ALPEX-Simulation

Summary In a project ALPEX-Simulation, sponsored by the Österreichischer Fond zur Förderung der wissenschaftlichen Forschung (FWF), all eight cases of ALPEX-SOP cyclones were numerically simulated with a fine mesh isentropic model of the atmosphere. These numerical simulations in six-hourly intervals allow a deeper insight into the synoptics and dynamics of the cyclogeneses in the Western Mediterranean, especially into the genesis of the two basic types of cyclones: the so-called Überströmungs-type and Vorderseiten-type. In the first phase of cyclogenesis of the Überströmungs-type, the blocking and flow splitting of the cold air due to the Alps and the canalization between the Alps and the Massif Central are important. Cold air flows cyclonically around the western part of the Alps, creating a vorticity maximum at the south western edge of the Alpine, bow and leads also to an enhanced PV. In connection with warm air in the Mediterranean, a strong baroclinic zone is generated. The interaction between the arriving PV maximum in the upper troposphere and the enhanced PV at the bottom leads to cyclogenesis in the Western Mediterranean. In the case of the Vorderseiten-type warm air advection dominates with the exception of a shallow layer of cold air in the inner Po-Valley, which is shielded by the Alpine ridge. A well-pronounced PV maximum builds up and couples with the PV maximum arriving at upper levels, even before the cold air, coming from the north-west, has surrounded the Alps. The cold air only intensifies the development by raising the baroclinity. Therefore, the Vorderseiten-cyclogenesis is an orographically modified cyclogenesis, in the course of which the cyclonic development is triggered by the Alps, whereas the Überströmungs-cyclogenesis is an orographically induced cyclogenesis i.e. a true lee cyclogenesis.With 14 FiguresDied in a tragic traffic accident on June 6, 1993.     

Nitrate in the atmospheric boundary layer of the tropical South Pacific: Implications regarding sources and transport

Weekly bulk aerosol samples collected at Funafuti, Tuvalu (8°30S, 179°12E), American Samoa (14°15S, 170°35W), and Rarotonga (21°15S, 159°45W), from 1983 through most of 1987 have been analyzed for nitrate and other constituents. The mean nitrate concentration is about 0.11 g m^–3 at each of these stations: 0.107±0.011 g m^–3 at Funafuti; 0.116±0.008 at American Samoa; and 0.117±0.010 at Rarotonga. Previous measurements of mineral aerosol and trace metal concentrations at American Samoa are among the lowest ever recorded for the near-surface troposphere and indicate that this region is minimally affected by transport of soil material and pollutants from the continents. Consequently, the nitrate concentration of 0.11 g m^–3 can be regarded as the natural level for the remote marine boundary layer of the tropical South Pacific Ocean. In contrast, over the tropical North Pacific which is significantly impacted by the transport of material from Asia and North America, the mean nitrate concentrations are about three times higher, 0.29 and 0.36 g m^–3 at Midway and Oahu, respectively. The major sources of the nitrate over the tropical South Pacific are still very uncertain. A very significant correlation between the nitrate concentrations at American Samoa and the concentrations of ²¹⁰Pb suggests that transport from continental sources might be important. This continental source could be lightning, which occurs most frequently over the tropical continents. A near-zero correlation with ⁷Be indicates that the stratosphere and upper troposphere are probably not the major sources. A significant biogenic source would be consistent with the higher mean nitrate concentrations, 0.16 to 0.17 g m^–3, found over the equatorial Pacific at Fanning Island (3°55N, 159°20W) and Nauru (0°32S, 166°57E). The lack of correlation between nitrate and nss sulfate at American Samoa does not necessarily preclude an important role for marine biogenic sources.     

Red dust rain within the Spanish Mediterranean area

Dust rain belongs to the climatological conditions of the Iberian Peninsula's Mediterranean seaboard. Traditionally known as muddy' or bloody rains, red dust rain has become a topical issue as a result of more frequent rainfall of this kind in recent years. In spite of the difficulties that studying this phenomenon involves, owing to the lack of systematically kept records at meteorological observatories, details are provided of the high frequency of such phenomena within the Spanish Mediterranean area, using records from other phenological sources. The study analyzes the chemical composition of red dust rain and the atmospheric factors giving rise to such phenomena. Whether there is a relationship betwen the higher frequency of dust rain and possible changes in global atmospheric circulation is as yet unclear.     

