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1.
Previous studies have shown that brines in an Ordovician paleokarst reservoir of the Lunnan oilfield in the Tarim Basin, China, are the product of mixing of paleo-evaporated seawater in the east with paleometeoric waters in the west. In order to put time constraints on the brine and related hydrocarbons in this field, 10 brine samples were collected, for which the iodine concentrations and 129I/I ratios were measured and discussed. The iodine concentration (3.70–31.2 mg/L) and the 129I/I ratio (189–897 × 10−15) show that the iodine in the paleoseawater and meteoric water (MW) had different origins and 129I characteristics. The paleoseawater has a high iodine content (∼31 mg/L), indicating that iodine was introduced into the reservoir along with thermally generated hydrocarbons, possibly in the Cretaceous, from the Caohu Sag in the eastern area. Based on consideration of all possible origins of iodine and 129I in the brines, it is suggested that the meteoric water maintained its initial iodine content (0.01 mg/L) and 129I/I ratio (1500 × 10−15), whereas the iodine-enriched paloseawater (IPSW) exhibited a secular 129I equilibrium (Nsq = 39 atom/μL) as a result of fissiogenic 129I input in the reservoir over a long period of time. The model of brine evolution developed on that basis confirmed that meteoric water entered the reservoir in the Miocene at about 10 Ma, and partially mixed with the iodine-enriched paleoseawater. The movement of meteoric water was facilitated by faults created during the Himalayan orogeny, then became more dense after dissolving Paleogene halite and infiltrated into the reservoir at high pressure. The iodine and 129I concentration in the brine contains information about the path and history of the fluid in the reservoir. This may be useful in oil exploration, since the movement of water was, to some extent, related to hydrocarbon migration.  相似文献   

2.
Soil and water samples were collected from farmsteads and provincial towns across the provinces of La Pampa and San Juan in Argentina. Inductively coupled plasma mass spectrometry was used for the determination of iodine in water following addition of TMAH to 1% v/v and soils extracted with 5% TMAH. Iodine in agricultural soils was in the range of 1.3–20.9 mg/kg in La Pampa located in central Argentina and 0.1–10.5 mg/kg in San Juan located in the northwest Andean region of Argentina, compared to a worldwide mean of 2.6 mg/kg. Mean selenium concentrations for soils from both provinces were 0.3 mg/kg, compared to a worldwide mean of 0.4 mg/kg. The majority of soils were slightly alkaline at pH 6.7 to 8.8. The organic content of soils in La Pampa was 2.5–5.9% and in San Juan 0.1–2.3%, whilst, mobile water extractable soil-iodine was 1–18% for La Pampa and 2–42% for San Juan. No simple relationship observed for pH and organic content, but mobile iodine (%) was highest when organic content was low, higher for lower total iodine concentrations and generally highest at pH > 7.5. Water drawn for drinking or irrigation of a variety of crops and pasture was found to range from 52 to 395 µg/L iodine and 0.8 to 21.3 µg/L selenium in La Pampa and 16–95 µg/L iodine and 0.6 to 8.2 µg/L selenium in San Juan. The water samples were all slightly alkaline between pH 8 and 10. Water–iodine concentrations were highest at pH 7.8 to 8.8 and in groundwaters positively correlated with conductivity. Raw water entering water treatment works in La Pampa was reduced in iodine content from approximately 50 µg/L in raw water to 1 µg/L in treated drinking water, similar to levels observed in regions experiencing iodine deficiency.  相似文献   

