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1.
A detailed analysis of dissolved organic carbon (DOC) distribution in the Western Arctic Ocean was performed during the spring and summer of 2002 and the summer of 2003. DOC concentrations were compared between the three cruises and with previously reported Arctic work. Concentrations of DOC were highest in the surface water where they also showed the highest degree of variability spatially, seasonally, and annually. Over the Canada Basin, DOC concentrations in the main water masses were: (1) surface layer (71±4 μM, ranging from 50 to 90 μM); (2) Bering Sea winter water (66±2 μM, ranging from 58 to 75 μM); (3) halocline layer (63±3 μM, ranging from 59 to 68 μM), (4) Atlantic layer (53±2 μM, ranging from 48 to 57 μM), and (5) deep Arctic layer (47±1 μM, ranging from 45 to 50 μM). In the upper 200 m, DOC concentrations were correlated with salinity, with higher DOC concentrations present in less-saline waters. This correlation indicates the strong influence that fluvial input from the Mackenzie and Yukon Rivers had on the DOC system in the upper layer of the Chukchi Sea and Bering Strait. Over the deep basin, there appeared to be a relationship between DOC in the upper 10 m and the degree of sea-ice melt water present. We found that sea-ice melt water dilutes the DOC signal in the surface waters, which is contrary to studies conducted in the central Arctic Ocean.  相似文献   

2.
北冰洋楚科奇海陆架到陆坡表层沉积物有机碳载荷的变化   总被引:2,自引:0,他引:2  
沉积物单位表面积上吸附的有机碳被广泛用于示踪有机碳载荷的变化。本文研究了北冰洋典型边缘海——楚科奇海表层沉积物的有机碳载荷。研究发现陆架区沉积物的有机碳载荷高于陆坡区。相比于已报道的东西伯利亚海和马更些河,楚科奇海陆坡区沉积物的有机碳载荷也较低。这种有机碳载荷的变化可能和陆坡区的初级生产力较低,以及沉积物在传输过程中经历的氧化降解有关。沉积物的有机碳含量和比表面积呈线性相关,在有机碳轴上有正截距,表明一部分有机碳来自于岩石的贡献。此外,陆架区低有机碳载荷的沉积物含有的岩石有机碳更高。本研究的数据有助于深刻理解楚科奇海区域的碳循环问题。  相似文献   

3.
Spectral light attenuation profiles and concentrations of total and dissolved carbon (C), nutrients and chlorophyll a (Chla) were studied along transects running from the river mouth to the Kara Sea during late summer 2003 for the Yenisey and fall 2005 for the Ob estuaries. Earth Observation data were used to generate composite images of water color and Chla distribution over the estuaries and the Kara Sea to reveal the spatial impact of the river efflux in terms of optical properties.  相似文献   

4.
Suspended matter (SM) and surface sediments were analysed for polycyclic aromatic hydrocarbons (PAH) throughout the Ob and Yenisei River estuaries and in the Kara Sea in order to evaluate the contamination of Arctic shelves by these two major Siberian rivers. PAH concentrations were extremely low, among the lowest measured up to now in the Arctic region. Particle-associated PAH were in many cases non-detectable. A total PAH maximum value of 3·2ngl − 1was found in surface waters. In surficial sediments, they spanned a range from 24 to 115ngg − 2in the Ob River, from 40 to 131ngg − 2in the Yenisei and from 16 to 94ngg − 2in the Kara Sea. Compositional features revealed a contribution of detrital material eroded from soils of the drainage basins and inputs from airborne pyrolytic PAH emitted at lower latitudes and from industrial complexes in Siberia. Particulate and sedimentary PAH distributions were highly variable both in type and concentration. The Ob and Yenisei estuaries are geographically large features where hydro-dynamical and sedimentary processes are complex. As a consequence, inhomogeneities—in the form of patch-structures—develop and make it difficult to resolve the fate of riverborne constituents based on ship measurements only. Remote sensing in conjunction with oceanographic observations may provide further guidance to study large river systems.  相似文献   