Transport-Dissipation Analytical Solutions to the E-∈Turbulence Model and their Role in Predictions of the Neutral ABL

E- turbulence model predictions of the neutralatmospheric boundary layer (NABL) are reinvestigated to determine thecause for turbulence overpredictions found in previous applications. Analytical solutions to the coupled E and equations for the case of steady balance between transport and dissipation terms, the dominant balance just below the NABL top, are derived. It is found that analytical turbulence profiles laminarizeat a finite height only for values of closure parameter ratio c ₂ /_e equal toor slightly greater than one, with laminarization as z for greater . The point = 2 is additionally foundthat where analytical turbulent length scale (l) profilesmade a transition from ones ofdecreasing ( < 2) to increasing ( > 2)values with height. Numerically predicted profiles near the NABL topare consistent with analytical findings. The height-increasingvalues of l predicted throughout the NABL with standard values ofclosure parameters thus appear a consequence of 2.5(> 2), implied by these values (c ₂ = 1.92, _{= 1.3}, _{e = 1}). Comparison of numericalpredictions with DNS data shows that turbulence overpredictions obtained with standard-valued parameters are rectifiedby resetting and _e to 1.1 and 1.6, respectively, giving, with c ₂ = 1.92, 1.3, and laminarization of the NABL's cappingtransport-dissipation region at a finite height.     

Trajectory Curvature As A Selection Criterion For valid Lagrangian Stochastic Dispersion Models

Among well-mixed multi-dimensional Lagrangian stochastic (LS) dispersion models, we observe that those in poorest agreement with observations produce spiralling trajectories, with an associated reduction in dispersion. We therefore investigate statistics of increments d ' to the orientation '= arctan(W'/U') of the Lagrangian velocity-fluctuation vector – as a possible means to distinguish the better LS models within the well-mixed class. Zero-spin models, having d' = 0, are found to provide best agreement with observations. It is not clear however, whether imposition of the zero-spin property selects (in conjunction with the well-mixed condition) a unique model.     

Stable Isotope Ratios: Hurricane Olivia

The oxygen and hydrogen isotopic compositions of rains from HurricaneOlivia (1994) in the eastern Pacific were measured. The rains werecollected on 24 and 25 September during airplane flights conducted at anelevation of 3 km. Hurricane Olivia peaked in intensity to a category-4storm between the two dates. Isotope ratios of rains from HurricaneOlivia were markedly lower ( ¹⁸O = –13.9to –28.8) than that of rain collected from a thunderstormat an elevation of 2.3 km outside the influence of Olivia (¹⁸O = –3.8). A distinct decrease in isotoperatios from the first day to the next ( ¹⁸O =–18.4 to –21.9) in Hurricane Olivia wasattributed to decreased updraft velocities and outflow aloft. Thisshifted the isotopic water mass balance so that fewer hydrometeors werelifted and more ice descended to flight level. A decrease in the averagedeuterium excess from the first day to the next (d = 15.5 to 7.1)was attributed to an increase in the relative humidity of the watervapor `source' area. We hypothesize that the `source' region for therain was in the boundary layer near the storm center and that becausethe hurricane was at peak intensity prior to the second day the relative humidity was higher.     

An observational study of heat fluxes and their relationships with net radiation

Experimental evidence indicates that the diurnal behaviour of the fluxes of heat into the ground and into the atmosphere versus the net flux of radiation can be modelled by closed curves, the hourly values folowing one another in either a clockwise or counter clockfashion. A general formulation to express the different heat fluxes as a function of net radiation is proposed. This relationship between the different heat fluxes and can be expressed as a sum of three terms: the first indicates a direct proportionality to , the second gives the deviation from linearity and depends on /t, and the third gives the value of the flux when = 0. The formulae are then expressed as a function of time and the ratios between the heat fluxes and are evaluated. A comparison with the approximations generally used shows that the latter may be considered as particular cases of the more general equations proposed here.     

Similarity of atmospheric Reynolds shear stress and heat flux fluctuations over a rough surface

Horizontal u and vertical w velocity fluctuations have been measured together with temperature fluctuations in the atmospheric surface layer, at a small height above a wheat crop canopy. Marginal probability density functions are presented for both individual fluctuations u, w, and for the instantaneous Reynolds stress uw, and heat fluxes w and u. Probability density functions of the velocity fluctuations deviate less significantly from the Gaussian form than the probability density of temperature. There appears to be closer similarity between statistics of the instantaneous heat fluxes than between the momentum flux and either of the heat fluxes investigated. The mean momentum flux receives equal contributions from the events referred to as ejections and sweeps in laboratory boundary layers. Sweeps provide the largest contribution to the heat fluxes.     

