Granulite facies metasomatism: zoned calc-silicate boudins from the Rauer Group,East Antarctica

Calc-silicate boudins from the Rauer Group, East Antarctica, were metamorphosed under granulite facies conditions during late Proterozoic (ca. 1,000 Ma) M3 metamorphism. Boudin cores contain low to moderate a_{CO 2} assemblages including wollastonite, grossularandradite (grandite) garnet, clinopyroxene, scapolite, plagioclase, quartz±calcite. Petrological and stable isotopic evidence suggests that these core assemblages resulted from pre-peak M3 infiltration of water-rich fluids; there is no evidence for a pervasive fluid phase under peak M3 conditions. The boudins are separated from the surrounding Fe-rich pelites and semi-pelites by a series of concentric, high-variance reaction zones developed under peak M3 conditions. Variations in mineral assemblage, mineral composition and whole rock composition across these zones suggest that they formed by diffusional masstransfer, controlled principally by a chemical potential gradient in Ca across the original calc-silicate-paragneiss lithological boundary. As a consequence of the nearcomplete decarbonation of the calc-silicatesbefore the M3 peak, development of the diffusion-controlled reaction zones did not liberate significant CO₂ during granulite facies metamorphism. Similar calcite-poor, low a_{CO 2} calc-silicate horizons in other granulite facies terrains are unlikely to have been important local fluid sources during deep crustal metamorphism.     

Geomorphology and glacial history of Rauer Group, East Antarctica

The presence of glacial sediments across the Rauer Group indicates that the East Antarctic ice sheet formerly covered the entire archipelago and has since retreated at least 15 km from its maximum extent. The degree of weathering of these glacial sediments suggests that ice retreat from this maximum position occurred sometime during the latter half of the last glacial cycle. Following this phase of retreat, the ice sheet margin has not expanded more than ∼ 1 km seaward of its present position. This pattern of ice sheet change matches that recorded in Vestfold Hills, providing further evidence that the diminutive Marine Isotope Stage 2 ice sheet advance in the nearby Larsemann Hills may have been influenced by local factors rather than a regional ice-sheet response to climate and sea-level change.     

东南极茹尔群岛超高温麻粒岩的研究进展

茹尔群岛(又称赖于尔群岛)位于东南极普里兹构造带的东部边缘,是一个由太古宙和中元古代岩石组成的复合高级变质地体。中元古代岩石是含有富Fe-Al的含石榴子石-矽线石的费拉副片麻岩组合,经历了格林维尔和泛非两期变质作用。太古宙正片麻岩是含有富Mg-Al的含假蓝宝石的超高温泥质麻粒岩组合(梅瑟副片麻岩组合),主要由经历超高温变质作用的含假蓝宝石的泥质麻粒岩、富Mg的石榴子石-矽线石泥质片麻岩、斜方辉石-矽线石石英岩、含石榴子石镁铁质麻粒岩和钙硅酸盐麻粒岩等组成。其中,含假蓝宝石泥质麻粒岩中石榴子石变斑晶和矽线石集合体(蓝晶石假象)周围分别发育峰期后由假蓝宝石+斜方辉石和假蓝宝石+堇青石后成合晶组成的典型减压结构。含石榴子石镁铁质麻粒岩中石榴子石变斑晶周围则发育峰期后由斜方辉石+斜长石后成合晶组成的典型白眼圈减压结构。不同研究者得出了具有不同超高温峰期条件、峰期前及峰期后演化历史、不同形式的顺时针变质P-T轨迹。对超高温变质事件发生的时间和构造背景的认识也存在较大分歧,有认为超高温变质事件发生于格林维尔期(~1000 Ma)并与碰撞造山和弧岩浆作用有关,也有研究认为发生于泛非期(~590 Ma或~530 Ma)并与普里兹造山及冈瓦纳大陆聚合有关。因此,为理清该区超高温麻粒岩的变质演化历史和构造背景,需要对其进一步进行详细深入的矿物组合-变质结构分析、P-T轨迹重建及高精度的锆石-独居石U-Pb年代学研究,并进行区域上对比。     

Pressure–temperature evolution of metapelitic granulites in a polymetamorphic terrane: the Rauer Group, East Antarctica

