放射性碳测年国际比对活动的初步结果

中国科学院地球环境研究所^14C实验室作为中国唯一的代表参加了第四届放射性碳测年国际比对活动(FIRI），取得了比较优异的成绩。初步分析了本届比对活动的测年结果，得出如下结论：不同的^14C测年方法对测年结果无明显的影响，不同现代碳标准的选择对大部分样品的测年结果有较明显的影响，而采用不同的本底物质仅对老年龄样品的定年有显著影响；加速器质诺测年法在各种^14C测年方法中最准确、精度最高，正逐渐成为国际^14C测年方法的主流。     

Pitfalls in the AMS radiocarbon-dating of terrestrial macrofossils

The AMS ¹⁴C technique has the advantage that small samples of Late Quaternary age can be dated with high accuracy, and that errors due to reservoir effects can be avoided if specifically determined terrestrial micro- and macrofossils are measured. However, to obtain such high-accuracy measurements, it is important how small samples are handled prior to treatment in the radiocarbon laboratories. Here we present a set of 51 AMS ¹⁴C measurements, of which 31 dates gave expected ages and 20 dates resulted in anomalously young ages, despite the fact that all samples consisted of clearly identified Late Weichselian terrestrial plant macrofossils. To evaluate possible sources of error, we compared these samples in respect to preparation methods, sample storage and sample weight. Our results show that the long-term storage of wet macrofossil samples appears to have a significant effect on the radiocarbon age obtained, even when the samples are kept cool. Fungi or micro-organisms may easily be incorporated into a sample during preparation and identification, and can easily contribute to the contamination of a sample, if stored cool and wet for several months. © 1998 John Wiley & Sons, Ltd.     

Combined dendrochronological and radiocarbon dating of six Russian icons from the 15th–17th centuries

The results of dendrochronological and radiocarbon dating by means of accelerator mass spectrometry (AMS) of six medieval icons, originating from northern European Russia and painted on wooden panels made from Scots pine, dated to the 15th to 17th centuries are presented. The panels of each icon were studied using dendrochronology. Five to six AMS dates were obtained for four icons. Although five icons were dendro-dated successfully, one failed to be reliably cross-dated with the existing master tree-ring chronologies and it was dated by radiocarbon wiggle-matching. Dendrochronological dating and wiggle-matching of radiocarbon dates allowed us to determine the narrow chronological intervals of icon creation.

     

Comparison of accelerator and radiometric radiocarbon measurements obtained from Late Devesian Lateglacial lake sediments from Llyn Gwernan, North Wales, UK

Accelerator mass spectrometry measures of the radiocarbon activity of various chemical fractions prepared from Late Devensian Lateglacial lake sediments from the site of Llyn Gwernan, near Cader Idris, North Wales are presented and assessed. These are compared with radiocarbon measurements obtained by radiometric (decay) counting which were reported earlier from the same site and are considered in the light of pollen-stratigraphic information. The potential advantages of accelerator radiocarbon measurements to the assessment of the chronology and correlation of Lateglacial lake sediments are evaluated.     

Direct comparison of UK temperatures and Greenland snow accumulation rates, 15000—12000 yr ago

A palaeotemperature record based on fossil coleopteran evidence and dated by accelerator mass spectroscopy (AMS) ¹⁴C determinations on plant macrofossils has been obtained for the last glacial-interglacial transition from the site of Gransmoor in eastern England. Calibration of the radiocarbon measurements enabled a direct comparison to be made between this palaeotemperature curve and the snow accumulation record from the GISP-2 Greenland ice-core. The similarity between the two data sets suggests a degree of correspondence in the pattern and timing of climatic change in Greenland and the British Isles at the end of the last cold stage.     

