the evolution of volatiles in lunar magmas.     

Estimated impact shock production of N2 and organic compounds on early Titan

Bombardment of Titan by Uranus-Neptune planetesimals and/or fragments of a disrupted Hyperion progenitor supplied more than enough energy to drive vigorous atmospheric shock chemistry. Chemical equilibrium modeling of the shock products in simulated atmospheres indicates that impact energy has produced large amounts of N₂ and organic compounds over Titan's history. The mole fraction of organic compounds in the shocked gas mixture (T = 1200−2500°K, P = 10⁻¹−10³bar) reaches a maximum of approximately 3% in a current Titan mixture and 12% in a primordial CH₄, NH₃-rich mixture. Atmospheric water mixing ratio controls the organic yield in shock reactions, but its limiting effect may have been reduced by cold-trapping of water in a cooling atmosphere. Kinetic inhibition of graphite formation in the shocked gas enhanced the yield of radicals and organic. The resulting mixture of carbonaceous soot and condensed hydrocarbons subsequently settled onto the surface; the depth of the generated layer was on the order of hundreds of meters. Impact shock energy was capable of converting massive amounts of NH₃ to N₂ early in Titan history—over twice the present atmospheric and 1.5 times the total ocean-atmospheric inventory of N₂. Shock conversion of NH₃ into N₂ bypasses the difficulties of other schemes of N₂ production and may have been of singular importance in Titan's atmospheric evolution.     

Interpretation of the carbon abundance in Saturn measured by Cassini

Spectral observations of Saturn from the far infrared spectrometer aboard the Cassini spacecraft [Flasar, F.M., et al., 2005. Temperatures, winds, and composition in the Saturnian system. Science 307, 1247-1251] have revealed that the C/H ratio in the planet is in fact about twice higher than previously derived from ground based observations and in agreement with the C/H value derived from Voyager IRIS by Courtin et al. [1984. The composition of Saturn's atmosphere at northern temperate latitudes from Voyager IRIS spectra - NH₃, PH₃, C₂H₂, C₂H₆, CH₃D, CH₄, and the Saturnian D/H isotopic ratio. Astrophys. J. 287, 899-916]. The implications of this measurement are reanalyzed in the present report on the basis that volatiles observed in cometary atmospheres, namely CO₂, CH₄, NH₃ and H₂S may have been trapped as solids in the feeding zone of the planet. CH₄ and H₂S may have been in the form of clathrate hydrates while CO₂ presumably condensed in the cooling solar nebula. Carbon may also have been incorporated in organics. Conditions of temperature and pressure ease the hydratation of NH₃. Such icy grains were included in planetesimals which subsequently collapsed into the hydrogen envelope of the planet, then resulting in C, N and S enrichments with respect to the solar abundance. Our calculations are consistent, within error bars, with observed elemental abundances on Saturn provided that the carbon trapped in planetesimals was mainly in the form of CH₄ clathrate and CO₂ ice (and maybe as organics) while nitrogen was in the form of NH₃ hydrate. Our approach has implications on the possible pattern of noble gases in Saturn, since we predict that contrary to what is observed in Jupiter, Ar and Kr should be in solar abundance while Xe might be strongly oversolar. The only way to verify this scenario is to send a probe making in situ mass spectrometer measurements. Our scenario also predicts that the ¹⁴N/¹⁵N ratio should be somewhat smaller in Saturn than measured in Jupiter by Galileo.     

The abundance of CH3D in the atmosphere of Titan,derived from 8- to 14-μm thermal emission

The 8.6-μm emission feature of Titan's infrared spectrum was analyzed using the Voyager temperature-pressure profile. Although both C₃H₈ and CH₃D have bands at that wavelength, we show that CH₃D dominates the observed emission on Titan. We derived a CH₃D/CH₄ mixing ratio using this band and the strong CH₄ band at 7.7 μm. The corresponding D/H ratio is 4.2_?1.5⁺² × 10^?4, neglecting deuterium fractionation with other molecules. The main uncertainty in this value comes from the continuum emission characteristics. The D/H ratio is apparently significantly enhanced on Titan with respect to published values for Saturn.     

An estimate of the PH3, CH3D,and GeH4 Abundances on Jupiter from the Voyager IRIS data at 4.5 μm

The abundances of PH₃, CH₃D, and GeH₄ are derived from the 2100- to 2250-cm^?1 region of the Voyager 1 IRIS spectra. No evidence is seen for large-scale variations of the phosphine abundance over Jovian latitudes between ?30 and +30°. In the atmospheric regions corresponding to 170–200°K, the derived PH₃/H₂ value is (4.5 ± 1.5) × 10^?7 or 0.75 ± 0.25 times the solar value. This result, compared with other PH₃ determinations at 10 μm, suggests than the PH₃/H₂ ratio on Jupiter decreases with atmospheric pressure. In the 200–250°K region, we derive, within a factor of 2, CH₃D/H₂ and GeH₄/H₂ ratios of 2.0 × 10^?7 and 1.0 × 10^?9, respectively. Assuming a C/H value of 1.0 × 10^?3, as derived from Voyager, our CH₃D/H₂ ratio implies a D/H ratio of 1.8 × 10^?5, in reasonable agreement with the interstellar medium value.     

