中国主要斑岩钨矿床特征

根据我国主要斑岩型钨矿床地质地球化学资料,斑岩钨矿床产布在特定板块构造位置,受中生代区域深(大)断裂的控制,其成矿与燕山中晚期花岗闪长斑岩、花岗斑岩、石英斑岩和二长花岗斑岩体有关,总结综合了我国斑岩钨矿床成矿特征和成矿模式。 斑岩钨矿床常与斑岩型和其他型钼、铜、锡矿床产于同一成矿区带;成矿具有深源岩浆热液成矿和深源岩浆热液一表生改造成矿系列;斑岩钨矿床成矿于斑岩体内外接触带,而以内带为主;矿体形态有板状、脉状、似层状和岩钟状,矿化类型常见为钨型和钨钼型,矿物简单;矿化-蚀变具有分带特征。     

西藏羌堆斑岩-夕卡岩复合型铜矿地质特征及找矿前景

羌堆铜矿位于冈底斯斑岩型铜(钼)成矿带中东段的拉抗俄-吹败子铜(钼)矿集区内,是斑岩-夕卡岩复合型矿床,含矿斑岩体为花岗斑岩及石英斑岩,具全岩矿化特征,斑岩体与白垩系门中组灰岩的接触带形成夕卡岩型矿床.研究表明,地表和浅部出露的含矿斑岩体只是其岩枝,矿床剥蚀程度低,主斑岩体尚未出露,深部找矿潜力巨大.     

西藏羌堆斑岩-夕卡岩复合型铜矿地质特征及找矿前景

羌堆铜矿位于冈底斯斑岩型铜（钼）成矿带中东段的拉抗俄-吹败子铜（钼）矿集区内，是斑岩-夕卡岩复合型矿床，含矿斑岩体为花岗斑岩及石英斑岩，具全岩矿化特征，斑岩体与白垩系门中组灰岩的接触带形成夕卡岩型矿床。研究表明，地表和浅部出露的含矿斑岩体只是其岩枝，矿床剥蚀程度低，主斑岩体尚未出露，深部找矿潜力巨大。     

滇西北红山晚白垩世花岗斑岩型Cu-Mo成矿系统及其大地构造学意义

红山铜多金属矿床位于滇西北中甸红山一带,其一直被认为是印支期夕卡岩型矿床。新的研究结果表明红山矿区存在两个成矿系统:1与印支期石英二长斑岩有关的夕卡岩型铜多金属成矿系统,其典型矿床是与石榴子石夕卡岩伴生的含铜磁铁矿体与磁黄铁矿体;2与花岗斑岩有关的斑岩型Cu-Mo-Pb-Zn成矿系统,其包括地表喷溢沉积成因的含铁钙硅质岩、可能为流体通道相的Cu-Mo多金属石英网脉与大脉、充填于岩溶洞穴中的层状Pb-Zn矿体、花岗斑岩内部的浸染状Cu-Mo矿化、及岩体外接触带夕卡岩型多金属矿床。含矿石英脉6个辉钼矿样品Re-Os模式年龄介于75.46~78.46Ma之间,等时线年龄为77Ma,红山矿区花岗斑岩型Cu-Mo矿床形成时代为晚白垩世。红山矿区晚白垩世花岗斑岩及其伴生斑岩型Cu-Mo矿床和大规模流体活动是滇西地区晚白垩世区域构造-流体-成矿体系的一部分,其形成与印度—亚洲大陆碰撞有关,据此可推断印度—亚洲大陆的碰撞作用及其伴生的大规模成矿作用在77Ma就已开始。红山矿区晚白垩世斑岩型Cu-Mo矿床成矿系统的厘定对于斑岩型矿床成矿流体结构模型和区域成矿与构造学的研究具重要的启示意义。     

