Experimental constraints on the solidification of a hydrous lunar magma ocean

The identification of hydrogen in a range of lunar samples and the similarity of its abundance and isotopic composition with terrestrial values suggest that water could have been present in the Moon since its formation. To quantify the effect of water on early lunar differentiation, we present new analyses of a high‐pressure, high‐temperature experimental study designed to model the mineralogical and geochemical evolution of the solidification material equivalent to 700 km deep lunar magma oceans first reported in Lin et al. (2017a). We also performed additional experiments to better quantify water contents in the run products. Water contents in the melt phases in hydrous run products spanning a range of crystallization steps were quantified directly using a secondary ion mass spectrometry (SIMS). Results suggest that a significant but constant proportion (68 ± 5%) of the hydrogen originally added to the experiments was lost from the starting material independent of run conditions and run duration. The volume of plagioclase formed during our crystallization experiments can be combined with the measured water contents and the observed crustal thickness on the Moon to provide an updated lunar interior hygrometer. Our data suggest that at least 45–354 ppm H₂O equivalent was present in the Moon at the time of crust formation. These estimates confirm the inference of Lin et al. (2017a) that the Moon was wet during its magma ocean stage, with corrected absolute water contents now comparable to estimates derived from the water content in a range of lunar samples.     

Lunar Water: A Brief Review

One of the most exciting recent developments in the field of lunar science has been the unambiguous detection of water (either as OH or H₂O) or water ice on the Moon through instruments flown on a number of orbiting spacecraft missions. At the same time, continued laboratory-based investigations of returned lunar samples by Apollo missions using high-precision, low-detection, analytical instruments have for the first time, provided the absolute abundance of water (present mostly as structurally bound OH⁻ in mineral phases) in lunar samples. These new results suggest that the Moon is not an anhydrous body, questioning conventional wisdom, and indicating the possibility of a wet lunar interior and the presence of distinct reservoirs of water on the lunar surface. However, not all recent results point to a wet Moon and it appears that the distribution of water on the Moon may be highly heterogeneous. Additionally, a number of sources are likely to have contributed to the water inventory of the Moon ranging from primordial water to meteorite-derived water ice through to the water formed during the reaction of solar-wind hydrogen with the lunar soil. Water on the Moon has implications for future astrobiological investigations as well as for generating resources in situ during future exploration of the Moon and other airless bodies in the Solar System.     

Lunar Beagle and Lunar Astrobiology

The study of the elements and molecules of astrobiological interest on the Moon can be made with the Gas Analysis Package (GAP) and associated instruments developed for the Beagle 2 Mars Express Payload. The permanently shadowed polar regions of the Moon may offer a unique location for the “cold-trapping” of the light elements (i.e. H, C, N, O, etc.) and their simple compounds. Studies of the returned lunar samples have shown that lunar materials have undergone irradiation with the solar wind and adsorb volatiles from possible cometary and micrometeoroid impacts. The Beagle 2’s analytical instrument package including the sample processing facility and the GAP mass spectrometer can provide vital isotopic information that can distinguish whether the lunar volatiles are indigenous to the moon, solar wind derived, cometary in origin or from meteoroids impacting on the Moon. As future Lunar Landers are being considered, the suite of instruments developed for the Mars Beagle 2 lander can be consider as the baseline for any lunar volatile or resource instrument package.     

