火山通道相节理的分类及成因探讨——以山东昌乐地区死火山群火山通道相为例

山东昌乐地区死火山群火山通道相节理非常发育,形态独特,引人注目.经过系统观察认为此处存在三类火山通道相节理:面状节理、"倒扇型"柱状节理和"直立型"柱状节理.通过对三种节理的形态、整体规模、节理开度等的详细分析,认为前一种节理是岩浆在冷却过程中内外岩浆形成一定的温差而形成的平行于岩浆表面的平面状节理,也称其为"等温面";后两种节理在直观上存在巨大的差异,经研究认为其成因为火山通道的规模不同,导致岩浆在喷发过程巾冷却速度不同,最终导致残余岩浆的地层压力不同,致使上部冷却的岩浆岩产生不同的柱状节理.     

松辽盆地东南隆起区营城组柱状节理流纹岩特征和成因

松辽盆地东南隆起区下白垩统营城组出露柱状节理流纹岩。柱状节理属于原生构造节理,岩相为火山通道相次火山岩亚相-侵出相,柱体排列方式为近水平式、倾斜式、近直立式,截面为不规则的四方柱、五方柱、六方柱,柱体规模属于中小型,流纹岩中常发育隐爆角砾结构。通过对柱状节理流纹岩成分及结构构造的研究,表明本区的流纹岩柱体直径与其对应的显微组构斑晶大小成正比例相关。柱状节理的成因是熔岩冷却收缩形成的,由于受到种种内外因素制约,形成的柱状节理形态各异。     

海拉尔盆地上库力组两类流纹岩的球粒对比研究

通过野外观察,结合薄片、铸体薄片等手段研究,发现海拉尔盆地呼伦湖凹陷西界上库力组火山通道相次火山亚相的柱状节理流纹岩和喷溢相上部亚相的球粒流纹岩中发育两种不同结构的球粒,两种球粒均形成于高的过冷却动力学效应下。柱状节理流纹岩中的球粒肉眼不可见,球粒直径小于0. 2 mm,球粒中心发育结晶核,组成球粒的纤维体多为隐晶质。条带状球粒流纹岩中的球粒在野外露头上醒目,圆形、椭圆形特征明显,球粒直径在0. 5～2 mm之间,均匀分布,结晶核不明显,组成球粒的纤维体为霏细质。本文认为导致这两种球粒结构差异性的主要原因是受熔浆过冷度大小的影响,柱状节理流纹岩过冷度较条带状球粒流纹岩大,因此成核速率高,成核密度大,球粒直径小,排列紧密,条带状球粒流纹岩较之相反。同时,流纹质熔浆的均质性程度影响了球粒间孔的充填特征。此外,研究发现,球粒间孔的发育程度和球粒形态直接相关。柱状节理流纹岩基质中的球粒结构紧密排列,球粒受相互生长制约呈不规则状,由于柱状节理本身由十分致密的球粒构成,储集空间不发育,因此不含油。由于条带状球粒流纹岩的球粒排列相对疏松,孔隙大量发育,可能含有丰富的油气,储集空间主要类型为球粒间孔和球粒溶蚀孔。     

玄武质熔结凝灰岩中发现柱状节理构造

柱状节理是基性熔岩中常见的一种构造,火山碎屑岩则仅见于酸性熔结凝灰岩中,如美国的新墨西哥州伐耶斯山和我国浙江衢县的流纹质熔结凝灰岩中,发育有较好的柱状节理为造.而玄武质熔结凝灰岩中的柱状节理构造,本文以前未见有报道.1981年,作者在海南岛文昌蓬莱岭火山锥公路北壁(人工剥露面)的中更新世玄武质熔结凝灰岩中,见有柱状节理构造.玄武质熔结凝灰岩是近水平状产出,灰黑色、紫红色,块状构造、局部见假流动构造,较新鲜者镜下呈     

玄武岩柱状节理的成因机制——局部贝纳德对流模型

<正>厚层玄武岩和火山颈通常发育柱状节理,例如长白山十五道沟、福建牛头山、英国巨人之路等。关于柱状节理的成因机制(Aydin and De Graff,1988)一个普遍接受的解释是岩浆热对流形成的贝纳德花纹,但是迄今为止对于岩浆对流的物理机制和柱状节理特大的长:宽比值缺少合理的解释。本文设计了一个岩浆从顶部向下逐步冷却的模型,对流仅仅发生在固/液边界线之下一个有限的厚度范围,而不是全岩浆房对流,     

