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1.
N. Stark R. Wilkens V. B. Ernstsen M. Lambers-Huesmann S. Stegmann A. Kopf 《Geotechnical and Geological Engineering》2012,30(1):1-14
The societal usage of coastal zones (including offshore wind energy plants, waterway deepening, beach conservation and restoration)
is of emerging importance. Sediment dynamics in these areas result in sandy deposits due to strong tidal and wave action,
which is difficult to simulate in laboratory geotechnical tests. Here, we present data from in situ penetrometer tests using
the lightweight, free-fall Nimrod penetrometer and complementary laboratory experiments to characterize the key physical properties of sandy seafloors in areas
dominated by quartzose (North Sea, Germany) and calcareous (Hawaii, USA) mineralogy. The carbonate sands have higher friction
angles (carbonate: 31–37°; quartz: 31–32°) and higher void ratios (carbonate: 1.10–1.40; quartz: 0.81–0.93) than their siliceous
counterparts, which have partly been attributed to the higher angularity of the coral-derived particles. During the in situ
tests, we consistently found higher sediment strength (expressed in deceleration as well as in estimated quasi-static bearing
capacity) in the carbonate sand (carbonate: 68–210 g; quartz: 25–85 g), which also showed a greater compressibility. Values
were additionally affected by seafloor inclination (e.g., along a sub-aqueous dune or a channel), or layering in areas of
sediment mobilization (by tides, shorebreak or currents). The study shows that the differences in in situ measured penetration
profiles between carbonate sands and quartz sands are supported by the laboratory results and provide crucial information
on mobile layers overlying sands of various physical properties. 相似文献
2.
The competitive adsorption of trace elements is a key issue in assessing the mobility of trace elements in calcareous soils
and can be affected by disposal of sewage sludge, municipal waste, and poultry manure. The effect of municipal sewage sludge,
poultry manure, and municipal waste compost on the sorption of cadmium (Cd), copper (Cu), zinc (Zn), and nickel (Ni) in surface
samples of three calcareous soils was studied. As the applied concentrations increased, Cu and Cd adsorption increased, while
Zn and Ni adsorption decreased in all treatments. Based on the distribution coefficient (K
d) values and proportion of increase or decrease in metal adsorption, the selectivity sequence in control and amended soils
found was Cu ≫ Cd ≫ Ni > Zn and Cu ≫ Cd ≫ Zn > Ni, respectively. In general, among control and amended soils, control soils
showed the highest K
d for Cd, Cu, and Ni, while sludge, poultry manure, and composted waste-amended soils had lowest K
d for Cd, Cu, and Ni, respectively. In the case of Zn, composted waste-amended and control soils had highest and lowest K
d, respectively. The present experimental results indicated that the addition of organic amendments to these calcareous soils
reduced the sorption of Cd, Cu, and Ni. Thus, the effects of preferential adsorption and organic matter should be considered
in assessing the risk associated with applying sewage sludge, poultry manure, and composted material to calcareous soils. 相似文献
3.
Soil hydraulic properties such as soil infiltration rate and hydraulic conductivity are closely linked to runoff generation
and infiltration processes but little is known about them on karst hillslopes. The objectives of this paper were to investigate
the change in soil stable infiltration rate (q
s) and near-saturated hydraulic conductivity (K
ns) in different slope positions and to understand their relationship with rock fragment content and soil texture within the
topsoil in subtropical karst regions of southwest China. Tension infiltrometers (20 cm in diameter) were used to measure q
s and K
ns at pressure head of −20 mm on hillslopes 1 (a disintegrated landslide failure) and 2 (an avalanche slope). The change of
q
s and K
ns was great and they mostly had a moderate variability with coefficient of variations (CV) between 0.1 and 1.0 in the different
slope positions. On average, q
s ranged from 0.43 to 4.25 mm/min and K
ns varied from 0.75 to 11.00 mm/min. These rates exceed those of most natural rainfall events, confirming that overland flow
is rare on karst hillslopes. From bottom to top, q
s and K
ns had a decrease–increase–decrease trend due to the presence of large rock outcrops (>2 m in height) on hillslope 1 but had
an increasing trend on hillslope 2 with less complex landform. They tended to increase with increase in total rock fragment
content (5–250 mm) within the topsoil as well as slope gradient on both hillslopes. Pearson correlation analysis suggested
that higher coarse pebble (20–75 mm), cobble (75–250 mm), and sand (2–0.05 mm) contents as well as total rock fragment content
could significantly facilitate water infiltration into soils, but higher clay (<0.002 mm) content could restrict water movement.