5.
As part of the Western Arctic Shelf–Basin Interactions (SBI) project, the production and fate of organic carbon and nitrogen from the Chukchi and Beaufort Sea shelves were investigated during spring (5 May–15 June) and summer (15 July–25 August) cruises in 2002. Seasonal observations of suspended particulate organic carbon (POC) and nitrogen (PON) and large-particle (>53 μm) size class suggest that there was a large accumulation of carbon (C) and nitrogen (N) between spring and summer in the surface mixed layer due to high phytoplankton productivity. Considerable organic matter appeared to be transported from the shelf into the Arctic Ocean basin in an elevated POC and PON layer at the top of the upper halocline. Seasonal changes in the molar carbon:nitrogen (C:N) ratio of the suspended particulate organic matter (POM) pool reflect a change in the quality of the organic material that was present and presumably being exported to the sediment and to Arctic Ocean waters adjacent to the Chukchi and Beaufort Sea shelves. In spring, low particulate C:N ratios (<6; i.e., N rich) were observed in nitrate-replete surface waters. By the summer, localized high particulate C:N ratios (>9; i.e., N-poor) were observed in nitrate-depleted surface waters. Low POC and inorganic nutrient concentrations observed in the surface layer suggest that rates of primary, new and export production are low in the Canada Basin region of the Arctic Ocean.  相似文献   

6.
The coupling of upper ocean-benthic carbon dynamics in the ice-free western Arctic Ocean(the Chukchi Sea and the Canada Basin) was evaluated during the late July–early September 2003 using natural stable(13C) and radioactive(238U-234Th) isotope tracers. POC export flux estimated from 234Th/238 U disequilibria and dissolved CO2 concentration([CO2(aq)]) pointed out that the strengthened biological pump in the Chukchi Shelf have significantly lowered [CO2(aq)] and altered the magnitude of isotopic(12C/13C) fractionation during carbon fixation in the surface ocean. Further, d13 C signatures of surface sediments(d13Csed) are positively correlated to those of weighted d13 CPOC in upper ocean(d13Csed =13.64+1.56×d13CPOC, r2=0.73, p0.01), suggesting that the POC isotopic signals from upper ocean have been recorded in the sediments, partly due to the rapid export of particles as evidenced by low residence times of the highly particle-reactive 234 Th from the upper water column. It is suggested that there probably exists an upper ocean-benthic coupling of carbon dynamics, which likely assures the sedimentary d13 C record an indicator of paleo-CO2 in the western Arctic Ocean.  相似文献   

7.
The sea ice conditions in the Kara Sea have important impacts on Arctic shipping, oil and gas production, and marine environmental changes. In this study, sea ice coverage (CR) less than 30% is considered as open water, its onset and end dates are defined as Topen and Tclose, respectively. The sea ice melt onset (Tmelt) is defined as the date when ice-sea freshwater flux initially changes from ice into the ocean. Satellite-based sea ice concentration (SIC) from 1989 to 2019 shows a negative correlation between Topen and Tclose (r = –0.77, p < 0.01) in the Kara Sea. This phenomenon is also obtained through analyzing the hindcast simulation from 1994 to 2015 by a coupled ocean and sea-ice model (NAPA1/4). The model results reveal that thermodynamics dominate the sea ice variations, and ice basal melt is greater than the ice surface melt. Heat budget estimation suggests that the heat flux is significant correlated with Topen (r = –0.95, p < 0.01) during the melt period (the duration of multi-year averaged Tmelt to Topen) influenced by the sea ice conditions. Additionally, this heat flux is also suggested to dominate the interannual variation of the heat input during the whole heat absorption process (r = 0.81, p < 0.01). The more heat input during this process leads to later Tclose (r = 0.77, p < 0.01). This is the physical basis of the negative correlation between Topen and Tclose. Therefore, the duration of open water can be predicted by Topen and thence support earlier planning of marine activities.  相似文献   