3.
Iodine enrichment in the Atacama Desert of northern Chile is widespread and varies significantly between reservoirs, including nitrate-rich “caliche” soils, supergene Cu deposits and marine sedimentary rocks. Recent studies have suggested that groundwater has played a key role in the remobilization, transport and deposition of iodine in Atacama over scales of millions-of-years. However, and considering that natural waters are also anomalously enriched in iodine in the region, the relative source contributions of iodine in the waters and its extent of mixing remain unconstrained. In this study we provide new halogen data and isotopic ratios of iodine (129I/I) in shallow seawater, rivers, salt lakes, cold and thermal spring water, rainwater and groundwater that help to constrain the relative influence of meteoric, marine and crustal sources in the Atacama waters. Iodine concentrations in surface and ground waters range between 0.35 μM and 26 μM in the Tarapacá region and between 0.25 μM and 48 μM in the Antofagasta region, and show strong enrichment when compared with seawater concentrations (I = ∼0.4 μM). In contrast, no bromine enrichment is detected (1.3–45.7 μM for Tarapacá and 1.7–87.4 μM for Antofagasta) relative to seawater (Br = ∼600 μM). These data, coupled to the high I/Cl and low Br/Cl ratios are indicative of an organic-rich sedimentary source (related with an “initial” fluid) that interacted with meteoric water to produce a mixed fluid, and preclude an exclusively seawater origin for iodine in Atacama natural waters. Iodine isotopic ratios (129I/I) are consistent with halogen chemistry and confirm that most of the iodine present in natural waters derives from a deep initial fluid source (i.e., groundwater which has interacted with Jurassic marine basement), with variable influence of at least one atmospheric or meteoric source. Samples with the lowest isotopic ratios (129I/I from ∼215 to ∼1000 × 10−15) strongly suggest mixing between the groundwater and iodine storage in organic-rich rocks (with variable influence of volcanic fluids) and pre-anthropogenic meteoric water, while samples with higher values (∼2000–93,700 × 10−15) indicate the input of anthropogenic meteoric fluid. Taking into account the geological, hydrologic and climatic features of the Atacama region, we propose that the mean contribution of anthropogenic 129I is associated with 129I releases during nuclear weapon tests carried out in the central Pacific Ocean until the mid 1990's (129I/I = ∼12,000 × 10−15). This source reflects rapid redistribution of this radioisotope on a global scale. Our results support the notion of a long-lived continental iodine cycle in the hyperarid margin of western South America, which is driven by local hydrological and climate conditions, and confirm that groundwater was a key agent for iodine remobilization and formation of the extensive iodine-rich soils of Atacama.  相似文献   

4.
Variation of the stable iodine supply was evaluated in the soils of around more than 700 settlements in the regions (oblasts) of Belarus and the Russian Federation contaminated after the Chernobyl accident. It involved the use of regional information on iodine content in different types of soil cover, biogeochemical criteria of iodine deficiency in food chains, and the available soil maps.  相似文献   

5.
Assessment of iodine concentration in blood and urine samples is one of the major strategies in knowing the iodine levels in goitre or iodine endemic patients. Sixty two (62) blood and urine samples were collected from fifty six (56) goitre and six (6) non-goitre patients within five (5) communities (Igbogila, Egua, Sawonjo, Imoto and UNAAB) in order to determine the levels or concentrations of iodine in the blood and urine of goitre and non-goitre patients within these communities using iodometric titration method. The results show that the mean blood and urine of the goitre patients in Igbogila community range from 14.2 to 14.7 μg/l and 15.7 to 16.8 μg/l respectively while the mean blood and urine iodine levels of the goitre patients in Egua community indicate iodine concentration in the range of 11.1–11.3 μg/l and 14.3–14.7 μg/l respectively. The mean blood and urine iodine concentration of the goitre patients in Sawonjo ranges from 13.4 to 13.7 μg/l and 17.2 to 17.8 μg/l and the mean blood and urine iodine levels in Imoto range from 11.1 to 13.4 μg/l and 13.1 to 15.8 μg/l. Similarly, the mean blood and urine of the non-goitre patients in the UNAAB community (the control area) range from 122.5 to 129.0 μg/l and 137.2 to 138.8 μg/l respectively. Comparison of the obtained levels of iodine in the blood and urine samples of the goitre and non-goitre patients with the WHO recommended iodine level of > 100 μg/l in the blood and urine of non-goitre patients indicates that the goitre patients in Igbogila, Egua, Sawonjo and Imoto were severely deficient in their blood and urine iodine levels while the blood and urine iodine levels of the people in the UNAAB community were found to be adequate (i.e. no indication of iodine deficiency).  相似文献   

