Cu and Fe chalcopyrite leach activation energies and the effect of added Fe

The leaching kinetics of chalcopyrite (CuFeS₂) concentrate in sulfuric acid leach media with and without the initial addition of Fe³⁺ under carefully controlled solution conditions (E_h 750 mV SHE, pH 1) at various temperatures from 55 to 85 °C were measured. Kinetic analyses by (i) apparent rate (not surface area normalised), and rate dependence using (ii) a shrinking core model and (iii) a shrinking core model in conjunction with Fe³⁺ activity, were performed to estimate the activation energies (E_a) for Cu and Fe dissolution.The E_a values determined for Cu and Fe leaching in the absence of added Fe³⁺ are within experimental error, 80 ± 10 kJ mol⁻¹ and 84 ± 10 kJ mol⁻¹, respectively (type iii analyses E_a are quoted unless stated otherwise), and are indicative of a chemical reaction controlled process. On addition of Fe³⁺ the initial Cu leach rate (up to 10 h) was increased and Cu was released to solution preferentially over Fe, with the E_a value of 21 ± 5 kJ mol⁻¹ (type ii analysis) suggestive of a transport controlled rate determining process. However, the rate of leaching rapidly decreased until it was consistently slower than for the equivalent leaches where Fe³⁺ was not added. The resulting E_a value for this leach regime of 83 ± 10 kJ mol⁻¹ is within experimental error of that determined in the absence of added Fe³⁺. In contrast to Cu release, Fe release to solution was consistent with a chemical reaction controlled leach rate throughout. The Fe release E_a of 76 ± 10 kJ mol⁻¹ is also within experimental error of that determined in the absence of added Fe³⁺. Where type (ii) and (iii) analyses were both successfully carried out (in all cases except for Cu leaching with added Fe³⁺, <10 h) the E_a derived are within experimental error. However, the type (iii) analyses of the leaches in the presence of added Fe³⁺ (>10 h), as compared to in the absence of added Fe³⁺, returned a considerably smaller pre-exponential factors for both Cu and Fe leach analyses commensurate with the considerably slower leach rate, suggestive of a more applicable kinetic analysis.XPS examination of leached chalcopyrite showed that the surface concentration of polysulfide and sulfate was significantly increased when Fe³⁺ was added to the leach liquor. Complementary SEM analysis revealed the surface features of chalcopyrite, most likely due to the nature of the polysulfide formed, are subtly different with greater surface roughness upon leaching in the absence of added Fe³⁺ as compared to a continuous smooth surface layer formed in the presence of added Fe³⁺. These observations suggest that the effect of Fe³⁺ addition on the rate of leaching is not due to the change in the chemical reaction controlled mechanism but due to a change in the available surface area for reaction.     

Investigation of zinc extraction from different leach residues by acid leaching

With different properties, zinc is one of the most important non-ferrous metals and it is used in various application areas, especially as an anti-corrosion agent. In Turkey, zinc production was based on zinc carbonate ores (ZnCO₃), at Çinkur plant from establishment to 1997 due to high reserves of zinc carbonate. After that, zinc concentrate coming from Iran was used in this plant over the last two decades. Thus, two different leach residues called as Turkish leach residue (TLR) and Iranian leach residue (ILR) were accumulated more than one million ton in Çinkur stock piles. In this study, it is aimed to investigate zinc recovery for each leach residue by use of sulphuric acid (H₂SO₄) and to compare the TLR and the ILR. Initially, detailed chemical, mineralogical and thermal analyses of these different leach residues were carried out. In order to investigate the effect of acid concentration and reaction duration on zinc recovery, leaching experiments were carried out at following conditions: 95 °C, 100 g/L pulp density and 600 rpm stirring rate. According to the characterization results, the chemical compositions for both residues are nearly similar; however, experimental results show that zinc recovery per cent of the ILR was higher than that of TLR for all experimental durations and acid concentrations. This may be due to the presence of Zn-containing compounds in the both residues at different percentages.     