江西会昌锡坑迳斑岩型锡矿床成矿系统发育特征与找矿模型

锡坑迳矿田位于南岭成矿带东段与武夷山成矿带交会部位,以早白垩世连续的岩浆喷发-侵入活动与多类型锡多金属成矿作用为特色。矿田内围绕似斑状花岗岩和花岗斑岩发育了岩背斑岩型、淘锡坝和矿背隐爆层间裂隙带型、苦竹岽和凤凰岽云英岩-破碎带蚀变岩型等大中型锡矿床。这些矿床的矿化-蚀变特征可与玻利维亚锡矿带、银岩、维拉斯托和洋滨等国内外斑岩型锡矿床类比,又独具特色,是研究斑岩型锡成矿系统发育特征与找矿模型的理想区域。文章在详细的野外地质调查基础上,系统总结了锡坑迳矿田内各类锡多金属矿化组合特征和蚀变结构,并对岩背矿床和淘锡坝矿床锡石开展了电子探针和LA-ICP-MS原位微区分析。研究结果显示,所有锡石样品均具有La、Pr、Gd和Tb的正异常、Ce与Eu的负异常、明显的Zr/Hf分馏和不规则的稀土元素配分模式,指示成矿热液早期阶段及锡石沉淀阶段经历了流体不相容。岩背锡石较淘锡坝锡石具有高的Ti/Zr和Ti/Sc比值,指示其更为靠近矿化中心。笔者研究认为,锡坑迳斑岩型锡成矿系统矿化类型包括细脉状、浸染状和细网脉状,围岩蚀变由早到晚、由成矿中心向外依次发育黄玉石英带、绿泥石-黄玉石英岩化带、绿泥石-绢云母化带和黏土化-碳酸盐化带。与斑岩型铜钼成矿系统相比,其成矿岩浆岩不仅有花岗斑岩,还有似斑状黑云母花岗岩,矿体在斑岩、花岗岩及上覆火山岩中均有赋存。相较于玻利维亚斑岩型锡成矿带发育的大面积石英-电气石化,锡坑迳斑岩成矿系统更富F,蚀变矿物中出现了大量黄玉、萤石和白云母等。对比国内外典型锡矿床的矿化-蚀变结构和锡石矿物学特征,文章建立了锡坑迳式斑岩型锡成矿系统的找矿模型。     

初论广西大瑶山地区多期次花岗质岩浆活动与成矿系列

广西大瑶山地区位于钦杭成矿带西南端,以盛产石英脉型金矿闻名,近年来又新发现了一批与花岗岩类有关的斑岩型钨钼铜金矿床,显示良好的找矿前景。在总结矿床地质特征和相关岩浆岩的基础上,结合高精度成岩成矿年龄数据,将大瑶山地区花岗质岩浆岩划分为加里东期(430~470 Ma)、海西—印支期(240~270 Ma)、燕山早期(150~170 Ma)和燕山晚期(90~110 Ma)等4期,并将与花岗岩类有关的矿床划分为加里东期(430~440 Ma)斑岩-夕卡岩-石英脉型钨钼成矿系列、燕山早期(145~155 Ma)斑岩型铜钼(金)成矿系列和燕山晚期(90~110 Ma)斑岩型-蚀变破碎带型钼金银铜铅锌成矿系列等3个成矿系列。提出大瑶山地区加里东期岩浆活动的强度、范围和成矿作用可与燕山期的媲美,具有巨大的找矿潜力,是今后大瑶山地区寻找夕卡岩-斑岩型钨钼铜矿床的主攻方向之一。     

老挝川圹省PhuKham铜金矿床地质特征及找矿方向

老挝Phu Kham铜金矿为大型斑岩-夕卡岩型铜金矿床,地处老挝川圹省西南部。通过野外地质调查和室内工作,研究了Phu Kham铜金矿床形成的地质背景、矿床地质特征、成矿时代、找矿模式及成因类型。结果表明:铜金矿容矿岩系为石炭-二叠系碳酸盐岩、火山碎屑岩、夕卡岩及斑岩脉;矿石矿物主要为黄铁矿、黄铜矿、蓝铜矿、斑铜矿及孔雀石等;矿床成因为斑岩-夕卡岩型,成矿时代为晚石炭世—早二叠世。预测在Phu Kham矿区及长山成矿带内具有寻找大型-超大型铜金铁锡矿床的潜力。     

