Geochemistry of tin in rivers and estuaries

On the basis of measurements from a large number of rivers from pristine and polluted regions, we estimate the riverine fluxes of tin to the oceans to be 0.76 × 10⁶molyr⁻¹ for the dissolved fraction and 300–600 × 10⁶ mol yr⁻¹ for the paniculate fraction. The paniculate flux agrees with the flux calculated from denudation rates. Estuaries were found not to have a large effect upon the transport of tin to the oceans. Evidence for the remobilization of tin was found in an estuary that is highly polluted with tin from mining and smelting activities. Monobutyltin was found to be present in polluted estuaries and is presumed to be a degradation product of tributyltin additives to antifouling paint.     

The aquatic chemistry of rare earth elements in rivers and estuaries

Laboratory experiments were carried out to determine how pH, colloids and salinity control the fractionation of rare earth elements (REEs) in river and estuarine waters. By using natural waters as the reaction media (river water from the Connecticut, Hudson and Mississippi Rivers) geochemical reactions can be studied in isolation from the large temporal and spatial variability inherent in river and estuarine chemistry. Experiments, field studies and chemical models form a consistent picture whereby REE fractionation is controlled by surface/solution reactions. The concentration and fractionation of REEs dissolved in river waters are highly pH dependent. Higher pH results in lower concentrations and more fractionated composition relative to the crustal abundance. With increasing pH the order of REE adsorption onto river particle surfaces is LREEs > MREEs > HREEs. With decreasing pH, REEs are released from surfaces in the same order. Within the dissolved (<0.22 µm) pool of river waters, Fe-organic colloids are major carriers of REEs. Filtration through filters and ultrafilters with progressively finer pore sizes results in filtrates which are lower in absolute concentrations and more fractionated. The order of fractionation with respect to shale, HREEs > MREEs > LREEs, is most pronounced in the solution pool, defined here as <5K and <50K ultrafiltrates. Colloidal particles have shale-like REE compositions and are highly LREE enriched relative to the REE composition of the dissolved and solution pools. The addition of sea water to river water causes the coagulation of colloidal REEs within the dissolved pool. Fractionation accompanies coagulation with the order of sea water-induced removal being LREEs > MREEs > HREEs. While the large scale removal of dissolved river REEs in estuaries is well established, the release of dissolved REEs off river particles is a less studied process. Laboratory experiments show that there is both release and fractionation of REEs when river particles are leached with seawater. The order of sea water-induced release of dissolved REE(III) (LREEs > MREEs > HREEs) from Connecticut River particles is the same as that associated with lowering the pH and the same as that associated with colloidal particles. River waters, stripped of their colloidal particles by coagulation in estuaries, have highly evolved REE composition. That is, the solution pool of REEs in river waters are strongly HREE-enriched and are fractionated to the same extent as that of Atlantic surface seawater. This strengthens the conclusions of previous studies that the evolved REE composition of sea water is coupled to chemical weathering on the continents and reactions in estuaries. Moreover, the release of dissolved Nd from river particles to sea water may help to reconcile the incompatibility between the long oceanic residence times of Nd (7100 yr) and the inter-ocean variations of the Nd isotopic composition of sea water. Using new data on dissolved and particle phases of the Amazon and Mississippi Rivers, a comparison of field and laboratory experiments highlights key features of REE fractionation in major river systems. The dissolved pool of both rivers is highly fractionated (HREE enriched) with respect to the REE composition of their suspended particles. In addition, the dissolved pool of the Mississippi River has a large negative Ce-anomaly suggesting in-situ oxidation of Ce(III). One intriguing feature is the well developed maximum in the middle REE sector of the shale normalized patterns for the dissolved pool of Amazon River water. This feature might reflect competition between surface adsorption and solution complexation with carbonate and phosphate anions.     