This result indicated that rock fragment, sand, and clay contents may remarkably affect water flow in the topsoil layers,
and should be considered in hydrological modeling on karst hillslopes in subtropical regions. 相似文献
4.
A. Pavese V. Diella V. Pischedda M. Merli R. Bocchio M. Mezouar 《Physics and Chemistry of Minerals》2001,28(4):242-248
The thermoelastic parameters of natural andradite and grossular have been investigated by high-pressure and -temperature
synchrotron X-ray powder diffraction, at ESRF, on the ID30 beamline. The P–V–T data have been fitted by Birch-Murnaghan-like EOSs, using both the approximated and the general form. We have obtained for
andradite K
0=158.0(±1.5) GPa, (dK/dT )0=−0.020(3) GPa K−1 and α0=31.6(2) 10−6 K−1, and for grossular K
0=168.2(±1.7) GPa, (dK/dT)0=−0.016(3) GPa K−1 and α0=27.8(2) 10−6 K−1. Comparisons between the present issues and thermoelastic properties of garnets earlier determined are carried out.
Received: 7 July 2000 / Accepted: 20 October 2000 相似文献
5.
Margaret Hanrahan Gerhard Brey Alan Woodland Rainer Altherr Hans-Micheal Seitz 《Contributions to Mineralogy and Petrology》2009,158(2):169-183
An eclogite barometer has profound importance in the study of upper mantle processes and potential application to diamond
prospecting. Studies on the partitioning of Li between clinopyroxene (cpx) and garnet (grt) in natural samples have shown
that this particular element is very sensitive to changes in pressure and could be calibrated as the barometer demanded for
bimineralic eclogites. Experiments were performed from 4 to 13 GPa and 1,100–1,400°C in the CMAS (CaO, MgO, Al2O3, SiO2) system with Li added as Li3PO4 to quantify this pressure dependence into a barometer expressed in the following equation: P = (0.00255T – ln K
d)/0.2351 where P is in GPa, T is in °C and K
d is defined as the partition coefficient of Li (in ppm) between clinopyroxene and garnet. The experimental pressures are reproduced
to ±0.38 GPa (1σ) by this equation. This barometer is strictly applicable only to CMAS. Experiments at 1,300°C, 8–12 GPa showed
that Henry’s Law is fulfilled for Li partitioning between cpx and grt in the concentration range of approximately 0.01–1 wt%
Li. Direct application of the equation to experiments in natural systems performed at 1,300°C from 4 to 13 GPa consistently
overestimates pressures by approximately 2 GPa.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
6.
Laura Borgnino Carlos P. De Pauli Pedro J. Depetris 《Environmental Earth Sciences》2012,65(2):441-451
Arsenate adsorption was studied in three clastic sediments, as a function of solution pH (4.0–9.0) and arsenate concentration.
Using known mineral values, protolytic constants obtained from the literature and K
ads values (obtained by fitting experimental adsorption data with empirical adsorption model), the constant capacitance surface
complexation model was used to explain the adsorption behavior. The experimental and modelling approaches indicate that arsenate
adsorption increases with increased pH, exhibiting a maximum adsorption value before decreasing at higher pH. Per unit mass,
sample S3 (smectite–quartz/muscovite–illite sample) adsorbs more arsenate in the pH range 5–8.5, with 98% of sites occupied at pH 6.
S1 and S2 have less adsorption capacity with maxima adsorption in the pH ranges of 6–8.5 and 4–6, respectively. The calculation of
saturation indices by PHREEQC at different pH reveals that the solution was undersaturated with respect to aluminum arsenate
(AlAsO42H2O), scorodite (FeAsO42H2O), brucite and silica, and supersaturated with respect to gibbsite, kaolinite, illite and montmorillonite (for S3 sample). Increased arsenate concentration (in isotherm experiments) may not produce new solid phases, such as AlAsO42H2O and/or FeAsO42H2O. 相似文献
7.
Simultaneous competitive adsorption behavior of Cd, Cu, Pb and Zn onto nine soils with a wide physical–chemical characteristics
from Eastern China was measured in batch experiments to assess the mobility and retention of these metals in soils. In the
competitive adsorption system, adsorption isotherms for these metals on the soils exhibited significant differences in shape
and in the amount adsorbed. As the applied concentration increased, Cu and Pb adsorption increased, while Cd and Zn adsorption
decreased. Competition among heavy metals is very strong in acid soils with lower capacity to adsorb metal cations. Distribution
coefficients (K
dmedium) for each metal and soil were calculated. The highest K
dmedium value was found for Pb and followed by Cu. However, low K
dmedium values were shown for Zn and Cd. On the basis of the K
dmedium values, the selectivity sequence of the metal adsorption is Pb > Cu > Zn > Cd and Pb > Cu > Cd > Zn. The adsorption sequence
of nine soils was deduced from the joint distribution coefficients (K
dΣmedium). This indicated that acid soils with low pH value had lower adsorption capacity for heavy metals, resulting in much higher
risk of heavy metal pollution. The sum of adsorbed heavy metals on the soils could well described using the Langmuir equation.
