南秦岭Pb,Zn,Ag,Cu,Hg,Sb,菱铁矿成矿系列

以泥盆系占优势的南秦岭成矿带中存在有重要的Ｐｂ－Ｚｎ－Ａｇ，Ａｕ，Ｈｇ－Ｓｂ及Ｃｕ矿床。它们形成中晚古生带扬子地块北部被动大陆边缘的沉积盆地演化与造山期中，成矿系列显示出时间与空间的演化特征，构在了一个热水沉积成矿系列，成矿发生于一个热旋回中，各种矿化有相似的物源，每一种地质事件都有特定的金属富集及富集在型和大型矿床是该地区构造－岩浆变质变形作用的最终产物。     

黔东南地区Au,Sb,Pb,Zn矿床分布与重力场关系的初步分析

本文根据1／20万区域重力资料所圈定的异常及其对深部构造的初步解译等,结合该区Au,Sb,Pb,Zn等矿床的空间分布,初步探讨其与区域重力场等的关系,对黔东南地区上述矿床的研究和找矿有一定的参考价值。     

Geology,fluid inclusions,and geochemistry of the Zhazixi Sb–W deposit,Hunan, South China

The Zhazixi Sb–W deposit in the Xuefeng uplift, South China, exhibits a unique metal association of W and Sb, where the W orebodies are hosted by interlayer fractures and the Sb orebodies are contained within NW-trending faults. This study proposes that the W and Sb mineralization took place in two separate periods. The mineral paragenesis of the W mineralization reveals a mass of quartz, scheelite and minor calcite. The mineral assemblage of the Sb mineralization developed after W mineralization and consists of predominantly quartz and stibnite, and small amounts of native Sb, berthierite, chalcostibnite, pyrite, and chalcopyrite. Fluid inclusions in quartz and coexisting scheelite are dominated by two-phase, liquid-rich, aqueous inclusions at room temperature. Microthermometric studies suggest that ore-forming fluids for W mineralization are characterized by moderate temperatures (170–270 °C), low salinity (3–7 wt% NaCl equiv.), low density (0.75–0.95 g/cm³), and moderate to high pressure (57.2–99.7 MPa) and these fluids experienced a cooling and dilution evolution during W mineralization. Ore-forming fluids for Sb mineralization are epithermal types with low temperatures (150–230 °C), low salinity (4–6 wt% NaCl equiv.), moderate density (0.82–0.94 g/cm³), and high pressure (42.2–122.5 MPa) and these fluids display an evident decline in homogenization temperature during Sb mineralization. Laser Raman analyses of the vapor phase indicate that the ore-forming fluids for both W and Sb mineralization contain a small amount of CO₂.The ore-forming fluids for Sb mineralization are identified as predominantly originating from the continental crust, as suggested by the low ³He values (0.009 × 10⁻¹² cc.STP/g) and ³He/⁴He ratios (0.002–0.056 Ra) as well as high ³⁶Ar values (1.93 × 10⁻⁹ cc.STP/g) and ⁴⁰Ar/³⁶Ar ratios (909.5–2279.7). The source of S is identified to be the Neoproterozoic Wuqiangxi Formation, as traced by the δ³⁴S_V-CDT values of stibnite (3.1–9.4‰). The ²⁰⁸Pb/²⁰⁴Pb (37.643–40.222), ²⁰⁷Pb/²⁰⁴Pb (15.456–15.681), and ²⁰⁶Pb/²⁰⁴Pb (17.093–20.042) ratios suggest a mixture of lower crustal and supracrustal Pb sources.It is thus concluded that the ore genesis of the Zhazixi Sb–W deposit is related to the intracontinental orogeny during the early Mesozoic. Fluid mixing is considered to be the critical mechanism involved in W mineralization, whereas a fluid cooling process is responsible for Sb mineralization. Furthermore, the absence of Au is attributed to the low Σa_s content in Sb-mineralizing fluids.     

原子荧光光谱法测定化探样品时有机质对As,Sb,Bi的干扰

通过研究黑龙江省森林沼泽景观区有机水系沉积物（泥炭）、土壤中As,Sb,Bi的测定结果，发现样品中的有机质对王水消解氢化物原子荧光法测定上述元素存在极大的干扰，提出采用低温（＜450℃）灰化处理可完全消除干扰。对比研究还发现，过去森林沼泽景观区的区域化探扫面资料中的As,Sb,Bi数据存在问题，应专门对其进行评价研究。     

在线双管氢化AAS测定As,Sb和Bi的最佳条件

在线双管氢化AAS法是一种新的原子吸收氢化光谱法 ,具有简便、快速、灵敏度高和硼氢化钾用量少的优点。采用正交试验设计法对在线双管氢化AAS法测定低含量As、Sb和Bi的测定条件进行了系统的研究 ,确定了乙炔流量、燃烧器高度、硼氢化钾浓度和溶液酸度的最佳测定条件。在最佳条件下对实际样品土壤GSS -5、水系沉积物GSD -11、钨矿石GSO -W -1和GSO -W -2中As ,Sb ,Bi的含量进行了测定 ,测定的结果较准确 ,RSD <3 .2 6%。     

