天然有机质及其在地表环境中的重要性

天然有机质是地表各种环境介质中的重要化学组分,分布广泛.越来越多的研究已经表明:它在地表生态系统的物理、化学和生物过程中都起着十分重要的作用;它与生态系统的各个重要环节密切相关,是生态系统中能量与物质循环的重要途径.因此,天然有机质不仅是生物地球化学、生态学和环境科学等研究领域的重要内容之一,而且也是环境污染的评价、预测和治理研究中的基础理论问题,是目前环境质量、毒理学、环境立法和管理研究共同关注的科学问题.本文主要以陆地地表淡水湖泊与河流水环境为例,对天然有机质的来源、化学结构、循环特征,与养分循环的耦合关系,对有毒金属元素和有机污染物迁移转化和毒性影响机理等几个方面的研究进展进行了简要的总结;针对我国水体富营养化和环境污染等重要环境问题,阐述当前应该采取的研究思路和存在的主要科学内容,并对现代有机环境与生物地球化学学科的研究趋势进行了展望.     

Model‐based evaluation of impact of soil redistribution on soil organic carbon stocks in a temperate hedgerow landscape

Agroforestry systems are promoted for providing a number of ecosystem services and environmental benefits, including soil protection and carbon sequestration. This study proposes a modelling approach to quantify the impact of soil redistribution on soil organic carbon (SOC) storage in a temperate hedgerow landscape. Evolution of SOC stocks at the landscape scale was examined by simulating vertical and horizontal SOC transfers in the 0–105 cm soil layer due to soil redistribution by tillage and water processes. A spatially explicit SOC dynamics model (adapted from RothC‐26.3) was used, coupled with a soil‐redistribution model (LandSoil). SOC dynamics were simulated over 90 years in an agricultural hedgerow landscape dedicated to dairy farming, with a mix of cropping and grasslands. Climate and land use were simulated considering business‐as‐usual scenarios derived from existing information on the study area. A net decrease in SOC stocks was predicted at the end of the simulation period. Soil redistribution induced a net SOC loss equivalent to 2 kg C ha^?1 yr^?1 because of soil exportation out of the study site and an increase in SOC mineralization. Hedgerows and woods were the only land use in which soil redistribution induced net SOC storage. Soil tillage was the main process that induced soil redistribution within cultivated fields. Soil exportation out of the study area was due to erosion by water, but remained low because of the protective role of the hedgerow network. These soil transfers redistributed SOC stocks in the landscape, mostly within cultivated fields. Copyright © 2016 John Wiley & Sons, Ltd.     

River network travel time is correlated with dissolved organic matter composition in rivers of the contiguous United States

Most terrestrial allochthonous organic matter enters river networks through headwater streams during high flow events. In headwaters, allochthonous inputs are substantial and variable, but become less important in streams and rivers with larger watersheds. As allochthonous dissolved organic matter (DOM) moves downstream, the proportion of less aromatic organic matter with autochthonous characteristics increases. How environmental factors converge to control this transformation of DOM at a continental scale is less certain. We hypothesized that the amount of time water has spent travelling through surface waters of inland systems (streams, rivers, lakes, and reservoirs) is correlated to DOM composition. To test this hypothesis, we used established river network scaling relationships to predict relative river network flow-weighted travel time (FWTT) of water for 60 stream and river sites across the contiguous United States (3090 discrete samples over 10 water years). We estimated lentic contribution to travel times with upstream in-network lake and reservoir volume. DOM composition was quantified using ultraviolet and visible absorption and fluorescence spectroscopy. A combination of FWTT and lake and reservoir volume was the best overall predictor of DOM composition among models that also incorporated discharge, specific discharge, watershed area, and upstream channel length. DOM spectral slope ratio (R² = 0.77) and Freshness Index (R² = 0.78) increased and specific ultraviolet absorbance at 254 nm (R² = 0.68) and Humification Index (R² = 0.44) decreased across sites as a function of FWTT and upstream lake volume. This indicates autochthonous-like DOM becomes continually more dominant in waters with greater FWTT. We assert that river FWTT can be used as a metric of the continuum of DOM composition from headwaters to rivers. The nature of the changes to DOM composition detected suggest this continuum is driven by a combination of photo-oxidation, biological processes, hydrologically varying terrestrial subsidies, and aged groundwater inputs.     