Distinctive lithological associations and geological relationships, and initial geochronological results indicate the presence of an areally extensive region of reworked Archaean basement containing polymetamorphic granulites in the Rauer Group, East Antarctica.
Structurally early metapelites from within this reworked region preserve complex and varied metamorphic histories which largely pre-date and bear no relation to a Late Proterozoic metamorphism generally recognized in this part of East Antarctica. In particular, magnesian metapelite rafts from Long Point record extreme peak P–T conditions of 10–12 kbar and 100–1050°C, and an initial decompression to 8 kbar at temperatures of greater than 900°C. Initial garnet–orthopyroxene–sillimanite assemblages contain the most magnesian (and pyrope-rich) garnets ( X _Mg= 0.71) yet found in granulite facies rocks. A high-temperature decompressional P–T history is consistent with reaction textures in which the phase assemblages produced through garnet breakdown vary systematically with the initial garnet X _Mg composition, reflecting the intersection of different divariant reactions in rocks of varied composition as pressures decreased. This history is thought to relate to Archaean events, whereas a lower-temperature ( c. 750–800°C) decompression to 5 kbar reflects Late Proterozoic reworking of these relict assemblages.
The major Late Proterozoic ( c. 1000 Ma) granulite facies metamorphism is recorded in a suite of younger Fe-rich metapelites and associated paragneisses in which syn- to post-deformational decompression, through 2–4 kbar from maximum recorded P–T conditions of 7–9 kbar and 800–850°C, is constrained by geothermobarometry and reaction textures. This P–T evolution is thought to reflect rapid tectonic collapse of crust previously thickened through collision.     

Stable isotopic signatures of superposed fluid events in granulite facies marbles of the Rauer Group, East Antarctica

The role of volatiles in the stabilization of the lower (granulite facies) crust is contentious. Opposing models invoke infiltration of CO₂-rich fluids or generally vapour-absent conditions during granulite facies metamorphism. Stable isotope and petrological studies of granulite facies metacarbonates can provide constraints on these models. In this study data are presented from metre-scale forsteritic marble boudins within Archaean intermediate to felsic orthogneisses from the Rauer Group, East Antarctica. Forsteritic marble layers and associated calcsilicates preserve a range of ¹³C- and ¹⁸O-depleted calcite isotope values (δ¹³C= -9.9 to -3.0% PDB, δ¹⁸O = 4.0 to 12.1% SMOW). A coupled trend of ¹³C and ¹⁸O depletion (～2%, ～5%, respectively) from core to rim across one marble layer is inconsistent with pervasive CO₂ infiltration during granulite facies metamorphism, but does indicate localized fluid-rock interaction. At another locality, more pervasive fluid infiltration has resulted in calcite having uniformly low, carbonatite-like δ¹⁸O and δ¹³C values. A favoured mechanism for the low δ¹⁸O and δ¹³C values of the marbles is infiltration by fluids that were derived from, or equilibrated with, a magmatic source. It is likely that this fluid-rock interaction occurred prior to high-grade metamorphism; other fluid-rock histories are not, however, ruled out by the available data. Coupled trends of ¹³C and ¹⁸O depletion are modified to even lower values by the superposed development of small-scale metasomatic reaction zones between marbles and internally folded mafic (?) interlayers. The timing of development of these layers is uncertain, but may be related to Archaean high-temperature (>1000d?C) granulite facies metamorphism.     

