Evaluation of the origin hypotheses of Pantheon Fossae, central Caloris basin, Mercury

The origin of Pantheon Fossae, a complex structure consisting of radial graben in the center of the Caloris basin, Mercury, has been debated since the structure was first imaged by the MESSENGER spacecraft. Three different formation hypotheses have been suggested, i.e. an origin associated with the Apollodorus impact into a previously domed Caloris basin floor, graben formation as surface expressions of dike intrusions and basin-interior uplift alone. In order to test the scenarios, detailed observations from the currently available imagery were compared to the proposed formation mechanisms. We evaluate these origin hypotheses by means of detailed interpretations of the graben characteristics and patterns, by comparing to radial structures from Earth and Venus, and by mechanical analyses for each formation hypothesis. Results indicate that the formation of Pantheon Fossae as the result of doming in the central part of the Caloris basin is more likely than it having formed in association with a radially symmetric stress field centered at or near the Apollodorus crater, that would have been created by a magma chamber or been superimposed on a pre-existing dome due to impact mechanics.     

Sequential deformation of plains at the margins of Alpha Regio,Venus: Implications for tessera formation

Abstract— The boundaries between the highly deformed tessera terrain and adjacent volcanic plains are primarily those of embayment, where the tessera are stratigraphically older than the plains. Previous studies show that <3% of these boundaries display evidence of tectonic tilting after the emplacement of the plains. One of these unusual boundaries is the western margin of Alpha Regio tessera, a zone ～ 100 km in width that separates the plains from the interior structures of Alpha. This zone is characterized by margin parallel, fine‐scale (1–5 km) fractures, graben, and ridges that truncate and postdate the broad‐scale (10–30 km) ridges and troughs of the interior of Alpha. The western margin is embayed by several volcanic plains units that are progressively tilted and deformed by graben with closer proximity to Alpha Regio. The earliest deformation of the plains consists of northeast‐trending graben ～1 km in width that are similar in morphology and spacing to graben that deform intratessera plains and plains at the eastern boundary of Alpha. Northwest‐trending graben then formed over an interval marked by the emplacement of two additional plains units; their similarity to northwest‐trending structures emanating from Eve corona and the Lada Terra rift suggests a possible genetic relationship. The tilting of the plains adjacent to western Alpha implies relative vertical movement of the margin, either uplift of tessera or downwarping of plains subsequent to the formation and relaxation of the interior of Alpha Regio. Subsidence of plains at this locale is supported by the presence of a basin to the west of Alpha surrounded by a fracture belt contiguous with western Alpha. Thus, the fractures and deformation at the western boundary of Alpha may be related to the formation of a basin to the west of Alpha with some influence from the northernmost extension of the Lada Terra rift. Such a basin is not present at a section along the eastern boundary of Alpha Regio, where the origin of tilted plains remains equivocal. We conclude that the deformation along the western margin of Alpha Regio is not directly related to the process of tessera formation but is an example of tessera modification and is consistent with the stratigraphic position of tessera as the oldest unit observed on Venus.     

Tectonics of Syrtis Major Planum on Mars

Mare ridges were caused by compressional tectonics and indicate the shortening of the planum surface foiled by lavas. At least two separate tectonic phases within Syrtis Major Planum can be found. The two central calderas are located on the southwestern continuation of the Nili Fossae graben zone at the junction of the N-S and NW-SE mare ridge sets. These central calderas were formed by surface collapses into relatively shallow magma chambers. Radial and concentric mare ridges around the two calderas represent a shortened surface environment within the large compressional megacaldera. Shortening was caused by sinking of the crust due to the lava load, plumbing of the magma chambers and cooling of the interiors. The main NW-SE ridge trend parallels highland faults of the major structural zone extending from Hesperia Planum to Vastitas Borealis. These NW-SE ridges indicate the large scale areal tectonic trend along the Scopulus Oenotria - Phison Rupes fault zone and support the idea of a main SW-NE compression. The N-S directed mare ridges of the northern planum area favour a change in compressional stress direction from SW-NE in the south to E-W in the northern planum, obviously due to the buried local topography. These linear mare ridges can also be interpreted as forming a large Isidis Planitia-concentric ridge circle connecting Nili Fossae to Libya Montes. Formation of the mare ridges was the youngest of the main tectonic phases involved within the area studied.     