“Mind the gap”: Caves,radiocarbon sequences,and the Mesolithic–Neolithic transition in Europe—lessons from the Mala Triglavca rockshelter site

Radiocarbon sequences from some northern Mediterranean cave sites show a temporal gap between Mesolithic and Neolithic occupations. Some authors regard this as a regional phenomenon and have sought to explain it in terms of a general population decline in the late Mesolithic, which facilitated the replacement of indigenous foragers by immigrant farmers. New evidence from the rockshelter site of Mala Triglavca, in Slovenia, leads us to question this view. We describe the deposits in the rockshelter and discuss the results of AMS radiocarbon dating of bone samples recovered in excavations in the 1980s. New archaeological investigations and associated soil/sediment analyses show that in the central part of the rockshelter a well‐defined stratigraphic sequence can be established, despite post‐depositional modification by soil forming processes. There is also evidence of substantial post‐depositional disturbance of the cave sediments by human agency and geomorphological processes, which have created “temporal gaps” and “inversions” in the radiocarbon sequence. The relatively large series of radiocarbon dates obtained enables some of the post‐depositional processes to be identified. © 2008 Wiley Periodicals, Inc.     

北京大学AMS 14 C 国际比对样品测量*

介绍了北京大学加速器质谱(AMS)实验室参加国际原子能机构 (IAEA) 组织的第五届¹⁴ C国际比对样品测量的过程和结果,包括样品制备、小型¹⁴ C测量加速器质谱计装置和比对测量结果的统计分析等。北京大学的测量结果与IAEA加权统计平均值的偏差在1σ之内, 这一结果较客观地体现了我国¹⁴ C AMS年代测定在国际同类实验室中所处的地位。     

New radiocarbon age constraints for the 120 km-long Toomba flow,north Queensland,Australia

The Toomba flow is the youngest flow of the Nulla volcanic province, located in north Queensland. This 120?km-long flow has yielded a published ⁴⁰Ar/³⁹Ar age of 21,000?±?3000 years. In contrast, seven published conventional radiocarbon (¹⁴C) analyses of carbon-bearing material beneath the flow yielded radiocarbon ages of 16,000 to <2500?BP. These radiocarbon ages are younger than the ⁴⁰Ar/³⁹Ar age, potentially due to contamination of the charcoal by younger carbon that was not removed by the acid–base pre-treatment. We have re-examined the radiocarbon age of Toomba flow using newly sampled charcoal buried beneath the Toomba flow in combination with hydrogen pyrolysis pre-treatment and accelerated mass spectrometer (AMS) measurements. We determined a calibrated radiocarbon age of 20,815–19,726?cal BP (2σ) for the material beneath the Toomba flow. Our radiocarbon age, therefore: (1) is older than previous radiocarbon ages for the Toomba flow, (2) provides the most precise age yet available for the Toomba flow, (3) is in agreement with the ⁴⁰Ar/³⁹Ar age, and (4) validates that hydrogen pyrolysis is a robust and effective pre-treatment method, for subtropical conditions where samples are susceptible to contamination by younger carbon. The Toomba flow erupted during the Last Glacial Maximum, but the preserved surface suggests that the rate of weathering and soil formation has been almost negligible in this region, despite being situated in a subtropical climate that experiences highly variable often intense rainfall.     

Reinvestigation of the classic late‐glacial Bølling Sø sequence,Denmark: chronology,macrofossils, Cladocera and chydorid ephippia