New constraints on metamorphism in the Rauer Group, Prydz Bay, east Antarctica

Abstract Granulite facies metapelites of the Mather and Filla Paragneisses within the Rauer Group, east Antarctica, possess markedly different compositions. The metamorphic evolution of the two metapelite types has been interpreted as temporally distinct, with the Rauer Group preserving at least two distinct granulite facies tectonothermal episodes. Calculated P–T pseudosections and orthopyroxene Al content indicate the revised maximum‐preserved P–T conditions within the Mather Paragneiss to lie in the vicinity of 950–975 °C and 10–10.6 kbar, less extreme than previous estimates. The range of possible P–T paths for the Mather Paragneiss consistent with mineral textural relationships and pseudosections contoured for mineral proportion are significantly shallower (dP/dT) than previous estimates. A near‐isothermal decompression P–T path, and extreme peak metamorphic conditions, are not necessary to explain the development of preserved mineral reaction textures. The Filla Paragneiss contains pelitic assemblages less amenable to rigorous quantitative analysis. Nevertheless, possibilities for the shared or otherwise metamorphic evolution of the Mather and Filla Paragneisses may be postulated on the basis of calculated pseudosections in the context of existing geochronology for the Rauer Group and preserved microstructures. A shared evolution, most likely during Pan‐African granulite facies metamorphism, is plausible and consistent with mineral assemblage development, geochronology and microstructures. A revised interpretation of the Rauer Group's preserved metamorphic evolution may warrant the revision of existing tectonic models, applicable also to the remainder of Prydz Bay. More generally, the employed approach may incite a revision of peak P–T and P–T paths in other granulite facies terranes.     

东南极茹尔群岛梅瑟半岛富铁铝副片麻岩超高温变质作用：相平衡模拟与锆石U-Pb年龄

东南极梅瑟半岛出露大量的副片麻岩。本文以岩相学和矿物化学为基础,结合相平衡模拟、地质温度计及年代学分析方法对费拉副片麻岩中的含尖晶石榴夕线石片麻岩和梅瑟副片麻岩中的含堇青石榴夕线石片麻岩进行综合研究,结果显示片麻岩经历了超高温(UHT)麻粒岩相变质作用。两个样品峰期前阶段(M1)进变质条件为600~650℃和0.63~0.85GPa;峰期UHT阶段(M2)变质条件为930~1000℃和0.9~1GPa;峰期后变质重结晶阶段(M3)变质条件为610~780℃和0.3~0.39GPa。三个不同阶段的变质条件定义了一致的顺时针的P-T演化轨迹。锆石U-Pb年龄分析结果表明两个片麻岩样品的超高温变质和相关的深熔作用发生在990~920Ma期间的早新元古代格林威尔期,而流体改造与变质重结晶作用发生在~510Ma的早古生代泛非期。结合区域地质特征,超高温变质作用发生的构造背景可能与以放射性元素衰变为热源的大型热碰撞造山带相关。

     

Proterozoic Granulites from the Rauer Group, East Antarctica. I. Decompressional Pressure-Temperature Paths Deduced from Mafic and Felsic Gneisses

Granulites from the Rauer Group, East Antarctica, were metamorphosedat 860?40?C during a high-grade tectonothermal episode youngerthan 1400 Ma and probably close to 1000 Ma in age. A spatialvariation of pressures of metamorphism at the thermal peak iscalculated for felsic and mafic granulites preserving garnet-orthopyroxene-plagioclaseassemblages with or without additional clinopyroxene and quartz.Pressures of 6 to 7.5 kb are derived for the northern partsof the Rauer Group, whereas 7–8?5 kb pressures are calculatedfor similar granulites some 10–20 km further south. Post-deformational reaction textures including orthopyroxene-plagioclasesymplectites after garnet in basic granulites and plagioclasemoats or rims on garnet and orthopyroxene in felsic granulitesindicate a decompressional pressure-temperature-time evolution(P-T-t) which is confirmed by garnet-orthopyroxene-plagioclase-quartzand garnet-orthopyroxene barometry of zoned and regrown minerals.A pervasive decompression through c. 2 to 3–5 kb in thenorthern Rauer Group and to 5–6 kb in the southern partof the region occurred at temperatures above 700?C and probablyin excess of 750?C. This P-T evolution, which indicates a uniformunroofing of some 6–9 km while quite high mid- to lower-crustaltemperatures only decreased by c. 100?C, is consistent withthe later stages of a prolonged collision-related thermal evolution.Comparisons of the P-T-t paths of the late Proterozoic granulitesfrom the Rauer Group and elsewhere in East Antarctica with calculatedP-T paths for simple collisional models where erosion terminatesthe heating phase show that externally- derived magmatic additionsand an enhanced total heat budget are necessary to produce theobserved high-temperature evolution.     