Mercury crater statistics from MESSENGER flybys: Implications for stratigraphy and resurfacing history

The primary crater population on Mercury has been modified by volcanism and secondary craters. Two phases of volcanism are recognized. One volcanic episode that produced widespread intercrater plains occurred during the period of the Late Heavy Bombardment and markedly altered the surface in many areas. The second episode is typified by the smooth plains interior and exterior to the Caloris basin, both of which have a different crater size-frequency distribution than the intercrater plains, consistent with a cratering record dominated by a younger population of impactors. These two phases may have overlapped as parts of a continuous period of volcanism during which the volcanic flux tended to decrease with time. The youngest age of smooth plains volcanism cannot yet be determined, but at least small expanses of plains are substantially younger than the plains associated with the Caloris basin. The spatial and temporal variations of volcanic resurfacing events can be used to reconstruct Mercury's geologic history from images and compositional and topographic data to be acquired during the orbital phase of the MESSENGER mission.     

Crosscutting relations and relative ages of ridges and faults in the Tharsis region of Mars

Observations of ridge-fault crosscutting relationships on the ridged plains units surrounding the Tharsis region of Mars have led to the development of a classification scheme involving three distinct types of intersections. Ridges crosscut by faults are designated Type C and account for 81% of the observed intersections. Ridges terminated at one end by a fault (Type T), as well as those superposed on grabens (Type S), are less numerous. Interpretation of the morphology of these intersections and the angles of intersection between ridges and faults with radial trends to major topographic features in the Tharsis region have led to the following conclusions: (1) the major ridge forming events in the Tharsis region were roughly coincident with, and in some cases possibly prior to, the extensional events that produced the faulting of the Tempe and Mareotis regions, the Coprates and Memnonia regions, and the rifting of Valles Marinrris; (2) the compressional events that formed most of the ridges are restricted in time both by the irrelationship to regional extensional events and by the age of the units on which they formed. The suggestion that compressional ridges are a result of a single long term viscoelastic response of the lithosphere to loading of the crust is not supported by this study. A model involving one or more isostatically compensated uplifts and subsequent relaxation of the crust after the emplacement of the ridged plains volcanic units is favored.     

The morphology of Mercury’s Caloris basin as seen in MESSENGER stereo topographic models

A digital terrain model (1000-m effective spatial resolution) of the Caloris basin, the largest well-characterized impact basin on Mercury, was produced from 208 stereo images obtained by the MESSENGER narrow-angle camera. The basin rim is far from uniform and is characterized by rugged terrain or knobby plains, often disrupted by craters and radial troughs. In some sectors, the rim is represented by a single marked elevation step, where height levels drop from the surroundings toward the basin interior by approximately 2 km. Two concentric rings, with radii of 690 km and 850 km, can be discerned in the topography. Several pre-Caloris basins and craters can be identified from the terrain model, suggesting that rugged pre-impact topography may have contributed to the varying characteristics of the Caloris rim. The basin interior is relatively smooth and shallow, comparable to typical lunar mascon mare basins, supporting the idea that Caloris was partially filled with lava after formation. The model displays long-wavelength undulations in topography across the basin interior, but these undulations cannot readily be related to pre-impact topography, volcanic construction, or post-volcanic uplift. Because errors in the long-wavelength topography of the model cannot be excluded, confirmation of these undulations must await data from MESSENGER’s orbital mission phase.     