The maximum adsorption capacity (Q
m) of soils ranged from 32.57 to 90.09 mmol kg−1. Highly significant positive correlations were found between the K
dΣmedium and Q
m of the metals and pH value and cation exchange capacity (CEC) of soil, suggesting that soil pH and CEC were key factors controlling
the solubility and mobility of the metals in soils. 相似文献
8.
Yunfeng Li Weifeng Wan Wanfang Zhou Juan Xie Yaoguo Wu Jiangxia Wang 《Environmental Earth Sciences》2011,64(6):1647-1651
Untreated disposal of wastewater from coal-fired power plants has environmental and public health concerns in the developing
Shanbei Energy Base, Northwest China. An in situ experiment was conducted in the easily accessible wind-blown sands to study
their efficiency in removal of pollutants. Approximately 245 l of wastewater was used in the test, which lasted 409 min. Sand
samples were collected at 5 discrete depths, 0.2, 0.4, 0.6, 1, and 1.5 m from the surface before, at the end of, and 20 days
after the infiltration test. Pollutants commonly found in wastewater were analyzed for all the sand samples. 20 days after
infiltration, the content of As in the sand samples had a general reduction, decreased from original 0.0109–0.0132 to 0.005 mg/kg.
The content of N-NH4 also decreased from original 1.1–1.5 to 0.8–1.0 mg/kg. But the content of Cd and petroleum was stable and had no decreasing
trend. The test indicates the wind-blown sands are more effective for As and N-NH4, but less effective for petroleum and Cd. 相似文献
9.
Angela Ullrich Ronald Miletich Tonci Balic-Zunic Lars Olsen Fabrizio Nestola Manfred Wildner Haruo Ohashi 《Physics and Chemistry of Minerals》2010,37(1):25-43
A compressional study of (Na,Ca)(Ti3+,Mg)Si2O6-clinopyroxenes was carried out at high pressures between 10−4 and 10.2 GPa using in situ single-crystal X-ray diffraction, Raman spectroscopy and optical absorption spectroscopy. Compressional
discontinuities accompanied by structural changes, in particular, the appearance of two distinct Ti3+–Ti3+ distances within the octahedral chains at 4.37 GPa, provide evidence for the occurrence of a phase transition in NaTi3+Si2O6. Equation-of-state parameters are K
0 = 115.9(7) GPa with K′ = −0.9(3) and K
0 = 102.7(8) GPa with K′ = 4.08(5) for the low- and high-pressure range, respectively. The transition involves a C2/c–P
[`1] \overline{1} symmetry change, which can be confirmed by the occurrence of new modes in Raman spectra. Since no significant discontinuity
in the evolution of the unit-cell volume with pressure has been observed, the transition appears to be second-order in character.
The influence of the coupled substitution Na+Ti3+↔Ca2+Mg2+ on the static compression behavior and the structural stability has been investigated using a sample of the intermediate
composition (Na0.54Ca0.46)(Mg0.46Ti0.54)Si2O6. No evidence for a deviation from continuous compression behavior has been found, neither in lattice parameter nor in structural
data and the fit of a third-order Birch–Murnaghan equation-of-state to the pressure–volume data yields a bulk modulus of K
0 = 109.1(5) GPa and K′ = 5.02(13). Raman and polarized absorption spectra have been compared to NaTiSi2O6 and reveal major similarities. The main driving force for the phase transition in NaTi3+Si2O6 is the localization of the Ti3+
d-electron and the accompanying distortion, which is suppressed in the (Na,Ca)(Ti3+,Mg)Si2O6-clinopyroxene. 相似文献
10.