东南极格罗夫山泛非期麻粒岩相变质作用

东南极格罗夫山主要由麻粒岩相高级变质岩和花岗岩类组成，其中变质岩以浅色和暗色含斜方辉石长英质片麻岩占主导地位，夹有少量镁铁质麻粒岩、变沉积岩和含方柱石钙硅酸盐岩。这些岩石一般都展示了平衡的矿物共生结构，但在镁铁质麻粒岩的单斜辉石中普遍发育斜方辉石(易变辉石)的出溶片晶。根据出溶辉石的重组分析获得麻粒岩相变质作用的峰期温度约为850℃，而浅色片麻岩中的石榴子石—斜方辉石—斜长石—石英组合给出的变质压力为0．61～0．67GPa。镁铁质麻粒岩中火成亚钙质普通辉石斑晶的保存表明格罗夫山地区可能只发育单一的泛非期高温麻粒岩相变质事件，岩石在高温变质之后经历了缓慢冷却过程，这主要归因于花岗质岩浆的板底垫托作用。     

No significant ice-sheet expansion beyond present ice margins during the past 4500 yr at Rauer Group, East Antarctica

The history of glacial advances and retreats of the East Antarctic ice sheet during the Holocene is not well-known, due to limited field evidence in both the marine and terrestrial realm. A 257-cm-long sediment core was recovered from a marine inlet in the Rauer Group, East Antarctica, 1.8 km in front of the present ice-sheet margin. Radiocarbon dating and lithological characteristics reveal that the core comprises a complete marine record since 4500 yr. A significant ice-sheet expansion beyond present ice margins therefore did not occur during this period.     

(Th+U)-Pb monazite ages from Al-Mg-rich metapelites,Rauer Group,east Antarctica

The age of high-temperature granulite-facies metamorphism (>~800–850 °C) in the Rauer Group, Prydz Bay, east Antarctica, is relevant for establishing the metamorphic and temporal architecture of the Prydz Bay mobile belt. Monazites within Al-Mg-rich granulite-facies metapelites give an overall tanh-estimated Pan-African age of ~511±4 Ma (2) using in-situ electron microprobe-based (Th+U)-Pb chronology, consistent with existing U-Pb zircon geochronology from the Rauer Group and Prydz Bay. Monazite occurs primarily within cordierite-bearing coronae and symplectic mineral reaction textures, and also within biotite. Pan-African granulite-facies metamorphism is preferred as responsible for the development of the cordierite-bearing microstructures, and probably (peak) coarse-grained assemblages, constrained using an integrated geologic, geochronologic and metamorphic framework. Thus, Pan-African granulite-facies metamorphism affected the Rauer Group, within the Prydz Bay mobile belt. Moreover, integrated monazite geochronology may be used to decipher the temporal metamorphic histories of potentially complex high-temperature terrains.Electronic Supplementary Material Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.Editorial responsibility: B. Collins     

Experimental Constraints on the Thermal Peak of a Granulite from McIntyre Island, Enderby Land, East Antarctica

High-pressure experiments have been carried out at 11-22 kbar and 900-1200°C using a piston cylinder apparatus to constrain the thermal peak condition of a granulite characterized by the mineral assemblage of orthopyroxene+sillimanite+quartz from McIntyre Island, Enderby Land, East Antarctica. The bulk composition of the starting material is 85 wt.% McIntyre granulite+15 wt.% sillimanite. At 11 kbar, orthopyroxene, sillimanite and quartz are stable below 1000°C. At 1050°C sillimanite does not appear, and sapphirine coexists with orthopyroxene and quartz. These experimental results indicate that the McIntyre granulite has undergone the ultra high-temperature metamorphism at 1000-1050°C represented by the diagnostic mineral assemblage of orthopyroxene, sillimanite and quartz.     