Variation in surface turbulence and the gas transfer velocity over a tidal cycle in a macro-tidal estuary

The gradient flux technique, which measures the gas transfer velocity (k), and new observational techniques that probe turbulence in the aqueous surface boundary layers were conducted over a tidal cycle in the Plum Island Sound, Massachusetts. Efforts were aimed at testing new methods in an estuarine system and to determine if turbulence created by tidal velocity can be responsible for the short-term variability ink. Measurements were made during a low wind day, at a site with tidal excursions of 2.7 m and a range in tidal velocity of nearly 1 m s⁻¹. Estimates ofk using the gradient flux technique were made simultaneously with the Controlled Flux Technique (CFT), infrared imagery, and high-resolution turbulence measurements, which measure the surface renewal rate, turbulent scales, and the turbulent dissipation rate, respectively. All measurements were conducted from a small mobile catamaran that minimizes air- and water-side flow distortions. Infrared imagery showed considerable variability in the turbulent scales that affect air-water gas exchange. These measurements were consistent with variation in the surface renewal rate (range 0.02 to 2 s⁻¹), the turbulent dissipation rate (range 10⁻⁷ to 10⁻⁵ W kg⁻¹), andk (range 2.2 to 12.0 cm hr⁻¹). During this low wind day, all variables were shown to correlate with tidal speed. Taken collectively our results indicate the promise of these methods for determining short-term variability in gas transfer and near surface turbulence in estuaries and demonstrate that turbulent transport associated with tidal velocity is a potentially important factor with respect to gas exchange in coastal systems.     

河流中潜流交换研究进展

河水和地下水交换——潜流交换对溶质和污染物的归宿起着重要作用。潜流交换机理主要包括泵吸交换和冲淤交换。泵吸交换是由于河床形态引起的水头梯度,这些水头梯度诱导了对流传输;冲淤交换发生是由于移动河床截留和释放孔隙水。潜流交换的主要影响因素包括:河道流量、河床水力传导性、河床形态、河道弯曲、河床不均匀和背景条件。还探讨了反应性溶质、胶体颗粒共存情况下潜流交换的规律。对潜流交换研究现存的主要问题及未来研究展望提出了看法。     

Speciation of dissolved selenium in the Kaoping and Erhjen rivers and estuaries,southwestern Taiwan

Analytical methods of dissolved Se species in river water and seawater were established and applied to study dissolved Se speciation in the Kaoping and Erhjen rivers and estuaries, southwestern Taiwan. The Kaoping and Erhjen rivers and estuaries were respectively in relatively oxygenated and oxygen-deficient conditions as revealed from the distributions of dissolved oxygen, DOC, nutrients, and dissolved Mn. Concentrations of dissolved total Se increased downstream in the riverine sections, ranging from 0.6 nM to 1.2 nM for the Kaoping River and from 0.8 nM to 1.05 nM for the Erhjen River. The dissolved total Se was only slightly higher in the Erhjen middle estuary than in the Kaoping middle estuary in spite of heavier pollution in the former. The dissolved total Se behaved rather conservatively in the Kaoping estuary but nonconservatively in the Erhjen estuary resulting from anthropogenic inputs, and in this respect showed similarities with the behavior of redox-sensitive Mn. The predominant species of selenium were Se(VI) and organic Se in the Kaoping River and Se(VI) in the Kaoping estuary. The elevated concentration of Se(VI) in the Kaoping estuary may stem from the degradation of organic Se and oxidation of Se(IV). On the other hand, Se(IV) and organic Se were equally dominant in the Erhjen River, and Se(IV) was predominant through most of the Erhjen estuary. The elevated distribution of Se(IV) in the Erhjen middle estuary may result mostly from partial decomposition of organic Se, but further oxidation of Se(IV) was inhibited in reducing waters. However, Se(VI) became dominant at Erhjen outer estuary where water was oxygenated by the replacement of intruded coastal seawater. Apparently, the speciation of dissolved Se was mainly controlled by the biological and redox processes in the Kaoping and Erhjen rivers and estuaries.     