8.
As part of the 2002 Western Arctic Shelf–Basin Interactions (SBI) project, spatio-temporal variability of dissolved inorganic carbon (DIC) was employed to determine rates of net community production (NCP) for the Chukchi and western Beaufort Sea shelf and slope, and Canada Basin of the Arctic Ocean. Seasonal and spatial distributions of DIC were characterized for all water masses (e.g., mixed layer, halocline waters, Atlantic layer, and deep Arctic Ocean) of the Chukchi Sea region during field investigations in spring (5 May–15 June 2002) and summer (15 July–25 August 2002). Between these periods, high rates of phytoplankton production resulted in large drawdown of inorganic nutrients and DIC in the Polar Mixed Layer (PML) and in the shallow depths of the Upper Halocline Layer (UHL). The highest rates of NCP (1000–2850 mg C m−2 d−1) occurred on the shelf in the Barrow Canyon region of the Chukchi Sea and east of Barrow in the western Beaufort Sea. A total NCP rate of 8.9–17.8×1012 g for the growing season was estimated for the eastern Chukchi Sea shelf and slope region. Very low inorganic nutrient concentrations and low rates of NCP (<15–25 mg C m−2 d−1) estimated for the mixed layer of the adjacent Arctic Ocean basin indicate that this area is perennially oligotrophic.  相似文献   

9.
南大洋浮游植物现存量对颗粒有机碳的贡献   总被引:5,自引:1,他引:5  
根据中国第15、16次南极考察观测的颗粒有机碳、叶绿素a浓度的数据,探讨浮游植物现存量对南大洋颗粒有机碳的贡献。结果表明,普里兹湾内浮游植物碳对颗粒有机碳的贡献高于湾北部的大洋区,真光层上部浮游植物碳对颗粒有机碳的贡献高于深层水。同时分析两个航次测区叶绿素a浓度和航程途中叶绿素a浓度的分布,以期了解浮游植物在南大洋颗粒有机碳来源中的作用。  相似文献   

10.
After a short introduction to the physical setting and the history of biological research the pelagic ecosystem of the Kara Sea is described. Main emphasis is on regional aspects of the plankton communities and their seasonal dynamics using mostly data collected between 1996 and 2001. In the zooplankton, for which most data were available, four regional aggregations were separated: (1) the rivers and estuaries of the Southern Kara Sea, (2) the south-western and (3) the central Kara Sea, and (4) the northern troughs and slope. The phytoplankton communities had a similar distribution. To provide components for detailed carbon budgets the regional dynamics of bacterial, phytoplankton and zooplankton biomass and production are described and carbon requirements of bacteria and zooplankton are estimated. For completeness a short literature review on higher trophic levels is included. Finally, recent observations of the pelago-benthic coupling are considered. Estimates of the carbon requirements from the plankton and benthos reveal a large underestimation of primary production, which to date, together with seasonal aspects, shows the largest gap in our knowledge.  相似文献   

11.
Incorporation of 14C-depleted (old) dissolved organic carbon (DOC) on/into particulate organic carbon (POC) has been suggested as a possible mechanism to explain the low Δ14C-POC values observed in the deep ocean [Druffel, E.R.M., Williams, P.M., 1990. Identification of a deep marine source of particulate organic carbon using bomb 14C. Nature, 347, 172–174.]. A shipboard incubation experiment was performed in the Sargasso Sea to test this hypothesis. Finely ground dried plankton was incubated in seawater samples from the deep Sargasso Sea, both with and without a biological poison (HgCl2). Changes in parameters such as biochemical composition and carbon isotopic signatures of bulk POC and its organic compound classes were examined to study the roles of sorptive processes and biotic activity on POC character. Following a 13-day incubation, the relative abundance of the acid-insoluble organic fraction increased. Abundances of extractable lipids and total hydrolyzable amino acids decreased for both treatments, but by a greater extent in the non-poisoned treatment. The Δ14C values of POC recovered from the non-poisoned treatment were significantly lower than the value of the unaltered plankton material used for the incubation, indicating incorporation of 14C-depleted carbon, most likely DOC. The old carbon was present only in the lipid and acid-insoluble fractions. These results are consistent with previous findings of old carbon dominating the same organic fractions of sinking POC from the deep Northeast Pacific [Hwang, J., Druffel, E.R.M., 2003. Lipid-like material as the source of the uncharacterized organic carbon in the ocean? Science, 299, 881–884.]. However, the Δ14C values of POC recovered from the poisoned treatment did not change as much as those from the non-poisoned treatment suggesting that biological processes were involved in the incorporation of DOC on/into POC.  相似文献   

