离心实验在污染物迁移研究中的应用

离心实验模拟以其可以获得与原型一致的应力水平并且能够大大缩短原型历时而被应用于污染物迁移实验研究。在离心相似理论及离心实验模拟的相似基础上,重点回顾了离心机在饱和带水分、非饱和带水分、保守性溶质、NAPLs、重金属、核素迁移以及污染场地修复方面的实验应用。最后讨论了离心模拟中土壤预制和加速度选择的问题,并简单介绍了离心监测方法。可以得出结论:离心机能够成功用于各类物质迁移的实验研究中,离心实验模拟能够为理论和数值等分析方法快速提供真实可靠的参数依据,但离心实验的理论基础和监测方法需要进一步完善,此外也应积极开展更接近实际情况下的离心实验模拟研究。     

氮类污染物在土壤中迁移转化规律试验研究

在分析氮物质迁移过程的基础上,借助于土柱物理模型试验装置,试验研究了氮类污染物在土壤中迁移转化规律,得到了NH₄+-N、NO₃--N在土柱内的时空变化过程。在分析实测资料后,建立了考虑氮的迁移和转化的数学模型。根据实测资料和数学模型的数值解,运用最优化技术率定模型参数,参数验证结果与独立的实测值吻合良好。     

锚杆在坡残积土中锚固机理的探讨

根据深圳市文锦广场深基坑喷锚支护及锚杆拉拔试验成果，探讨砂浆锚杆和摩擦锚杆在坡残积土中的锚固机理，认为砂浆锚杆锚固力主要取决于砂浆与坡残积土的一系列物理化学作用；摩擦锚杆锚固力主要取决于锚杆与土体间的摩擦力。     

Geotechnical reconnaissance and liquefaction analyses of a liquefaction site with silty fine sand in Southern Taiwan

Geotechnical reconnaissance of a recurrent liquefaction site at a Quaternary alluvial deposit in southern Taiwan was conducted to establish a comprehensive case history for liquefaction on silty fine sand with high fines content. The liquefaction occurred at a silty fine sand layer with D₅₀ = 0.09 mm and fines content greater than 35% and was triggered by a M_w = 6.4 earthquake on March 4, 2010, which induced maximum horizontal acceleration up to 0.189 g at the site. In situ subsurface characterizations, including standard penetration test, cone penetration test, and shear wave velocity measurement, were performed as well as cyclic simple shear tests on undisturbed specimens retrieved by a modified hydraulic piston sampler. Comparisons of cyclic resistance ratios (CRRs) indicate that CPT sounding with standard penetration rate could overestimate the resistance ratio and drainage conditions during penetration should be considered for high fines content soil in the liquefaction analysis. Additionally, variations of CRRs from different in situ tests indicate that correlations among in situ tests and CRR could be soil specific and precautions should be taken when using these curves on silty fine sands.     

石油类污染物在土壤中的吸附/解吸机理研究及展望

石油类污染物在土壤中的吸附与解吸研究是目前土壤学及环境科学研究的重要领域,石油类污染物在土壤中的吸附/解吸影响因素、机理及研究方法已有大量研究,但由于吸附/解吸传统研究方法受各种参数的限制,对影响因素、吸附模式、机理的研究难以进一步深入,多种影响因素之间的相互作用也是一个重要的研究方向;石油类污染物的吸附模式随着吸附方式的不同而适用于不同土壤的吸附,而用SPE技术可以从分子水平来认识吸附/解吸的本质。同时本文提出了石油类污染物在土壤中吸附/解吸机理研究中存在的问题,并展望未来的发展趋势。     

北部湾盆地涠西南凹陷断裂系统成因的砂箱实验研究及启示

北部湾盆地涠西南凹陷的断裂系统十分复杂,为了揭示其成因机制,在三维地震资料构造解析的基础上,应用砂箱物理模拟技术,对涠西南凹陷的形成机制进行了系统研究.结果表明,南北向的不协调伸展作用实验模型能够成功地模拟涠西南凹陷晚始新世以来复杂的断裂系统,断裂系统的主体特征在这一实验模型中均得到了很好的再现.涠两南凹陷复杂的断裂系统是在基底先1竽构造基础之上,在递进变形过程中逐渐形成的,其裂陷期(晚始新世一渐新世)断裂系统是在一个伸展期内形成(南北向伸展)、并非是多期构造叠加变形的结果.这一认识不但能够有效地指导涠西南凹陷三维地震资料的精细构造解释,同时也能够为南海周缘盆地的形成和演化研究提供借鉴.     