On the chronology of lunar origin and evolution

An origin of the Moon by a Giant Impact is presently the most widely accepted theory of lunar origin. It is consistent with the major lunar observations: its exceptionally large size relative to the host planet, the high angular momentum of the Earth–Moon system, the extreme depletion of volatile elements, and the delayed accretion, quickly followed by the formation of a global crust and mantle.According to this theory, an impact on Earth of a Mars-sized body set the initial conditions for the formation and evolution of the Moon. The impact produced a protolunar cloud. Fast accretion of the Moon from the dense cloud ensured an effective transformation of gravitational energy into heat and widespread melting. A “Magma Ocean” of global dimensions formed, and upon cooling, an anorthositic crust and a mafic mantle were created by gravitational separation.Several 100 million years after lunar accretion, long-lived isotopes of K, U and Th had produced enough additional heat for inducing partial melting in the mantle; lava extruded into large basins and solidified as titanium-rich mare basalt. This delayed era of extrusive rock formation began about 3.9 Ga ago and may have lasted nearly 3 Ga.A relative crater count timescale was established and calibrated by radiometric dating (i.e., dating by use of radioactive decay) of rocks returned from six Apollo landing regions and three Luna landing spots. Fairly well calibrated are the periods ≈4 Ga to ≈3 Ga BP (before present) and ≈0.8 Ga BP to the present. Crater counting and orbital chemistry (derived from remote sensing in spectral domains ranging from γ- and x-rays to the infrared) have identified mare basalt surfaces in the Oceanus Procellarum that appear to be nearly as young as 1 Ga. Samples returned from this area are needed for narrowing the gap of 2 Ga in the calibrated timescale. The lunar timescale is not only used for reconstructing lunar evolution, but it serves also as a standard for chronologies of the terrestrial planets, including Mars and possibly early Earth.The Moon holds a historic record of Galactic cosmic-ray intensity, solar wind composition and fluxes and composition of solids of any size in the region of the terrestrial planets. Some of this record has been deciphered. Secular mixing of the Sun was constrained by determining ³He/⁴He of solar wind helium stored in lunar fines and ancient breccias. For checking the presumed constancy of the impact rate over the past ≈3.1 Ga, samples of the youngest mare basalts would be needed for determining their radiometric ages.Radiometric dating and stratigraphy has revealed that many of the large basins on the near side of the Moon were created by impacts about 4.1 to 3.8 Ga ago. The apparent clustering of ages called “Late Heavy Bombardment (LHB)” is thought to result from migration of planets several 100 million years after their accretion.The bombardment, unexpectedly late in solar system history, must have had a devastating effect on the atmosphere, hydrosphere and habitability on Earth during and following this epoch, but direct traces of this bombardment have been eradicated on our planet by plate tectonics. Indirect evidence about the course of bombardment during this epoch on Earth must therefore come from the lunar record, especially from additional data on the terminal phase of the LHB. For this purpose, documented samples are required for measuring precise radiometric ages of the Orientale Basin and the Nectaris and/or Fecunditatis Basins in order to compare these ages with the time of the earliest traces of life on Earth.A crater count chronology is presently being built up for planet Mars and its surface features. The chronology is based on the established lunar chronology whereby differences between the impact rates for Moon and Mars are derived from local fluxes and impact energies of projectiles. Direct calibration of the Martian chronology will have to come from radiometric ages and cosmic-ray exposure ages measured in samples returned from the planet.     

Robotic search for ices and hydrous minerals at the lunar poles using a combined X-ray diffraction and fluorescence instrument

There is a growing body of evidence that points to the survival of water or hydrous minerals on the Moon and the potential for large aqueous reservoirs in shadowed craters at the lunar poles. CheMin, an XRD/XRF instrument that is currently under development, could provide a definitive test of whether the polar hydrogen signal measured by the recent Lunar Prospector mission is an indication of a significant water reservoir or merely reflects an anomalously rich accumulation of solar-wind hydrogen. Proposed enhancements of CheMin could be used in conjunction with a drilling system capable of penetrating the upper few tens of centimeters of the lunar regolith to search for ices or hydrous minerals. This advanced version of the CheMin instrument would be within the size, mass, and power constraints of Ariane 5 micromissions.     

Tektites - volcanic ejecta from the moon?

The problem of the origin of the enigmatic tektites is still unsolved. The two leading hypotheses - viz., ejecta from terrestrial impacts, and ejecta from lunar volcanoes or lunar impacts, each encounters serious difficulties. The former has ballistic and water content difficulties, while the latter has some compositional difficulties, especially in the trace elements, as determined from the returned samples. It is possible that the latter problem may be met through lunar volcanic ejecta from sites suggesting more differentiation than the majority of the Moon. That such features may exist is suggested from the identity of some granitic material in the returned rocks and soil samples implying fairly sizable source regions on the Moon. The rare terrestrial strewn tektite fields require restrictive ballistic trajectories from the Moon. Calculations reveal that ellipses of varying, decreasing sizes which depend on velocity of vertical ejection from which ejecta will intersect the earth at low-entrance angles occur on the nearside of the Moon. Reasonable velocities were chosen (2.55 to 3.0 km s^?1) and these ellipses circumscribe areas with longitudes between 30 and 50° east and latitudes between 7° north and south of the Moon's equator. These areas were searched for evidence of volcanism. As tektites have compositions ranging from acidic (major tektites) to basic (micro-tektites) contents of silica (SiO₂) both acidic and basic volcanic features were sought. Since tektites range in age from about 30 million to 700000 yr old, they imply recent volcanism. Lunar Transient Phenomena (LTP) and data from various Apollo missions indicate that mild internal activity may still be occurring on the Moon. LTP sites are logical sources to investigate, of which four occur within the above delimited regions. These and their surroundings were examined and a number of possible explosive volcanism sites were found. These sites are identified and discussed after a review of the manifestations found from the various kinds of terrestrial volcanism for which lunar counterparts were sought.     