Short term fluctuations in dissolved organic matter concentrations in streamflow draining a forested watershed and their relation to the catchment budget

Dissolved organic matter (DOM) concentrations in throughfall, throughflow, and runoff were recorded in a small (95 ha) woodland catchment in North Warwickshire for a period of eight weeks following a prolonged dry spell. DOM is shown to be positively related to stream discharge over the sampling period, although distinctive flushing effects were identified. The net contribution of DOM to total dissolved solids load carried in the river was only 2.4 per cent, and represented significantly less than published carbon losses by mineralization of soil organic matter. Throughfall inputs were some 100 times higher than streamflow outputs from the catchment.     

Erodibility of soil and organic matter: independence of organic matter resistance to interrill erosion

The enrichment of organic matter in interrill sediment is well documented; however, the respective roles of soil organic matter (SOM) and interrill erosion processes for the enrichment are unclear. In this study, organic matter content of sediment generated on two silts with almost identical textures, but different organic matter contents and aggregations, was tested. Artificial rainfall was applied to the soils in wet, dry and crusted initial conditions to determine the effects of soil moisture and rainfall and drying history on organic matter enrichment in interrill sediment. While erosional response of the soils varied significantly, organic matter enrichment of sediment was not sensitive to initial soil conditions. However, enrichment was higher on the silt with a lower organic matter content and lower interrill erodibility. The results show that enrichment of organic matter in interrill sediment is not directly related to either SOM content or soil interrill erodibility, but is dominated by interrill erosion processes. As a consequence of the complex interaction between soil, organic matter and interrill erosion processes, erodibility of organic matter should be treated as a separate variable in erosion models. Further research on aggregate breakdown, in particular the content and fate of the organic matter in the soil fragments, is required. Copyright © 2007 John Wiley & Sons, Ltd.     

On the use of loss‐on‐ignition techniques to quantify fluvial particulate organic carbon

The fluvial flux of carbon (C) from terrestrial to marine environments represents an important component of the global C‐cycle, which can transfer C from the atmosphere to sedimentary storage. Fluvial fluxes of C are also an essential resource for freshwater ecosystems, critical for habitat heterogeneity and function. As such it is crucial that we are able to quantify this flux accurately. However, at present there are a number of different techniques used to quantify concentrations of fluvial C, and these techniques vary in their accuracy. In this article, we compare particulate organic carbon (POC) measurements derived from two commonly‐used techniques; a simple combustion and loss‐on‐ignition (LOI) technique, and an oxidative–combustion and carbon dioxide (CO₂) detection technique. The techniques were applied to water samples collected from 10 contrasting reference‐condition, temperate river ecosystems. The POC measurements derived from the LOI technique were up to 16 times higher (average four times higher), than those derived from the oxidative–combustion and CO₂ detection technique. This difference was highly variable both across the different river ecosystems and within each river ecosystem over time, suggesting that there is no simple way of converting the mass measured by LOI to estimates of fluvial POC. It is suggested that the difference in POC measured by these two techniques is a consequence of: (1) the loss of inorganic carbon at LOI combustion temperatures of > 425 °C, (2) the potential during the LOI combustion stage to lose hygroscopic and intercrystalline water, not completely driven off by the drying stage at temperatures of < 150 °C, and (3) the variable C content of fluvial organic matter, meaning that the simple application of a fixed correction factor to values obtained from the LOI technique may not be appropriate. These findings suggest that oxidative–combustion and CO₂ detection techniques are preferential for quantifying fluvial POC. Copyright © 2013 John Wiley & Sons, Ltd.     