Steeve Gréaux Yoshio Kono Norimasa Nishiyama Takehiro Kunimoto Kouhei Wada Tetsuo Irifune 《Physics and Chemistry of Minerals》2011,38(2):85-94
The thermoelastic parameters of synthetic Ca3Al2Si3O12 grossular garnet were examined in situ at high-pressure and high-temperature by energy dispersive X-ray diffraction, using
a Kawai-type multi-anvil press apparatus coupled with synchrotron radiation. Measurements have been conducted at pressures
up to 20 GPa and temperatures up to 1,650 K: this P, T range covered the entire high-P, T stability field of grossular garnet. The analysis of room temperature data yielded V
0,300 = 1,664 ± 2 ?3 and K
0 = 166 ± 3 GPa for K¢0 K^{\prime}_{0} fixed to 4.0. Fitting of our P–V–T data by means of the high-temperature third order Birch–Murnaghan or the Mie–Grüneisen–Debye thermal equations of state,
gives the thermoelastic parameters: (∂K
0,T
/∂T)
P
= −0.019 ± 0.001 GPa K−1 and α
0,T
= 2.62 ± 0.23 × 10−5 K−1, or γ
0 = 1.21 for fixed values q
0 = 1.0 and θ
0 = 823 (Isaak et al. Phys Chem Min19:106–120, 1992). From the comparison of fits from two different approaches, we propose to constrain the bulk modulus of grossular garnet
and its pressure derivative to K
T0 = 166 GPa and K¢T0 K^{\prime}_{T0} = 4.03–4.35. Present results are compared with previously determined thermoelastic properties of grossular-rich garnets. 相似文献
11.
Competitive adsorption,release and speciation of heavy metals in the Yellow River sediments,China 总被引:2,自引:0,他引:2
Qingyun Fan Jiang He Hongxi Xue Changwei LÜ Ying Liang Saruli Ying Sun Lili Shen 《Environmental Geology》2007,53(2):239-251
The competitive adsorption and the release of selected heavy metals and their speciation distribution before and after adsorption
in the Yellow River sediments are discussed. The adsorption of metals onto sediments increases with increasing pH value and
decreases with increasing ionic strength. The competitive coefficient K
c and the distribution coefficient K
d are obtained to analyze the competitive abilities of selected heavy metals, which are ranked as Pb > Cu >> Zn > Cd. The competition
among selected heavy metals becomes more impetuous with increasing ion concentration in water. Speciation analysis was done
by an improved analytical procedure involving five steps of sequential extraction. Cu, Pb and Zn were mainly transformed into
the carbonate-bound form (50.8–87.7%) in adsorption. Most of (60.7–77.3%) Cd was transformed into the exchangeable form, and
the percentage of carbonate-bound Cd was 19.7–30.4%. The release reaction was so quick that the release capacity of selected
heavy metals from sediments to aqueous solution reached half of the maximum value only in 30 s. As opposed to adsorption,
the release capacities of selected heavy metals were ranked as Cd > Zn >> Cu > Pb. In this study, Cd produces the most severe
environmental hazards, because its concentration in the release solution is 85.8 times more than the human health criteria
of US EPA. 相似文献
12.
Phosphorus Speciation in Stream Bed Sediments from an Agricultural Watershed: Solid-Phase Associations and Sorption Behavior 总被引:1,自引:0,他引:1
The sorption behavior and solid-phase associations of phosphorus (P) in fine-grained sediments (<63 μm) from two upstream
tributaries and one downstream main stem site of the Spoon River in west-central Illinois were characterized to better understand
phosphorus bioavailability in this agriculturally dominated watershed. The P sorption affinities, as indicated by linear distribution
coefficients (K
d), of all sediments were 330–5,150 L/kg, and negatively correlated with equilibrium phosphorus concentration (EPCo) values, which ranged between 0.2 and 2.2 μM. pH values measured at the conclusion of the sorption experiments varied only
slightly (7.45–8.10) but were nonetheless strongly positively correlated to EPCo values, and negatively correlated to K
d values, suggesting the importance of pH to the observed sorption behavior. K
d values were generally lower and EPCo values higher at the main stem site than at the upstream tributary sites, suggesting dissolved reactive P (DRP) bioavailability
(specifically orthophosphate) increased downstream. The solid phase associations of P were operationally assessed with the
streamlined SEDEX (sedimentary extraction) procedure, and most sediment P (≥50%) was released during the step designed to
determine iron oxide–associated P. On average, 70–90% of the total sediment P pool was potentially bioavailable, as estimated
by the sum of the iron oxide-, authigenic carbonate-, and organic-associated P fractions. Considerable calcium was also extracted
from some sediments during the step designed to specifically remove iron oxide–associated P. It is hypothesized that the severe
drought conditions that persisted between April and October, 2005 allowed authigenic carbonates (perhaps partly amorphous)
to accumulate, and that these carbonates dissolved during the iron oxide extraction step. The extensive benthic algal populations
also present may have aided carbonate precipitation, which under more normal hydrologic conditions would be periodically flushed
downstream and replaced by fresh sediment. This suggests antecedent hydrologic conditions played a dominant role in the P
sorption and solid phase associations identified. 相似文献
13.