云南省马关县都龙花石头矿区钨锡矿化特征与成矿远景

滇东南老君山成矿区是滇东南—桂西锡多金属成矿带的重要组成部分之一。花石头位于老君山花岗岩体西南侧,老君山燕山两期花岗岩均有出露,锡钨石英脉型矿床(点)众多,但相关地质研究程度较低。该区矿化类型包括蚀变花岗岩型钨锡矿化、接触蚀变带铜钨锡矿化、强硅化带中铜铅锌多金属矿化等。围岩蚀变以云英岩化为主,其次包括硅化、钾长石-高岭土化和黄铁矿化等。结合近期地质勘探所揭露的新信息,本文对该区锡钨成矿地质特征进行了初步总结,提出该区钨锡成矿作用与燕山晚期老君山中酸性岩浆侵入活动(以第2期为主)密切,属于岩浆期后热液充填交代形成的锡钨石英脉型矿床。燕山晚期中酸性岩体,特别是第2期中细粒二云二长花岗岩对成矿作用是主要的控矿因素。其中,2期岩体接触带、岩体与围岩内外接触带是有利成矿部位。在此基础上,建立了花石头矿区钨锡岩浆期后热液成矿模式。     

西藏玉龙铜矿床成矿斑岩的厘定及地质意义

位于青藏高原东缘的玉龙铜矿是我国最大的斑岩铜矿之一,其形成一致认为与矿区中心产出的二长花岗质复式斑岩体有关,但成矿与复式岩体的确切关系并不清楚。本文通过详细的野外地质填图,特别是矿床8号勘探线12个钻孔的重新编录,在复式岩体中识别出一套花岗斑岩岩枝,岩枝中不规则状石英-钾长石脉广泛发育,同时还见有单向固结结构、粗晶及细晶结构,这些特征表明该岩浆中的流体曾经发生过饱和。同时结合矿床高品位(0.6%,质量分数)铜矿化紧密围绕花岗斑岩分布、含矿脉体自花岗斑岩向外围逐渐由高温石英-钾长石A脉过渡为中低温石英-硫化物脉、热液蚀变自花岗斑岩向外由高温钾硅酸盐化过渡为中低温石英-绢云母化的规律,最终确定这套花岗斑岩为玉龙矿床的成矿斑岩。玉龙铜矿成矿斑岩的厘定,较好地解释了矿床矿化类型及金属的分布规律,为进一步深入理解矿床形成过程提供了帮助。     

陕西柞水-山阳矿集区冷水沟铜钼矿床成矿特征及成矿机制探讨

柞水_山阳矿集区内矿产多种多样,构造_岩浆_成矿作用明显,斑岩_矽卡岩型铜矿床成矿条件良好,尤其是冷水沟地区岩浆活动频繁,燕山期花岗斑岩体与成矿作用关系密切。从冷水沟斑岩体到外围表现为斑岩型铜钼矿床(洞子沟和孔雀垭地段)、矽卡岩型铜矿床(双龙寨和银洞垭地段)、构造蚀变岩型金银矿床(南沟和徐家湾地段),构成了完整的斑岩成矿体系。岩体蚀变强烈,其中绢英岩化和矽卡岩化与成矿关系最密切。根据脉体穿插关系,可将成矿期分为4个成矿阶段,铜钼矿床主要形成于热液早_中期。斑岩体显示高钾钙碱性地球化学特征,属I型或I→A过渡型,形成环境属燕山期陆内碰撞后伸展环境。文章综合研究了矿化特征、流体包裹体、成矿物理化学条件、岩体特征及成矿机制,建立了冷水沟铜钼矿床的成矿模型,并总结了找矿标志。下一步找矿工作的重点应放在对构造_岩浆_热液成矿作用的研究,加强对岩体和矿体深部的控制。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).