Elysium planitia,mars: Regional geology,volcanology, and evidence for volcano-ground ice interactions

Geological mapping of Elysium Planitia has led to the recognition of five major surface units, in addition to the three volcanic constructs Elysium Mons, Hecates Tholus, and Albor Tholus. These units are interpreted to be both volcanic and sedimentary or erosional in origin. The volcano Elysium Mons is seen to have dominated constructional activity within the whole region, erupting lava flows which extend up to 600km from the summit. A major vent system, covering an area in excess of 75 000 km², is identified within the Elysium Fossae area. Forty-one sinuous channels are visible within Elysium Planitia; these channels are thought to be analogous to lunar sinuous rilles and their formation in this region of Mars is attributed to unusually high regional topographic slopes (up to ~ 1.7). Numerous circumferential graben are centered upon Elysium Mons. These graben, located at radial distances of 175, 205–225, and 330km from the summit, evidently post-dated the emplacement of the Elysium Mons lava flows but pre-dated the eruption of extensive flood lavas to the west of the volcano. A great diversity of channel types is observed within Elysium Fossae. The occurrences of streamlined islands and multiple floor-levels within some channels suggests a fluvial origin. Conversely, the sinuosity and enlarged source craters of other channels suggests a volcanic origin. Impact crater morphology, the occurrence of chaotic terrain, probable pyroclastic deposits upon Hecates Tholus and fluvial channels all suggest extensive volcano-ground ice interactions within this area.NASA Summer Intern.     

The stratigraphy of the Amenthes region, Mars: Time limits for the formation of fluvial, volcanic and tectonic landforms

We present results of our morphologic and stratigraphic investigations in the Amenthes region for which our observations suggest a complex spatial and temporal interrelation between volcanic and possibly water-related processes. We have produced a series of self-consistent geological maps and a stratigraphic correlation chart that show the spatial and temporal distribution of volcanic, fluvial and tectonic processes.The Amenthes region consists of a broad trough-like topographic depression that has served as a path for the supply of materials from Hesperia Planum to Isidis Planitia. It is most likely that Hesperia Planum and, in particular the area north of Hesperia Planum, including Tinto Vallis, Palos crater and the surrounding dissected highlands have acted as a source region for materials that were transported into the Amenthes trough and farther into the Isidis basin. The Amenthes trough, as well as the graben of Amenthes Fossae were formed after the Isidis impact in the Noachian and represent likely the oldest features in the Amenthes region. Dendritic valley networks, that bear evidence for surface runoff, have dissected the highlands adjacent to Amenthes Planum and within the Tinto Vallis and Palos crater region before ∼3.7 Ga. The ridged volcanic plains located near the Palos crater and Tinto Vallis region, within Amenthes Planum as well as within the Isidis transitional plains were formed between ∼3.5 and 3.2 Ga and represent the volcanic activity which resulted in the flooding of the Amenthes trough. The sinuous channel of Tinto Vallis was formed in the Hesperian (?3.5 Ga) and shows characteristics, which are consistent with both ground water sapping and igneous processes. The Palos crater outflow channel was formed nearly at the same time as Tinto Vallis, between ∼3.5 Ga and ∼3.2 Ga and postdates the volcanic flooding of the Amenthes trough in the Hesperian. Small valleys (∼3.4-2.8 Ga) incised into the ridged plains of Amenthes Planum appear also within the transitional plains located between the Amenthes plains and the Isidis interior plains. Our model ages show that Tinto Vallis, the Palos crater outflow channel as well as the small valleys are unlikely formed at the same time and by the same processes as the dendritic valley networks and represent an episode that clearly postdates the volcanic activity.     