玄武质火山机构火山岩的储集性能分析——来自福建漳州牛头山古火山机构的类比研究

火山岩作为特殊的油气储集岩类型,在国内外均有成功的勘探和开发实例。然而因其规模和储量相对较小,储集空间和成藏系统较为复杂,研究工作起步较晚。鉴于前人研究多依赖于钻井岩芯描述和测井数据分析,为了获得岩石孔隙和各类裂缝在古火山机构中的空间分布规律,本文对福建漳州牛头山玄武质火山岩进行了野外调查和岩石物性分析。牛头山古火山历经四期喷发,地表可见四层喷溢相玄武岩层和两处火山颈相岩石出露。喷溢相玄武质火山岩的孔隙度变化较大,从5.34%到23.73%间不等,但渗透率均较低（平均值为0.173×10-3μm2）。火山机构中节理和裂缝较为发育,除火山颈相的柱状节理、火山喷溢相的爆炸缝、冷凝节理外,熔岩/下伏地层接触热变质成因的高孔带、幔源包体裂缝和爆炸孔以及后期形成的构造裂缝、风化破碎带等均有着重要的意义,这些面型单元构成了贯通整个火山机构的空间网络,使古火山机构的储集潜力不容忽视。     

香港国家地质公园粮船湾组火山岩岩石学研究

在香港国家地质公园西贡火山岩园区,核心地质景观是白垩纪粮船湾组(Kkh)火山岩优美的六方形石柱(柱状节理),它们的岩石类型长期存在熔岩和火山碎屑岩之争。笔者等经野外调查和薄片岩石学研究,确认粮船湾组火山岩实属一种特殊的熔岩——流纹质碎斑熔岩,以普遍的柱状节理、斑晶具有碎斑结构和珠边结构、基质发育霏细结构和流动构造为特征;它们不仅代表了香港地区中生代最晚期火山喷发的产物,而且构成了西贡破火山机构的中央侵出相岩穹。推断粮船湾组火山岩石柱是地球上已知面积最大的流纹质碎斑熔岩石柱群(～150 km2),目前所见的火山岩石柱仅是长期剥蚀后的残余部分。     

浙江中生代酸性火山岩柱状节理构造的发现及其地质意义

柱状节理构造历来被众多学者认为只能发育在粘度小、流动性大的基性熔岩中。近年来，在浙江多处中生代酸性火山岩中，发现了十分典型、甚具规模的柱状节理构造。本文从岩石化学角度，对浙江四例酸性火山岩柱状节理构造与浙、苏二省四例玄武岩柱状节理构造做了比较研究。浙江含良好柱状节理构造的酸性火山岩的平均粘度是基性熔岩平均粘度的１０４倍，酸性火山岩的最大粘度甚至可达基性熔岩粘度的１０６倍。如此巨大的酸、基性火山岩粘度比率表明，传统冷却收缩说关于柱状节理构造只能发育在基性熔岩中，因而岩浆粘度是制约柱状节理构造发育与否的主要因素的观点应予修正。最后，本文还讨论了关于柱状节理形成机制的流体动力学观点。     

柱状节理玄武岩隧洞破坏模式及其力学机制模拟

柱状节理岩体由于其内部赋存大量的隐节理面,开挖卸荷后极易出现隐节理面开裂松弛等特征,导致其破坏模式异于一般岩体。其破坏模式主要受到异常发育的节理面和较高地应力的共同作用影响。由于柱状节理岩体节理面发育,岩体结构控制型破坏占主要部分,包括单临空面节理面滑移（塌方）、多临空面节理面滑移（塌方）、与错动带、断层等弱面相组合的坍塌等破坏模式;应力控制型破坏主要为河谷侧顶拱喷层开裂;应力-结构面型破坏主要为岩性交界处的节理岩体塌落等。柱状节理岩体表层主要发生柱内竖直隐节理面和柱间节理面的拉破坏,而围岩内部的柱状节理主要发生柱间节理面的剪切破坏。因此,现场柱状节理的支护也应主要包括两个方面：以喷射混凝土钢纤维来阻止柱状节理岩体表层的张性开裂,以系统锚杆来控制柱状节理岩体内部的剪切破坏。     

新疆柯坪二叠纪层状玄武岩的发育特征及其地质意义

通过野外实地测量和遥感影像识别,并对不同剖面的发育状况进行了对比。新疆柯坪地区发育的二叠纪玄武岩共可分为8层,包括库普库兹曼组2层和开派兹雷克组6层。多层玄武岩是多期喷发作用的结果,每次喷发可以来自不同的岩浆房或火山通道,但岩浆源区基本一致。每期喷发作用都具有一定的序列,先是稳定的熔岩流,发育柱状节理,往上则为致密块状玄武岩,在喷发末期发育火山角砾岩或凝灰岩。多期玄武岩浆喷发作用,指示了该区二叠纪玄武岩的岩浆房经历了"积聚—喷发—再积聚—再喷发"的过程,而熔融岩浆的源区则经历了不断"部分熔融"和"岩浆抽提"的过程。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.