重力驱动作用——滦平盆地下白垩统西瓜园组沉积时期主要的搬运机制

通过对冀北滦平盆地下白垩统西瓜园组沉积地层的实地考察,发现盆地内发育丰富的重力驱动作用沉积物。文中描述西瓜园组发育的滑动和滑塌现象,指出露头剖面中存在的挤压变形现象并非构造成因,而是由于滑动块体和滑塌块体前端的挤压应力环境造成的。在介绍西瓜园组重力流沉积发育环境的基础上,对露头中存在的若干重力流沉积进行了描述,并使用砂质碎屑流这一概念对这些现象进行了较为合理的成因解释。通过对滑动和滑塌(重力块体运动)和砂质碎屑流—浊流(重力流)沉积物研究,结合前人对该地区冲积扇—扇三角洲的研究成果,认为重力驱动作用是滦平盆地下白垩统西瓜园组沉积时期主要的搬运机制。     

Modelling Transport of Linearly Sorbing Solutes in a Single Fracture: Asymptotic Behavior of Solute Velocity and Dispersivity

The asymptotic behavior of the solute velocity and dispersivity for a system of parallel fractures with matrix diffusion is made using numerical modeling and theoretical analyses. The study is limited to linearly sorbing solutes with a constant continuous source boundary condition. Expressions are provided for solute velocity and effective dispersivity in terms of fracture porosity during asymptotic stage using spatial moment analyses. The importance of matrix porosity and fracture porosity on solute velocity as well as the relationship governing effective dispersivity and fracture porosity is discussed for both non-reactive and linearly sorbing solutes. By using a dimensionless effective dispersivity parameter it is shown that the relationship between the fracture porosity and dimensionless effective dispersivity is linear for non-reactive solutes. It is also shown that this holds true for the linearly sorbing solutes with the same proportionality constant.     

Experimental monitoring and numerical study of pesticide (carbofuran) transfer in an agricultural soil at a field site

We studied the transport of a pesticide at field scale, namely carbofuran molecule, which is known for its high mobility, especially in sandy soils with high hydraulic conductivity and low organic matter. To add to our knowledge of the future of this high-mobility molecule in this type of soils, we developed a mechanistic numerical model allowing the simulation of hydric and solute transfers (bromide and carbofuran) in the soil. We carried out this study in an agricultural plot in the region of Mnasra in Morocco. Confrontation of the measured and simulated values allowed the calibration of the parameters of hydric transfer and carbofuran. The developed model accurately reproduces the measured values. Despite a weak irrigation and precipitation regime, carbofuran was practically leached beyond the root zone. Prospective simulations show that under a more important irrigation regime, carbofuran reaches a 100-cm depth, whereas it does not exceed 60 cm under a deficit regime.     

Assessment of soil erosion in a tropical mountain river basin of the southern Western Ghats,India using RUSLE and GIS

Revised Universal Soil Loss Equation(RUSLE) model coupled with transport limited sediment delivery(TLSD) function was used to predict the longtime average annual soil loss, and to identify the critical erosion-/deposition-prone areas in a tropical mountain river basin, viz., Muthirapuzha River Basin(MRB; area=271.75 km~2), in the southern Western Ghats, India. Mean gross soil erosion in MRB is 14.36 t ha~(-1) yr~(-1), whereas mean net soil erosion(i.e., gross erosion-deposition) is only 3.60 t ha~(-1) yr~(-1)(i.e., roughly 25% of the gross erosion). Majority of the basin area(~86%) experiences only slight erosion(5 t ha~(-1) yr~(-1)), and nearly 3% of the area functions as depositional environment for the eroded sediments(e.g., the terraces of stream reaches, the gentle plains as well as the foot slopes of the plateau scarps and the terrain with concordant summits). Although mean gross soil erosion rates in the natural vegetation belts are relatively higher, compared to agriculture, settlement/built-up areas and tea plantation, the sediment transport efficiency in agricultural areas and tea plantation is significantly high,reflecting the role of human activities on accelerated soil erosion. In MRB, on a mean basis, 0.42 t of soil organic carbon(SOC) content is being eroded per hectare annually, and SOC loss from the 4th order subbasins shows considerable differences, mainly due to the spatial variability in the gross soil erosion rates among the sub-basins. The quantitative results, on soil erosion and deposition, modelled using RUSLE and TLSD, are expected to be beneficial while formulating comprehensive land management strategies for reducing the extent of soil degradation in tropical mountain river basins.     