西藏古堆—隆子地区Sb,Pb,Zn化探元素的分形研究及其地质意义

文章根据西藏古堆—隆子地区Sb,Pb,Zn化探元素品位分析结果,结合区域地质资料,基于分形几何学的理论基础,对研究区Sb,Pb,Zn的分布规律进行了定量研究。结果表明,4个研究区Sb,Pb都具有多重分维的性质,且与矿化有关的分维值D2ⅡD2Ⅲ,同一研究区同一元素的各组分维值差距较大,Ⅲ区和Ⅳ区的Zn只有一个维数值,说明典型矿床发育的地区成矿元素具有多重的分维结构和低分维值D2,基于此理论成功验证了恰嘎研究区具有寻找锑矿前景。通过研究Sb,Pb,Zn的分形特征,揭示出化探元素的分维结构和分维值的大小与矿化程度有关,并为找矿勘查工作提供一定的地质依据。     

As–Sb–Bi–Au mineralization in the Baogutu gold deposit,Xinjiang, NW China

Here we report the occurrence of some uncommon mineral assemblages including pääkönenite, aurostibite, native arsenic, native antimony, and native bismuth found in the Baogutu gold deposit in the western Junggar, Xinjiang, NW China. The mineralization could be generally subdivided into two types: the gold-bearing quartz-vein type mineralization and disseminated mineralization in the wall rocks. The sulfide minerals in gold lodes commonly include pyrite, arsenopyrite, marcasite, and stibnite. However, the L7 lode in No. 4 orebody and the L1 lode in No. 11 orebody of the Baogutu gold deposit are quite different in terms of their mineral assemblages. The L7 lode contains native arsenic–quartz veins in shallow levels and stibnite–quartz veins at depth. Gold-bearing minerals (electrum, native gold, and rarely aurostibite) mainly coexist with pääkönenite, stibnite, native arsenic, and native antimony. The crystallization of As- and Sb-bearing minerals was likely to have consumed H₂S from the hydrothermal fluid, which probably triggered the precipitation of native gold. The L1 lode consists of several discontinuous sulfide-dominated lensoid orebodies. The massive sulfide ores that produced most of the gold resource are characterized by an intimate association between native bismuth and native gold mineralization.     

华南沉积岩系Hg、Sb丰度

从区域构造地球化学演化的角度来看,华南Hg、Sb矿床的形成主要可划分为三个阶段:(1)沉积层(主要是元古宙基底沉积层)堆积过程中Hg、Sb的储集;(2)元古宙基底(沉积层)的下沉-熔融-花岗岩形成与Hg、Sb释放;(3)在有利构造的引控下,含Hg、Sb流体形成、演化与成矿,简称为储存-释放-富集宏观三阶段。本文重点阐述的是第一阶段,华南沉积层特别是元古宙基底沉积层的Hg、Sb丰度。文中将华南沉积层Hg、Sb丰度分为四种类型:Ⅰ原生本底丰度;Ⅱ同生异常丰度;Ⅲ后生丰度;Ⅳ混合丰度。本文计算、统计出华南沉积岩系本底丰度Hg为0.368μg/g,Sb为1.28μg/g。华南元古宙基底沉积岩系本底丰度Hg为0.363μg/g,Sb为1.45μg/g都明显高于地壳及花岗岩Hg、Sb丰度值。     

黔东南永乐—都江地区水系沉积物中Ba,Cu,Sb元素的区域分布及实用意义

黔东南永乐－都江地区Ｂａ，Ｃｕ，Ｓｂ元素的区域分布与地层分布及主要断层存在着密切的对应关系。利用不同地层分布区水系沉积物中元素平均确定的界线值，所作的等值线基本沿地质界线延伸或大致吻合，反映了化探资料对解决基础地质问题具有一定的实用意义。     

First Data on Au–Sb Mineralization of the Ariadnoe Ultramafic Intrusion,Primor’e

Doklady Earth Sciences - A new promising source of mineral deposits is found in the southern part of the Far East of Russia: the Ti-bearing intrusions of ultramafic rocks of the Sikhote-Alin...     

Chemical composition and evolution of tourmaline-supergroup minerals from the Sb hydrothermal veins in Rožňava area,Western Carpathians,Slovakia

Mineralogy and Petrology - Tourmaline-supergroup minerals are common gangue minerals in Sb-hydrothermal veins on Betliar – Straková, Čučma – Gabriela and...     