Uranium isotopes in rivers,estuaries and adjacent coastal sediments of western India: their weathering,transport and oceanic budget

The two major river systems on the west coast of India, Narbada and Tapti, their estuaries and the coastal Arabian sea sediments have been extensively studied for their uranium concentrations and ${}^{238}\text{U}{}^{238}\text{U}$ activity ratios.The ²³⁸U concentrations in the aqueous phase of these river systems exhibit a strong positive correlation with the sum of the major cations, σ Na + K + Mg + Ca, and with the HCO₃^? ion contents. The abundance ratio of dissolved U to the sum of the major cations in these waters is similar to their ratio in typical crustal rocks. These findings lead us to conclude that ²³⁸U is brought into the aqueous phase along with major cations and bicarbonate. The strong positive correlation between ²³⁸U and total dissolved salts for selected rivers of the world yield an annual dissolved ²³⁸U flux of 0.88 × 10¹⁰g/yr to the oceans, a value very similar to its removal rate from the oceans, 1.05 × 10¹⁰g/yr, estimated based on its correlation with HCO₃^? contents of rivers.In the estuaries, both ²³⁸U and its great-grand daughter ²³⁴U behave conservatively beyond chlorosities 0.14 g/l. These data confirm our earlier findings in other Indian estuaries. The behavior of uranium isotopes in the chlorosity zone 0.02–0.14 g/l, was studied in the Narbada estuary in some detail. The results, though not conclusive, seem to indicate a minor removal of these isotopes in this region. Reexamination of the results for the Gironde and Zaire estuaries (Martin et al., 1978a and b) also appear to confirm the conservative behavior of U isotopes in unpolluted estuaries. It is borne out from all the available data that estuaries beyond 0.14 g/l chlorosities act neither as a sink nor as a source for uranium isotopes, the behavior in the low chlorosity zones warrants further detailed investigation.A review of the uranium isotope measurements in river waters yield a discharge weighted-average ²³⁸U concentration of 0.22 μg/l with a ${}^{234}\text{U}{}^{238}\text{U}$ activity ratio of 1.20 ± 0.06ismissing. The residence time of uranium isotopes in the oceans estimated from the ²³⁸U concentration and the ${}^{234}\text{U}{}^{238}\text{U}$ A. R. of the rivers yield conflicting results; the material balance of uranium isotopes in the marine environment still remains a paradox. If the disparity between the results is real, then an additional ²³⁴U flux of about 0.25 dpm/cm₂·10³ yr into the oceans (about 20% of its river supply) is necessitated.     

Gas holdup and single bubble velocity profile

Single bubble velocity profile (velocity vs. distance) has been measured for a 1.45 mm diameter bubble to try to explain reported differences in gas holdup in two systems: F150 vs. 1-pentanol, and MIBC vs. NaCl. It was found that in F150 the bubble slowed rapidly to reach the terminal velocity stage of the profile while in 1-pentanol the bubble remained in the deceleration stage and was consequently moving faster, at almost twice the speed. The lower rise velocity in F150 means longer bubble residence time and corresponding higher gas holdup than with 1-pentanol, as reported. In the second system, the bubble in MIBC reached terminal velocity more rapidly than in NaCl which agrees with the reported higher gas holdup in MIBC compared to NaCl. An implication for gas holdup evaluation is that the value may depend on the part of the velocity profile over which it is measured. Possible exploitation of this reagent effect on bubble rise velocity in flotation is considered.     

Control of phytoplankton biomass in estuaries: A comparative analysis of microtidal and macrotidal estuaries

Macrotidal estuaries (mean tidal range >2m) generally exhibit a tolerance to pollution with nitrogen-containing nutrients despite high loadings originating from freshwater outflows. These systems, which are characterized by high tidal energy, generally exhibit lower levels of chlorophylla than systems with lower tidal energy. A comparative analysis of data from 40 microtidal and macrotidal estuaries shows that mean annual chlorophylla levels are significantly lower in systems with high tidal energy even when nitrogen concentrations are equal to nitrogen levels in the microtidal systems. Tidal range and associated processes (e.g., tidal mixing, current velocity, light penetration, and sediment resuspension) influence phytoplankton biomass in some estuaries.     