Global stratigraphy of Venus: analysis of a random

The age relations between 36 impact craters with dark paraboloids and other geologic units and structures at these localities have been studied through photogeologic analysis of Magellan SAR images of the surface of Venus. Geologic settings in all 36 sites, about 1000 × 1000 km each, could be characterized using only 10 different terrain units and six types of structures. These units and structures form a major stratigraphic and geologic sequence (from oldest to youngest): 1) tessera terrain; 2) densely fractured terrains associated with coronae and in the form of remnants among plains; 3) fractured and ridged plains and ridge belts; 4) plains with wrinkle ridges; 5) ridges associated with coronae annulae and ridges of arachnoid annulae which are contemporary with wrinkle ridges of the ridged plains; 6) smooth and lobate plains; 7) fractures of coronae annulae, and fractures not related to coronae annulae, which disrupt ridged and smooth plains; 8) rift-associated fractures; 9) craters with associated dark paraboloids, which represent the youngest 10% of the Venus impact crater population (Campbellet al., 1992), and are on top of all volcanic and tectonic units except the youngest episodes of rift-associated fracturing and volcanism; surficial streaks and patches are approximately contemporary with dark-paraboloid craters.Mapping of such units and structures in 36 randomly distributed large regions (each 10⁶ km²) shows evidence for a distinctive regional and global stratigraphic and geologic sequence. On the basis of this sequence we have developed a model that illustrates several major themes in the history of Venus. Most of the history of Venus (that of its first 80% or so) is not preserved in the surface geomorphological record. The major deformation associated with tessera formation in the period sometime between 0.5–1.0 b.y. ago (Ivanov and Basilevsky, 1993) is the earliest event detected. In the terminal stages of tessera formation, extensive parallel linear graben swarms representing a change in the style of deformation from shortening to extension were formed on the tessera and on some volcanic plains that were emplaced just after (and perhaps also during the latter stages of the major compressional phase of tessera emplacement. Our stratigraphic analyses suggest that following tessera formation, extensive volcanic flooding resurfaced at least 85% of the planet in the form of the presently-ridged and fractured plains. Several lines of evidence favor a high flux in the post-tessera period but we have no independent evidence for the absolute duration of ridged plains emplacement. During this time, the net state of stress in the lithosphere apparently changed from extensional to compressional, first in the form of extensive ridge belt development, followed by the formation of extensive wrinkle ridges on the flow units. Subsequently, there occurred local emplacement of smooth and lobate plains units which are presently essentially undeformed. The major events in the latest 10% of the presently preserved history of Venus (less than 50 m.y. ago) are continued rifting and some associated volcanism, and the redistribution of eolian material largely derived from impact crater deposits.Detailed geologic mapping and stratigraphic synthesis are necessary to test this sequence and to address many of the outstanding problems raised by this analysis. For example, we are uncertain whether this stratigraphic sequence corresponds to geologic events which were generally synchronous in all the sites and all around the planet, or whether the sequence is simply a typical sequence of events which occurred in different places at different times. In addition, it is currently unknown whether the present state represents a normal consequence of the general thermal evolution of Venus (and is thus representative of the level of geological activity predicted for the future), or if Venus, has been characterized by a sequence of periodic global changes in the composition and thermal state of its crust and upper mantle (in which case, Venus could in the future return to levels of deformation and resurfacing typical of the period of tessera formation).     

The tectonic and volcanic history of Dione

The tectonic and volcanic modifications of Dione are described and interpreted. It is proposed that after the formation of a brittle outer shell, but before the end of heavy meteoritic bombardment, global expansion due to radionuclide heating (and perhaps a loss of oblateness due to tidal despinning and orbital recession) produced a global system of lineaments. An NH₃ · H₂O melt was produced and “erupted” on the surface to form plains units. Cooling of the interior (or a phase change) led to horizontal compression in the surface. Compression of a thick deposit of plains material, possibly overlying a décollement surface, is proposed to explain cratered-plains ridges developed as thrust or high-angle reverse faults. Following formation of ridges and smooth plains, the surface experienced light cratering.     

