Dependence of the effective attachment coefficient of small ions upon the size of condensation nuclei

Summary To clarify the ionization equilibrium near the ground, simultaneous measurements of the rate of ion pair production (q), the concentrations of small ions (n) and condensation nuclei (Z), and the diffusion coefficient of condensation nuclei (D) were carried out at several stations in the central area of Japan. The total rate of ion pair production (q) was estimated fromq=q(Rn)+q(Tn)+q()+q(+CR). The value ofq was estimated as 10J to 20J. The mean life () and the effective attachment coefficient () of small ions were also estimated at each station. Correlations amongn, Z, q, andD were also studied. If we take the variation ofD into consideration, the correlation was expressed by the simple formula;q=n Z. The dependence of upon size of nuclei (2r) were also measured, and was found to correlate well withD orr.     

The vertical distribution of condensation nuclei near the ground

Summary Measurements have been made of the concentration of condensation nuclei, Z, at four heights between the ground and 300 cms in country air close to Cambridge. When the results are averaged over sufficiently long periods a systematic variation of Z with height is found and this variation itself has a diurnal variation. The results imply the production of nuclei in the atmosphere in this region. With the aid of simplifying assumptions, estimates of the rate of production are made for various periods of the day and night.     

Metal point discharge nuclei and the production of multiply charged ions from condensation nuclei

Summary Very small uncharged nuclei are produced by electric discharge at a metal point. By measuring the size and the super-saturation required for condensation it is shown that there is a vapour pressure deficit of 15%. The nuclei increase in size and in heterogeneity during storage. The range of radius is from 1.0×10^–7 cm to 6.6×10^–7 cm.When atmospheric nuclei are drawn past a discharging point they become multiply charged. The relation between the mobility, the diffusion coefficient and the charge per ion of these multiply charged ions does not agree with well-established theory.

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Zusammenfassung Elektrische Entladung von einer Metallspitze erzeugt sehr kleine, ungeladene Kerne. Durch Messung ihrer Grösse und der Übersättigung, welche für die Kondensation benötigt wird, kann gezeigt werden, dass ein Dampfdruckdefizit von 15% besteht. Während der Speicherung wachsen die Kerne und ihre Heterogenität nimmt zu. Ihre Radien liegen zwischen 1.0×10^–7 cm und 6.6×10^–7 cm.Kondensationskerne der Atmosphäre, welche an einer sich entladenden Spitze vorbeigesaugt werden, nehmen mehrfache Ladungen an. Die Beziehung zwischen der Beweglichkeit, dem Diffusionskoeffizienten und der Ladung per Ion dieser mehrfach geladenen Ionen stimmt nicht mit der bisher als gültig angenommenen Theorie überein.

     

Measurements of the effective attachment coefficient between RaA ions and condensation nuclei

Summary To clarify the interaction between RaA ions and condensation nuclei, simultaneous measurements of the concentration of RaA ions (n _A), radon-222, and condensation nuclei (Z) were carried out at several stations. In some occasions, the diffusion coefficients of nuclei (D) were also measured. It was found that the correlation among them may be well expressed by the simple formula;q _A = _A n_A Z. The correlation between _A andD (or radius of nuclei) was also obtained.The effective attachment coefficient of RaA ions was compared with that of small ordinary ions, and it was presumed that about one fourth of RaA atoms formed on the decay of radon-222 is positively charged, and the rest is neutral.     

Some factors controlling the concentration of small ions near the ground

Summary During continuous measurements of the concentration of small ions near the ground made over the period of many months, several causes of variation were identified. During rain in large electric fields, ions of sign opposite to that of the potential gradient were produced in sufficiently large numbers to give rise to very high concentrations over short periods. Sometimes, after rain, a considerable increase in the density of small ions was found, suggesting a reduction in the numbers of nuclei and large ions. In moderate electric fields, a reduction was observed in the concentration of ions of sign opposite to that of the potential gradient in a way corresponding to the electrode effect. A simplified theory of the effect predicts results similar to those found in practice.The paper will appear elsewhere.     

The nuclei of atmospheric condensation

Summary Our present knowledge concerning the abundance, size, physical properties, origin and nature of condensation nuclei is reviewed and critically assessed.     

Polarization of reffected solar radiation over land,sea and cloud surfaces

Summary Results of the measurements of the polarization of reffected solar radiation in the visible region over various land, sea and cloud surfaces carried out from a high altitude aircraft are presented. It is shown that the measurable polarization can be used as a sensitive parameter to determine atmospheric turbidity and the aerosol content.     