Cosmic ray synthesis of organic molecules in Titan's atmosphere

We have studied the possible synthesis of organic molecules by the absorption of galactic cosmic rays in an N₂CH₄H₂ Titan model atmosphere. The cosmic-ray-induced ionization results in peak electron densities of 2 × 10³ cm^?3, with NH₄⁺, C₃H₉⁺, and C₄H₉⁺ being among the important positive ions. Details of the ion and neutral chemistry relevant to the production of organic molecules are discussed. The potential importance of $\text{N}\text{(}{}^2\text{D)}$ reactions with CH₄ and H₂ is also demonstrated. Although the integrated production rate of organic matter due to the absorption of the cosmic ray cascade is much less than that by solar ultraviolet radiation, the production of nitrogen-bearing organic molecules by cosmic rays may be greater.     

The D/H Ratio in Methane in Titan: Origin and History

We propose a new interpretation of the D/H ratio in CH₄ observed in the atmosphere of Titan. Using a turbulent evolutionary model of the subnebula of Saturn (O. Mousis et al. 2002, Icarus156, 162-175), we show that in contrast to the current scenario, the deuterium enrichment with respect to the solar value observed in Titan cannot have occurred in the subnebula. Instead, we argue that values of the D/H ratio measured in Titan were obtained in the cooling solar nebula by isotopic thermal exchange of hydrogen with CH₃D originating from interstellar methane D-enriched ices that vaporized in the nebula. The rate of the isotopic exchange decreased with temperature and became fully inhibited around 200 K. Methane was subsequently trapped in crystalline ices around 10 AU in the form of clathrate hydrates formed at 60 K, and incorporated into planetesimals that formed the core of Titan. The nitrogen-methane atmosphere was subsequently outgassed from the decomposition of the hydrates (Mousis et al. 2002). By use of a turbulent evolutionary model of the solar nebula (O. Mousis et al. 2000, Icarus148, 513-525), we have reconstructed the entire story of D/H in CH₄, from its high value in the early solar nebula (acquired in the presolar cloud) down to the value measured in Titan's atmosphere today. Considering the two last determinations of the D/H ratio in Titan—D/H=(7.75±2.25)×10⁻⁵ obtained from ground-based observations (Orton 1992, In: Symposium on Titan, ESA SP-338, pp. 81-85), and D/H=(8.75^+3.25_−2.25)×10⁻⁵, obtained from ISO observations (Coustenis et al. 2002, submitted for publication)—we inferred an upper limit of the D/H ratio in methane in the early outer solar nebula of about 3×10⁻⁴. Our approach is consistent with the scenario advocated by several authors in which the atmospheric methane of Titan is continuously replenished from a reservoir of clathrate hydrates of CH₄ at high pressures, located in the interior of Titan. If this scenario is correct, observations of the satellite to be performed by the radar, the imaging system, and other remote sensing instruments aboard the spacecraft of the Cassini-Huygens mission from 2004 to 2008 should reveal local disruptions of the surface and other signatures of the predicted outgassing.     

The atmospheric composition and structure of Jupiter and Saturn from ISO observations: a preliminary review

Infrared spectra of Jupiter and Saturn have been recorded with the two spectrometers of the Infrared Space Observatory (ISO) in 1995–1998, in the 2.3–180 μm range. Both the grating modes (R=150–2000) and the Fabry-Pérot modes (R=8000–30,000) of the two instruments were used. The main results of these observations are (1) the detection of water vapour in the deep troposphere of Saturn; (2) the detection of new hydrocarbons (CH₃C₂H, C₄H₂, C₆H₆, CH₃) in Saturn’s stratosphere; (3) the detection of water vapour and carbon dioxide in the stratospheres of Jupiter and Saturn; (4) a new determination of the D/H ratio from the detection of HD rotational lines. The origin of the external oxygen source on Jupiter and Saturn (also found in the other giant planets and Titan in comparable amounts) may be either interplanetary (micrometeoritic flux) or local (rings and/or satellites). The D/H determination in Jupiter, comparable to Saturn’s result, is in agreement with the recent measurement by the Galileo probe (Mahaffy, P.R., Donahue, T.M., Atreya, S.K., Owen, T.C., Niemann, H.B., 1998. Galileo probe measurements of D/H and ³He/⁴He in Jupiters atmosphere. Space Science Rev. 84 251–263); the D/H values on Uranus and Neptune are significantly higher, as expected from current models of planetary formation.     