The chronology of Mercury's geological and geophysical evolution: The vulcanoid hypothesis

Previous discussions of Mercury's evolution have assumed that its cratering chronology is tied to that of the Moon, i.e., with Caloris forming about 3.9 Gyr ago as part of a late heavy bombardment that affected all of the terrestrial planets. That assumption requires that Mercury's core formed very early, because associated expansion features are not visible, and must have been erased before the cratering flux declined. Moreover, the modest amount of global shrinkage inferred from visible compressional features on Mercury's surface implies that the core is either largely molten at present, or had largely solidified before the end of the bombardment. The former interpretation requires a significant volatile content or implausibly large internal heat sources, while the latter raises questions about how to generate the planet's magnetic field. We have investigated whether constraints on Mercury's chronology could be relaxed by effects of a Mercury-specific bombarding population of planetesimals interior to its orbit, encountering the planet only occasionally due to secular perturbations. Such “vulcanoids” could have been a significant source of early cratering. However, those in orbits that can cross Mercury's are depleted by mutual collisions in ⪅1 Gyr, and can provide at most a modest extension of the period of heavy bombardment. Further inside Mercury's orbit, lower collisional velocities might allow survival of vulcanoids to the present. We report on a search for such bodies and on observational limits to such a population. We also review evidence that Mercury's intercrater plains are of volcanic origin and mainly predate Caloris, and that scarp formation (and global contraction) mainly postdates Caloris and has continued to recent times. If global lineaments are the product of tidal despinning, they constrain core formation to the first half of the planet's lifetime. While some questions and inconsistencies remain, the preponderance of evidence suggests that Mercury differentiated early, and at least half of its core volume is presently molten, probably due to a significant content of some light element such as sulfur.     

Tectonic implications for the gravity structure of Caloris Basin,Mercury

Studies of tectonic landforms associated with Caloris Basin on Mercury suggest that isostatic adjustment has occurred in response to basin excavation, and that the smooth plains inside Caloris were emplaced significantly before isostatic equilibrium was attained. Combined with dynamical considerations, this leads us to propose that the Caloris region is characterized by a circular negative or zero free air gravity anomaly centered inside Caloris, and an annular positive anomaly which coincides with extensive tracts of young smooth plains outside the basin. This proposed gravity pattern differs markedly from that associated with mare-filled basins on the Moon.     

Onset Time and Duration of Corona Activity on Venus: Stratigraphy and History from Photogeologic Study of Stereo Images

The details of stratigraphic units and structures making up six coronae and their regional surroundings on Venus were examined using full resolution Magellan images and stereoscopic coverage. Altimetry and stereoscopic coverage were essential in establishing the local stratigraphic relationships and the timing of corona-related topography. The degree of preservation of signatures of earlier corona-related activities and the scale of later corona-related activities vary significantly from corona to corona. We compared the geologic sequence in each corona to regional and global stratigraphic units, placing the coronae in the broader context of the geologic history of Venus. The results of this study were compared with earlier analyses bringing the total number of corona considered to about 15% of the total corona population. We found that corona started forming soon after tessera formation and largely spanned a significant part of the subsequent geologic history of Venus, over about 200–400 million years. Topographic annulae were initiated in early post-tessera time but were largely completely formed by the time of emplacement of regional plains with wrinkle ridges. Some coronae ceased activity by this time, while others continued until closer to the present, although showing evidence of waning activity. Coronae-associated volcanism dominated many coronae during this later stage. Convincing evidence of pre-regional plains corona- related volcanism was not found in the population examined here. We conclude that coronae formed in a two stage process; the first stage (tectonic phase) involved the annular warping of early extensive stratigraphic units of volcanic origin and the second (volcanic phase) involved coronae-related lava flow activity and local fracturing. For the vast majority of coronae, the first tectonic phase was largely complete prior to the emplacement of the regional plains (Pwr, plains with wrinkle ridges). The vast majority of corona-related volcanic activity (emplacement of Pl, lobate flows) occurred subsequent to the emplacement of regional plains. We found no evidence of coronae initiation in substantially later periods of the observed history of Venus. This revised version was published online in July 2006 with corrections to the Cover Date.     