河道潜流交换水动力过程现场监测研究进展

河道潜流带是河水与地下水交互作用的关键过渡区,具有高度的动态性和敏感性,频繁的水力交换易引发其内部的生物地球化学反应,并对河流生态安全产生重要影响。为提高河道潜流交换水动力监测结果的真实性和有效性,介绍渗流、水压、溶质、温度等监测方法及其适用性,归纳河床和河岸的监测点布设参数和不同监测手段的数据采集频率,系统总结河段、河床及河岸的潜流交换理论与计算方法,探讨导致潜流监测结果不确定的因素。针对现有监测方法的不足和未来研究的发展方向,提出今后需加强多方法联合监测和多技术集成的应用,开展河岸侧向潜流监测及不确定性分析等工作,为潜流带水文-生物地球化学过程耦合机制研究提供可靠数据。     

Variability of the gas transfer velocity of CO<Subscript>2</Subscript> in a macrotidal estuary (the Scheldt)

We report a large set of 295 interfacial carbon dioxide (CO₂) flux measurements obtained in the Scheldt estuary in November 2002 and April 2003, using the floating chamber method. From concomitant measurements of the air-water CO₂ gradient, we computed the gas transfer velocity of CO₂. The gas transfer velocity is well correlated to wind speed and a simple linear regression function gives the most consistent fit to the data. Based on water current measurements, we estimated the contribution of water current induced turbulence to the gas transfer velocity, using the conceptual relationship of O'Connor and Dobbins (1958). This allowed us to construct an empirical relationship to compute the gas transfer velocity of CO₂ that accounts for the contribution of wind and water current. Based on this relationship, the spatial and temporal variability of the gas transfer velocity in the Scheldt estuary was investigated. Water currents contribute significantly to the gas transfer velocity, but the spatial and temporal variability (from daily to seasonal scales) is mainly related to wind speed variability.     

Surface fronts in estuaries: A review

Recent advances in the understanding of the physics of estuarine fronts (small-scale regions of significant changes in hydrographic variables) are reviewed. These fronts may be classified in three groups—tidal mixing fronts, plume fronts, and shear fronts—on the basis of the mechanism dominating the local rate of change in the horizontal density gradient. These classes are not independent, however, since it appears that both tidal mixing fronts and shear fronts can produce buoyancy-driven flow structures that propagate away from the generation region as plume fronts. Field observations of typical examples of each class are presented and laboratory experiments and theoretical models which isolate the important physical processes are summarized. Some important unresolved questions are identified and suggestions for further research are offered.     

Magnitude and frequency in proglacial rivers: a geomorphological and sedimentological perspective

Proglacial fluvial sedimentary systems receive water from a variety of sources and have variable discharges with a range of magnitudes and frequencies. Little attention has been paid to how these various magnitude and frequency regimes interact to produce a distinctive sedimentary record in modern and ancient proglacial environments. This paper reviews the concept of magnitude and frequency in relation to proglacial fluvial systems from a geomorphic and sedimentary perspective rather than a hydrological or statistical perspective. The nature of the meltwater inputs can be characterised as low-magnitude–high-frequency, primarily controlled by ablation inputs from the source glacier, or high-magnitude–low-frequency, primarily controlled by ‘exceptional’ inputs. The most important high-magnitude–low-frequency inputs are catastrophic outburst floods, often referred to by the term jökulhlaup (Icelandic for glacier-burst). Glacier surges are an additional form of cyclical variation impacting the proglacial environment, which briefly alter the volumes and patterns of meltwater input. The sedimentary consequences of low-magnitude–high-frequency discharges are related to frequent variations in stage, the greater directional variability that sediment will record, and the increased significance of channel confluence sedimentation. In contrast, the most significant characteristics of high-magnitude–low-frequency flooding include the presence of large flood bars and mid-channel ‘jökulhlaup’ bars, hyperconcentrated flows, large gravel dunes, and the formation of ice-block kettle hole structures and rip-up clasts. Glacier surges result in a redistribution of low-magnitude–high-frequency processes and products across the glacier margin, and small floods may occur at the surge termination. Criteria for distinguishing magnitude and frequency regimes in the proglacial environment are identified based on these major characteristics. Studies of Quaternary proglacial fluvial sediments are used to determine how the interaction of the various magnitude and frequency regimes might produce a distinctive sedimentary record. Consideration of sandur architecture and stratigraphy shows that the main controls on the sedimentary record of proglacial regions are the discharge magnitude and frequency regime, sediment supply, the pattern of glacier advance or retreat, and proglacial topography. A model of sandur development is suggested, which shows how discharge magnitude and frequency, in combination with sandur incision and aggradation (controlled by glacier advance and retreat) can control sandur stratigraphy.     