Export of fine particulate organic carbon from redwood‐dominated catchments

Recently, researchers have recognized the significant role of small mountainous river systems in the transport of carbon from terrestrial environments to the ocean, and the scale of such studies have ranged from channel bed units to continents. In temperate zones, these mountain river systems commonly drain catchments that are largely forested. However, the magnitude of carbon export from rivers draining old‐growth redwood forests has not been evaluated to date. Old‐growth redwood stands support some of the largest quantities of biomass in the world, up to 350 000 Mg of stem biomass km^‐2 and soil organic carbon can reach 46 800 Mg km^‐2. In north coastal California, suspended sediment samples were collected at three gaging stations for two to four years on streams draining old‐growth redwood forests. Carbon content, determined through loss‐on‐ignition tests, was strongly correlated with turbidity, and continuous turbidity records from the gaging stations were used to estimate annual carbon exports of 1 · 6 to 4 · 2 Mg km^‐2 yr^‐1. These values, representing 13 to 33% of the suspended sediment load, are some of the highest percentages reported in the global literature. The fraction of organic carbon as part of the suspended sediment load decreased with discharge, but reached an asymptote of 5 to 10% at flows 10 to 20 times the mean annual flows. Although larger rivers in this region exhibit high sediment yields (up to 3600 Mg km^‐2 yr^‐1), mainly attributed to high rates of uplift, mass movement, and timber harvest, the small pristine streams in this study have sediment yields of only 8 to 100 Mg km^‐2 yr^‐1. Because the current extent of old‐growth redwood stands is less than 5% of its pre‐European‐settlement distribution, the present organic carbon signature in suspended sediment loads in this region is likely different from that in the early 20th century. Published 2015. This article is a U.S. Government work and is in the public domain in the USA.     

The effects of soil organic matter on soil water retention and plant water use in a meadow of the Sierra Nevada,CA

Tuolumne Meadows is a groundwater dependent ecosystem in the Sierra Nevada of California, USA, that is threatened by hydrologic impacts that may lead to a substantial loss of organic matter in the soil. In order to provide a scientific basis for management of this type of ecosystem, this paper quantifies the effect of soil organic content on soil water retention and water use by plants. First, we show a substantial dependence of soil water retention on soil organic content by correlating Van Genuchten soil water retention parameters with soil organic content, independent of soil texture. Then, we demonstrate the impact of organic content on plants by simulating the degree to which root water uptake is affected by soil water retention with the use of a physically based numerical model of variably saturated groundwater flow. Our results indicate that the increased water retention by soil organic matter contributes as much as 8.8 cm to transpiration, or 35 additional water‐stress free days, during the dry summer when plants experience increased water stress.     

Erosion,deposition, and the persistence of soil organic matter: mechanistic considerations and problems with terminology

The effect of erosional detachment, transport, and deposition of topsoil on the stock of soil organic matter (SOM) and its association with soil minerals has been a focus of a growing number of studies. A particularly lively debate is currently centered on the questions of whether terrestrial sedimentation of previously eroded SOM may constitute a relevant sink for atmospheric carbon dioxide (CO₂), and how ‘stable’ such carbon (C) might be on multidecadal timescales. In this commentary, we illustrate how redistribution of eroded SOM within a landscape can create situations that are not adequately described by the jargon commonly used to characterize C turnover dynamics. We argue that more quantitative and scientifically rigorous categories are needed to describe soil C turnover and to promote the development of innovative, numerical models of C dynamics in landscapes characterized by significant mass movement. Copyright © 2013 John Wiley & Sons, Ltd.     