The crystal structure of chromite FeCr2O4 was investigated to 13.7 GPa and ambient temperature with single-crystal X-ray diffraction techniques. The unit-cell parameter
decreases continuously from 8.3832 (5) to 8.2398 (11) Å up to 11.8 GPa. A fit to the Birch–Murnaghan equation of state (EoS)
based on the P–V data gives: K
0 = 209 (13) GPa, K′ = 4.0 (fixed), and V
0 = 588 (1) Å3. The FeO4 tetrahedra and CrO6 octahedra are compressed isotropically with pressure with their Fe–O and Cr–O bond distances decreasing from 1.996 (6) to
1.949 (7) Å and from 1.997 (3) to 1.969 (7) Å, respectively. The tetrahedral site occupied by the Fe2+ cation is more compressible than the octahedral site occupied by the Cr3+ cation. The resulting EoS parameters for the tetrahedral and the octahedral sites are K
0 = 147 (9) GPa, K′ = 4.0 (fixed), V
0 = 4.07 (1) Å3 and K
0 = 275 (24) GPa, K′ = 4.0 (fixed), V
0 = 10.42 (2) Å3, respectively. A discontinuous volume change is observed between 11.8 and 12.6 GPa. This change indicates a phase transition
from a cubic (space group Fd-[`3]{\overline{3}}
m) to a tetragonal structure (space group I41
/amd). At the phase transition boundary, the two Cr–O bonds parallel to the c-axis shorten from 1.969 (7) to 1.922 (17) Å and the other four Cr–O bonds parallel to the ab plane elongate from 1.969 (7) to 1.987 (9) Å. This anisotropic deformation of the octahedra leads to tetragonal compression
of the unit cell along the c-axis. The angular distortion in the octahedron decreases continuously up to 13.7 GPa, whereas the distortion in the tetrahedron
rises dramatically after the phase transition. At the pressure of the phase transition, the tetrahedral bond angles along
the c-axis direction of the unit cell begin decreasing from 109.5° to 106.6 (7)°, which generates a “stretched” tetrahedral geometry.
It is proposed that the Jahn–Teller effect at the tetrahedrally coordinated Fe2+ cation becomes active with compression and gives rise to the tetrahedral angular distortion, which in turn induces the cubic-to-tetragonal
transition. A qualitative molecular orbital model is proposed to explain the origin and nature of the Jahn–Teller effect observed
in this structure and its role in the pressure-induced phase transition. 相似文献
14.
A set of sheeted quartz veins cutting 380 Ma monzogranite at Sandwich Point, Nova Scotia, Canada, provide an opportunity to
address issues regarding fluid reservoirs and genesis of intrusion-related gold deposits. The quartz veins, locally with arsenopyrite
(≤5%) and elevated Au–(Bi–Sb–Cu–Zn), occur within the reduced South Mountain Batholith, which also has other zones of anomalous
gold enrichment. The host granite intruded (P = 3.5 kbars) Lower Paleozoic metaturbiditic rocks of the Meguma Supergroup, well known for orogenic vein gold mineralization.
Relevant field observations include the following: (1) the granite contains pegmatite segregations and is cut by aplitic dykes
and zones (≤1–2 m) of spaced fracture cleavage; (2) sheeted veins containing coarse, comb-textured quartz extend into a pegmatite
zone; (3) arsenopyrite-bearing greisens dominated by F-rich muscovite occur adjacent the quartz veins; and (4) vein and greisen
formation is consistent with Riedel shear geometry. Although these features suggest a magmatic origin for the vein-forming
fluids, geochemical studies indicate a more complex origin. Vein quartz contains two types of aqueous fluid inclusion assemblages
(FIA). Type 1 is a low-salinity (≤3 wt.% equivalent NaCl) with minor CO2 (≤2 mol%) and has T
h = 280–340°C. In contrast, type 2 is a high-salinity (20–25 wt.% equivalent NaCl), Ca-rich fluid with T
h = 160–200°C. Pressure-corrected fluid inclusion data reflect expulsion of a magmatic fluid near the granite solidus (650°C)
that cooled and mixed with a lower temperature (400°C), wall rock equilibrated, Ca-rich fluid. Evidence for fluid unmixing,
an important process in some intrusion-related gold deposit settings, is lacking. Stable isotopic (O, D, S) analyses for quartz,
muscovite and arsenopyrite samples from vein and greisens indicate the following: (1) δ18Oqtz = +11.7‰ to 17.8‰ and δ18Omusc = +10.7‰ to +11.2‰; (2) δDmusc = −44‰ to−54‰; and (3) δ34Saspy = +7.8‰ to +10.3‰. These data are interpreted, in conjunction with fluid inclusion data, to reflect contamination of a magmatic-derived
fluid (d18OH2O {\delta^{{{18}}}}{{\hbox{O}}_{{{{\rm{H}}_{{2}}}{\rm{O}}}}} ≤ +10‰) by an external fluid (d18OH2O {\delta^{{{18}}}}{{\hbox{O}}_{{{{\rm{H}}_{{2}}}{\rm{O}}}}} ≥ +15‰), the latter having equilibrated with the surrounding metasedimentary rocks. The δ34S data are inconsistent with a direct igneous source based on other studies for the host intrusion (d18OH2O {\delta^{{{18}}}}{{\hbox{O}}_{{{{\rm{H}}_{{2}}}{\rm{O}}}}} = +5‰) and are, instead, consistent with an external reservoir for sulphur based on δ34SH2S data for the surrounding metasedimentary rocks. Divergent fluid reservoirs are also supported by analyses of Pb isotopes
for pegmatitic K-feldspar and vein arsenopyrite. Collectively the data indicate that the vein- and greisen-forming fluids
had a complex origin and reflect both magmatic and non-magmatic reservoirs. Thus, although the geological setting suggests
a magmatic origin, the geochemical data indicate involvement of multiple reservoirs. These results suggest multiple reservoirs
for this intrusion-related gold deposit setting and caution against interpreting the genesis of intrusion-related gold deposit
mineralization in somewhat analogous settings based on a limited geochemical data set. 相似文献
15.