Titan's corona: The contribution of exothermic chemistry

The contribution of exothermic ion and neutral chemistry to Titan's corona is studied. The production rates for fast neutrals N₂, CH₄, H, H₂, ³CH₂, CH₃, C₂H₄, C₂H₅, C₂H₆, N(⁴S), NH, and HCN are determined using a coupled ion and neutral model of Titan's upper atmosphere. After production, the formation of the suprathermal particles is modeled using a two-stream simulation, as they travel simultaneously through a thermal mixture of N₂, CH₄, and H₂. The resulting suprathermal fluxes, hot density profiles, and energy distributions are compared to the N₂ and CH₄ INMS exospheric data presented in [De La Haye, V., Waite Jr., J.H., Johnson, R.E., Yelle, R.V., Cravens, T.E., Luhmann, J.G., Kasprzak, W.T., Gell, D.A., Magee, B., Leblanc, F., Michael, M., Jurac, S., Robertson, I.P., 2007. J. Geophys. Res., doi:10.1029/2006JA012222, in press], and are found insufficient for producing the suprathermal populations measured. Global losses of nitrogen atoms and carbon atoms in all forms due to exothermic chemistry are estimated to be and .     

Radioastronomical observations of comets IRAS-Araki-Alcock (1983d) and Sugano-Saigusa-Fujikawa (1983e)

Detections and upper limits to the continuum emission (1 ≤ λ ≤6 cm) and spectral line emission (OH, CO, CS, HCN, HCO⁺, CN, CH₃CN, CH₃C₂H, NH₃, H₂O, HC₃N, CH₃CH₂CN) are reported from radio observations of Comets 1983d and 1983e. Comparison is made with observations of CN at optical wavelengths. These results may be useful in planning future cometary observations.     

Infrared study of ion-irradiated N2-dominated ices relevant to Triton and Pluto: formation of HCN and HNC

Infrared spectra and radiation chemical behavior of N₂-dominated ices relevant to the surfaces of Triton and Pluto are presented. This is the first systematic IR study of proton-irradiated N₂-rich ices containing CH₄ and CO. Experiments at 12 K show that HCN, HNC, and diazomethane (CH₂N₂) form in the solid phase, along with several radicals. NH₃ is also identified in irradiated N₂ + CH₄ and N₂ + CH₄ + CO. We show that HCN and HNC are made in irradiated binary ice mixtures having initial N₂/CH₄ ratios from 100 to 4, and in three-component mixtures have an initial N₂/(CH₄ + CO) ratio of 50. HCN and HNC are not detected in N₂-dominated ices when CH₄ is replaced with C₂H₆, C₂H₂, or CH₃OH.The intrinsic band strengths of HCN and HNC are measured and used to calculate G(HCN) and G(HNC) in irradiated N₂ + CH₄ and N₂ + CH₄ + CO ices. In addition, the HNC/HCN ratio is calculated to be ∼1 in both icy mixtures. These radiolysis results reveal, for the first time, solid-phase synthesis of both HCN and HNC in N₂-rich ices containing CH₄.We examine the evolution of spectral features due to acid-base reactions (acids such as HCN, HNC, and HNCO and a base, NH₃) triggered by warming irradiated ices from 12 K to 30-35 K. We identify anions (OCN⁻, CN⁻, and N3−) in ices warmed to 35 K. These ions are expected to form and survive on the surfaces of Triton and Pluto. Our results have astrobiological implications since many of these products (HCN, HNC, HNCO, NH₃, NH₄OCN, and NH₄CN) are involved in the syntheses of biomolecules such as amino acids and polypeptides.     

Molecular emission in dense massive clumps from the star-forming regions S231–S235

The paper is concerned with the study of the star-forming regions S231–S235 in radio lines of molecules of the interstellar medium—carbon monoxide (CO), ammonia (NH₃), cyanoacetylene (HC₃N), in maser lines—methanol (CH₃OH) and water vapor (H₂O). The regions S231–S235 belong to the giant molecular cloudG174+2.5. The goal of this paper is to search for new sources of emission toward molecular clumps and to estimate their physical parameters from CO and NH₃ molecular lines. We obtained new detections ofNH₃ andHC₃Nlines in the sources WB89673 and WB89 668 which indicates the presence of high-density gas. From the CO line, we derived sizes, column densities, and masses of molecular clumps. From the NH₃ line, we derived gas kinetic temperatures and number densities in molecular clumps. We determined that kinetic temperatures and number densities of molecular gas are within the limits 16–30 K and 2.8–7.2 × 10³ cm^?3 respectively. The shock-tracing line of CH₃OH molecule at a frequency of 36.2 GHz was detected in WB89 673 for the first time.     

On the C/H and D/H ratios in the atmospheres of Jupiter and Saturn

Using a method defined in a previous paper [M. Combes and T. Encrenaz, Icarus39 1–27 (1979)], we reestimated the C/H ratio in the atmospheres of Jupiter and Saturn by the measurements of the weak visible CH₄ bands, the CH₄ 3ν₃ band, and the (3-0) and (4-0) quadrupole bands of H₂. In the case of Jupiter we conclude that the C/H ratio is enriched by a factor ranging from 1.7 to 3.6 relative to the solar value. In the case of Saturn, our derived C/H value ranges from 1.2 to 3.2 times the solar value. The Jovian D/H ratio derived from this study is 1.2 × 10^?5 < D/H < 3.1 × 10^?5. The value derived for the D/H ratio on Saturn is not precise enough to be conclusive.