The late‐glacial Bølling period was first identified by Johs. Iversen on the basis of pollen results from Lake Bølling Sø in Denmark. Because there were no radiocarbon dates from the sequence the Bølling Chronozone (12 000–13 000 ¹⁴C yr BP) was later established on the basis of dates from other sites. A new project is reinvestigating the sediments from the Bølling Sø sequence with AMS radiocarbon dating and multiproxy analyses. Here we present results of AMS radiocarbon dating, macrofossil analyses, cladoceran analyses (Cladocera concentrations and chydorid ephippia) and Pediastrum analyses (concentrations). The AMS dates on land plant remains show that the lower part of the sequence is around 12 500 ¹⁴C yr BP, and thus clearly pre‐dates the Allerød chronozone. However, construction of a chronology for the sequence was problematic, partly because of reworking of macroscopic plant remains. The climate ameliorated after glacial conditions to such an extent that growth of plants could begin at ca. 12 500 ¹⁴C yr BP, but the results of multiproxy analyses show little evidence for a further warming period during the pre‐Allerød part of the sequence. Lake productivity was low, and tree birch rare or maybe absent. This may reflect widespread occurrence of dead ice, unstable soils, heavy in‐wash of minerogenic matter to the lake, resulting in turbid water and rapid sedimentation. The early pioneer vegetation was characterised by Salix polaris and Dryas octopetala, and by herbs. The Allerød Chronozone, and especially its initial part, appears to have been relatively warm but reduced cladoceran concentrations and increased proportion of chydorid ephippia suggest that climate cooled in the middle Allerød and that the late Allerød was colder than the early part. The early Younger Dryas was probably colder than the late Younger Dryas. Clear warming is apparent at the beginning of the Holocene, where the first macrofossil evidence of trees (Betula pubescens, Populus tremula) is found. Copyright © 2004 John Wiley & Sons, Ltd.     

Holocene peat growth and decay dynamics in sub-arctic peat plateaus, west-central Canada

Peat and net carbon accumulation rates in two sub-arctic peat plateaus of west-central Canada have been studied through geochemical analyses and accelerator mass spectrometry (AMS) radiocarbon dating. The peatland sites started to develop around 6600–5900 cal. yr BP and the peat plateau stages are characterized by Sphagnum fuscum peat alternating with rootlet layers. The long-term peat and net carbon accumulation rates for both profiles are 0.30–0.31 mm/yr and 12.5–12.7 gC/m²yr, respectively. These values reflect very slow peat accumulation (0.04–0.09 mm/yr) and net carbon accumulation (3.7–5.2 gC/m²yr) in the top rootlet layers. Extensive AMS radiocarbon dating of one profile shows that accumulation rates are variable depending on peat plateau stage. Peat accumulation rates are up to six times higher and net carbon accumulation rates up to four times higher in S. fuscum than in rootlet stages. Local fires represented by charcoal remains in some of the rootlet layers result in very low accumulation rates. High C/N ratios throughout most of the peat profiles suggest low degrees of decomposition due to stable permafrost conditions. Hence, original peat accretion has remained largely unaltered, except in the initial stages of peatland development when permafrost was not yet present.     

Modelling relationship between bulk susceptibility and AMS in rocks consisting of two magnetic fractions represented by ferromagnetic and paramagnetic minerals — Implications for understanding magnetic fabrics in deformed rocks

Measurement of Anisotropy of Magnetic Susceptibility (AMS) has become an important tool for Structural Geological analysis in the past few decades. In the past, AMS data have been used for petrofabric analysis of deformed rocks as well as for gauging strain. However, the AMS of some rocks can be carried by both ferromagnetic and paramagnetic minerals. Separating effects of these mineral groups on the rock’s AMS is difficult because of expensive and commercially less available instrumentation. On the other hand, instrumentation is available in most rock magnetic and palaeomagnetic laboratories for resolving bulk susceptibility into ferromagnetic and paramagnetic components. Mathematical modelling was made of the relationship between bulk susceptibility and AMS. If the contribution of the ferromagnetic or the paramagnetic fraction to the rock susceptibility is dominant (let us say higher than 80%), the resultant AMS is relatively near to the AMS of the dominating fraction in all aspects, the degree of AMS, shape parameter and orientation of principal susceptibilities. In the interpretation of the AMS of rocks with dominating one fraction, the resolution of the AMS into paramagnetic and ferromagnetic components is not necessary, the resolution of bulk susceptibility into components is sufficient that can be made using the instrumentation available in most rock magnetic and palaeomagnetic laboratories.     