Vertical profiles of condensation nuclei in the stratosphere

An automatic condensation nuclei counter was developed for the concentration range of about 1 to 400 particles per cubic centimeter. After expansion, the water droplets are photographed when they are still suspended in the air so that the counter can be considered an absolute one. The volume in which the droplets are counted is determined by the size of the picture of the droplets as a function of their distance from the focal plane. To eliminate any effect of decreasing pressure with altitude, the cloud chamber is filled with clean air prior to expansion to about half an atmosphere above ambient pressure. This counter was used to obtain vertical profiles of condensation nuclei up to altitudes of 27 km with high altitude balloons. A total of seven profiles was obtained over a period of about one year at 47° N over the United States. Because of the restrictions in the range of the meter no data could be obtained below 5 km. The profiles show the following main features:

1. 1.
   Although there are pronounced fluctuations in the individual flights the average nuclei concentration of 200 to 300/cm³ remains fairly constant from 5 km to the tropopause.     
   
   

On some measurements of the condensation of different vapors upon Aitken condensation nuclei

No final theory on the activity of Aitken nuclei has been established yet. In particular the supersaturation is not known for the Aitken nuclei to grow into droplets, f.e. according toF. Volz only nuclei of radius >0.1 can cause condensation under atmospheric conditions. On the other hand according toH. G. Müller condensation over the continents has to occur at the Aitken nuclei since precipitation washes out the other nuclei.This uncertainty becomes obvious in the interpretation of the experimental results.Chr. Junge found that the necessary activation supersaturation of a continental Aitken aerosol and of artificial aerosols of the same size of nuclei lies between 2 and 20%, 10% being sufficient for the main fraction of nuclei to grow.In contrastW. Wieland was able to activate in a mixing cloud chamber a big portion, if not all, of the nuclei of a continental aerosol at supersaturations below 1.5%. Some of our own results, obtained with the same technic, agree with this. At supersaturations below 0.8% at least half of the Aitken nuclei present are activated. To obtain the same result with benzene and acetone we found, that benzene required a slightly smaller, and acetone a somewhat bigger supersaturation.However later experiments revealed a considerable effect of the geometry of the mixing cloud chamber upon the results. Since the physics of the chamber has not been fully explored the method was abandoned. Instead the principle of cooling by adiabatic expansion was used. An expansion apparatus based on the principle of a fotoelectric nucleus counter was developed allowing us to measure with two cathode ray oscillographs the pressure and simultaneously the change of intensity of a lightbeam due to the scattering on the forming cloud as a function of time. The length of the lightbeam could be chosen between 60 and 200 cm. The overpressure before the expansion was always 180 mm of mercury. The ratio of expansion rates was 12.53060 at the beginning of the expansion. The slowest rate was about 6 seconds, corresponding to a rate of ascent of 210 m/s at the beginning of the expansion. Smaller rates could not be obtained because of heat transfer at the chamber walls.The present work has been performed for the Eidgenössische Kommission zum Studium der Hagelbildung und der Hagelabwehr (Switzerland) at the research station Osservatorio Ticinese Locarno-Monti della Centrale Meteorologica Svizzera     

On the condensation nuclei about the time of sunrise

Summary Some marked variations of the content of condensation nuclei in the air deserve to be considered individually. it is shown that by simultaneous measurements of phenomena other condensation nuclei, especially atmospheric electrical, a more complete insight into all the processes involved could be obtained, when investigating the condensation nuclei during the time about sunrise.

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Zusammenfassung Einzelne ausgeprägte Variationen des Gehaltes an Kondensantionskernen in der Luft verdienen individuell behandelt zu werden. Es wird gezeigt, dass mit gleichzeitig ausgeführten Messungen anderer, besonders luftelektrischer Erscheinungen, neben jenen der Kondensationskerne eine vollständigere Einsicht in alle in Betracht kommenden Prozesse erhalten wird, wenn die Kondensationskerne vor und nach dem Sonnenaufgang untersucht werden.

     

A comparison of concentrations of fission products,radon 222, and cloud condensation nuclei over the North Atlantic

The concentrations of airborne fission products were observed to be air mass dependent during a cruise of the USNSHayes from Norfolk, Va to Athens, Greece in May–June 1977. Minimum concentrations of fission products, radon, and CCN (cloud condensation nuclei) were measured in maritime air which had previously transited northern North America. Higher fission products, radon, and CCN concentrations were measured in recent, continental air traceable to mid North America or central Europe. These data are consistent with either entrainment by strong winds of previously precipitated fission products (the continental effect) or greater transfer of fission products from the stratosphere to low levels by tropospheric folding.     

Production of atmospheric condensation nuclei by sunrays

Summary 1) It is confirmed that in filtered, nucleus-free air, in a polyethylene balloon, if irradiated by sunglight, an immediate large number of condensation nuclei appear. — 2) The nucleus count rises to about 35. 000/cm³ and if the irradiation is continued does not increase, but decreases. This decreased is accelerated in the dark. — 3) Less intensive sunlight as when the sun was covered by clouds, gives slower and smaller increases. — 4) The same was observed if, instead of air, inducstrial oxygen or nitrogen was used. — 5) Traces of H₂S increase the sun effect enormously. — 6) Traces of NH₃ also increase it, but less than H₂S. — 7) SO₂ filtered through cottonwool gave also in the dark nuclei, which then decreased in number. — 8) It is supposed that H₂S is oxydized by the photochemical action of the sun's visible spectrum to SO₂ SO₃ SO₄ which is a nucleus. With NH₃ the formation of (NH₃)₂ SO₄ is probable. But no direct proof is given that these are the actual impurities which explain the sun's action on air. It is calculated that dilutions of 10^–15 of an impurity of the type of H₂S can quantitatively explain the sun effect. — 9) The work ofAitken is extensively quoted, who noticed, 50 years ago, the «fog produced by sun».