A scaling model for quantification of earthquakes in and near Japan

A simple method is developed to determine seismic moments of earthquakes. The method is qualified through criteria such as simplicity of calculations, coverage of wide magnitude range, and insensitivity to detailed instrumental response. The method is applied to 163 major earthquakes which occurred underneath Japan and the Japan Sea in the time from 1926 to 1977. Magnitudes of these earthquakes, which have been determined by the Japan Meteorological Agency, (M_JMA) cover the range from 4.3 to 7.5. At first, source spectra are analyzed through a very simple way introducing two new parameters: characteristic period T_c and seismic-moment factor M_c. The former is defined as an average value of apparent periods of seismic waves with the maximum trace amplitude at many stations. The latter is an average of products of maximum trace amplitude and its apparent period multiplied by epicentral distance. It is shown that T_c corresponds to the period of the corner frequency of an earthquake and M_c to the seismic-moment density at the period of T_c. A scaling model of earthquake source spectra is presented which satisfies the empirical relations between the surface-wave magnitude M_s and M_JMA, and M_JMA and the body-wave magnitude m_b. Those relations are independent of the Gutenberg and Richter relation between M_s and m_b, because M_JMA is determined from maximum amplitudes of seismic waves with a period of about 4 sec. The static seismic moment of each earthquake can be estimated from calculated M_c using the source spectra of the scaling model. Seismic moments of 18 earthquakes determined by conventional analyses from near- and/or far-field observations are consistent with static seismic moments thus estimated over the range from 2 × 10²³ to 3 × 10²⁷ dyne cm. This shows the potential in practice of the present method, especially in the routine processing of seismic data.     

Distribution of titanium atoms in oxy-kaersutite

The distribution of Ti atoms in oxy-kaersutite has been studied by the neutron diffraction method. The cation distribution over the three octahedral sites determined by the x-ray method (Kitamura and Tokonami, 1971) is as follows; M1∶0.40MG+0.60 FE, M2∶0.75 MG+0.25 FE, M3∶0.50 MG+0.50 FE, where MG and FE represent (Mg+Al) and (Fe+Ti), respectively. The neutron diffraction study indicates that Ti atoms are enriched in the M1 site more than M2 and M3 sites as follows; M1∶0.40 MG+0.33 Fe+0.27 Ti, M2∶ 0.75 MG+0.23 Fe+0.02 Ti, M3∶0.50 MG+0.46 Fe+0.04 Ti. This distribution agrees with the result based on the Madelung energy of oxy-kaersutite by Whittaker (1972).     

Structures and cohesive properties of hydroxides and fluorides calculated using the modified electron gas ionic model

Molecular cluster calculations using the purely theoretical modified electron gas (MEG) version of the ionic model predict M-OH and M-F distances with an average error of less than 0.03 Å for a wide range of M cations. Such accuracy compares favorably with that obtained using the more expensive ab initio self-consistent-field molecular orbital (MO) method. The frequencies of totally symmetric stretching vibrations are also predicted with an average error of about 25% using the MEG method but cohesive energies are often in error by large amounts. Cohesive energy errors are highly correlated with electronegativity differences, suggesting that they should be ascribed to ovalent bonding effects. The increase of M-X distance with increasing M coordination number can be simply interpreted in terms of the magnitude and number of M-X attractive and X-X repulsive interactions within the MEG model.     

