N—间甲苯基—N‘—（对氨基苯磺酸钠）硫脲与铜的显色反应及应用

研究了新试剂N-间甲苯基-N'-(对氨基苯磺酸钠)硫脲(MMPT)与Cu2+的显色反应.结果表明,在pH 4.6～5.6的HAc-NaAc介质中,Cu2+与MMPT形成的配合物至少稳定5 h,其λmax=370 nm,表观摩尔吸光系数为1.12×105 L.mol-1.cm-1.Cu2+的质量浓度在0.08～1.4 mg/L时符合比尔定律,相关系数r=0.9991.方法简便、快速,用于铅矿中铜的分析,测定结果与监控样推荐值相符,对w(Cu)=0.8%的试样测定6次,RSD=3.2%.     

Kinetic Spectrophotometric Determination of Trace Iron（Ⅲ）with p—Amino—N,N—Dimethylaniline Dihydrochloride and Hydrogen Peroxide

A new, simple and highly sensitive kinetic method for the determination of trace iron (III) has been developed based on the catalytic effect of iron (III) on color reaction ofp-amino-N, N-dimethylaniline dihydrochloride (p-DMA) oxidated by hydrogen peroxide. The reaction is followed spectrophotometrically by measuring the absorbance at 510 nm. The detection limit is 4.47×10⁻¹¹ g/ml, and the calibration curve is linear in the range of 0–0.10μg Fe(III) /25 ml with a relative standard deviation of ±3.25%. The method has been applied to the determination of iron in tap-water, chemical reagents and human hair.     

干旱半干旱地区农田土壤N03—N深层积累及其影响因素

以长期试验资料为基础，着重分析了干旱半干旱地区农田系统中施肥、作物、降水、耕作措施以及土壤类型和特性对产生土壤NO3-N深层积累的影响。分析发现，氮肥的过量施用和400—800mm降水量偏低是导致干旱半干旱地区土壤NO3—N积累在100—300cm土层的主要因素。随着氮肥用量的增加，NO3—N深层积累显著增加；氮磷配施有助于降低其积累量。不同作物对氮素的吸收利用效率也是影响NO3—N深层积累的因素，作物之间的轮作方式会有效降低NO3—N深层积累；休闲期种植合理植物可有效降低NO3—N深层积累。NO3—N深层积累主要产生在质地较重的土壤上，带正电荷粘土矿物对NO3—N吸附是导致热带土壤中NO3—N积累的主要因素。深入研究深层积累NO3—N的生物有效性、迁移变化机理、与作物根系之间的关系以及对土壤性状和环境的影响具有重要意义。     

南桥高度亏损N—MORB的发现及其地质意义

对赣西北九岭古岛弧西延部分的湖南浏阳南桥玄武岩进行了单颗粒锆石蒸发法2 0 7Pb/ 2 0 6Pb年龄测定 ,结果为 12 71± 2Ma。该玄武岩辉绿岩显示高度亏损的地球化学特性 :K2 O极低 ,不相容的高场强元素和稀土元素的丰度均低于 (少数接近 )N_MORB的平均丰度 ,εNd(12 71Ma)为 6 .86～ 8.98,具典型N_MORB特性 ,可能为沿古俯冲带分布的洋壳残片 ,为九岭古岛弧提供了新的证据。     

Gravettian environmental changes in a N — S transect of central Europe

The area defined as the N — S transect of Central Europe encompasses Slovenia, Croatia, Hungary, southern Slovakia, northern Austria, Moravia and southern Poland. Physical and biological environmental analysis have been undertaken for the Gravettian period of the last glacial, between 31 and 22 ka cal BP. Mammal faunas have been recorded from different provinces, which have climatic differences. These climatic differences are reflected in the sediments, the plant cover and the fauna. Over the course of several warm and cold events from 31–22 ka the biodiversity of the individual provinces has remained roughly the same, but important quantitative changes have occurred in the individual faunas.     