The formation of Mercury's smooth plains

There has been extensive debate about whether Mercury's smooth plains are volcanic features or impact ejecta deposits. We present new indirect evidence which supports a volcanic origin for two different smooth plains units. In Borealis Planitia, stratigraphic relations indicate at least two distinct stages of smooth plains formation. At least one of these stages must have had a volcanic origin. In the Hilly and Lineated Terrain, Petrarch and several other anomalously shallow craters apparently have been volcanically filled. Areally extensive smooth plains volcanism evidently occurred at these two widely separated areas on Mercury. These results, combined with work by other researchers on the circum-Caloris plains and the Tolstoi basin, show that smooth plains volcanism was a global process on Mercury. Present data suggest to us that the smooth and intercrater plains may represent two distinct episodes of volcanic activity on Mercury and that smooth plains volcanism may have been triggered by the Caloris impact. High-resolution and multispectral imaging from a future Mercury spacecraft could resolve many of the present uncertainties in our understanding of plains formation on Mercury.     

Radar imagery of the southern Caloris region, Mercury

Radar imagery from July 2005 Arecibo observations has provided new information on surface relief over the southern portion of Caloris Basin and the smooth plains to the south of the basin. A lobe of smooth plains has been identified in the Mariner-unimaged region southwest of Mozart Crater that coincides precisely with topographically down-bowed terrain seen in earlier Arecibo radar altimetry. A 105-km-diameter crater has been found at 193.6° W, 25.6° N that appears to be the largest crater in the Caloris basin floor.     

Eminescu impact structure: Insight into the transition from complex crater to peak-ring basin on Mercury

Peak-ring basins represent an impact-crater morphology that is transitional between complex craters with central peaks and large multi-ring basins. Therefore, they can provide insight into the scale dependence of the impact process. Here the transition with increasing crater diameter from complex craters to peak-ring basins on Mercury is assessed through a detailed analysis of Eminescu, a geologically recent and well-preserved peak-ring basin. Eminescu has a diameter (∼125 km) close to the minimum for such crater forms and is thus representative of the transition. Impact crater size-frequency distributions and faint rays indicate that Eminescu is Kuiperian in age, geologically younger than most other basins on Mercury. Geologic mapping of basin interior units indicates a distinction between smooth plains and peak-ring units. Our mapping and crater retention ages favor plains formation by impact melt rather than post-impact volcanism, but a volcanic origin for the plains cannot be excluded if the time interval between basin formation and volcanic emplacement was less than the uncertainty in relative ages. The high-albedo peak ring of Eminescu is composed of bright crater-floor deposits (BCFDs, a distinct crustal unit seen elsewhere on Mercury) exposed by the impact. We use our observations to assess predictions of peak-ring formation models. We interpret the characteristics of Eminescu as consistent with basin formation models in which a melt cavity forms during the impact formation of craters at the transition to peak ring morphologies. We suggest that the smooth plains were emplaced via impact melt expulsion from the central melt cavity during uplift of a peak ring composed of BCFD-type material. In this scenario the ringed cluster of peaks resulted from the early development of the melt cavity, which modified the central uplift zone.     

Tectonic and stratigraphic implications of the relative ages of venusian plains and wrinkle ridges