The recent characteristics of Asian dust and haze events in Seoul, Korea

Summary The study on the characteristics of aerosol in Seoul during springtime from 1998 to 2003 is performed by the size-resolved number concentrations of aerosol. Asian dust events occur in spring most frequently, but it has been often observed in wintertime since 1999. Since 2000, the number of Asian dust days has been increasing, and the intensity has been more severe until 2002. However, there were only 3 dust days in Seoul during the spring of 2003, since the synoptic cyclone was relatively not intense enough to rise and transport dust to Korean peninsula, and the air stream was usually tiled to north of Korean peninsula. In addition, the precipitation was relatively plentiful and the air temperature was cold enough not to keep dry soil condition.Haze is the suspended particles in the air, reducing visibility by scattering light, and it is often a mixture of aerosols and photochemical smog. Dry particles with diameters of the order of 0.1µm, are small enough to scatter short wavelengths of light. Haze occurs well in winter and spring, and severe haze is observed in the afternoon. The occurrence frequency of haze has been decreasing since 2000 except in May of 2003.During Asian dust events from 1998 to 2003, the number concentration of aerosol with diameters from 0.3µm to 0.5µm decreases notably, but that larger than 1µm increases rapidly. On the other hand, for the haze events the number concentration from 0.3µm to 0.5µm increases notably, but that larger than 1µm decreases.     

Plötzlicher Herztod und Wetter

Zusammenfassung An einem Material von 100 Fällen eindeutig gesicherten Herztodes, die im Institut für Gerichtliche und Soziale Medizin in Frankfurt am Main aus einem bestimmten Bereich — Raum Frankfurt am Main — und einer bestimmten zeit—Kalenderjahre 1948 bis 1950—zur Autopsie gelangten, einerseits und den bioklimatischen Daten für den gleichen Raum und die gleiche Zeit anderseits, wurde der Zusammenhang von Herztodesfällen und Wettervorgängen mit der Wahrscheinlichkeitsüberlegung, dem Wahrscheinlichkeitsintegral und formalstatistischen Methoden überprüft. Die Auswertung ergab, daß eine starke Abhängigkeit des Herztodes vom Wettergeschehen besteht. Die Häufung der Herztodesfälle konnte für die Sammelgruppe Wetterstörungen, für labiles Aufgleiten, Warmfront mit Aufgleiten und Kaltfront mit Turbulenz ebenso eindeutig gesichert werden, wie die Verminderung der Herztodesfälle in störungsfreien Zeiten. Die hohe Wahrscheinlichkeit einer Beziehung besteht ferner für Kaltfront mit Aufgleiten und in geringerem Maße auch für Föhndurchbruch. Während bei Okklusion das Material zu einem abschließenden Urteil zu gering war, konnte bei allen übrigen Wetterlagen eine Beziehung zum plötzlichen Herztod nicht nachgewiesen werden. Auch für die Gruppen, bei denen eine enge Beziehung statistisch gesichert werden konnte, sei betont, daß die Wettervorgänge nicht die alleinige Ursache des plötzlichen Herztodes, sondern nur ein auslösendes Moment bei schon vorher schwer geschädigten Herzen darstellen.

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Summary On the basis of 100 ascertained cases of cardiac death from a certain region—province Frankfort on-the-Main—and a certain period—calendar years 1948 to 1950—, submitted to autopsy in the Institute for Legal and Social Medicine at Frankfort on-the-Main, and of bioclimatic data from the same region and period, the relation between cardiac death and meteorological phenomena was examined by means of probability considerations, the probability integral, and methods of formal statistics. Evaluation of this material showed cardiac death to be strongly dependent on weather conditions. Increase of frequency of cardiac death could be established without any doubt for the collective groups weather disturbances, unstable ascending motion, warm front with ascending motion, cold front with turbulence, whereas decrease of frequency was found in undisturbed periods. Furthermore, high probability of an existing relation was found for cold front with ascending motion and, to a lesser degree, also for foehn invasion. As to occlusion no definite conclusions could be drawn for scarcity of observations. For all the other weather types no relation to sudden cardiac death could be proved. Meteorological phenomena are by no means the only cause of sudden cardiac death, not even for the groups in which a close relation could be established statistically. They have but an initiatory effect in case of prior severe heart diseases.