黔西南地区Au、Sb成矿与找矿方向探讨

通过区域成矿地质背景结合矿产分布特征的总结分析,认为峨眉地幔柱活动是幔源成矿物质来源的重要地质事件,深部岩浆活动为区内成矿提供了另一部分物质来源和重要的热源,断裂和沉积不整合界面是深源成矿流体运移的主要通道;从成矿系列的角度对黔西南金等中低温热液成矿进行了探讨,物源、热源和液源为成矿系列的形成、运移、成矿提供了物质基础,成矿系列与印支—燕山期沉积作用—构造活动—岩浆活动密切相关,初步分析认为黔西南地区金等中低温矿床属南盘江—右江地区燕山期与岩浆活动、沉积作用、构造活动有关的金、砷、锑、汞(铊)矿床成矿系列。通过成矿分析提出本区域横向和纵向找矿方向。     

SiO2与成矿元素Sb络合作用的实验研究

实验测定了250℃时Sb在含硅和无硅体系中的溶解度。对比研究指出，SiO2的存在明显有利于Sb的溶解，并且Sb溶解度随NaOH浓度的增加而增大。在无硅NaOH体系中，Sb（OH）03基络合物是Sb的主要存在形式。含硅体系中，大量可溶Si的存在，使其有可能与Sb络合形成Sb－Si络合物，在低温贫硫富硅热液中溶解、迁移。体系各种条件的改变，促使SiO2沉淀，是导致Sb－Si络合物不稳定、引起Sb沉淀的主要因素，也是硅化与Sb矿化密切共生的原因所在。     

Mineralogy of Copper in Sulfide-Free Endogenic Pb–Zn–Sb Mineralization of the Pelagonian Massif,Republic of North Macedonia

Geology of Ore Deposits - Behavior of copper in sulfide-free metasomatic ores of the Pelagonian massif, Republic of North Macedonia has been studied. It is shown that the highest copper activity...     

An Experimental Study on Three Quaternary Phases in the Fe-Sn-Sb-S System: Pb-Free Franckeite, Pb-Free Cylindrite and (Fe, Sb)-Ottemannite s.s.

Experimental studies on the two solid solutions franckeite s.s. and cylindrite s.s. yielded among others thePb-free endmembers of franckeite and cylindrite respectively. In these endmembers the lead content of the twomineral phases are completely substituted by bivalent tin. A third phase, ottemannite s.s. with (Fe. Sb)-bearingcompositions, was further identified in the Pb-free 4-component system Fe-Sn-Sb-S. Pb-free franckeite andcylindrite could only be synthesized as homogeneous phases at high temperatures. The ottemannite s.s. was ob-tained at 600℃ but an extensive existing range was also confirmed at temperatures below 500℃. The phase relations were discussed in the pseudoternary subsystem SnS-SnS_2-FeSb_2S_4. The following se-quence of Pb-free phases and phase assemblages were observed under increasing Sn~(4+) content at 600℃:herzenhergite (SnS)+franckeite, franckeite, franckeite+cylindrite, cylindrite, cylindrite+(Fe, Sb)-ottemannite.(Fe, Sb)-ottemannite. (Fe. Sb)-ottemannite+berndtite (SnS_2). The assemblage cylindrite+berndtite was identi-fied in synthetic systems involving Pb. The phase Fe. Sb-ottemannite s.s. appears to be stable only under Pb-de-ficient and high sulfur fugacity conditions.     

Light Hydrocarbons in Fluid Inclusions and Their Constraints on Ore Genesis: A Case Study of the Songxi Ag (Sb) Deposit, Eastern Guangdong, China

The Songxi deposit is a newly discovered large Ag (Sb) deposit. By using a suite of high-vacuum quadrupole gas mass spectrometer systems, the authors have recognized many kinds of light hydrocarbons in fluid inclusions of minerals. These hydrocarbons are mainly composed of C1-C4 saturated alkanes, while the contents of C2-C4 unsaturated alkenes and aromatic hydrocarbons are quite low, suggesting that the metallogenic processes have not been affected by magmatic activities. Chemical equilibrium studies show that these hydrocarbons may be a mixture of organic gases generated by microorganism activity and those by thermal cracking of type-n kerogens (kukersite) in sedimentary host rocks, and the former may constitute more than two-thirds, implying that microorganism might have played an important role in the metallogenesis. The equilibrium temperature of the latter is about 300℃, which is much higher than the geothermal temperature at the estimated depth of metallogenesis. Thus, the light hydrocarbons gen     

原子荧光光谱法直接连续测定化探样品中的As Sb Bi Hg

研究了还原性介质中原子荧光光谱法直接连续测定化探样品中Ａｓ、Ｓｂ、Ｂｉ、Ｈｇ的方法。按拟定的条件进行测定,各元素的检出限分别为Ａｓ２．９×１０－９、Ｓｂ１．３×１０－１０、Ｂｉ１．８×１０－１０、Ｈｇ５×１０－１１。应用于区域化探扫面工作中,效果良好。