Late Neanderthals at Jarama VI (central Iberia)?

Previous geochronological and archaeological studies on the rock shelter Jarama VI suggested a late survival of Neanderthals in central Iberia and the presence of lithic assemblages of Early Upper Paleolithic affinity. New data on granulometry, mineralogical composition, geochemical fingerprints and micromorphology of the sequence corroborate the previous notion that the archaeological units JVI.2.1 to JVI.2.3 are slackwater deposits of superfloods, which did not experience significant post-depositional changes, whereas the artifact-rich units JVI.3 and JVI.1 mainly received sediment inputs by sheetwash and cave spall. New AMS radiocarbon measurements on three samples of cut-marked bone using the ultrafiltration technique yielded ages close to, or beyond, the limit of radiocarbon dating at ca. 50 ¹⁴C ka BP, and hence suggest much higher antiquity than assumed previously. Furthermore, elevated temperature post-IR IRSL luminescence measurements on K feldspars yielded burial ages for subunits JVI.2.2 and JVI.2.3 between 50 and 60 ka. Finally, our reappraisal of the stone industry strongly suggests that the whole sequence is of Mousterian affinity. In conclusion, Jarama VI most probably does not document a late survival of Neanderthals nor an Early Upper Paleolithic occupation in central Iberia, but rather indicates an occupation breakdown after the Middle Paleolithic.     

Quaternary and Holocene coastal uplift in Ikaria Island,Aegean Sea

Abstract

Geomorphological, biological and AMS radiocarbon dating provide evidence of an about lm high elevated palaeo-shoreline at the NE coast of Ikaria Island,Aegean Sea, and to a seismic uplift which occurred after AD950-1150 and was probably responsible for damage in an ancient tower. These data are important for several reasons. They provide evidence for a strong earthquake in an island usually assumed aseismic, coastal uplifts and coastal fauna are scarce in this region, while the Late Holocene uplift correlates with a flight of marine terraces of probably Quaternary age, at least up to 40m high. Long-term uplift is not observed at the footwall of a fault bounding a major graben north of Ikaria, it represents a structural puzzle and it may help to shed some light to the evolution of various extensional terranes.     

天然放射性碳同位素在海洋有机地球化学中的应用

天然放射性碳（¹⁴C）是年代测定的有效手段，它在考古学和地质学的应用已有几十年的历史。过去10年中，伴随着加速器质谱仪（AMS）技术和检测灵敏度的提高，AMS已经能够检测少于mg C量级样品中自然丰度水平的¹⁴C，这大大扩展了¹⁴ C在自然科学，特别是地球科学研究中的应用范畴。简要评述了利用天然¹⁴ C进行海洋地球化学研究的应用，重点介绍了前景广阔、并已取得显著成果的应用领域。     

The magnitude of error in conventional bulk-sediment radiocarbon dates from central North America

Although the carbon-reservoir problem with bulk-sediment radiocarbon dates from lakes has long been recognized, many synoptic studies continue to use chronologies derived from such dates. For four sites in central North America, we evaluate chronologies based on conventional radiocarbon dates from bulk sediment versus chronologies based on accelerator mass spectrometry (AMS) radiocarbon dates from terrestrial plant macrofossils. The carbon-reservoir error varies among sites and temporally at individual sites from 0 to 8000 yr. An error of 500–2000 yr is common. This error has important implications for the resolution of precise event chronologies.     