6.
河西走廊疏勒河流域水资源管理问题分析   总被引:1,自引:0,他引:1  
从水资源管理体制、配置程序、市场化管理等方面探讨了河西走廊疏勒河流域水资源管理及存在的问题。目前流域已建成较健全的用水者协会体系,水价和水权在不断调整以适应水资源管理的需求。其管理存在以下问题:受地方行政、企业等多方权力博弈的影响,地表水和地下水处于双线管理状态,未能实现流域水资源的全面统一管理;用水者协会的职能未得到充分发挥,公众参与水资源管理不积极;流域内水价、水权制度不完善。建议如下:应在甘肃省水利厅和酒泉市政府之间形成协调机制,以协调各相关方的权益,完善流域管理局和地方政府统一协调的水资源管理体系,实现流域水资源的集成管理;加强流域机构立法,实现流域水资源的统一管理与调配;将协会的职责和义务融入到村委会的职务中,并完善水价制度,建立水权交易市场,以调动公众的自我管理和实现水资源的高效利用。  相似文献   

7.
A reconnaissance bulk geochemical study was carried out on ten samples from the Palaeoproterozoic Hotazel iron formation, South Africa, with emphasis on iodine and bromine abundances. Very low-absolute contents recorded for both halogens, i.e. 0.08–0.26 μg/g for I and 0.35–1.23 μg/g for Br, indicate that they should largely have been lost during burial diagenesis. Bulk I/Br ratios (0.08–0.50), however, show marginal variation across the selected sample set and broadly resemble those that typify recent marine sediments containing organic matter. The possibility emerges that both elements are organic matter-sourced and may thus provide a potential proxy for the role of biological processes during deposition and diagenesis of Precambrian iron formations.  相似文献   

8.
The distribution behavior of tellurium (Te) between soil and water in a synthetic soil-water system was studied coupled with the speciation of Te both in soil and water phases by using X-ray absorption fine structure (XAFS) spectroscopy and a high-performance liquid chromatography connected to an ICP-MS (HPLC-ICP-MS), respectively. The results were compared with a similar data set for Se, which was simultaneously obtained in this study. The oxidation states and host phases of Te and Se in the soil samples were given by XAFS, while the oxidation states in water were given by HPLC-ICP-MS. It was found that both Te and Se in soil are mainly associated with Fe(III) hydroxides under oxic conditions. From the EXAFS analyses, the outer-sphere complex is important for the Se(VI) sorbed on Fe(III) hydroxides in soils, while Se(IV), Te(IV), and Te(VI) form inner-sphere complexes. Under reducing condition, it was found that Te(0) and Se(0) species were formed and that Se was more readily reduced to Se(0) than Te, as is predicted from their Eh-pH diagrams. The reduction process from hexavalent to zerovalent species was different between Se and Te, that is, the direct reduction from Se(VI) to Se(0) was observed for Se, while Te was reduced stepwise from Te(VI) to Te(0) via Te(IV). In terms of the distribution between soil and water, Se distribution to water was much higher than that of Te under wide redox conditions. For Se, selenate is the predominant species in water even under reducing condition due to the much higher solubility of Se(VI) than Se(IV). Furthermore, a much smaller distribution of Te in water was primarily due to the larger affinities of Te(IV) and Te(VI) to Fe(III) hydroxides than Se(VI), which originates from the formation of the inner-sphere complexes of Te(IV) and Te(VI) to Fe(III) hydroxides.  相似文献   

9.
A study of tritium content and some physicochemical parameters has been performed in order to investigate interconnection between surface and atmospheric waters and underground waters in Belgrade area. Samples of the precipitation at Zeleno Brdo-Belgrade meteorological station, the Danube and the Sava river water, and underground water (Ranney wells and piezometers) have been analyzed. The3H content, the content of dissolved ions, total hardness, and electrical conductivity have been measured. The tritium data show existence of two water strata in the aquifer. The upper stratum (about 16 m thick) contains older water (mean monthly3H concentration of 17 TU) and has weak interaction with the river and the precipitation. Below this stratum lies the principal water bearing stratum, strongly connected with the river with the3H concentration similar to that of surface water (mean monthly3H concentration of 50 TU) and spreading out through the entire aquifer. The contribution of the Sava river water and the two water layers at the Ranney well are calculated starting with the hydrological aquifer model, which supposes that three water components are mixed in the pumped Ranney well water. According to calculation results using the3H concentration and physicochemical characteristics as parameters, more than 70 percent of the water pumped by the Ranney well (in 1983) comes from the Sava with a time delay of less that 15 days.Properties of tritium distribution in precipitation, river waters, and underground water in the Belgrade region are established from the results of measurements of3H concentrations in the period 1976–1983.  相似文献   