The apparent lack of lunar-like swirls on Mercury: Implications for the formation of lunar swirls and for the agent of space weathering

Images returned by the MESSENGER spacecraft from the Mercury flybys have been examined to search for anomalous high-albedo markings similar to lunar swirls. Several features suggested to be swirls on the basis of Mariner 10 imaging (in the craters Handel and Lermontov) are seen in higher-resolution MESSENGER images to lack the characteristic morphology of lunar swirls. Although antipodes of large impact basins on the Moon are correlated with swirls, the antipodes of the large impact basins on Mercury appear to lack unusual albedo markings. The antipodes of Mercury’s Rembrandt, Beethoven, and Tolstoj basins do not have surface textures similar to the “hilly and lineated” terrain found at the Caloris antipode, possibly because these three impacts were too small to produce obvious surface disturbances at their antipodes. Mercury does have a class of unusual high-reflectance features, the bright crater-floor deposits (BCFDs). However, the BCFDs are spectral outliers, not simply optically immature material, which implies the presence of material with an unusual composition or physical state. The BCFDs are thus not analogs to the lunar swirls. We suggest that the lack of lunar-type swirls on Mercury supports models for the formation of lunar swirls that invoke interaction between the solar wind and crustal magnetic anomalies (i.e., the solar-wind standoff model and the electrostatic dust-transport model) rather than those models of swirl formation that relate to cometary impact phenomena. If the solar-wind standoff hypothesis for lunar swirls is correct, it implies that the primary agent responsible for the optical effects of space weathering on the Moon is solar-wind ion bombardment rather than micrometeoroid impact.     

The evolution of the moon

The thermal evolution of the Moon as it can be defined by the available data and theoretical calculations is discussed. A wide assortment of geological, geochemical and geophysical data constrain both the present-day temperatures and the thermal history of the lunar interior. On the basis of these data, the Moon is characterized as a differentiated body with a crust, a 1000-km-thick solid mantle (lithosphere) and an interior region (core) which may be partially molten. The presence of a crust indicates extensive melting and differentiation early in the lunar history. The ages of lunar samples define the chronology of igneous activity on the lunar surface. This covers a time span of about 1.5 billion yr, from the origin to about 3.16 billion yr ago. Most theoretical models require extensive melting early in the lunar history, and the outward differentiation of radioactive heat sources.Thermal history calculations, whether based on conductive or convective computation codes define relatively narrow bounds for the present day temperatures in the lunar mantle. In the inner region of the 700 km radius, the temperature limits are wider and are between about 100 and 1600°C at the center of the Moon. This central region could have a partially or totally molten core.The lunar heat flow values (about 30 ergs/cm²s) restrict the present day average uranium abundance to 60 ± 15 ppb (averaged for the whole Moon) with typical ratios of K/U = 2000 and Th/U = 3.5. This is consistent with an achondritic bulk composition for the Moon.The Moon, because of its smaller size, evolved rapidly as compared to the Earth and Mars. The lunar interior is cooling everywhere at the present and the Moon is tectonically inactive while Mars could be and the Earth is definitely active.     

Lunar X-ray fluorescence observations by the Chandrayaan-1 X-ray Spectrometer (C1XS): Results from the nearside southern highlands

The Chandrayaan-1 X-ray Spectrometer (C1XS) flown on-board the first Indian lunar mission Chandrayaan-1, measured X-ray fluorescence spectra during several episodes of solar flares during its operational period of ∼9 months. The accompanying X-ray Solar Monitor (XSM) provided simultaneous spectra of solar X-rays incident on the Moon which are essential to derive elemental chemistry. In this paper, we present the surface abundances of Mg, Al, Si, Ca and Fe, derived from C1XS data for a highland region on the southern nearside of the Moon. Analysis techniques are described in detail including absolute X-ray line flux derivation and conversion into elemental abundance. The results are consistent with a composition rich in plagioclase with a slight mafic mineral enhancement and a Ca/Al ratio that is significantly lower than measured in lunar returned samples. We suggest various possible scenarios to explain the deviations.     