Iron colloids/organic matter associated transport of major and trace elements in small boreal rivers and their estuaries (NW Russia)

The chemical status of major and trace elements (TE) in various boreal small rivers and watershed has been investigated along a 1500-km transect of NW Russia. Samples were filtered in the field through a progressively decreasing pore size (5, 0.8 and 0.22 μm; 100, 10, and 1 kD) using a frontal filtration technique. All major and trace elements and organic carbon (OC) were measured in filtrates and ultrafiltrates. Most rivers exhibit high concentration of dissolved iron (0.2–4 mg/l), OC (10–30 mg/l) and significant amounts of trace elements usually considered as immobile in weathering processes (Ti, Zr, Th, Al, Ga, Y, REE, V, Pb). In (ultra)filtrates, Fe and OC are poorly correlated: iron concentration gradually decreases upon filtration from 5 μm to 1 kD whereas the major part of OC is concentrated in the <1–10 kD fraction. This reveals the presence of two pools of colloids composed of organic-rich and Fe-rich particles. According to their behavior during filtration and association with these two types of colloids, three groups of elements can be distinguished: (i) species that are not affected by ultrafiltration and are present in the form of true dissolved inorganic species (Ca, Mg, Li, Na, K, Sr, Ba, Rb, Cs, Si, B, As, Sb, Mo) or weak organic complexes (Ca, Mg, Sr, Ba), (ii) elements present in the fraction smaller than 1–10 kD prone to form inorganic or organic complexes (Mn, Co, Ni, Zn, Cu, Cd, and, for some rivers, Pb, Cr, Y, HREE, U), and (iii) elements strongly associated with colloidal iron in all ultrafiltrates (P, Al, Ga, REE, Pb, V, Cr, W, Ti, Ge, Zr, Th, U). Based on size fractionation results and taking into account the nominal pore size for membranes, an estimation of the effective surface area of Fe colloids was performed. Although the total amount of available surface sites on iron colloids (i.e., 1–10 μM) is enough to accommodate the nanomolar concentrations of dissolved trace elements, very poor correlation between TE and surface sites concentrations was observed in filtrates and ultrafiltrates. This strongly suggests a preferential transport of TE as coprecipitates with iron oxy(hydr)oxides. These colloids can be formed on redox boundaries by precipitation of Fe(III) from inflowing Fe(II)/TE-rich anoxic ground waters when they meet well-oxygenated surface waters. Dissolved organic matter stabilizes these colloids and prevents their aggregation and coagulation. Estuarine behavior of several trace elements was studied for two small iron- and organic-rich rivers. While Si, Sr, Ba, Rb, and Cs show a clear conservative behavior during mixing of freshwaters with the White sea, Al, Pb and REE are scavenged with iron during coagulation of Fe hydroxide colloids.     

Behavioral of sediment transport at lowland and mountainous rivers: a special reference to selected Malaysian rivers

Mountain rivers and lowland rivers differ in many ways. Some of the many elements that distinguish both river systems apart are the rivers’ geomorphological appearances, hydraulic geometry, pollution transport, sediment transport, and its own roughness and coarseness. In this particular study, the element of sediment transport is given distinctive attention too. This study employs the deterministic approach for bed load prediction entailing the use of the parameterization concept where particle size and flow variation is taken into full consideration. Apart from that, the classical approach of Shields number is also used to determine the transport rates at the fluvial system. However, due to some limitation and range of applicability, the Shields number approach was re-modified to suit the range of applicability. Changes were made to the alleviating critical stress term and formulating exponential approach. For this research, it was important to deduce the underlying principles which are universal and common to all river systems, due to obvious and distinct differences between the mountain and lowland rivers. A special attribute was given to the Malaysian natural rivers because of the limited recorded data available. All datasets were compiled and tested with the bed load predictors to observe the commonality pattern between the lowland and mountain river systems. Most of the bed load transport equations limit the range of applicability by isolating the flow regime or bed roughness individually. Thus, it was vital for researchers to find the commonality pattern between these two river systems which needed to be statistically sound in its form. It was postulated that the particle densimetric Froude number is graphically and statistically fit for both river systems. Hence, this predictor is used as it has a high potential to be included in the sediment transport parameterization for Malaysian natural rivers.     