Spatial and temporal variation in particle size and particulate organic matter content in suspended particulate matter from peatland‐dominated catchments in Finland

Properties of suspended particulate matter play a vital role in transport processes, but information from boreal lowland river systems with high organic loads is limited. This study analysed data from 2 years of sampling at 30 locations in Finland (204 samples in total) using suspended particulate matter samplers to determine effective and absolute particle size and organic fractions. Mean d₅₀ value was 22 and 49 µm for absolute and effective particle size, respectively. The organic fraction content ranged from 2.1% to 36% (mean 9.6%), highlighting the importance of particle organic matter for suspended particulate matter flux in the region. The results indicated that the suspended particulate matter particle size distribution and load in the study region is dominated by composite particles. There were considerable spatial and temporal variations in transport of organic fractions, effective particle size and degree of aggregation (range 1.5–93%). Headwaters and, in particular, late summer and spring flood conditions with flow peaks produced the largest composite particles, whereas agriculture‐dominated sites produced smaller but more tightly compacted particles. Organic plant fibres appeared to play a vital role in floc formation in peat‐covered catchments, whereas in agriculture‐dominated catchments, land use‐derived aggregates dominated the composition. This study provides empirical evidence of the importance of effective particle size measurement in understanding the dynamics of suspended particulate matters in boreal lowland river systems. Copyright © 2014 John Wiley & Sons, Ltd.     

Hydroclimatic controls on dissolved organic matter (DOM) characteristics and implications for trace metal transport in Hwangryong River Watershed,Korea, during a summer monsoon period

Frequent heavy rainfalls during the East Asian summer monsoon drastically increase water flow and chemical loadings to surface waters. A solid understanding of hydroclimatic controls on watershed biogeochemical processes is crucial for water quality control during the monsoon period. We investigated spatio‐temporal variations in the concentrations and spectroscopic properties of dissolved organic matter (DOM) and the concentrations of trace metals in Hwangryong River, Korea, during a summer period from the relatively dry month of June through the following months with heavy rainfall. DOM and its spectroscopic properties differed spatially along the river, and also depended on storm and flow characteristics around each sampling time. At a headwater stream draining a forested watershed, the concentrations (measured as dissolved organic carbon (DOC)), aromaticity (measured as specific UV absorbance at 254 nm), and fulvic acid‐ and protein‐like fluorescence of DOM were higher in stormflow than in baseflow waters. DOC concentrations and fluorescence intensities increased along the downstream rural and urban sites, in which DOC and fluorescence were not higher in stormflow waters, except for the ‘first flush’ at the urban site. The response of DOM in reservoir waters to monsoon rainfalls differed from that of stream and river waters, as illustrated by storm‐induced increases in DOM aromaticity and fulvic‐like fluorescence, and no significant changes in protein‐like fluorescence. The results suggest that surface water DOM and its spectroscopic properties differentially respond to changes in hydroclimatic conditions, depending on watershed characteristics and the influence of anthropogenic organic matter loadings. DOC concentrations and intensities of spectroscopic parameters were positively correlated with some of the measured trace metals (As, Co, and Fe). Further research will be needed to obtain a better understanding of climate effects on the interaction between DOM and trace metals. Copyright © 2006 John Wiley & Sons, Ltd.     

Effect of water table drawdown on peatland dissolved organic carbon export and dynamics

Peatlands play an important role in the global carbon cycle, and loss of dissolved organic carbon (DOC) has been shown to be important for peatland carbon budgets. The objective of this study was to determine how net production and export of DOC from a northern peatland may be affected by disturbance such as drainage and climate change. The study was conducted at a poor fen containing several pool–ridge complexes: (1) control site–no water table manipulation; (2) experimental site–monitored for one season in a natural state and then subjected to a water table drawdown for 3 years; (3) drained site–subjected to a water table drawdown 9 years prior to monitoring. The DOC concentration was measured in pore water along a microtopographic gradient at each site (hummock, lawn and hollow), in standing water in pools, and in discharge from the experimental and drained sites. The initial water table drawdown released ～3 g of carbon per square metre in the form of DOC, providing a large pulse of DOC to downstream ecosystems. This value, however, represents only 1–9% of ecosystem respiration at this site. Seasonal losses of DOC following drainage were 8–11 g of carbon per square metre, representing ～17% of the total carbon exchange at the experimental study site. Immediately following water table drawdown, DOC concentrations were elevated in pore water and open water pools. In subsequent seasons, DOC concentration in the pool declined, but remained higher than the control site even 11 years after water‐table drawdown. This suggests continued elevated net DOC production under lower water table conditions likely related to an increase in vegetation biomass and larger water table fluctuations at the experimental and drained sites. However, the increase in concentration was limited to initially wet microforms (lawns and hollows) reflecting differences in vegetation community changes, water table and soil subsidence along the microtopographic gradient. Copyright © 2008 John Wiley & Sons, Ltd and Her Majesty the Queen in right of Canada.     