10.
黑河流域水环境演变及其驱动机制研究进展   总被引:10,自引:0,他引:10  
基于近几十年来诸多学者对西北干旱区典型内陆河流域——黑河流域水环境演变诸方面研究成果,综述了上游山区成水环境、中游绿洲用水环境和下游荒漠天然绿洲水成环境在不同时间尺度上的演变过程及其驱动机制。通过对各种古环境代用指标的对比研究表明:在大尺度上,流域上下游表现出阶段性的一致性水环境演变趋势;在小尺度上,则表现水环境演变的时空异质性。驱动机制方面,在空间上,流域上、中、下游水环境演变的气候变化和人类活动影响驱动作用各有侧重;在时间上,表现为不同尺度上气候变化与流域人类活动耦合作用的驱动机制。  相似文献   

11.
Observations of water surface elevation (WSE) and bathymetry of the lagoons and cenotes of the Yucatán Peninsula (YP) in southeast Mexico are of hydrogeological interest. Observations of WSE (orthometric water height above mean sea level, amsl) are required to inform hydrological models, to estimate hydraulic gradients and groundwater flow directions. Measurements of bathymetry and water depth (elevation of the water surface above the bed of the water body) improve current knowledge on how lagoons and cenotes connect through the complicated submerged cave systems and the diffuse flow in the rock matrix. A novel approach is described that uses unmanned aerial vehicles (UAVs) to monitor WSE and bathymetry of the inland water bodies on the YP. UAV-borne WSE observations were retrieved using a radar and a global navigation satellite system on-board a multi-copter platform. Water depth was measured using a tethered floating sonar controlled by the UAV. This sonar provides depth measurements also in deep and turbid water. Bathymetry (wet-bed elevation amsl) can be computed by subtracting water depth from WSE. Accuracy of the WSE measurements is better than 5–7 cm and accuracy of the water depth measurements is estimated to be ~3.8% of the actual water depth. The technology provided accurate measurements of WSE and bathymetry in both wetlands (lagoons) and cenotes. UAV-borne technology is shown to be a more flexible and lower cost alternative to manned aircrafts. UAVs allow monitoring of remote areas located in the jungle of the YP, which are difficult to access by human operators.  相似文献   

12.
第二松花江流域地表水与地下水相互关系   总被引:8,自引:0,他引:8       下载免费PDF全文
通过野外采样和室内分析,采用稳定氢氧同位素和水化学相结合的方法,研究了第二松花江地表水和地下水的相互关系。地表水和地下水中稳定氢氧同位素(δD,δ18O)空间差异明显,上游水体中同位素最贫化,下游最富集。水化学类型从长白山源区的Na-HCO3型,演化成Ca-Mg-HCO3型;而在人类活动的影响下,向Ca(Mg)-Cl(SO4)演化。运用端元法定量计算了地表水与地下水的相互转换比例,上游山区深层地下水接受江水和浅层地下水的补给,浅层地下水补给比例占50%左右;下游平原区浅层地下水补给江水,补给比例占20%左右。研究结果可为综合利用地表水和地下水、促进水资源的可持续利用提供理论基础。  相似文献   

13.
Water and poverty in the United States   总被引:1,自引:0,他引:1  
Contrary to reports of 100% access to safe water and sanitation in international surveys, the United States (US) has a complex landscape of low-income water problems. This paper begins with a critical international perspective on water and poverty in the US. It shows that the US had a declining role in international water programs during the late-20th century, which contributed to limited international awareness of low-income water programs in the US, and limited US awareness of low-income water issues. To address the first problem, we provide an overview of low-income water programs in the US with an emphasis on those that serve small communities. We then examine census data on inadequate water systems in Colorado, which indicate that severe plumbing deficiencies persist despite these public water programs. Inadequate plumbing rates are lower than income poverty rates, however, which indicate partially successful strategies for achieving low-income water services. Analysis of local data in urban, rural, and mountainous areas of the state shows that poverty and water problems are correlated in complex ways, which has implications for all nations striving for universal access to safe water and sanitation.  相似文献   