Experimental study of the alteration process of labradorite in acid hydrothermal solutions

Labradorite was altered artificially by HC1 solution ranging from M = 1 to M = 0.003 at 245 and 230°C. The products of alteration were examined by X-ray diffraction, electron microscopy, electron diffraction, infrared spectroscopy and the electron microprobe and the solution was analyzed chemically.Amorphous silica only was formed in solutions with M_HCl = 1 and M_HCl = 0.3. In a solution with M_HCl = 0.2, amorphous silica was initially formed, later dissolved and replaced by kaolinite. A mixture of microcrystalline boehmite and amorphous aluminosilicate was formed, altering to kaolinite in solutions with M_HCl = 0.1 and 0.3. Small amounts of kaolinite were initially formed but the alteration soon stopped in solution with M_HCl = 0.003. Relationships between the alteration processes and pH of the solutions can be roughly explained by using solubility diagrams assuming the congruent dissolution of labradorite and precipitation of the products in partial equilibrium. However, these assumptions are not valid with strongly acid solutions.The rate of dissolution of labradorite is controlled not only by its surface area, but also by the diffusion of matter through the layer of alteration products.     

A Mössbauer study of ferric iron in olivine

Natural and synthetic olivines with ferrous and ferric iron have been studied by Mössbauer spectroscopy. Their spectra exhibit three superimposed quadrupole-split doublets corresponding to Fe²⁺ at M1 and M2 sites and Fe³⁺ at an unidentified position, which is probably M2. The hyperfine parameters of Fe³⁺ at temperatures between 300°C and 450°C are: Δ=0.67–1.23 mm/s, δ=0.04–0.23 mm/s relative to metallic iron, and the full width at half height, HW=0.15–0.43 mm/s. The Fe²⁺ populations of M2 decrease with increasing Fe³⁺ content. However, Fe²⁺ prefers M1 in synthetic olivines, even at high temperatures (800°–1,400°C). In kirschsteinite, Fe²⁺ and Fe³⁺ are exclusively in M1. Fe²⁺/Fe³⁺ ratios estimated from the peak areas are consistent with chemical analyses.     

Chemical and structural study of 1M- and 2M 1-phlogopites coexisting in the same Kasenyi kamafugitic rock (SW Uganda)

In the present work, crystal chemical variations between 1M and 2M ₁ phlogopites coexisting in the same rock sample from kamafugite of Kasenyi (southwest Uganda, west branch of the East African Rift) were explored by electron probe microanalyses, single crystal X-ray diffraction and M?ssbauer spectroscopy. Chemical analyses revealed close similarity both within and between the two polytypic arrangements as well as high TiO₂ (~4.9?wt%) and Al₂O₃ (~12.9?wt%), and low Cr₂O₃ (~0.8?wt%), F (~0.3?wt%) and BaO (~0.2?wt%) contents. Room temperature ⁵⁷Fe M?ssbauer investigation proved that the studied mica is a tetraferriphlogopite with: ^IVFe³⁺?=?19(1)?%, ^VIFe²⁺?=?58(1)?%, ^VIFe³⁺?=?23(1)?%. Single crystal refinement showed that both polytypes have narrow range of variation in terms of some relevant unit cell parameters and similar values in terms of mean bond lengths, mean atomic numbers and distortion parameters. Similar substitutions were active in the structure of the 1M and 2M ₁ studied phlogopites. However, in 2M ₁ polytypes the oxy-type substitutions were found to occur to a greater extent. Comparison of unit layer of 1M mica (in the 2M ₁ setting) with that of the 2M ₁ ones showed that the 2M ₁ polytypes are affected to different extent by relative shifts of the upper and lower triads of octahedral oxygens along the ±b directions. This effect did not cause any symmetry lowering in the T-O-T layer of the studied samples.     

Kinetics and mechanisms of the leaching of low Fe sphalerite

The surface speciation and leaching kinetics of 38- to 75-μm sphalerite (0.45 wt.% Fe) particles reacted in O₂ purged perchloric acid (at pH 1.0) at 25, 40, 60, and 85 °C over a leach period of 144 h were investigated. In all cases, an initial rapid leach rate is observed followed by a slower leach rate. These two leach regimes can each be adequately modeled using straight-line interpolation, and thus two activation energies (E_a) have been derived. E_a for the fast and slow Zn dissolution rates were 33 ± 4 kJ mol⁻¹ and 34 ± 4 kJ mol⁻¹ respectively, suggesting the same rate-determining step.     