Thermal stability of soil organic carbon subjected to water erosion as a function of edaphic factors

The stability of soil organic carbon （SOC）,as it relates to resistance to decomposition,is important for greenhouse gas emission and climate change.However,the SOC stabilization and its related influencing factors subjected to water erosion remain uncertain.The objective of the current study was to determine the SOC stability under long-term water erosion and to investigate the link between SOC stability and edaphic factors.Soil samples from eroded,depositional,and control sites in a closed wate...     

Refined chloride mass‐balance method and its application in Saudi Arabia

The rainfall and infiltration elements of the hydrological cycle in arid regions are characterized by temporal and spatial variations that are random and sporadic. Consequently, the chloride concentration in rainfall has a similar behaviour. Despite this, the classical chloride mass balance (CMB) approach only employs arithmetic and weighted averages for recharge estimation. In this paper, the classical CMB method is modified by taking into account some perceived deficiencies in the methodology. The modified CMB method takes into consideration additional statistical parameters, namely variances and the correlation coefficient between variables concerned based on the application of the perturbation method. Strategic aquifer planning in the Kingdom of Saudi Arabia requires a quick method for estimating groundwater recharge in order to determine the temporal management of available water resources. To demonstrate the difference between the classical and the refined CMB methods, both were applied to a representative basin, i.e. Wadi Yalamlam, in the western part of Saudi Arabia. Based on the refined calculations, recharge to groundwater is found to be 11% of the effective annual rainfall. This refined method provides higher recharge rates because it takes into account the actual variability in the variables concerned and can, thus, improve the accuracy of future groundwater recharge estimation studies. Copyright © 2006 John Wiley & Sons, Ltd.     

Distribution of trace metals in the Odra River system: Water–suspended matter–sediments

Extensive investigations of trace metals concentrations in water, suspended particulate matter (SPM) and bottom sediments of the whole Odra River system were carried out over the years 1997–2000. The vertical distribution of selected metals and their mobility were also studied in the sediment cores from upper and middle river sections. Significant levels of metal contamination were found. Median concentrations (Cd, Pb, Cu, Zn and As) in the SPM and sediments were (mg kg⁻¹) 7.1 and 8.9 Cd, 128 and 146 Pb, 81 and 119 Cu, 1198 and 1204 Zn, 48 and 54 As, respectively. The highest metal pollution of the Odra River solids was found with cadmium, zinc, lead and arsenic, showing high similarity in their frequency distributions in both SPM and sediments. Cd, Zn and As appear to be of particular concern because of the high levels, that appear to be bioavailable, and their high mobility. The exchangeable and carbonate chemical forms of Cd and Zn reached up to 50% of their total amount. Besides the determination of total metal concentration, the metal chemical forms in river solids were investigated. The results of very wide studies of the Odra River system through 4 years suggest that metal pollution decreased, especially for Zn, Pb and Cu. Among all metals studied in the Odra River sediments, substantial reductions of Cd contamination were observed neither in the period after ’97 flood, nor if compared with the earlier results obtained before ’97. No essential differences of the metal contents were observed among the samples for the same river compartment, from the same locality, taken within the five sampling campaigns. The pattern of spatial and vertical metal distributions in the river solids indicates that a variety of sources might be responsible for the contamination; very intensive, historical and current mining and smelting activities probably are the most important ones.     