14.
干旱区植物水分来源的D、18O同位素示踪研究进展   总被引:2,自引:1,他引:1  
在干旱、半干旱地区,水是生态系统的主要限制因子,对植物水源的研究有助于指导干旱、半干旱地区的生态建设.在水分被根系吸收和从根系向叶片输送的过程中,其δ(D)、δ(18O)值一般不会发生变化.因此,水中天然δ(D)、δ(18O)值的分析为确定植物的水分来源提供了一种有效的途径:只要各潜在水源的稳定同位素组成具有显著差异,就可通过植物体内水的δ(D)、δ(18O)值和各潜在水源δ(D)、δ(18O)值的对比,定量确定植物对这些水源的吸收情况.但是,由于各潜在水源的不确定性和蒸发富集等因素的影响,该技术还存在一些不足.另外,隐性降水是干旱环境下植物的重要水源,但目前尚未开展隐性降水对植物补给作用的定量评价.利用稳定同位素技术定量评价干旱区植物隐性水源将是今后重要的研究方向.  相似文献   

15.
华北地区大气水汽含量特征及其变化趋势   总被引:13,自引:0,他引:13       下载免费PDF全文
使用美国国家环境保护委员会/国家大气研究中心(NCEP/NCAR)1948-2003年再分析格点资料,研究了华北地区大气中水汽含量的时空分布特征、沿375°N不同经度和沿115°E不同纬度大气中水汽含量的年变化、大气中水汽含量的变化趋势。分析结果表明:①华北地区大气中水汽含量主要集中在东部和南部,西部和北部水汽含量较少;②华北地区大气中水汽含量夏季最多,冬季最少;③华北地区大气中水汽含量自20世纪50年代末至80年代中期呈持续下降趋势。大气水汽含量高值期出现在20世纪40年代末至70年代中期。70年代中期至21世纪初期,大气水汽含量距平基本处于0线以下,为低值期;④华北地区大气水汽含量的年际波动变化与厄尔尼诺(ElNino)与南方涛动(ENSO)事件有很好的相关性。  相似文献   

16.
天然成因的高氟地下水是世界范围内备受关注的环境问题和饮用水安全问题。前人对高氟地下水的形成过程已开展了大量研究,但是对于高原盆地复杂水文地质条件下不同类型含水层组(第四系松散层含水层、基岩裂隙或岩溶含水层以及新生代古近纪以来的碎屑岩含水层)高氟地下水的分布和形成过程尚不明确。本文以化隆—循化盆地为研究区,通过采集、测试研究区内的各类地下水样品,分析研究区内不同类型含水层中地下水的化学特征及同位素特征。结果表明,高氟地下水(1.007.73 mg/L)主要分布在沿黄河的河谷区域和巴燕低山丘陵区域的泉水和潜水中以及深部的承压水中,在垂向上高氟地下水无明显分布规律。接受黄河水入渗补给的河谷潜水中氟离子浓度较低,补给黄河的河谷潜水中氟离子浓度较高。贫钙富钠的弱碱性苏打型水有利于地下水中氟的富集。泉水和潜水中氟主要来源于萤石的溶解,而承压水中氟除了来源于萤石外,还来源于其他含氟矿物。对于潜水和第四系松散层泉水,蒸发浓缩作用促进了地下水中氟的富集。另外,阴离子竞争吸附作用、阳离子交换吸附作用是泉水(第四系松散层泉水和基岩裂隙泉水)和潜水中氟元素富集的主要原因,而承压水中氟离子浓度受竞争吸附作用影响较大,阳离子交换吸附作用影响较小。研究成果可为化隆—循化盆地低氟地下水的勘查和开发提供科学依据。  相似文献   

17.
玛曲高原区地下水是黄河的重要补给水源,然而其水化学特征及形成机理认识还十分有限。通过采集玛曲潜水、河水和黄河河道沉积物,系统研究了玛曲高原区地下水水化学、同位素特征以及水文地球化学过程。结果表明:河水和潜水的溶解性总固体含量低,分别为72~195 mg/L和207~459 mg/L,水化学成分以Ca2+和HCO3-为主,水样中砷浓度为0.46~17.7μg/L。氢氧同位素结果表明,地下水和河水补给来源为当地大气降水,河水相对潜水富集δ18O和δD。河水水化学组成主要受蒸发浓缩作用的影响,而潜水主要受碳酸盐岩溶解作用的影响。潜水水样SI白云石小于0的占68%,表明潜水中白云石处于不饱和状态。某些潜水砷含量超标的原因可能是沉积物铁锰氧化物矿物的还原性溶解,而砷的来源可能是玛曲河道和浅层松散沉积物中吸附态砷。研究成果有助于揭示黄河上游玛曲段地下水的来源及地下水化学成分的形成机理。  相似文献   