Experimental Study of the Melting Reaction and Genetic Mechanism of Mineral Phase Transformation in Granulite Facies Metamorphism

The high-temperature and high-pressure experiment on natural block rock indicates that dehydration-melting of hydrous biotite (Bi) and partial melting of felsic minerals in garnet-biotite-plagioclase gneiss are mainly controlled by temperature, while mineral phase transformation is not only controlled by temperature-pressure conditions but also genetically associated with hydrous mineral dehydration-melting and partial melting of felsic minerals. According to the characteristics of biotite dehydration-melting and garnet transformation reaction, three stages may be distinguished: (1) when the experimental temperature is 700℃, biotite transforms to ilmenite (Ilm) + magnetite (Mt) + H2O and garnet to magnetite (Mt); (2) when the temperature is 730-760℃, biotite is dehydrated and melted and transformed into K2O-rich melt + Ilm + Mt, and garnet, into hypersthene (Hy) + cordierite (Crd); (3) when the temperature is up to or higher than 790℃, biotite is dehydrated and melted and transformed into melt + Hy +     

山区河流两岸泥石流形成的机理和力学条件

泥石流是山区沟谷的主要地质灾害类型之一,对其开展研究是很有价值的,但目前对其进行的针对性研究很少。本文重点研究山区沟谷泥石流形成的机理和力学条件。根据地形地貌、气候环境条件与土质学原理,研究了山区河流泥石流的形成机理及影响因素。河流两岸山坡岩土结构、人为活动与持续降雨或暴雨是山区河流泥石流形成的主要影响因素,不同土质结构与组成的土层的滑移破坏机理也不相同。山区河流泥石流的物源可概化为粘性土块体与松散砂砾两种典型固相物质。基于剪切破坏理论,建立了粘性土块的失稳滑动平衡条件;基于动量理论与重力分解原理,提出了松散砂砾启动的力学计算公式和失稳条件。     

西峰油田长8储层微观孔隙结构非均质性与渗流机理实验

为深入剖析超低渗储层微观孔隙结构非均质性对渗流机理的影响程度,选取鄂尔多斯盆地西峰油田长8储层有代表性的样品进行了真实砂岩微观模型水驱油和CT扫描水驱油驱替实验。通过真实砂岩微观模型水驱油实验发现,对于没有微裂缝存在的岩样,水驱油效果往往与渗透率成正比关系,而微裂缝的存在使得微观孔隙结构非均质性显得更加突出,渗流机理将完全改变,从而水驱油效果也表现出较大的差异。CT扫描水驱油驱替实验结果也表明,微裂缝的存在明显增加了孔喉微观非均质程度,使得水驱效果变差。而环压对具有双重孔隙介质储层的注水效果会产生较大影响。可见对于超低渗储层,微观孔隙结构非均质性是造成注入水波及效率不高、水驱油效果差的主要原因。     

川东某场镇后山滑坡发育特征与机理分析

四川盆地红层丘陵地区局部垂向裂隙发育的坡体容易受强降雨影响发生平推式滑坡,对于该类滑坡前人已有较为系统的研究,但对该类滑坡体局部复活特征的研究尚不深入。以川东某地老平推式滑坡体上发育的现代滑坡为例,分析了这类老滑坡局部复活的机理特征,5·12强震对滑坡体完整性造成了一定程度的破坏,是老滑坡复活的因素之一;但后缘人工弃渣的加载是其复活最直接的激发因素。文章对治理方案进行了可行性探讨,最终选用"前缘抗滑桩+后缘截水沟+裂缝夯实"方案。     

Estimating groundwater recharge through tills: a sensitivity analysis of soil moisture budgets and till properties in Ireland