Development of a national VNIR soil-spectral library for soil classification and prediction of organic matter concentrations

Soil visible-near infrared diffuse reflectance spectroscopy(vis-NIR DRS)has become an important area of research in the fields of remote and proximal soil sensing.The technique is considered to be particularly useful for acquiring data for soil digital mapping,precision agriculture and soil survey.In this study,1581 soil samples were collected from 14 provinces in China,including Tibet,Xinjiang,Heilongjiang,and Hainan.The samples represent 16 soil groups of the Genetic Soil Classification of China.After air-drying and sieving,the diffuse reflectance spectra of the samples were measured under laboratory conditions in the range between 350 and 2500 nm using a portable vis-NIR spectrometer.All the soil spectra were smoothed using the Savitzky-Golay method with first derivatives before performing multivariate data analyses.The spectra were compressed using principal components analysis and the fuzzy k-means method was used to calculate the optimal soil spectral classification.The scores of the principal component analyses were classified into five clusters that describe the mineral and organic composition of the soils.The results on the classification of the spectra are comparable to the results of other similar research.Spectroscopic predictions of soil organic matter concentrations used a combination of the soil spectral classification with multivariate calibration using partial least squares regression(PLSR).This combination significantly improved the predictions of soil organic matter(R2=0.899;RPD=3.158)compared with using PLSR alone(R2=0.697;RPD=1.817).     

Effects of eastern redcedar encroachment on soil hydraulic properties along Oklahoma's grassland‐forest ecotone

In north‐central Oklahoma eastern redcedar (Juniperus virginiana), encroachment into grassland is widespread and is suspected of reducing streamflow, but the effects of this encroachment on soil hydraulic properties are unknown. This knowledge gap creates uncertainty in understanding the hydrologic effects of eastern redcedar encroachment and obstructs fact‐based management of encroached systems. The objective of this study was to quantify the effects of eastern redcedar encroachment into tallgrass prairie on soil hydraulic properties. Leaf litter depth, soil organic matter, soil water repellency, soil water content, sorptivity, and unsaturated hydraulic conductivity were measured near Stillwater, OK, along 12 radial transects from eastern redcedar trunks to the center of the grassy intercanopy space. Eastern redcedar encroachment in the second half of the 20th century caused the accumulation of 3 cm of hydrophobic leaf litter near the trunks of eastern redcedar trees. This leaf litter was associated with increased soil organic matter in the upper 6 cm of soil under eastern redcedar trees (5.96% by mass) relative to the grass‐dominated intercanopy area (3.99% by mass). Water repellency was more prevalent under eastern redcedar than under grass, and sorptivity under eastern redcedar was 0.10 mm s^?1/2, one seventh the sorptivity under adjacent prairie grasses (0.68 mm s^?1/2). Median unsaturated hydraulic conductivity under grass was 2.52 cm h^?1, four times greater than under eastern redcedar canopies (0.57 cm h^?1). Lower sorptivity and unsaturated hydraulic conductivity would tend to decrease infiltration and increase runoff, but other factors such as rainfall interception by the eastern redcedar canopy and litter layer, and preferential flow induced by hydrophobicity must be examined before the effects of encroachment on streamflow can be predicted. Copyright © 2011 John Wiley & Sons, Ltd.     

Determination of dissolved organic matter in streamwater using visible spectrophotometry

Absorbance at 360 nm was measured on 44 filtered streamwater samples of different dissolved organic matter (DOM) contents. A regression equation of DOM on absorbance predicted DOM with a standard error of estimate of 1.26 mgl^?1, Use of a published equation relating dissolved organic carbon (DOC) to absorbance gave DOC values for the samples which were consistent with measured DOM. The method offers considerable potential for rapid quantification of dissolved organic matter concentrations in streamwater.