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Résumé Disposant d'un matériel médical de 100 cas de mort cardiaque qui ont fait l'objet d'autopsies à l'Institut de médecine légale et sociale de Francfort sur le Mein (région de Francfort et période de 1948 à 1950), et disposant d'autre part pour la même région et pour la même période d'observations bioclimatologiques, l'auteur a étudié la relation de ces décès avec les phénomènes météorologiques à l'aide des méthodes modernes de statistique, de l'intégrale de probabilité etc. Le résultat montre une étroite dépendance centre les cas de mort cardiaque et les conditions météorologiques. On a pu vérifier sans doute possible l'augmentation des décès lors de «perturbations», d'«ascendances labiles», de «fronts chauds avec glissement ascendant», de «fronts froids avec turbulence», de même que leur diminution lors de périodes non troublées. La forte corrélation subsiste avec les «fronts froids avec ascendance» et à un moindre degré avec «l'invasion du foehn». Tandis que pour les «occlusions» le matériel disponible était trop restreint pour aboutir à une conclusion, l'examen des situations autres que les précédentes n'a pas conduit à une relation intime. Il convient de remarquer que pour tous les groupes de météores ayant donné une corrélation statistique très nette, les phénomènes météorologiques n'ont joué qu'un rôle déclancheur chez des malades déjà gravement atteints.

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Mit 2 Textabbildungen.     

Arctic hazes in summer over Greenland and the North American Arctic: II. Nature and concentrations of accumulation-mode and giant particles

Airborne measurements made during August 1985 over Greenland and its environs show that both accumulation-mode (0.1 m D2.0 m) and giant (D2 m) particles were present in relatively high concentrations in arctic haze layers and that the accumulation-mode particles dominated light scattering. Particles with diameters (D) between 1 and 4 m consisted predominately of mixed materials, small and dense inclusions, and probably organic compounds containing sulfur. Many of the particles from 0.1 to 1 m in diameter were also of mixed composition, with sulfuric acid, ammonium sulfate and organics probably the dominant constituents.     

The behaviour of a mixed-layer model of the convective boundary layer coupled to a big leaf model of surface energy partitioning

Daily mean values of the Priestley-Taylor coefficient, ¯, are derived from a simple model of the daily growth of a convective boundary layer. For a particular control set of driving environmental variables, ¯ is related to the prescribed bulk surface resistance, r_S by 1/¯ = 1/₀ + mr_S for parameters ₀ and m. The dependence of the parameters ₀ and m on weather is explored and a potential use of this linear relation to provide information about regional values of r_S is indicated.     

Gas-Phase Ozone Oxidation of Monoterpenes: Gaseous and Particulate Products

Atmospheric oxidation of monoterpenes contributes to formation of tropospheric ozone and secondary organic aerosol, but their products are poorly characterized. In this work, we report a series of outdoor smog chamber experiments to investigate both gaseous and particulate products in the ozone oxidation of four monoterpenes: -pinene, -pinene, ³-carene, and sabinene. More than ten oxygenated products are detected and identified in each monoterpene/O₃ reaction by coupling derivatization techniques and GC/MS detection. A denuder/filter pack sampling system is used to separate and simultaneously collect gas and aerosol samples. The identified products, consisting of compounds containing carbonyl, hydroxyl, and carboxyl functional groups, are estimated to account for about 34–50%, 57%, 29–67%, and 24% of the reacted carbon mass for -pinene, sabinene, -pinene, and ³-carene, respectively. The identified individual products account for >83%, 100%, >90%, and 61% of the aerosol mass produced in the ozone reaction of -pinene, sabinene, -pinene, and ³-carene. The uncertainty in the yield data is estimated to be ±50%. Many of the products partition between gas and aerosol phases, and their gas-aerosol partitioning coefficients are determined and reported here. Reaction schemes are suggested to account for the products observed.     