Microbial mutualism in leaching of Cu−Ni sulfide concentrate

With tightening legislations on air pollution and decreasing grades of Cu and Ni ores, the mineral processing industry will have to find an alternative to smelting. One such hydrometallurgical alternative is bacterial leaching; it utilizes the action of Thiobacillus ferrooxidans on sulfide minerals converting them to metal sulfates which can be leached by acid produced by the bacteria. The metal is recovered by cementation, solvent extraction or electrowinning. In the present paper, the authors report their test work with a Cu-Ni sulfide concentrate and show that the mutualistic association of T. ferrooxidans with nitrogen-fixing bacteria Beijerinckia lacticogenes helps leach more metal faster in a leaching medium devoid of any added carbon or nitrogen source. Use of intentionally mixed bacterial culture in ore leaching has not been previously reported.     

Metastable staurolite–cordierite assemblage of the Bossòst dome: Late Variscan decompression and polyphase metamorphism in the Axial Zone of the central Pyrenees

A kilometre-scale shear zone is recognized in the Cambro–Ordovician schist of the Bossòst dome, a Variscan metamorphic and structural dome in the Axial Zone of the central Pyrenees. Non-coaxial deformation is recorded by rotated garnet and staurolite porphyroblasts following regional metamorphism M₁, while coaxial conditions prevailed during later contact metamorphic M₂ growth of andalusite and cordierite. Mineral compositions and bulk rock analyses show that garnet–staurolite–andalusite–cordierite assemblages are significantly enriched in Mg and Mn over the garnet–staurolite assemblage, which lacks sufficient Mg for cordierite to form. The garnet–staurolite assemblage preserves conditions during M₁, estimated by AFM diagrams and P–T pseudosections to be 5.5 kbar and 580 °C, respectively. Pseudosections also indicate that staurolite is not a stable phase in cordierite–andalusite assemblages of M₂, suggesting polyphase metamorphism and decompression along a clockwise P–T path for the staurolite–cordierite–andalusite assemblages. This concurs with proposed extensional tectonics along the regional shear zone. To cite this article: J.E. Mezger et al., C. R. Geoscience 336 (2004).     