The study highlights the dangers of limiting recharge calculations in humid climates to meteorological and soil considerations. It highlights the importance of developing a conceptual understanding of the influence of geology on recharge mechanisms and recharge rates. Uncertainties in recharge estimates through tills are examined by a study of the available literature, combined with sensitivity analyses of soil moisture budget parameters and of hypothetical scenarios of till properties and hydraulic gradients that are realistic for Irish conditions. The sensitivity analyses demonstrate that till properties have a greater influence over recharge than the soil moisture budgeting parameters. Results are considered in terms of recharge coefficients, representing the proportion of effective precipitation that becomes actual recharge to the aquifer. The literature review identifies a range in recharge coefficients from 4% to 90% in selected field and catchment scale studies from bedrock aquifers in Ireland and the U.K. The sensitivity analyses are able to simulate a similar range in recharge coefficient of 2% to 80% by varying only till permeability, thickness and vertical hydraulic gradients. In the scenarios examined, the greatest sensitivity to vertical till permeability lies between 0.001 m/day and 0.01 m/day. The sensitivity to soil moisture budgeting parameters is much less apparent. It is concluded that this is due to the dominance of grassland in Ireland and the relatively wet summers, resulting in the limited development of soil moisture deficits by comparison with some parts of the U.K.

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Résumé Cette étude met en lumière les dangers résultants de la pratique consultant à limiter les calculs de recharge aux données météorologiques ainsi qu’aux considérations liées au sol. Elle met en lumière l’importance de développer des modèles conceptuels comprenant l’influence de la géologie sur les mécanismes de la recharge et les taux de recharge. Les incertitudes sur les estimations de la recharge à travers les argiles sont examinées à travers les données disponibles dans la littérature, combinées avec une analyse de sensibilité des paramètres du bilan hydrique et des scénarios hypothétiques reprenant les propriétés des argiles et les gradients hydrauliques qui sont réalistes dans le contexte irlandais de l’étude. Les analyses de sensibilité démontrent que les propriétés des argiles ont une plus grande influence sur la recharge que les paramètres du bilan hydrique des sols. Les résultats sont considérés en terme de coefficients de recharge, représentant la proportion de précipitation effective qui devient la recharge réelle de l’aquifère. La littérature identifie des coefficients de recharge allant de 4 à 90% sur des terrains sélectionnés à l’échelle de bassins-versants, sur les aquifères de socle en Irlande et au Royaume-Uni. Les analyses de sensibilité sont capables de simuler une variation aussi large de coefficients de recharge, en ne changeant rien que la perméabilité des argiles, leur épaisseur et les gradients hydrauliques verticaux. Dans les scénarios étudiés, la meilleure sensibilité à la perméabilité verticale se situe entre 0.001 et 0.01 m/jour. La sensibilité au bilan hydrique est beaucoup moins apparente. On en conclut que ceci est du à la dominance des prairies en Ireland et aux étés relativement humides, résultant des déficits en eau des sols relativement modérés en comparaison avec certaines zones du Royaume-uni.

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Resumen El estudio resalta los peligros de limitar los cálculos de recarga en climas húmedos a las consideraciones meteorológicas y del suelo. Se destaca la importancia de desarrollar un entendimiento conceptual de la influencia de la geología en los mecanismos de recarga y los ritmos de recarga. Se examinan las incertidumbres en los estimados de recarga a través de tills mediante un estudio de la literatura disponible combinado con análisis de sensibilidad de parámetros de balance de humedad del suelo y de escenarios hipotéticos de las propiedades del till y gradientes hidráulicos que son realistas para condiciones típicas de Irlanda. Los análisis de sensibilidad demuestran que las propiedades del till tienen una influencia más grande en la recarga que los parámetros del balance de humedad del suelo. Se consideran los resultados en términos de coeficientes de recarga, representando la proporción de precipitación efectiva que se convierte en recarga real al acuífero. La revisión de literatura identifica un rango de coeficientes de recarga que varía de 4% a 90% en estudios seleccionados de cuencas y escala de campo realizados en acuíferos de macizo rocoso en Irlanda y el Reino Unido. Los análisis de sensibilidad pueden simular un rango similar en los coeficientes de recarga de 2% a 80% al variar únicamente la permeabilidad del till, el espesor y los gradientes verticales hidráulicos. En los escenarios examinados, la relación de sensibilidad más grande con la permeabilidad vertical del till se encuentra entre 0.001 m/día y 0.01 m/día. La sensibilidad en relación a los parámetros del balance de humedad del suelo es mucho menos aparente. Se concluye que esto se debe a la predominancia de tierras con hierba en Irlanda y los veranos relativamente húmedos, lo que resulta en el desarrollo limitado de déficit de humedad de suelo en comparación con algunas partes del Reino Unido.