12.
黄海、东海颗粒有机碳的分布特征及其影响因子分析   总被引:16,自引:4,他引:16  
分析研究了2001年春季黄海、东海颗粒有机碳(POC),结果表明POC的浓度为2~3815μg/dm3,其平面分布呈现近岸高、远岸低的特点.海水表层POC浓度与三磷酸腺苷(ATP)呈显著的正相关,这表明2001年真光层POC主要是海洋生物源.对不同海区POC垂直分布的影响因素做了探讨:长江口附近受总悬浮颗粒物浓度的影响,POC呈现表层低、底层高的特征;陆架区POC的垂直分布是生物活动与水文条件(海水混合、层化)等因素共同作用的结果;在离岸较远的深水区,影响POC垂直分布的主要因素是大洋海水的性质.由海区4个周日连续站的观测结果得知黄海区POC的周日变化主要受生物周日活动的影响,而在东海区POC周日变化除了受生物周日活动影响外,还分别受到潮汐作用以及海水水团周日变化等因素的影响.  相似文献   

13.
To examine the source and preservation of organic matter in the shelf sediments of the East China Sea (ECS), we measured bulk C/N and isotopes, organic biomarkers (n-alkanes and fatty acids) and compound-specific (fatty acids) stable carbon isotope ratios in three sediment cores collected from two sites near the Changjiang Estuary and one in the ECS shelf. Contrasting chemical and isotopic compositions of organic matter were observed between the estuarine and shelf sediments. The concentrations of total n-alkanes and fatty acids in the shelf surface sediments (0–2 cm) were 5–10 times higher than those in estuarine surface sediments but they all decreased rapidly to comparable levels below the surface layer. The compositions of n-alkanes in the estuarine sediments were dominated by C26-C33 long-chain n-alkanes with a strong odd-to-even carbon number predominance. In contrast, the composition of n-alkanes in the shelf sediment was dominated by nC15 to nC22 compounds. Long-chain (>C20) fatty acids (terrestrial biomarkers) accounted for a significantly higher fraction in the estuarine sediments compared to that in the shelf sediment, while short-chain (<C20) saturated and unsaturated fatty acids were more abundant in the shelf surface sediments than in the estuarine sediments. Stable carbon isotopic ratios of individual fatty acids showed a general positive shift from estuarine to shelf sediments, consistent with the variations in bulk δ 13CTOCTOC. These contrasts between the estuarine and shelf sediments indicate that terrestrial organic matter was mainly deposited within the Changjiang Estuary and inner shelf of ECS. Post-depositional diagenetic processes in the surface sediments rapidly altered the chemical compositions and control the preservation of organic matter in the region.  相似文献   

14.
Vertical profiles of dissolved organic carbon (DOC) from eight hydrological stations in the Tyrrhenian Sea, Sardinia Channel and Algerian Sea, are reported. DOC exhibits concentrations ranging from 58 to 88 μM in surface water, 43–57 μM in the intermediate layer and 49–63 μM in deep waters. The assessment of the hydrological characteristics allows different water masses in the study area to be identified; moreover, different hydrological processes are observed in the Tyrrhenian and Algerian basins. DOC exhibits different values in the different water masses. The lowest DOC concentrations (43–46 μM) were found in the Tyrrhenian Levantine Intermediate Water (LIW). Correlations between DOC and apparent oxygen utilization (AOU), investigated within each water mass, exhibit different behaviors in the intermediate and deep waters, suggesting the occurrence of different processes of oxygen consumption in the different water masses.  相似文献   