The genesis of mid-ocean ridge basalt

The tholeiitic volcanics erupted at mid-ocean ridges (mid-ocean ridge basalts or MORB) constitute the dominant volcanic lithology on Earth. Analyses of tachylites from Atlantic, Pacific and Indian Ocean spreading centres range widely in 100 Mg/(Mg + Fe²⁺) ratios (= M) and M varies from 70 to 30. Glasses with M = 55?65 are the most common variants and only a small percentage of glass analyses has M approaching 70. The latter defines the M -value of basaltic melts in equilibrium with residual upper-mantle source peridotites with M ～ 88. The frequency histogram of the M -values of average compositions of MORB glasses at 88 ocean floor localities is similar in analysis distribution to the frequency histograms depicting variation in the M -values of glasses from the various spreading centres.M -values and nickel contents of MORB and the nature and compositions of the near-liquidus phases crystallized experimentally from MORB melts at elevated pressures have been applied to identify primary (unfractionated) melts erupted in a mid-ocean ridge environment. However, Ni abundances and high-pressure phase relationships are not necessarily unique or definitive parameters of primary melts. The latter are generally linked genetically with Mg-rich lherzolitic source rocks of ‘pyrolite’ type (M ～ 90. The spectrum of M -values displayed by MORB glasses, with a definite bias towards relatively Fe-rich compositions (average M of approximately 600 MORB glasses is 58.6), suggests that the melts may have evolved either via ferromagnesian fractionation of relatively Mg-rich parental melts (M = 70?80), or by partial melting of a heterogeneous upper mantle with variable M values, or as a result of magma mixing of already fractionated melts and primitive magma batches.For a number of reasons fractonation models based on the extraction of olivine or one or more of olivine, plagioclase and clinopyroxene, either from picritic melts (M > 75 or ‘primitive’ basaltic melts with M ～ 70, are questionable as prime controls of MORB chemistry. These include: (1) the extreme rarity of ‘quenched’ picritic or Mg-basaltic melts in ocean ridge environments; (2) the lack of adequate evidence of the appropriate (of necessity voluminous) complementary cumulates (dunites, allivalites, troctolites, anorthosites) demanded by olivine, plagioclase, or olivine + plagioclase fractionation models; and (3) the aberrent frequencies of glass M -values whereby the assumed derivatives (M = 55?65 are much more abundant (and presumably much more voluminous) than the alleged parents or transitional derivatives (65 < M < 75). The nature of the trends of Na₂O, CaO and Al₂O₃ in Galapagos Spreading Centre tachylites of extended composition (M = 65?30) indicates the ‘gabbroic’ fractionation is also unlikely to exert important controls on MORB chemistry.As their M -values increase, mid-ocean ridge basalts increase in Al, Ca, Ni, Co, Cr and decrease in Ti, Mn, Na, K and P. Except for Al and Ca, these trends are similar to those displayed by upper-mantle peridotites increasing in M, i.e., becoming more refractory following one or more partial melting episodes. It is suggested that at least a majority of mid-ocean ridge basalts is intrinsically primary and generated by variable degrees of partial melting of heterogeneous lherzolitic upper mantle (80 < M < 90) with variable abundances of elements such as Ti, Al, Ca and Na and also depleted in large ion lithophile (LIL) elements. Negative europium anomalies in the rare-earth patterns of some oceanridge basalts (ferrobasalts with low M) are ascribed mainly to the persistence of residual plagioclase in relatively Fe-rich plagioclase lherzolite source rocks, following low degrees of partial melting. The partial melting events leading to the generation of mid-ocean ridge basalts took place over a relatively modes pressure range (approximately 8–15 kb) which encompassed the transition of plagioclase lherzolite to spinel lherzolite. This proposal appears consistent with the nature and occurrence of megacrysts (xenocrysts) of tschermakitic Cr-diopside (Ca₄₃Mg₅₂Fe₅), olivine (mg 89–91), plagioclase (An_92-85) and spinel (Fe₂Al₆₀Cr₃₈) in some MORB. The megacryst compositions suggest that these phases represent disaggregated plagioclase peridotite or spinel lherzolite acquired by melts during their passage through the oceanic upper mantle.     

Combined loading of caisson foundations in cohesive soil: Finite element versus Winkler modeling

The undrained response of massive caisson foundations to combined horizontal, vertical and moment loading is parametrically investigated through a series of 3D finite element analyses. The parameters are: (a) the embedment ratio (D/B), (b) the factor of safety against initial vertical loading (FS_V) and (c) the ratio of the overturning moment to the horizontal force applied at the top of the caisson (M/Q). Emphasis is given on: (i) the identification of all possible failure mechanisms in M–Q–N space, (ii) the developed stress distributions along the caisson walls for various load levels up to complete failure conditions. The results are then used as a feedback for calibrating the parameters of a generalized four-type spring model, originally proposed by Gerolymos and Gazetas (2006), through a genetic algorithm-based optimization procedure. The predictions of the Winkler model compare very well with the FE results, not only at the local response level (in terms of stress distributions along the caisson shafts), but at a global response level (in terms of force–displacement curves and M–Q–N failure envelopes at the top of the caisson) as well. Contrary to established lateral soil resistance theories, it is shown that both the ultimate horizontal soil reaction and resisting moment per unit depth do not solely depend on the strength properties of soil and geometry of the caisson but are also functions of the applied load ratio M/Q and initial soil yielding due to vertical loading. Interesting conclusions are also drawn regarding the transition from the elastic to the ultimate limit state (hardening). Quantifying through analytical expressions the contribution of each of the two basic lateral resisting mechanisms to the response of the caisson, a classification method for embedded foundations is then proposed. The capabilities of the Winkler model are further demonstrated through comparison with FE analysis of the caisson cyclic lateral response.     