     

Experimental simulation and dynamic model analysis of Cadmium(Cd) release in soil affected by rainfall leaching in a coal-mining area

In order to explore the influence of rainfall on the release of heavy metal Cadmium(Cd)in soil in a coal-mining area,soil column leaching experiments were carried out by simulating 3 types of rainfall(acid rain,normal rainfall,and actual rainfall)with 5 different pH values(4,5,6,6.7,7),and 65 groups of data about leachate pH value and Cd concentration were obtained respectively.The results indicate the general change rule of Cd concentration in leachate:(1)the easiness of Cd release is negatively correlated to the pH value of leaching solution and positively correlated the leaching amount;(2)leaching solution with lower pH values shows more obvious release stages.Leached by solution with different pH values,the release of Cd in soil ranks as follows:Acid rain group>normal rainfall group>actual rainfall group.In the first stage,the acidity of rainfall has a significant impact on the release of Cd in soil,but in the second stage,the release of Cd is alleviated due to the soil buffering.Among the four dynamic equations to simulate the release of Cd in soil,the modified Elovich equation can describe the process most accurately,with the highest coefficient of determination R2 of 0.9975.These results can serve as a reference for further study on the migration,transformation and enrichment of Cd in soil.     

Numerical Modelling of Dissolving and Driving Exploitation of Potash Salt in the Qarhan Playa ? A Coupled Model of Reactive Solute Transport and Chemical Equilibrium in a Multi-component Underground Brine System

Firstly, the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer （salt deposit） in Qarhan Salt Lake was studied by using the Pitzer theory. The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented, which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake. And secondly, with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference, a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system （salt deposits） was developed by using the Pitzer theory. Meanwhile, the model was applied to model potassium/magnesium transport in Qarhan Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarhan Salt Lake.     

赣南部分岩体的锆石铀-铅同位素年代学研究及其对成岩成矿机制的再认识

赣南岩浆岩分布广泛,有的岩体成岩时代明确,有的则存在争议。利用激光多接收器电感耦合等离子体质谱(LA-MC-ICPMS)技术测定了田新、路迳、水头、白鹅、高山角、韩坊、杨村、湖南洞、珠兰埠、淋洋、大富足、油山、吉埠黄沙、阳埠和万田等岩体的U-Pb年龄,表明这些岩体不全是燕山期形成的,即使是燕山期的田新、路迳、水头、白鹅、韩坊、杨村等岩体中也存在有更早期的锆石,大部分岩体经历了6～10 Ma的结晶成岩历史。通过与以往K-Ar、Rb-Sr等时线方法的初步对比,指出赣南地区花岗岩虽然在同位素年龄数据上以侏罗纪为多,但印支期的岩体面积不小,前寒武纪和加里东期的信息也不断增多,说明赣南花岗岩型地壳的演化经历了漫长的历史过程,相当一部分岩体不是单一成岩期形成的,而是多期次多阶段形成的。加里东期的岩体以往不被注意,认为与钨矿关系不密切,但可以成为离子吸附型稀土矿的成矿母岩。     

浙江梧村超单元主要地质特征及其就位机制探讨

浙江梧村岩体是一个主要由石英二长岩、二长岩组成的中生代复式岩体.通过详细的野外填图和地质地球化学研究,发现该岩体具有结构和成分演化序列.依据侵入体之间及其与围岩的接触关系、岩石的矿物成分及岩石地球化学、结构构造等特征,可将其划分为大山、沐尘、下坞等3个岩石单元,归并为梧村超单元.从早期到晚期,岩浆的侵入具有明显的反序特征,这种"反序"现象是因为存在带状岩浆房.三个单元在格局上呈刺破式同心带状型式,这种就位很可能属于刺穿式底辟作用.     

南祁连亚曲含镍铜矿基性杂岩体形成年龄及机制探讨

通过亚曲岩体的实地调查和研究,利用ID-TIMS方法对岩体定年,获得(440.74±0.33) Ma成岩年龄,为加里东期.岩石地球化学特征分析及区域对比研究表明,亚曲基性杂岩体以低Ti、亏损Nb和Ta、富集轻稀土元素和大离子亲石元素为特征.结合其同位素特征,提出该岩体的形成与祁连山及其邻区460~440 Ma时期俯冲向碰撞转换的作用有关,可能是岛弧岩浆作用的结果.这对于南祁连化隆一带区域铜镍找矿具有重要意义,亦对丰富完善早古生代岩浆铜镍硫化物矿床的研究和形成机制具有借鉴作用.