15.
Seasonal and spatial variations of particulate organic carbon (POC) flux were observed with sediment traps at three sites in the Japan Sea (western and eastern Japan Basin and Yamato Basin). In order to investigate the transport processes of POC, radiocarbon (14C) measurements were also carried out. Annual mean POC flux at 1 km depth was 30.7 mg m−2day−1 in the western Japan Basin, 12.0 mg m−2day−1 in the eastern Japan Basin and 23.8 mg m−2day−1 in the Yamato Basin. At all stations, notably higher POC flux was observed in spring (March–May), indicating biological production and rapid sinking of POC in this season. Sinking POC in the high flux season showed modern Δ14C values (>0‰) and aged POC (Δ14C < −40‰) was observed in winter (December–January). The Δ14C values in sinking POC were negatively correlated with aluminum concentration, indicating that Δ14C is strongly related to the lateral supply of lithogenic materials. The Δ14C values also showed correlations with excess manganese (Mnxs) concentrations in sinking particles. The Δ14C-Mnxs relationship suggested that (1) the majority of the aged POC was advected by bottom currents and incorporated into sinking particles, and (2) some of the aged POC might be supplied from the sea surface at the trap site as part of terrestrial POC. From the difference in the Δ14C-Mnxs relationships between the Japan Basin and the Yamato Basin, we consider that basin-scale transport processes of POC occur in the Japan Sea.  相似文献   

16.
Changes from winter (July) to summer (February) in mixed layer carbon tracers and nutrients measured in the sub-Antarctic zone (SAZ), south of Australia, were used to derive a seasonal carbon budget. The region showed a strong winter to summer decrease in dissolved inorganic carbon (DIC;  45 µmol/kg) and fugacity of carbon dioxide (fCO2;  25 µatm), and an increase in stable carbon isotopic composition of DIC (δ13CDIC;  0.5‰), based on data collected between November 1997 and July 1999.The observed mixed layer changes are due to a combination of ocean mixing, air–sea exchange of CO2, and biological carbon production and export. After correction for mixing, we find that DIC decreases by up to 42 ± 3 µmol/kg from winter (July) to summer (February), with δ13CDIC enriched by up to 0.45 ± 0.05‰ for the same period. The enrichment of δ13CDIC between winter and summer is due to the preferential uptake of 12CO2 by marine phytoplankton during photosynthesis. Biological processes dominate the seasonal carbon budget (≈ 80%), while air–sea exchange of CO2 (≈ 10%) and mixing (≈ 10%) have smaller effects. We found the seasonal amplitude of fCO2 to be about half that of a study undertaken during 1991–1995 [Metzl, N., Tilbrook, B. and Poisson, A., 1999. The annual fCO2 cycle and the air–sea CO2 flux in the sub-Antarctic Ocean. Tellus Series B—Chemical and Physical Meteorology, 51(4): 849–861.] for the same region, indicating that SAZ may undergo significant inter-annual variations in surface fCO2. The seasonal DIC depletion implies a minimum biological carbon export of 3400 mmol C/ m2 from July to February. A comparison with nutrient changes indicates that organic carbon export occurs close to Redfield values (ΔP:ΔN:ΔC = 1:16:119). Extrapolating our estimates to the circumpolar sub-Antarctic Ocean implies a minimum organic carbon export of 0.65 GtC from the July to February period, about 5–7% of estimates of global export flux. Our estimate for biological carbon export is an order of magnitude greater than anthropogenic CO2 uptake in the same region and suggests that changes in biological export in the region may have large implications for future CO2 uptake by the ocean.  相似文献   

17.
Analysis of high-resolution seismic reflection profiles and sediment samples has revealed the evolution and sediment budget of the southeastern Yellow Sea mud belt (SEYSM) along the southwestern Korean Peninsula. The SEYSM, up to 50 m thick, over 250 km long and 20–55 km wide, can be divided into three stratigraphic units (A1, A2, and B, from oldest to youngest). Unit A1, overlying the acoustic basement, comprises the northern part of the SEYSM. Unit A2 comprises the southern part of the SEYSM; much of unit A2 is exposed at the seafloor. Unit B completely covers unit A1 and pinches out southward.