Analytical solutions for the Ekman layer

The PBL equation that governs the transition from the constant-stress surface layer to the geostrophic wind in a neutrally stratified atmosphere for which the eddy viscosityK(z) is assumed to vary smoothly from the surface-layer value U _*z (0.4,U _*=friction velocity,z=elevation) to the geostrophic asymptoteK _GU _*d forzd is solved through an expansion in fd/U _*1 (f=Coriolis parameter). The resulting solution is separated into Ekman's constant-K solution an inner component that reduces to the classical logarithmic form forzd and isO() relative to the Ekman component forzd. The approximationKU _*d is supported by the solution of Nee and Kovasznay's phenomenological transport equation forK(z), which yieldsK–U _*d exp(–z/d), where is an empirical constant for which observation implies, 1. The parametersA andB in Kazanskii and Monin's similarity relation forG/U _* (G=geostrophic velocity) are determined as functions of . The predicted values ofG/U _* and the turning angle are in agreement with the observed values for the Leipzig wind profile. The predicted value ofB based on the assumption of asymptotically constantK is 4.5, while that based on the Nee-Kovasznay model is 5.1; these compare with the observed value of 4.7 for the Leipzig profile. A thermal wind correction, an asymptotic solution for arbitraryK(z) and 1, and an exact (unrestricted ) solution forK(z)=U _*d[1–exp(–z/d)] are developed in appendices.     

Near-field dispersion from instantaneous sources in the surface layer

This paper considers the near-field dispersion of an ensemble of tracer particles released instantaneously from an elevated source into an adiabatic surface layer. By modelling the Lagrangian vertical velocity as a Markov process which obeys the Langevin equation, we show analytically that the mean vertical drift velocity w(t) is w()=bu _*(1–e ^–(1+)), where is time since release (nondimensionalized with the Lagrangian time scale at the source), b Batchelor's constant, and u _*, the friction velocity. Hence, the mean height and mean depth of the ensemble are calculated. Although the derivation is formally valid only when 1, the predictions for w, mean height and mean depth are consistent in the downstream limit ( 1) with surface-layer Lagrangian similarity theory and with the diffusion equation. By comparing the analytical predictions with numerical, randomflight solutions of the Langevin equation, the analytical predictions are shown to be good approximations at all times, both near-field and far-field.     

Nine fallacies of natural disaster: The case of the Sahel

This article presents nine statements which are generally accepted as true. However, when they are applied to a particular situation, in this case the recent prolonged drought in the Sahelian zone in West Africa, they are as often untrue as they are true. For example, such generalizations as people learn from their mistakes or when the rains come, everything will return to normal or technology is the answer, when applied uncritically to a specific situation often prove to become part of the problem as well as a hindrance to the attainment of a solution to that problem.It is strongly suggested that these nine generalizations, here called fallacies, be carefully assessed when applied, thereby removing one more obstacle in dealing with environmental problems in general and natural hazards in particular.Published in Michael H. Glantz (ed.), The Politics of Natural Disasters: The Case of the Sahel Drought (NY: Praeger Publ., 1976) reprinted by permission.Michael H. Glantz is a scientist in the Advanced Study Program at the National Center for Atmospheric Research which is sponsored by the National Science Foundation.     

Analysis of Astex-Stratocumulus Observational Data Using a Mass-Flux Approach

A mass-flux approach is applied to observational data obtained in a convective boundary layer topped with stratocumulus clouds. The observational data were obtained from aircraft measurements during the Atlantic Stratocumulus Transition Experiment (ASTEX). A conditional sampling method is used to calculate average updraft and downdraft values. The vertical fluxes calculated with the mass-flux approach are found to be proportional to the real (measured) fluxes, with a proportionality factor being about 0.6. This value is predicted by theory for two variables having a joint Gaussian distribution function; proportionality factor = 2^-1 0.637. The horizontal fractional entrainment and detrainment rates calculated from the data ( 1–2 × 10^-2 m^-1) are an order of magnitude higher than the rates obtained by large eddy simulations for cumulus convection ( 2–3 × 10^-3 m^-1) and two orders of magnitude higher than those used in modelling cumulus convection with a mass-flux scheme in an operational weather forecast model ( 3 × 10^-4 m^-1). A numerical mass-flux model for the thermodynamics was developed and showed that results are in good agreement when compared with measured profiles of the liquid water content.     