K–Ar dating and δO–δD tracing of illitization within and outside the Shea Creek uranium prospect,Athabasca Basin,Canada

Isotope analyses (K–Ar, δ¹⁸O and δD) were performed on illite from both the sandstone cover and the underlying basement, close to and distant from Shea Creek, an unconformity-type U deposit (Athabasca Basin, Canada); the illite had previously been characterized crystallographically. In the barren areas away from deposit, illite is mainly of the cis-vacant 1M polytype occurring as relatively coarse-grained lath-shaped particles, while it occurs as fine-grained particles of the trans-vacant 1M type next to and in the U mineralized strata. The tectonic-induced hydrothermal system that favored illite crystallization was multi-episodic 1453 ± 2, 1330 ± 20 and probably about 1235 Ma ago. These illite-forming episodes appear to have occurred contemporaneously to those favoring the concentration of the associated U oxides, which were dated independently by the U–Pb method in the Shea Creek deposits and elsewhere in the Athabasca Basin.     

Instabilities in the ionization zones around the first stars

We consider the evolution of the ionization zone around Population III stars with M _* ?? 25?C200M _?? in protogalaxies with M ?? 10⁷ M _?? at redshifts z = 12, assuming that the dark-energy profile is a modified isothermal sphere. We study the conditions for the growth of instabilities in the ionization zones. The Rayleigh-Taylor and thermal instabilities develop efficiently in the ionization zones around 25?C40M _?? stars, while this efficiency is lower for stars withM _* ?? 120M _??. For more massive stars (??200M _??), the flux of ionizing photons is strong enough to considerably reduce the gas density in the ionization zone, and the typical lifetimes of stars (??2 Myr) are insufficient for the growth of instabilities. The gas in a protogalaxy with M ?? 10⁷ M _?? with a 200M _?? central star is completely ionized by the end of the star??s lifetime; in the case of a 120M _?? central star, only one-third of the total mass of gas is ionized. Thus, ionizing photons from stars with M _* ? 120M _?? cannot leave protogalaxies with M ? 10⁷ M _??. If the masses of the central stars are 25 and 40M _??, the gas in protogalaxies of this mass remains essentially neutral. We discuss the consequences of the evolution of the ionization zones for the propagation of the envelope after the supernova explosions of the strs and the efficiency of enrichment of the intergalactic medium in heavy elements.     

Compositional dependence of the hyperfine interaction of 57Fe in anthophyllite

Hyperfine parameters of ⁵⁷Fe in anthophyllites (Mg²⁺, Fe²⁺)₇ Si₈O₂₂(OH, F)₂ mainly depend on the amount of Al present in the structure. The quadrupole splitting of the doublet due to Fe²⁺ in M1, M2 and M3 decreases systematically with the Al content, whereas that of the doublet due to Fe²⁺ in M4 and the half-width of the combined M1, M2, M3 doublet increases. Structurally these variations suggest that, with the incorporation of Al (miscibility towards gedrite), the distortion of the M4 polyhedron decreases, whereas the M1, M2 and M3 polyhedra become more distorted and dissimilar.     