14C data suggest that evolution of each unit is closely related to the postglacial sea-level changes. Unit A1 consists of estuarine/deltaic or shallow-water muds deposited during the early to middle stage of postglacial sea-level rise (ca. 14,000–7000 yr B.P.). Unit A2 corresponds to relict muds deposited during the last, deceleration stage of sea-level rise (ca. 7000–3.500 yr B.P.). Unit B consists of shelf muds deposited during the recent sea-level highstand (ca. <3500 yr B.P.).

Very low background activities of 210Pb of the surface sediment of unit A2 suggest that the present-day sediment accumulation is negligible in the southern SEYSM. On the other hand, 210Pb excess activity profiles in unit B yield an average sediment accumulation rate of 3.9 mm/yr, indicating active sediment accumulation in the northern SEYSM. The annual sink (3.0×107 tons/yr) of fine-grained sediment in unit B is about an order of magnitude greater than can be explained by the sediment input from the Korean rivers alone. We propose that reworking of unit A2 has provided large volumes of muds to unit B, resulting in excessive sediment accumulation in the northern SEYSM. Much of unit A2, in turn, is likely to have originated from erosion of unit A1 in the north. This rather unique erosional/depositional regime of the SEYSM is probably owing to the tidal and regional currents characteristic in the southeastern Yellow Sea.  相似文献   


18.
1 IntroductionThe carbon cycle in the ocean, related to theglobal warming and human food, is of great scientificsignificance. Studies for the carbon transfer and trans-formation in the ocean, including the assimilative andmetabolic capacity, have become one of key researchfoci in global biogeochemical studies (Tsunogai et al.,1997; Hu and Yang, 2001; Hansell et al., 2003; Wei etal., 2003; Yang et al., 2004; Yuan et al., 2004).As is known, POC is composed of living fractionsand organic debr…  相似文献   

19.
Four sources of surface heat flux (SHF) and the satellite remote sensing sea surface temperature (SST) data are combined to investigate the heat budget closure of the Huanghai Sea (HS) in winter. It is found that heat loss occurs all over the HS during winter and the area averaged heat content change decreases with a rate of -106 W/m2. Comparing with the area averaged SHF of -150 W/m-2 from the four SHF data sets, it can be concluded that the SHF plays a dominant role in the HS heat budget during winter. In contrast, the heat advection transported by the Huanghai Warm Current (Yellow Sea Warm Current, HWC) accounted for up to 29% of the HS heat content change. Close correlation, especially in February, between the storm events and the SST increase demonstrates that the HWC behaves strongly as a wind-driven compensation current.  相似文献   

20.
Modern (last 100 yr) accumulation rates of shelf mud deposits in the Yellow and East China Seas were investigated using the distribution of excess 210Pb (210Pbex) in sediment core samples. Compilation and merger of new and previously published data helped clarify sediment accumulation in these seas. The estimated accumulation rates, together with data of suspended sediment concentrations, provided findings on the sediment budget, origin, and transport pathway of the mud deposits. The overall accumulation distribution in the Yellow and East China Sea shelf revealed a general, cross-shelf decreasing trend along the sediment dispersal system away from the rivers, except for the South Sea (SSM) and southeastern Yellow Sea (SEYSM) mud patches found along the Korean coast. Notably, 210Pbex activity profiles within the SSM and the SEYSM yielded a relatively high accumulation rate of 2-5 mm/yr, implying a sedimentation rate of 4-15 × 107 tons per year in this coastal zone. Such an annual accumulation rate is about one order of magnitude greater than the total sediment discharge (6-20 × 106 tons/yr) from Korean rivers, suggesting an additional offshore source. The distribution pattern of the well-defined suspended plume clearly showed the possible transport and exchange of fine-grained sediments between the ECS shelf and the coastal area of Korea, especially during winter. Such a high accumulation in Korean coastal areas is attributable to the sediments supplied from the mud deposit of the ECS (i.e., SWCIM), with origins in Chinese rivers. Therefore, the Korean coastal area may be an important sink for some of Chinese river sediments being transported from the south by the Yellow Sea Warm Current.  相似文献   

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