Behavior of epidote at high pressure and high temperature: a powder diffraction study up to 10 GPa and 1,200 K 总被引:1,自引:0,他引:1
G. Diego Gatta Marco Merlini Yongjae Lee Stefano Poli 《Physics and Chemistry of Minerals》2011,38(6):419-428
The thermo-elastic behavior of a natural epidote [Ca1.925 Fe0.745Al2.265Ti0.004Si3.037O12(OH)] has been investigated up to 1,200 K (at 0.0001 GPa) and 10 GPa (at 298 K) by means of in situ synchrotron powder diffraction.
No phase transition has been observed within the temperature and pressure range investigated. P–V data fitted with a third-order Birch–Murnaghan equation of state (BM-EoS) give V
0 = 458.8(1)Å3, K
T0 = 111(3) GPa, and K′ = 7.6(7). The confidence ellipse from the variance–covariance matrix of K
T0 and K′ from the least-square procedure is strongly elongated with negative slope. The evolution of the “Eulerian finite strain”
vs “normalized stress” yields Fe(0) = 114(1) GPa as intercept values, and the slope of the regression line gives K′ = 7.0(4). The evolution of the lattice parameters with pressure is slightly anisotropic. The elastic parameters calculated
with a linearized BM-EoS are: a
0 = 8.8877(7) Å, K
T0(a) = 117(2) GPa, and K′(a) = 3.7(4) for the a-axis; b
0 = 5.6271(7) Å, K
T0(b) = 126(3) GPa, and K′(b) = 12(1) for the b-axis; and c
0 = 10.1527(7) Å, K
T0(c) = 90(1) GPa, and K’(c) = 8.1(4) for the c-axis [K
T0(a):K
T0(b):K
T0(c) = 1.30:1.40:1]. The β angle decreases with pressure, βP(°) = βP0 −0.0286(9)P +0.00134(9)P
2 (P in GPa). The evolution of axial and volume thermal expansion coefficient, α, with T was described by the polynomial function: α(T) = α0 + α1
T
−1/2. The refined parameters for epidote are: α0 = 5.1(2) × 10−5 K−1 and α1 = −5.1(6) × 10−4 K1/2 for the unit-cell volume, α0(a) = 1.21(7) × 10−5 K−1 and α1(a) = −1.2(2) × 10−4 K1/2 for the a-axis, α0(b) = 1.88(7) × 10−5 K−1 and α1(b) = −1.7(2) × 10−4 K1/2 for the b-axis, and α0(c) = 2.14(9) × 10−5 K−1 and α1(c) = −2.0(2) × 10−4 K1/2 for the c-axis. The thermo-elastic anisotropy can be described, at a first approximation, by α0(a): α0(b): α0(c) = 1 : 1.55 : 1.77. The β angle increases continuously with T, with βT(°) = βT0 + 2.5(1) × 10−4
T + 1.3(7) × 10−8
T
2. A comparison between the thermo-elastic parameters of epidote and clinozoisite is carried out. 相似文献
16.