Prediction of pressuremeter modulus and limit pressure of clayey soils by simple and non-linear multiple regression techniques: a case study from Mersin, Turkey

The Standard Penetration Test (SPT) is one of the most frequently applied tests during the geotechnical investigation of soils. Due to its usefulness, the development of empirical equations to predict mechanical and compressibility of soil parameters from the SPT blow count has been an attractive subject for geotechnical engineers and engineering geologists. The purpose of this study is to perform regression analyses between the SPT blow counts and the pressuremeter test parameters obtained from a geotechnical investigation performed in a Mersin (Turkey) city sewerage project. In accordance with this purpose, new empirical equations between pressuremeter modulus (E _M) and corrected SPT blow counts (N ₆₀) and between limit pressure (P _L) and corrected SPT blow counts (N ₆₀) are developed in the study. When developing the empirical equations, in addition to the SPT blow counts, the role of moisture content and the plasticity index of soils on the pressuremeter parameters are also assessed. A series of simple and nonlinear multiple regression analyses are performed. As a result of the analyses, several empirical equations are developed. It is shown that the empirical equations between N ₆₀ and E _M, and N ₆₀ and P _L developed in this study are statistically acceptable. An assessment of the prediction performances of some existing empirical equations, depending on the new data, is also performed in the study. However, the prediction equations proposed in this study and the previous studies are developed using a limited number of data. For this reason, a cross-check should be applied before using these empirical equations for design purposes.     

Molecular weight distribution,analytical and spectroscopic characterization of humic fractions sequentially isolated by organic solvents from a brown coal humic acid

A sequential fractionation procedure employing a series of selected mild organic solvents of different polarity has been applied for the isolation of chemically different organic fractions from a brown coal humic acid. Elemental composition, molecular weight distribution, i.r. and electron spin resonance analysis were carried out on the isolated humic fractions. They were characterized by: (a) a low polydispersity, (b) a decreasing aliphatic and increasing aromatic character along the series, (c) very different molecular weight which significantly correlated with E₄/E₆ ratios (particle aggregation and molecular association) and free radical concentrations (chemical and biochemical activity). Significant correlations were found between physico-chemical parameters of the isolated humic fractions, i.e. M_n, M_w, E₄/E₆ ratios, spins/g contents and the dielectric constants of the solvents used. This suggested the efficiency of the applied procedure in isolating chemically different organic fractions from the bulk, original humic acid.     

The mass of the black hole in the X-ray binary M33 X-7 and the evolutionary status of M33 X-7 and IC 10 X-1

We have analyzed the observed radial-velocity curve for the X-ray binary M33 X-7 in a Roche model. We have analyzed the dependence between the component masses and the degree of filling of the optical star’s Roche lobe to obtain the ratio of the masses of the optical star and compact object. For the most probable mass of the optical star, m _v = 70 M⊙, the mass of the compact object is m _x = 15.55 ± 3.20 M⊙. It has been shown that black holes with masses of mx = 15 M⊙ and even higher can form in binaries. We present characteristic evolutionary tracks for binary systems passing through an evolutionary stage with properties similar to M33 X-7-type objects. According to population-synthesis analyses, such binaries should be present in galaxies with masses of at least 10¹¹ M⊙. The present number of such systems in M33 should be of the order of unity. We have also studied the evolutionary status of the X-ray binary IC 10 X-1 with a Wolf-Rayet component, which may contain a massive black hole. The final stages of the evolution of the M33 X-7 and IC 10 X-1 systems should be accompanied by the radiation of gravitational waves.     

Exploration potential of Cu isotope fractionation in porphyry copper deposits

We examined the copper isotope ratio of primary high temperature Cu-sulfides, secondary low temperature Cu-sulfides (and Cu-oxides) as well as Fe-oxides in the leach cap, which represent the weathered remains of a spectrum of Cu mineralization, from nine porphyry copper deposits. Copper isotope ratios are reported as δ⁶⁵Cu‰ = ((⁶⁵Cu/⁶³Cu_sample/⁶⁵Cu/⁶³Cu_{NIST 976 standard}) − 1) ? 10³. Errors for all the analyses are ± 0.14‰ (determined by multiple analyses of the samples) and mass bias was corrected through standard-sample-standard bracketing. The overall isotopic variability measured in these samples range from − 16.96‰ to 9.98‰.