Formation of Embryos of the Earth and the Moon from a Common Rarefied Condensation and Their Subsequent Growth

Embryos of the Moon and the Earth may have formed as a result of contraction of a common parental rarefied condensation. The required angular momentum of this condensation could largely be acquired in a collision of two rarefied condensations producing the parental condensation. With the subsequent growth of embryos of the Moon and the Earth taken into account, the total mass of as-formed embryos needed to reach the current angular momentum of the Earth–Moon system could be below 0.01 of the Earth mass. For the low lunar iron abundance to be reproduced with the growth of originally iron-depleted embryos of the Moon and the Earth just by the accretion of planetesimals, the mass of the lunar embryo should have increased by a factor of 1.3 at the most. The maximum increase in the mass of the Earth embryo due to the accumulation of planetesimals in a gas-free medium is then threefold, and the current terrestrial iron abundance is not attained. If the embryos are assumed to have grown just by accumulating solid planetesimals (without the ejection of matter from the embryos), it is hard to reproduce the current lunar and terrestrial iron abundances at any initial abundance in the embryos. For the current lunar iron abundance to be reproduced, the amount of matter ejected from the Earth embryo and infalling onto the Moon embryo should have been an order of magnitude larger than the sum of the overall mass of planetesimals infalling directly on the Moon embryo and the initial mass of the Moon embryo, which had formed from the parental condensation, if the original embryo had the same iron abundance as the planetesimals. The greater part of matter incorporated into the Moon embryo could be ejected from the Earth in its multiple collisions with planetesimals (and smaller bodies).     

Primary and secondary magnetizations in lunar rocks - Implications for the ancient magnetic field of the Moon

The nature of the ancient magnetic field of the Moon, in which lunar rocks acquired their remanent magnetism, has emerged as an important potential source of evidence, if somewhat controversial, for a lunar core which at a period in the Moon's history was the source of the magnetic field. Many of the lunar rocks possess a stable, primary remanence (NRM) with characteristics consistent with and indicative of thermo-remanent magnetization, acquired when the rocks cooled in an ambient magnetic field. Also present are secondary components of magnetization, one type of which appears to have been acquired between collection on the Moon and reception in the laboratory and others which were apparently acquired on the Moon.An important question to be answered is whether meteorite impacts play any part in lunar magnetism, either in modifying pre-existing magnetizations or by imparting a shock remanent magnetism (SRM) in a transient magnetic field associated with the impact. With current knowledge, SRM, in either a global lunar magnetic field of a transient field, and TRM cannot be distinguished, and in the paper the secondary magnetization characteristic of lunar rocks are examined to investigate whether their nature favours the presence of a permanent lunar magnetic field or whether they are consistent with an origin as a transient field-generated SRM.Besides terrestrial processes of secondary magnetization, such as viscous, chemical and partial thermoremanent magnetization, possible processes peculiar to the Moon are discussed and their likely importance assessed in relation to lunar sample history. The nature of the secondary magnetizations appear to be best explained on the assumption that they are due to one or more of the processes that require an ambient lunar field, namely viscous, partial thermoremanent and shock magnetization. When associated with other types of evidence obtained from lunar magnetism studies, investigations of lunar sample remanent magnetism now favours the existence of an ancient lunar magnetic field.     

Capability of the penetrator seismometer system for lunar seismic event observation

We developed a seismometer system for a hard landing “penetrator” probe in the course of the former Japanese LUNAR-A project to deploy new seismic stations on the Moon. The penetrator seismometer system (PSS) consists of two short-period sensor components, a two-axis gimbal mechanism for orientation, and measurement electronics. To carry out seismic observations on the Moon using the penetrator, the seismometer system has to function properly in a lunar environment after a hard landing (impact acceleration of about 8000 G), and requires a signal-to-noise ratio to detect lunar seismic events. We evaluated whether the PSS could satisfactorily observe seismic events on the Moon by investigating the frequency response, noise level, and response to ground motion of our instrument in a simulated lunar environment after a simulated impact test. Our results indicate that the newly developed seismometer system can function properly after impact and is sensitive enough to detect seismic events on the Moon. Using this PSS, new seismic data from the Moon can be obtained during future lunar missions.     