18.
李凤林 《地球学报》1996,17(Z1):215-221
近些年来观察,渤海沿岸海蚀屡有增强,海滩变窄,浅滩、耕地缩小或消失,碉堡相继坠海,渔民被迫内迁,渔村被弃成废墟,临海村舍被冲,公路路基掏空,居民深感威胁之苦.据查证,主要是因修闸建库减少人海水沙,进而在海岸挖沙、毁堤等人为作用所致,但其根源却是干旱少雨之过.因此,防冶对策是:一节水、二改造污水、三增大重要复用水、四淡化和直用海水、五补给地下水、六要广泛植树造林增大人工降雨、七多向调水、八彻底改造黄河.以黄河为主干,构成多头、多尾、多腰的母亲河,形成全国水系联网,自行调节旱涝,化害为利,变化方干旱少雨为湿润多水,以便有更多的水沙人海,制止海蚀继续扩大.  相似文献   

19.
This article reviews and discusses environmental aspects related to vertical upward and downward groundwater flow. Flow systems are an important tool to understand groundwater functioning as related to the environment, in terms of obtaining indicators of human impact and solving specific questions about a groundwater-environment system that has been influenced by anthropogenic means. This involves two broad processes. First, groundwater changes due to activities of man in the surrounding environment as a result of: (1) alteration of recharge by modification of native vegetation and original soil cover; (2) reduction of groundwater discharge to coastal areas and to inland water bodies producing desiccation of wetlands, lakes and springs; (3) groundwater contamination from sewage looses and uncontrolled waste disposal locations, and (4) up-welling of undesirable water quality induced by extraction. Second, environmental alterations due to changes in the groundwater regime produce: (1) increase in soil erosion through the disappearance of vegetation due to water-table decline, (2) water-table rise due to unplanned artificial recharge resulting from water imports to a catchment, (3) decline in water levels for improper extraction regime, (4) soil subsidence due to extraction mismanagement, and (5) disappearance of phreatofites caused by excessive extraction. Unless further understanding between groundwater and the other components of the environment is sought, the relationship between people and its environment will be subject to some of these effects, potentially endangering adequate human development and sustainable water management.  相似文献   

20.
地幔转换带中的水及其地球动力学意义   总被引:3,自引:0,他引:3       下载免费PDF全文
综述了近20年国际上地幔转换带中水的研究进展。前人研究表明,地球深部的水主要以OH-(hy-droxyl)形式存储在名义上无水矿物(NAMs)中。高温高压实验研究表明,地幔转换带中的主要矿物均具有较高的储水能力,且在转换带的温压条件下,其储水能力随着温度的升高而降低,其中瓦兹利石(β-Ol)和林伍德石(γ-Ol)的储水能力为2%~3%,超硅石榴子石(Mj)的储水能力为0.1%左右,据此估算地幔转换带的储水能力约为1.2%~1.91%,是地表水总量的3.9~6.2倍;而转换带除外的上地幔和下地幔主要矿物的含水量或储水能力均小于0.1%,因此与上、下地幔相比,地幔转换带可能是地幔的主要储水库。尽管地幔转换带具有较强的储水能力,但对地幔转换带的实际含水量还存在干、湿两方面的地质和地球物理证据和争议。地幔转换带中的水会对转换带中一系列的过程产生重要影响,当水含量增加时,橄榄石(Ol)向β-Ol、γ-Ol分解以及超硅石榴石的分解反应分别向低压、高压和低压方向迁移,从而由橄榄石向β-Ol和γ-Ol分解两个相变反应界定的转换带宽度也会增加;水还会使地幔深部的部分熔融温度降低,熔体的密度降低;同时,水的加入可以很好地解释地幔岩"pyrolite"模型在410km不连续面处产生的与地震波测量不相符突变,也可以解决全地幔对流模式所不能解释的地幔成分分层问题。因此,深入研究和探讨转换带中的水对地球深部动力学过程的影响,包括中国东部地区受太平洋板块深俯冲作用的影响,均具有重要的约束和研究意义。  相似文献   

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