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Zusammenfassung 1) Es wird bestätigt, dass Sonnen-Bestrahlung von filtrierter kernfreier Luft, welche in einem Polyethylen-Ballon aufbewahrt ist, zum Entstehen einer hohen Zahl von Kondensations Kernen führt. — 2) Die Kernzahl steigt auf etwa 35 000/cm³. Wird die Bestrahlung fortgesetzt, dann steigt sie nicht weiter sondern nimmt ab. Die Abnahme wird im Dunkeln beschleunigt. — 3) Durch Wolken abgeschwächtes Sonnenlicht gibt eine langsamere, weniger grosse Kernbildung. — 4) Dieselben Beobachtungen wurden mit industriellem Sauerstroff und Stickstoff auch gemacht. — 5) Spuren von H₂S verstärken den Sonneneffekt enorm. — 6) Spuren von NH₃ verstärken ihn auch, jedoch weniger. — 7) SO₂ Gas, gefiltert durch Baumwollfilter giebt auch im Dunkeln schon Kerne, deren Zahl dann wieder abnimmt. — 8) Es wird angenommen, das H₂S durch photochemische Wirkung des sichtbaren Sonnenlichtes oxidiert wird zu SO₂ SO₃ SO₄ welch letzteres bereits als H₂HO₄ ein Kondensationskern ist. Mit NH₃)₂ SO₄ Kondensationskerne gebildet werden. Es sind jedoch keine direkten Beweise dafür vorhanden, dass diese Gase die Verunreinigungen der atmosphärischen Luft sind, welche den Sonnenffekt geben. Es wird aber berechnet, dass schon Verdünnungen von 10^–15 eine Verunreinigung H₂S den Sonnen-Effekt erklären. — 9)Aitken's Werk, der bereits vor 50 Jahren von « durch Sonne verursachten Nebel « sprach, wird gewürdigt.

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From the Clima-physiological Laboratory of St. Moritz-Bad.     

Influence of sunlight on atmospheric condensation nuclei

I has been shown that irradiation of air by sun-rays leads to a formation of atmospheric condensation nuclei, as measured with the automatic nucleus counter (1).To control the influence of the material, experiments were done in a gasometer where a rubber balloon was built in, also in a metal container covered either with uviol glass or window glass, or with air in a polyethylene balloon. The same influence of sunrays was observed in each case.Similar experiments were then done with compressed air from a metal container, or with oxygen gas, nitrogen gas or nitrous oxide all from metal containers. In all cases sun-rays produced condensation nuclei; the effect was present both at 1800 m and at 270 m altitude. Diffuse sunlight with high clouds also had an effect. Infra-red radiation and mechanical shaking were without result, but ultraviolet rays from a quartz-mercury lamp increased the nucleus count of the balloon whether it contained air or one of the above-mentioned gases.As yet it has not been possible to decide the mechanism of formation of these nuclei and what their meteorological and biological role might be.The detailed paper will appear later in «Geofisica pura e applicata».     

Production of atmospheric condensation nuclei by solar radiation

Summary Air with a very low count of atmospheric condensation nuclei was irradiated by direct sunlight through an uviol glass window, or through ordinary glass or in a polyethylene balloon. The nucleus count rises immediately and reaches very high values.

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Zusammenfassung Luft mit sehr niedriger Zahl von atmosphärischen Kondensations-Kernen wurde mit direktem Sonnenlicht bestrahlt, entweder durch ein UV Glas oder durch gewöhnliches Glas oder durch einen Polyethylen-Ballon. Die Zahl der atmosphärischen Kondensations-Kerne steigt sogleich und erreicht sehr hohe Werte.

     

The generation of condensation nuclei by ionising radiation

Summary The production of condensation nuclei by the irradiation of filtered nuclei-free air by X-rays, alpha particles and beta particles is described. It is found that nuclei are created in large numbers by such irradiation and that there appears to be a threshold radiation dose at which the nucleus concentration is increased by a factor of more than a hundred.The effect of varying sulphur dioxide content of the irradiated air has been investigated and for concentrations of between one and ten milligrams per cubic metre of air there is some proportionality between the sulphur dioxide content of the air and the nucleus concentration produced by a given radiation dose.It is shown, however, that sulphur dioxide cannot be exclusively responsible for the generation of condensation nuclei by irradiation of filtered air and other possible agents and mechanisms are suggested.     

The effects of condensation nuclei in atmospheric electricity

Summary The effects of condensation nuclei in the atmosphere are discussed, particularly in relation to the «sunrise effect» and it is shown that the introduction of positively charged nuclei is the only process yet suggested that can explain the observed results.