Lars Chresten Lund-Hansen Thorbjørn Joest Andersen Morten Holtegaard Nielsen Morten Pejrup 《Estuaries and Coasts》2010,33(6):1442-1451
Optical constituents as suspended particulate matter (SPM), chlorophyll (Chl-a), colored dissolved organic matter (CDOM),
and grain sizes were obtained on a transect in the arctic fjord-type estuary Kangerlussuaq (66°) in August 2007 along with
optical properties. These comprised diffuse attenuation coefficient of downwelling PAR (K
d(PAR)), upwelling PAR (K
u(PAR)), particle beam attenuation coefficient (c
p), and irradiance reflectance R(−0, PAR). PAR is white light between 400 and 700 nm. The estuary receives melt water from the Greenland Inland Ice and stations
covered a transect from the very high turbid melt water outlet to clear marine waters. Results showed a strong spatial variation
with high values as for suspended matter concentrations, CDOM, diffuse attenuation coefficient K
d(PAR), particle beam attenuation coefficients (c
p), and reflectance R(−0, PAR) at the melt water outlet. Values of optical constituents and properties decreased with distance from the melt water
outlet to a more or less constant level in central and outer part of the estuary. There was a strong correlation between inorganic
suspended matter (SPMI) and diffuse attenuation coefficient K
d(PAR) (r
2 = 0.92) and also for particle beam attenuation coefficient (c
p; r
2 = 0.93). The obtained SPMI specific attenuation—K
d*(PAR) = 0.13 m2 g−1 SPMI—and the SPMI specific particle beam attenuation—c
p* = 0.72 m2 g−1—coefficients were about two times higher than average literature values. Irradiance reflectance R(−0, PAR) was comparatively high (0.09−0.20) and showed a high (r
2 = 0.80) correlation with K
u(PAR). Scattering dominated relative to absorption—b(PAR)/a(PAR) = 12.3. Results strongly indicated that the high values in
the optical properties were related to the very fine particle sizes (mean = 2–6 μm) of the suspended sediment. Data and results
are discussed and compared to similar studies from both temperate and tropical estuaries. 相似文献
17.
D. W. Fan M. N. Ma W. G. Zhou S. Y. Wei Z. Q. Chen H. S. Xie 《Physics and Chemistry of Minerals》2011,38(2):95-99
The high-pressure X-ray diffraction study of a natural arsenopyrite was investigated up to 28.2 GPa using in situ angle-dispersive
X-ray diffraction and a diamond anvil cell at National Synchrotron Light Source, Brookhaven National Laboratory. The 16:3:1
methanol–ethanol–water mixture was used as a pressure-transmitting medium. Pressures were measured using the ruby-fluorescence
method. No phase change has been observed up to 28.2 GPa. The isothermal equation of state (EOS) was determined. The values
of K
0, and K′
0 refined with a third-order Birch–Murnaghan EOS are K
0 = 123(9) GPa, and K′
0 = 5.2(8). Furthermore, we confirm that the linear compressibilities (β) along a, b and c directions of arsenopyrite is elastically isotropic (β
a
= 6.82 × 10−4, β
b
= 6.17 × 10−4 and β
c
= 6.57 × 10−4 GPa−1). 相似文献
18.
Matteo Alvaro Fernando Cámara M. Chiara Domeneghetti Fabrizio Nestola Vittorio Tazzoli 《Contributions to Mineralogy and Petrology》2011,162(3):599-613
A natural Ca-poor pigeonite (Wo6En76Fs18) from the ureilite meteorite sample PCA82506-3, free of exsolved augite, was studied by in situ high-temperature single-crystal
X-ray diffraction. The sample, monoclinic P21/c, was annealed up to 1,093°C to induce a phase transition from P21/c to C2/c symmetry. The variation with increasing temperature of the lattice parameters and of the intensity of the b-type reflections (h + k = 2n + 1, present only in the P21/c phase) showed a displacive phase transition P21/c to C2/c at a transition temperature T
Tr = 944°C, first order in character. The Fe–Mg exchange kinetics was studied by ex situ single-crystal X-ray diffraction in
a range of temperatures between the closure temperature of the Fe–Mg exchange reaction and the transition temperature. Isothermal
disordering annealing experiments, using the IW buffer, were performed on three crystals at 790, 840 and 865°C. Linear regression
of ln k
D versus 1/T yielded the following equation:
ln k\textD = - 3717( ±416)/T(K) + 1.290( ±0.378); (R2 = 0.988) \ln \,k_{\text{D}} = - 3717( \pm 416)/T(K) + 1.290( \pm 0.378);\quad (R^{2} = 0.988) . The closure temperature (T
c) calculated using this equation was ∼740(±30)°C. Analysis of the kinetic data carried out taking into account the e.s.d.'s
of the atomic fractions used to define the Fe–Mg degree of order, performed according to Mueller’s model, allowed us to retrieve
the disordering rate constants C
0
K
dis+ for all three temperatures yielding the following Arrhenius relation:
ln( C0 K\textdis + ) = ln K0 - Q/(RT) = 20.99( ±3.74) - 26406( ±4165)/T(K); (R2 = 0.988) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = \ln \,K_{0} - Q/(RT) = 20.99( \pm 3.74) - 26406( \pm 4165)/T(K);\quad (R^{2} = 0.988) . An activation energy of 52.5(±4) kcal/mol for the Fe–Mg exchange process was obtained. The above relation was used to calculate
the following Arrhenius relation modified as a function of X
Fe (in the range of X
Fe = 0.20–0.50):
ln( C0 K\textdis + ) = (21.185 - 1.47X\textFe ) - \frac(27267 - 4170X\textFe )T(K) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = (21.185 - 1.47X_{\text{Fe}} ) - {\frac{{(27267 - 4170X_{\text{Fe}} )}}{T(K)}} . The cooling time constant, η = 6 × 10−1 K−1 year−1 calculated on the PCA82506-3 sample, provided a cooling rate of the order of 1°C/min consistent with the extremely fast late
cooling history of the ureilite parent body after impact excavation. 相似文献
19.