A major ongoing controversy concerns the style of crustal evolution on Venus. At one extreme is a directional model that proposes a sequence of depositional and deformational events that occur at specific times in the evolution of the crust and that are global in extent. At the other extreme is a model that argues for different ages of these events in different places on the planet. A test of the directional model is here focused on whether wrinkle ridges formed at a single time in the recorded crustal history of Venus. Where sets of wrinkle ridges intersect it commonly is possible to determine that one set is older than the other. Also, the deformation responsible for wrinkle ridges is, in places, clearly progressive with respect to stratigraphic material units. These observations are not consistent with a specific single time for the formation of wrinkle ridges within the stratigraphic sequence. Within an area including about 1/3 of the surface of Venus 15% of craters that are younger than regional plains are older than wrinkle ridges, 85% are younger than wrinkle ridges. Taking 750 myr as a reasonable mean age for the regional plains, this implies that the mean age of wrinkle ridges is ∼110 myr younger than the mean age of plains. Solomon et al. (1999, Science 286, 87) propose that the emplacement of a large volume of plains lava would lead to a major atmospheric temperature increase. Their model predicts thermal stresses in the lithosphere that, at shallow depth, would reach peak compressive stresses in about 100 myr, a number very similar to the time lag between plains emplacement and wrinkle ridge formation indicated by the crater data. The thermal compressive stresses responsible for wrinkle ridges would be maintained at a level sufficient to deform basalt for at least 100 myr and possibly for as long as 350 myr. These time intervals are not really short compared to the mean age of the plains. Finally, because wrinkle ridges are demonstrably younger than the plains they deform, they cannot be related to the processes that formed the plains and thus should not be used to define a “plains with wrinkle ridges” unit.     

Spectrophotometry of Comet Austin (1982g) during post-perihelion period

Lunar crustal shortening does not seem to be restricted to the lava-filled basins alone; but there are some young scarp-like terra ridges in places around mare areas where they often continue other tectonic structures. This crustal shortening has not reached the same intensity as in the case of the lobate scarp overthrusts on Mercury. Young lunar terra ridges indicate that crustal shortening with an areal extent also took place slightly around mare basins. Thus they link tensional rille tectonics with compressional mare ridge tectonics and indicate that areal heating/bending/extension — cooling/ shortening/compression may describe an important explaining factor in lunar mare- and near-mare tectonics in addition to the volcanic extrusions.     

Tectonics of the Caloris area on Mercury: An alternative view

Both morphologic and geometric studies of the “lineated terrains” around Caloris provide evidence of several types of tectonic motions inside the ejecta blanket of the basin. These motions preferentially occurred along a preexisting pattern. In spite of several similarities to mare-filled multiring basins on the Moon, many geometric and chronologic differences suggest that the ridge pattern inside the Caloris basin may not be produced, as observed on the Moon, exclusively by subsidence of the inner basin under volcanic loading. A model of membrane stresses which yield a decrease of the radius of Caloris and the observed tectonics is proposed.     

Spectral emissivity measurements of Mercury's surface indicate Mg- and Ca-rich mineralogy, K-spar, Na-rich plagioclase, rutile, with possible perovskite, and garnet

Mid-infrared 2-D spectroscopic measurements from 8.0 to 12.7 μm of Mercury were taken using Boston University's Mid-Infrared Spectrometer and Imager (MIRSI) mounted on the NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii, 7-11 April 2006. Measurements reported here cover radar bright region C, a dark plains region west of Caloris Basin, and the interior of Caloris Basin. By use of spectral deconvolution with a large spectral library composed of many mineral compositions and grain size separates, we fitted, or “unmixed”, the Mercury spectra. We find mineral suites composed of magnesium-rich orthopyroxene and olivine, Ca-, Mg-, Na-rich clinopyroxene, potassium feldspar, and Na-bearing plagioclase feldspar. Both Ca- and Mg-rich garnet (pyrope and grossular, respectively) are apparently present in small amounts. Opaque minerals are required for spectral matching, with rutile (TiO₂) repeatedly providing the “best fit”. However, in the case of the radar bright region C, perovskite also contributed to a very good fit. Caloris Basin infill is rich in both potassium feldspar and Na-rich plagioclase. There is little or no olivine in the Caloris interior smooth plains. Together with the high alkali content, this indicates that resurfacing magmas were low to intermediate in SiO₂. Data suggest the dark plains exterior to Caloris are highly differentiated low-iron basaltic magmas resulting in material that might be classified as oligoclase basalts.