Carbon Isotopic Values of Individual N—Alkanes in Pyrolysates of Algae

This paper presents the carbon isotopic values of individual n-alkanes in pyrolysates of algae,which are widely spread in marine and lacustrine environments.The carbon isotopic values of n-alkanes originated from different algal precursors vary greatly,and those of n-alka nes orginated from C.protothecoides,S.sp PCC 6803 and I.Galbana are even heavier than from higher plants,n-alkanes with different carbon numers derived from the sme organism may stem from different biomacromolecules.The dominant product nC31 diene yielded at 300℃ or lower temperature also is different from n-alkanes yielded at the same thermal evolution phase with respect to their origin.The catalysis of mineral components in limestone may lead to a lighter carbon isotope composition of n-alkanes.     

尕斯库勒油田N1—N2^1油藏砂西区Ⅱ油组储层非均质特征评价

储层非均质特征评价是储层特征研究很重要的一部分内容，储层非均质特征是描述储层的参数变化及非均质特性，非均质性的强弱直接影响着开发方案的设计和实施。本文以尕斯库勒油田N1—N2^1油藏砂西区Ⅱ油组为例，研究储层非均质性特征。用来描述储层非均质性的特征参数主要有：连通系数、重叠系数、夹层厚度、夹层频数以及均值、最大值、最小值、变异系数、级差、非均质系数。     

地表水中NO3——N在武汉东湖水质综合评价中的意义

武汉东湖区由称谓的郭郑湖、水果湖、团湖、后湖和喻家湖等组成。湖泊直线长度为11.3 km,最大宽度为8.1 km,有大小岬湾120多个,因而岸线全长111.5 km。湖的最高允许水位为21 m,此时湖水面积约33 km2,其容积为1.24×108m3。     

一种新的成矿流体示踪法——流体包裹体N2—Ar—He示踪体系

本文介绍一种新的成矿流体示踪法,Ｎ２－Ａｒ－Ｈｅ示踪体系,概述了其主要原理和分析方法,并以粤中长坑Ａｕ－Ａｇ矿和粤东嵩溪Ａｓ－Ｓｂ矿为例,进行了成矿流体Ｎ２－Ａｒ－Ｈｅ示踪体系研究,结果显示其成矿流体主要来自建造水或沉积热卤水,为矿床成因研究提供了新的证据。     

甘孜—理塘蛇绿混杂岩带存在N型洋脊玄武岩

甘孜－理塘蛇绿混杂岩带历经30余年的研究与争论，无论持何种观点者，均未能在带中找到N型洋脊玄武岩。近年我队在该带内的研究中发现现三处。最具典型意义的是产于甘孜电站的笨得古蛇绿混杂岩中的玄武岩，不仅具有“N”型洋脊玄武岩特有的亏损型稀土模式，同时具有蛇绿岩的典型层序，为该带古洋壳的砉产添新证据。     

Nitrogen and Oxygen Isotope Balance in Tropospheric N2O—An Improved Budget

In steady state the stable isotopic composition of nitrogen and oxygen in tropospheric N2O is balanced by isotopically light N2O emitted from soils and oceans and isotopically heavy N2O as a return flux from the stratosphere.However,no such balance was reached in calculations given by Kim and Caig(1993).Modifications have been made on their calculations based on the most recent reports on annual global emission of N2O.It is considered that the nitrogen and oxygen isotope budget in tropospheric N2O are approximately in balance if isotopic fractionation effects during the production of N2O in soils and furthermore this paper puts forward further evidence for validating the above results.     

N263浸渍树脂分离—富集Pb（Ⅱ）的研究及其应用

以Ｎ２６３浸渍在ＤＡ２０１大孔吸附树脂上制得了Ｎ２６３浸渍树脂，测定了静态时树脂Ｐｂ（Ⅱ）的吸附容量，通过柱层析法，试验了酸度，流速和干扰离子等因素对Ｎ２６３浸渍树脂吸附和洗脱Ｐｂ的影响。建立了Ｎ２６３浸渍树脂分离－富集后衔接原子吸收和比色法测定Ｐｂ（Ⅱ）的方法，测定了地质样品中Ｐｂ（Ⅱ），测试结果理想。     

箱技术测量土壤痕量气体释放通量中的误差因素—以N2O为例

箱技术是测量土壤痕量气体释放通量的最常用方法,本文在理论和实际应用上探讨了箱技术尤其是密闭箱技术使用过程中可能引起痕量气体释放通量偏差的若干问题及可能的解决方法。