A high‐resolution record of mire development and climatic change spanning the Late‐glacial–Holocene boundary at Church Moss,Davenham (Cheshire,England)

Excavations of deposits filling a closed basin within glacial drift at Church Moss, Davenham, near Northwich (Cheshire, England) revealed a sequence of Late‐glacial and Early Holocene sediments. Analyses of pollen and plant and invertebrate macrofossils were undertaken, together with loss‐on‐ignition analyses and a programme of AMS radiocarbon dating, to provide a record of changing biostratigraphy and climatic and ecological regimes. The infilling of features identified as frost‐cracks in the till flooring the basin gave remains that reflected conditions of extreme cold towards the end of the Devensian. The pollen record from a 3.5 m sequence of peat towards the deepest part of the basin, supported by radiocarbon dates, shows that organic deposition was initiated during the Late‐glacial Interstadial and continued into the early part of the Holocene. There was some evidence for a cool episode during the interstadial, with amelioration prior to the rapid onset of the tundra conditions of the Loch Lomond Stadial. Following the stadial, amelioration was rapid. There was evidence from both central and marginal sequences for a mosaic of fen dominated by sedges and often also mosses, with short‐lived small pools through much of the succession. Change to terrestrial conditions proceeded intermittently, probably as a result of subsidence caused by solution of underlying salt‐bearing strata. Copyright © 2000 John Wiley & Sons, Ltd.     

天然放射性碳年代测定(二)

本报告公布的系1975年至1976年用乙炔（C₂H₂）气体计数法和1977年底用液体闪烁计数法测定的部分地质样品年代数据。另外,为了验证液体闪烁计数法的可靠性,用液体闪烁计数法又测定了湖南长沙马王堆两个考古样品,在此也再次公布测定结果。     

Late Pleistocene giant short-faced bears, mammoths, and large carcass scavenging in the Saltville Valley of Virginia, USA

The Saltville Valley of southwestern Virginia contains an abundance of extinct Late Pleistocene megafauna. Recent excavations in the valley produced two particularly notable discoveries, the remains of a scavenged mammoth ( Mammuthus sp.) and a giant short-faced bear ( Arctodus simus ). The bear is the first carnivoran record from Saltville, and its large dental dimensions, dentary proportions, and exceptionally short-face, evince an exceedingly powerful bite for this individual. Mammoth remains are relatively abundant from Saltville, but the material described here preserves extreme examples of scavenging by carnivores. Based on comparisons with the feeding behavior and bone alteration patterns of extant hyenas, cats, wolves, and bears, we conclude that at least two types of large carnivorans scavenged this mammoth carcass. AMS radiocarbon dates of 14 510 ± 55 ¹⁴C yr BP on the Mammuthus and 14 853 ± 55 ¹⁴C yr BP on the A. simus demonstrate that they are nearly the same age. Very few direct radiocarbon dates on A. simus have been reported from the contiguous United States. The Saltville A. simus represents the most eastern date for the species, as well as the only date from the Appalachian Highlands.     

An 800-year long, radiocarbon-dated varve chronology from south-eastern Sweden

More than 50 varve-thickness diagrams, which were established from glacial varved clays in south-eastern Sweden were correlated with each other to form an 800-year long floating varve chronology. AMS |214|0C measurements on terrestrial macrofossils from the varved clays enabled synchronization of the record with other high-resolution archives. The synchronization indicates that the chronology spans between c. 13 150 and c. 12 350 calendar years BP and covers the later part of the Allerørd and the early part of the Younger Dryas. Calibrated radiocarbon dates, which were obtained on varved clays south of the floating chronology, indicate that the ice recession in south-eastern Sweden may have started during late Bølling. Our results indicate a longer time-span in varve years for the deglaciation than has been previously estimated     

湖泊沉积物的14 C和光释光测年* ——以固城湖为例

富含有机质的湖泊沉积物被认为是¹⁴ C测年建立古环境记录年代标尺的理想材料,光释光测年方法近年开始应用于水成沉积物的定年。应用¹⁴ C和光释光两种方法对江苏固城湖湖心钻孔岩芯进行了年龄测定,结果表明全样有机质的¹⁴ C年龄与石英的光释光年龄存在系统差异,后者较前者年轻约2000年。系统光释光测年研究排除了光释光年龄低估的可能性,所以,二者的差异可能是湖泊沉积物碳库效应的反映。