Pool-fills: a window to palaeoflood history and response in bedrock-confined rivers

Channel‐scale sedimentary units associated with bedrock‐controlled riffle‐pool morphology are examined in detail along Sandy Creek gorge, an ephemeral stream in arid south‐eastern central Australia. Pool‐fills comprise cut‐and‐fill assemblages of poorly sorted sediments ranging in texture from muds to boulders. Five unit types are defined based on particle size, sedimentary structures, geometry and bounding surface character: (1) coarse‐grained bar platform; (2) fine‐grained bar supraplatform; (3) fine‐grained pool‐fill; (4) fine‐grained bench; and (5) modern pool‐fill. The last coarse‐grained unit currently lining the pools suggests an altered sedimentation style over the post‐settlement period (post‐ad 1860s). Situated at bedrock valley constrictions, pool‐fills are compared with other sedimentary units associated with recirculating currents: eddy bars and slackwater deposits. But only the fine‐grained bench units reflect eddy recirculation; the pool‐fills are principally forced‐bars associated with bedrock‐controlled or ‘forced’ riffle‐pool morphology. A late Holocene palaeoflood history is proposed based on radiocarbon ages from the pool‐fills: multiple phases of cut‐and‐fill activity were preceded by a superflood 3400–1900 years ago that eroded the pool‐fills to bedrock. The resilience of the pool‐fills was illustrated by the passage of a 1‐in‐100‐year flood in 1992, which caused only minor erosion. The presence of pool‐fills may provide a window to past phases of river activity that cannot be extracted from either historical records/observations or palaeoflood slackwater sediment analyses. The formation and sedimentary preservation potential of these landforms reflect a combination of hydraulic and structural influences, but the occurrence of high‐magnitude floods exerts the dominant control.     

Aquaculture in estuaries: Feast or famine?

Living resources in estuarine systems have been so intensively harvested that many fisheries are severely depleted at a time when demand for these resources is rising. In addition, multiple use demands on estuaries often conflict, leaving unresolved management questions. With the movement of the population to the coastal regions, conflicts among uses and users of estuarine resources are increasing. Aquaculture offers one means to reconcile the conflicting demands for use of the estuarine resource. Yet, the nation has few, if any new policy or management approaches to address these conflicts. Management on the level of the watershed is one effective tool that should be more effectively used. Involvement of the full range of stakeholders or user groups in policy setting and management options has brought remarkable success in a small number of cases where this approach has been used. The nation will need to develop other tools and approaches if estuaries are to be restored and protected as protected as planned in federal, regional, and state laws and initiatives.     

Hypoxia and salinity in Virginia estuaries

Hypoxia, periods of reduced dissolved oxygen concentrations, has been observed not only in the Chesapeake Bay but also in the deeper waters of the Virginia estuaries that are tributaries to the Chesapeake Bay. When water temperature exceeded 20°C, minimum oxygen concentrations were observed to be <50% of saturation concentrations in 75%, 50% and 2% of the surveys in the estuaries of the Rappahannock, York and James rivers, respectively. The observation that hypoxia rarely occurred in the James River is surprising, given the fact that it receives the greatest amount of wastewater. Analysis of the oxygen budgets in these estuaries indicates that the variations in the frequency, duration, and severity of hypoxia are related to the net movement of bottom waters. This relationship has significant implications for the management of water quality and marine fisheries.     

Water quality variation and clam growth: Is pH really a non-issue in estuaries?