Dmytro M. Trots Alexander Kurnosov Leonid Vasylechko Marek Berkowski Tiziana Boffa Ballaran Daniel J. Frost 《Physics and Chemistry of Minerals》2011,38(7):561-567
A single crystal X-ray diffraction study on lithium tetraborate Li2B4O7 (diomignite, space group I41
cd) has been performed under pressure up to 8.3 GPa. No phase transitions were found in the pressure range investigated, and
hence the pressure evolution of the unit-cell volume of the I41
cd structure has been described using a third-order Birch–Murnaghan equation of state (BM-EoS) with the following parameters:
V
0
= 923.21(6) Å3, K
0
= 45.6(6) GPa, and K′ = 7.3(3). A linearized BM-EoS was fitted to the axial compressibilities resulting in the following parameters a
0
= 9.4747(3) Å, K
0a
= 73.3(9) GPa, K′
a
= 5.1(3) and c
0
= 10.2838(4) Å, K
0c
= 24.6(3) GPa, K′
c
= 7.5(2) for the a and c axes, respectively. The elastic anisotropy of Li2B4O7 is very large with the zero-pressure compressibility ratio β
0c
/β
0a
= 3.0(1). The large elastic anisotropy is consistent with the crystal structure: A three-dimensional arrangement of relatively
rigid tetraborate groups [B4O7]2− forms channels occupied by lithium along the polar c–axis, and hence compression along the c axis requires the shrinkage of the lithium channels, whereas compression in the a direction depends mainly on the contraction of the most rigid [B4O7]2− units. Finally, the isothermal bulk modulus obtained in this work is in general agreement with that derived from ultrasonic
(Adachi et al. in Proceedings-IEEE Ultrasonic Symposium, 228–232, 1985; Shorrocks et al. in Proceedings-IEEE Ultrasonic Symposium, 337–340, 1981) and Brillouin scattering measurements (Takagi et al. in Ferroelectrics, 137:337–342, 1992). 相似文献
20.
The accepted standard state entropy of titanite (sphene) has been questioned in several recent studies, which suggested a
revision from the literature value 129.3 ± 0.8 J/mol K to values in the range of 110–120 J/mol K. The heat capacity of titanite
was therefore re-measured with a PPMS in the range 5 to 300 K and the standard entropy of titanite was calculated as 127.2
± 0.2 J/mol K, much closer to the original data than the suggested revisions. Volume parameters for a modified Murgnahan equation
of state: V
P,T
= V
298° × [1 + a°(T − 298) − 20a°(T − 298)] × [1 – 4P/(K
298 × (1 – 1.5 × 10−4 [T − 298]) + 4P)]1/4 were fit to recent unit cell determinations at elevated pressures and temperatures, yielding the constants V
298° = 5.568 J/bar, a° = 3.1 × 10−5 K−1, and K = 1,100 kbar. The standard Gibbs free energy of formation of titanite, −2456.2 kJ/mol (∆H°f = −2598.4 kJ/mol) was calculated from the new entropy and volume data combined with data from experimental reversals on the
reaction, titanite + kyanite = anorthite + rutile. This value is 4–11 kJ/mol less negative than that obtained from experimental
determinations of the enthalpy of formation, and it is slightly more negative than values given in internally consistent databases.
The displacement of most calculated phase equilibria involving titanite is not large except for reactions with small ∆S. Re-calculated baric estimates for several metamorphic suites yield pressure differences on the order of 2 kbar in eclogites
and 10 kbar for ultra-high pressure titanite-bearing assemblages. 相似文献