On the deviation of the lunar center of mass to the East. Two possible mechanisms based on evolution of the orbit and rounding off the shape of the Moon

From the observations of the gravitational field and the figure of the Moon, it is known that its center of mass (briefly COM) does not coincide with the center of figure (COF), and the line “COF/COM” is not directed to the center of the Earth, but deviates from it to the South–East. Here we study the deviation of the lunar COM to the East from the mean direction to Earth.At first, we consider the optical libration of a satellite with synchronous rotation around the planet for an observer at a point on second (empty) orbit focus. It is found that the main axis of inertia of the satellite has asymmetric nonlinear oscillations with amplitude proportional to the square of the orbit eccentricity. Given this effect, a mechanism of tidal secular evolution of the Moon’s orbit is offered that explains up to \(20\%\) of the known displacement of the lunar COM to the East. It is concluded that from the alternative—evolution of the Moon’s orbit with a decrease or increase in eccentricity—only the scenario of evolution with a monotonous increase in orbit eccentricity agrees with the displacement of lunar COM to the East. The precise calculations available confirm that now the eccentricity of the lunar orbit is actually increasing and therefore in the past it was less than its modern value, \(e = 0.0549\).To fully explain the displacement of the Moon’s COM to the East was deduced a second mechanism, which is based on the reliable effect of tidal changes in the shape of the Moon. For this purpose the differential equation which governs the process of displacement of the Moon’s COM to the East with inevitable rounding off its form in the tidal increase process of the distance between the Earth and the Moon is derived. The second mechanism not only explains the Moon’s COM displacement to the East, but it also predicts that the elongation of the lunar figure in the early epoch was significant and could reach the value \(\varepsilon\approx0.31\). Applying the theory of tidal equilibrium figures, we can estimate how close to the Earth the Moon could have formed.     

Distribution, ,movement,and evolution of the volatile elements in the lunar regolith

The abundances and distributions of carbon, nitrogen, and sulfur in lunar soils are reviewed. Carbon and nitrogen have a predominantly extra-lunar origin in lunar soils and breccias, while sulfur is mostly indigeneous to the Moon. The lunar processes which effect the movement, distribution, and evolution of carbon, nitrogen, and sulfur, along with the volatile alkali elements sodium, potassium, and rubidium during regolith processes are discussed. Possible mechanisms which may result in the addition to or loss from the Moon of these volatile elements are considered.     

Constraints on the source of lunar cataclysm impactors

Multiple impact basins formed on the Moon about 3.8 Gyr ago in what is known as the lunar cataclysm or Late Heavy Bombardment. Many workers currently interpret the lunar cataclysm as an impact spike primarily caused by main-belt asteroids destabilized by delayed planetary migration. We show that morphologically fresh (class 1) craters on the lunar highlands were mostly formed during the brief tail of the cataclysm, as they have absolute crater number density similar to that of the Orientale basin and ejecta blanket. The connection between class 1 craters and the cataclysm is supported by the similarity of their size-frequency distribution to that of stratigraphically-identified Imbrian craters. Majority of lunar craters younger than the Imbrium basin (including class 1 craters) thus record the size-frequency distribution of the lunar cataclysm impactors. This distribution is much steeper than that of main-belt asteroids. We argue that the projectiles bombarding the Moon at the time of the cataclysm could not have been main-belt asteroids ejected by purely gravitational means.     