A tandem deployment system was used to critically evaluate relationships between important water chemistry parameters (pH, salinity, dissolved oxygen) and biotic performance based on clam growth. The effects of environmental conditions on growth of juvenile clams,Mercenaria mercenaria, were determined after 7-day field deployments in cages at reference sites from 1998 to 2000. Continuous measurements of the overlying water chemistry parameters were monitored by deploying an in situ water quality instrument (Hydrolab Datasonde) at the same time. While salinity was identified as an important determinant of clam growth over wide salinity ranges (10–35‰), pH was also found to be a very important parameter, especially in low-salinity regimes (<25‰). Average pH measurements ranged from 7.2 to 7.8; minimal pHs ranged from 6.9 to 7.6. The results indicated that when average pH levels fell below 7.5 or minimum pH levels fell below 7.2, growth rates were <50% that of clams deployed under higher pH conditions. Estuarine systems are generally perceived as being well-buffered so pH is frequently assumed to be unimportant, but our results suggest that pH levels can decline in estuarine systems to levels that can adversely affect biological responses. The potential impacts on biological resources of even moderate decreases in pH, particularly in systems that naturally tend to have lower pH conditions, may be more important than previously realized.     

Particle trapping in stratified estuaries: Application to observations

Estuarine turbidity maxima (ETM) retain suspended particulate matter (SPM) through advection, settling, aggregation, and nonlinearities in bed processes, but the relative importance of these processes varies strongly between systems. Observations from two strongly advective systems (the Columbia and Fraser Rivers) are used to investigate seasonal cycles of SPM retention and the effects of very high flows. Results for the Fraser and Columbia plus literature values for 13 other estuaries illustrate the applicability of scaling parameters and the response of ETM phenomena to a range of river flow (U _r ) levels and tidal forcing. The most efficient trapping (represented by Trapping EfficiencyE, the ratio of maximum ETM concentration to the source SPM concentration) occurs for low ratios of river flow to tidal current amplitude (U_T), represented by low values of the Supply number S_r.E in the Columbia is found to be maximal in a null zone where advection or tidal asymmetry (represented by Advection numberA) is weak(A ∼ 0). The ratio of aggregation to disaggregation (the Floc number Θ) is maximal on neap tides, while the ratio of erosion to deposition (the Erosion number P) is maximal on spring tides. The ratio of settling velocity to vertical mixing (Rouse numberP) is relatively constant in the Columbia ETM(P ∼ 0.7), because particle settling velocity and turbulence levels adjust together. Assuming that this result applies broadly, scaling variables and data are combined to express ETM properties in terms of the friction velocity (U_*),U _r , andU _T , allowing a considerable simplification of the parameters used to describe ETM.     

Estuary-specific variation in the air-water gas exchange coefficient for oxygen

Oxygen air-water gas exchange was measured using floating chambers in two shallow tidal estuaries of differing bathymetry and local terrain, near Waquoit Bay, Massachusetts (United States). The specific chamber design permitted measurements of gas flux in 15 min, allowing analysis of the relationship with wind speed and tidal stage. Exchange coefficients ranged from 0.5 to 2.5 g O₂·m^?2 h^?1 atm^?1 (equivalent to piston velocities of 1.5 to 7 cm h^?1) for wind speeds of 0.3 to 9 m s^?1 at 10 m elevation. While the relationships for each estuary appear linear (significant linear regressions with wind speed were shown for each estuary, and the slopes were different at the 99.5% confidence level), the range of speeds differed at the two sites and an exponential function of wind speed was consistent with the combined data from both estuaries. A power function of wind speed was not an acceptable model. The exchange coefficients for our estuaries are from 57% to as low as 9% of that predicted by previously published generic equations. Because the atmospheric correction can be significant in shallow, metabolically active coastal waters, we suggest that empirically determined relationships for gas exchange versus wind for a specific estuary are preferable to the predictions of the general equations. While the floating chamber method should be used cautiously, at low winds speeds (below 8 m s^?1) and in slowly flowing waters, it provides a convenient approach for quantifying these site-specific differences. The differences, especially those between shallow sheltered systems and the open waters best fit by some published relationships, are ecologically important and do not appear yet to be measurable by other methods.