Mineral Assemblages as Indicators of the Maturity of Oceanic Hydrothermal Sulfide Mounds

The composition of ore minerals in MAR sulfide occurrences related to ultramafic rocks was studied using methods of mineragraphy, electron microscopy, microprobe analysis, and X-ray analysis. The objects are located at various levels of the maturity of sulfide mounds owing to differences in age, duration, and degree of activity of the following hydrothermal systems: generally inactive Logatchev-1 field (up to 66.5 ka old), inactive Logatchev-2 field (3.9 ka), and generally active Rainbow field (up to 23 ka). Relative to MAR submarine ore occurrences in the basalt substrate, mineralization in the hydrothermal fields mentioned above is characterized by high contents of Au, Cd, Co, and Ni, along with the presence of accessory minerals of Co and Ni. The studied mounds differ in quantitative ratios of major minerals and structural-textural features of ores that suggest their transformation. Ores in the Logatchev-1 field are characterized by the highest Cu content and the development of a wide range of multistage contrast exsolution structures of isocubanite and bornite. In the Logatchev-2 field, sphalerite-chalcopyrite and gold-arsenic exsolution structures are present, but isocubanite exsolution structures are less diverse and contrast. The Rainbow field is marked by the presence of homogenous isocubanite and the subordinate development of exsolution structures. We have identified four new phases in the Cu-Fe-S system. Phases X and Y (close to chalcopyrite and isocubanite, respectively) make up lamellae among isocubanite exsolution products in Logatchev-1 and Logatchev-2. Phase Y includes homogenous zones in zonal chimneys of the Rainbow field. Phases A and B are formed in the orange bornite domain at low-temperature alteration of chalcopyrite in the Logatchev-1 field. Mineral assemblages of the Cu-S system are most abundant and diverse in the Logatchev-1 field, but their development is minimal in the Logatchev-2 field where mainly Cu-poor sulfides of the geerite-covellite series have been identified. Specific features of mineral assemblages mentioned above reflect the maturity grade of sulfide mounds and can serve as indicators of maturity.__________Translated from Litologiya i Poleznye Iskopaemye, No. 4, 2005, pp. 339–367.Original Russian Text Copyright © 2005 by Mozgova, Borodaev, Gablina, Cherkashev, Stepanova.     

东南极拉斯曼丘陵麻粒岩相岩石中早期残留矿物组合的特征及其变质作用条件

东南极拉斯曼丘陵出露的麻粒岩相泥质片麻岩和镁铁质麻粒岩经历了复杂的变形变质历史。代表前进的增厚事件的早期残留变质构造Ｄ１形成于１０００Ｍａ（Ｇｒｅｎｖｉｌｉａｎ）期间。对应于Ｄ１的变质峰期Ｍ１的变质组合以泥质片麻岩的石榴石和尖晶石变斑晶中的堇青石和夕线石包裹体以及镁铁质麻粒岩的石榴石变斑晶中的斜方辉石和斜长石包裹体为特征。在该区斯托尼斯半岛的紫苏黑云石英岩的粗粒紫苏辉石中发现了包裹的假蓝宝石＋磁铁矿和假蓝宝石＋尖晶石＋夕线石＋磁铁矿＋石英组合,这种假蓝宝石又包裹更细粒的尖晶石包裹体。石榴石－斜方辉石温度计及石榴石－斜方辉石－斜长石－石英压力计的计算表明Ｍ１变质作用最大的Ｐ－Ｔ条件为０．９５ＧＰａ和８７０℃。这些早期残留的矿物组合指示了其变质作用具有逆时针近等压冷却（ＩＢＣ）的Ｐ－Ｔ演化特征,反映了它们的形成是一个埋深期间前进加热的进变质作用过程。本文得出该区Ｍ１（１０００Ｍａ）变质作用的逆时针（ＩＢＣ）Ｐ－Ｔ轨迹可能与已存在的大陆壳下面的岩浆底侵作用及地壳内大量岩浆物质的侵入和结晶作用有关。此类型逆时针Ｐ－Ｔ轨迹不同于该区在晚期５００Ｍａ（Ｐａｎ－Ａｆｒｉｃａｎ）期间顺时针演化的Ｐ－Ｔ轨迹     