Hypervelocity Impact Experiments in the Laboratory Relating to Lunar Astrobiology

The results of a set of laboratory impact experiments (speeds in the range 1–5 km s⁻¹) are reviewed. They are discussed in the context of terrestrial impact ejecta impacting the Moon and hence lunar astrobiology through using the Moon to learn about the history of life on Earth. A review of recent results indicates that survival of quite complex organic molecules can be expected in terrestrial meteorites impacting the lunar surface, but they may have undergone selective thermal processing both during ejection from the Earth and during lunar impact. Depending on the conditions of the lunar impact (speed, angle of impact etc.) the shock pressures generated can cause significant but not complete sterilisation of any microbial load on a meteorite (e.g. at a few GPa 1–0.1% of the microbial load can survive, but at 20 GPa this falls to typically 0.01–0.001%). For more sophisticated biological products such as seeds (trapped in rocks) the lunar impact speeds generate shock pressures that disrupt the seeds (experiments show this occurs at approximately 1 GPa or semi-equivalently 1 km s⁻¹). Overall, the delivery of terrestrial material of astrobiological interest to the Moon is supported by these experiments, although its long term survival on the Moon is a separate issue not discussed here.     

Radio Cherenkov signals from the Moon: Neutrinos and cosmic rays

Neutrino production of radio Cherenkov signals in the Moon is the object of radio telescope observations. Depending on the energy range and detection parameters, the dominant contribution to the neutrino signal may come from interactions of the neutrino on the Moon facing the telescope, rather than neutrinos that have traversed a portion of the Moon. Using the approximate analytic expression of the effective lunar aperture from a recent paper by Gayley, Mutel and Jaeger, we evaluate the background from cosmic ray interactions in the lunar regolith. We also consider the modifications to the effective lunar aperture from generic non-standard model neutrino interactions. A background to neutrino signals are radio Cherenkov signals from cosmic ray interactions. For cosmogenic neutrino fluxes, neutrino signals will be difficult to observe because of low neutrino flux at the high energy end and large cosmic ray background in the lower energy range considered here. We show that lunar radio detection of neutrino interactions is best suited to constrain or measure neutrinos from astrophysical sources and probe non-standard neutrino-nucleon interactions such as microscopic black hole production.     

Accretion process of the moon

Recent geochemical and geophysical data suggest that the initial temperature of the Moon was strongly peaked toward the lunar surface. To explain such an initial temperature distribution, a simple model of accretion process of the Moon is presented. The model assumes that the Moon was formed from the accumulation of the solid particles or gases in the isolated, closed cloud. Two equations are derived to calculate the accretion rate and surface temperature of the accreting Moon. Numerical calculations are made for a wide range of the parameters particle concentration and particle velocity in the cloud. A limited set of the parameters gives the initial temperature profiles as required by geochemical and geophysical data. These models of the proto-moon cloud indicate that the lunar outershell, about 400 km thick, was partially or completely molten just after the accretion of the Moon and that the Moon should have been formed in a period shorter than 1000 yr. If the Moon formed at a position nearer to the Earth than its present one, the Moon might have been formed in a period of less than one year.On leave from Geophysical Institute, University of Tokyo.Contribution No. 2104, Division of Geological and Planetary Sciences, California Institute of Technology.     

Computer simulation of observations of stars from the moon using the polar zenith telescope of the Japanese project ILOM

The paper briefly describes the purpose and features of the Japanese project ILOM (In-situ Lunar Orientation Measurement) in which it is planned to install the zenith telescope with a CCD lens on one of the poles of the Moon for the observation of stars in order to determine the physical libration of the Moon (PhLM). The studies presented in this paper are the result of the first stage of the theoretical support of the project:

1. The compilation of the list of stars within the field of view of the telescope during the precessional motion of the lunar pole.
2. Modeling and analysis of the behavior of stellar tracks during the observation period.
3. Simulation and testing of the sensitivity of the measured selenographic star coordinates to changes in the parameters of the dynamic model of the Moon and the elastic parameters of the lunar body.

Direct and inverse PhLM problems are discussed. Within the scope of the direct problem visible “daily parallels” and one-year star tracks are calculated. Their behavioral features when observed from the lunar surface are shown. At this stage of the simulation selenographic star coordinates for the four models of the gravitational field of the Moon have been compared, i.e., the model constructed on the basis of the lunar laser ranging (LLR), GLGM-2, LP150Q, and SGM100h. It is shown that even when comparing modern models LP150Q and SGM100h stellar tracks differ from the arc by more than 10 ms of arc. At the stage of the inverse problem, the manifestation of viscoelastic properties of the Moon in selenographic coordinates has been studied. In the spectrum of the simulated residual differences harmonics have been identified which can serve as indicators to refine parameters, Love number k ₂ and the delay time characterizing the viscous properties of the lunar body.