AN E – ε – ℓ TURBULENCE CLOSURE SCHEME FOR PLANETARY BOUNDARY-LAYER MODELS: THE NEUTRALLY STRATIFIED CASE

The standard E – model generates aplanetary boundary layerthat appears to be much too deep. The cause of theproblem is traced to the equation for the dissipationrate () of turbulent kinetic energy (E), specifically theparameterization of dissipation production anddestruction. In the context of atmosphericboundary-layer modelling, we argue that a part of thedissipation production should be modelled as the inputto the spectral cascade from the energy-containingpart of the spectrum, with a characteristic length , while the equilibrium imbalancebetween local production and destruction ofdissipation is modelled as proportional toE2/E, as in the standard model. Wepropose an E – – turbulence closurescheme, in which both the mixing length, m, and are prescribed. The importance ofthe equation is diminished, though itstill determines the dissipation rate in the Eequation.     

Equatorial disturbances,monsoons, and 1982–1983 ENSO

Summary Interannual modes are described in terms of three-month running mean anomaly winds (u,v), outgoing longwave radiation (OLR), and sea surface temperature (T _* ). Normal atmospheric monsoon circulations are defined by long-term average winds (u _n,v _n) computed every month from January to December. Daily winds are grouped into three frequency bands, i.e., 30–60 day filtered winds (u _L,v _L); 7–20 day filtered winds (u _M,v _M); and 2–6 day filtered winds (u _S,v _S). Three-month running mean anomaly kinetic energy (signified asK _L , K _M , andK _S , respectively) is then introduced as a measure of interannual variation of equatorial disturbance activity. Interestingly, all of theseK _L , K _M , andK _S perturbations propagate slowly eastward with same phase speed (0.3 ms^–1) as ENSO modes. Associated with this eastward propagation is a positive (negative) correlation between interannual disturbance activity (K _L , K _M , K _S ) and interannualu (OLR) modes. Namely, (K _L , K _M , K _S ) becomes more pronounced than usual nearly simultaneously with the arrival of westerlyu and negativeOLR (above normal convection) perturbutions. In these disturbed areas with (K _L , K _M , K _S >0), upper ocean mixing tends to increase, resulting in decreased sea surface temperature, i.e.T _* 0. Thus, groups (not individual) of equatorial disturbances appear to play an important role in determiningT _* variations on interannual time scales. HighestT _* occurs about 3 months prior to the lowestOLR (convection) due primarily to radiational effects. This favors the eastward propagation of ENSO modes. The interannualT _* variations are also controlled by the prevailing monsoonal zonal windsu _n, as well as the zonal advection of sea surface temperature on interannual time scales. Over the central Pacific, all of the above mentioned physical processes contribute to the intensification of eastward propagating ENSO modes. Over the Indian Ocean, on the other hand, some of the physical processes become insignificant, or even compensated for by other processes. This results in less pronounced ENSO modes over the Indian Ocean.With 10 FiguresContribution No. 89-6, Department of Meteorology, University of Hawaii, Honolulu, Hawaii.     

Scavenging Efficiency of ‘Aerosol Carbon’ and Sulfate in Supercooled Clouds at Mt. Sonnblick (3106 m a.s.l., Austria)

Cloud water and interstitial aerosol samples collected at Mt. Sonnblick (SBO) were analyzed for sulfate and aerosol carbon to calculate in-cloud scavenging efficiencies. Scavenging efficiencies for sulfate (_SO) ranged from 0.52 to 0.99 with an average of 0.80. Aerosol carbon was scavenged less efficiently with an average value (_AC) of 0.45 and minimum and maximum values of 0.14 and 0.81, respectively. Both _SO and _AC showed a marked, but slightly different, dependence on the liquid water content (LWC) of the cloud. At low LWC, _SO increased with rising LWC until it reached a relatively constant value of 0.83 above an LWC of 0.3 g/m³. In the case of aerosol carbon, we obtained a more gradual increase of _AC up to an LWC of 0.5 g/m³. At higher LWCs, _{_} remained relatively constant at 0.60. As the differences between _SO and _A varied across the LWC range observed at SBO, we assume that part of the aerosol carbon was incorporated into the cloud droplets independently from sulfate. This hypothesis is supported by size classified aerosol measurements. The differences in the size distributions of sulfate and total carbon point to a partially external mixture. Thus, the different chemical nature and the differences in the size and mixing state of the aerosol particles are the most likely candidates for the differences in the scavenging behavior.