The Age of Rift-Related Basalts in East Antarctica

The Lambert Rift, which is a large intracontinental rift zone in East Antarctica, developed over a long period of geological time, beginning from the Late Paleozoic, and its evolution was accompanied by magmatic activity. The latest manifestation of magmatism is eruption of alkaline olivine–leucite basalts on the western side of the Lambert Rift; Rb–Sr dating referred its time to the Middle Eocene, although its genesis remained vague. In order to solve this problem, we found geochronometer minerals in basaltic samples and 68 apatite grains appeared to be suitable for analysis. Their ages and ages of host basalts, determined by the U–Pb local method on the SIMS SHRIMP-II, were significantly different (323 ± 31 Ma) from those assumed earlier. This age corresponds to the earliest stage of crustal extension in East Antarctica and to most of Gondwana. The new data crucially change the ideas about the evolution of Lambert Rift and demonstrate the ambiguity of К–Ar dates of the alkali effusive formed under long-term rifting.     

Deep structure of the Vostok Basin,East Antarctica as deduced from seismological observations

Seismological observations using the earthquake converted-wave method were carried out from December 7, 2002 to January 23, 2003 (season 48 of the Russian Antarctic Expedition) in the southern part of Vostok Subglacial Lake for the purpose of studying the structure of the Earth’s crust. Three observation points were placed. One of them was located at the Vostok Station and the other two were located at distances of 8.7 and 12.02 km to the east and to the west of the station, respectively. The performed investigation showed that the thickness of the Earth’s crust in the studied area is 34–36 km. The crust is subdivided into three blocks of different ranks. The low-velocity block is situated immediately beneath the Vostok Basin. Seven interfaces of mode conversion were detected. The results obtained allow us to suggest an increase in heat flow in the Vostok Basin and to the east of this basin. The seismic layering of the ice cover is correlated with the results of radioecho sounding and the structure of the glacier documented in cores of 5G-1 Borehole. The interfaces within the glacier near the Vostok Station are located at depths of 700 ± 100 m, 1600 ± 100 m, and 2200 ± 100 m.     

Human impacts in Antarctica: trace-element geochemistry of freshwater lakes in the Larsemann Hills, East Antarctica

Fresh water lakes are found in basement rock basins in the Larsemann Hills, East Antarctica, during the summer months. These lakes constitute a relatively simple natural laboratory to investigate the effects of recent and well-documented anthropogenic impact on a “pristine” environment. Larsemann Hills freshwaters have extremely low salinity (typically <1‰), and contain very low concentrations of trace elements of environmental significance such as Pb, U, and Zn. Typical Pb concentrations range from less than 5 ppt to 250 ppt. Although trace metal concentrations appear to be higher in lakes situated in the vicinity of stations, they are consistently lower (by several orders of magnitude, for some elements) than Standard International Drinking Water Guidelines. The chemistry of the lake waters is dominated by sea-spray input. Consequently, it is primarily a function of geographical factors, such as distance from the shore and exposure to winds. Shallow-level groundwater and surface water also contribute to the lake chemistry. No evidence was found for contamination from global air circulation. Although contamination resulting from activities at the research stations is generally near or below detection levels, very low levels of trace metal anthropogenic contamination were found in the vicinity of some research stations. Received: 13 November 1998 · Revised: 23 March 1999 Accepted: 12 April 1999     

The Holocene fossil marine macrofauna of the Vestfold Hills, East Antarctica

The Holocene (< 10,000 years old) fossil marine macrofauna (molluscs, polychaetes, mammals and birds) of the Vestfold Hills, Antarctica (68°30'S, 78°00'E) is described. All species are extant, with circumantarctic or wider distributions and wide depth ranges. At Heidemann Bay, Pleistocene-age (> 30 ky old) shell fragments occur in a Holocene moraine. These are interpreted as being glacially reworked fossil shells. Holocene benthic estuarine and coastal molluses and serpulid worm tubes are abundant on the flanks of terraces above saline and hypersaline lakes. Extensive radiocarbon dating gives a chronology of these deposits which were not synchronous. Mummies of seals and penguins, which are concentrated on the shores of the saline lakes and scattered across the Hills, are of no use in dating geomorphological events. Marine fossils in moraines are difficult to interpret because they can be glacially-transported live or fossil shells, or deposited after wind transport. The fossil fauna has such a wide ecological range that it indicates only in general terms that for part of the Pleistocene and most of the Holocene, climatic conditions were broadly similar to the present.