Application of multivariate statistical procedures to the hydrochemical study of a coastal aquifer: an example from Crete,Greece

A variety of multivariate statistical procedures were applied to three separate sets of quantitative analytical data from a coastal aquifer located in Malia, Crete (Greece), in order to identify the major hydrochemical processes affecting the groundwater quality and to investigate the evolution of groundwater composition in three different sampling periods. Two of them were carried out on October 2001 and September 2002 at the end of the dry season and the third on April 2002 at the end of the wet period. Two factors were found that explained major hydrochemical processes in the aquifer. These factors reveal the existence of an intensive intrusion of seawater and mechanisms of nitrate contamination of groundwater. Bivariate plots of the scores of the two main factors showed that the seawater intrusion and nitrate pollution processes are maintained through three surveys and that the process of nitrate pollution increases from the first to the second dry survey. Q‐mode factor analysis and discriminant analysis of the three sampling periods clearly showed a seasonal variation of the whole chemistry of groundwater samples. This seasonal variation can be attributed to the freshwater recharge and seawater intrusion that affect the groundwater quality of the Malia aquifer. The results of trend surface analysis are in agreement with those of factor analysis. Moreover, the fourth‐order trend surfaces of EC, Cl^? and NO₃^? showed that the salinization process is more intensive during the first dry period and the spatial variation of NO₃^? maxima plumes are strongly affected by the flow regime of the Malia aquifer. Copyright © 2007 John Wiley & Sons, Ltd.     

Groundwater mineralisation processes in Mediterranean semi‐arid systems (Cap‐Bon,North east of Tunisia): hydrogeological and geochemical approaches

The groundwater of the Korba plain represents major water resources in Tunisia. The Plio‐Quaternary unconfined aquifer of the Cap‐Bon (north‐east Tunisia) is subject to the intensive agricultural activities and high groundwater pumping rates due to the increasing of the groundwater extraction. The degradation of the groundwater quality is characterized by the salinization phenomena. Groundwater were sampled and analysed for physic‐chemical parameters: Ca²⁺, Mg²⁺, Na⁺, K⁺, Cl^‐, SO₄^2‐, HCO₃^‐, NO₃^‐, pH, electrical conductivity (EC), and the temperature (T°). The hydrochemical analysis is coupled with the calculation of the saturation indexes (SI gypsum, SI halite, SI calcite and SI dolomite), ionic derivation and with the ion correlations compared to chloride concentrations: Na⁺/ Cl^‐, Ca²⁺/ Cl^‐ and Mg²⁺/ Cl^‐ ratios. Seawater fractions in the groundwater were calculated using the chloride concentration. Those processes can be used as indicators of seawater intrusion progression. EC methods were also conducted to obtain new informations on the spatial scales and dynamics of the fresh water–seawater interface of coastal groundwater exchange. The mixing zone between freshwater and saltwater was clearly observed from the EC profile in the investigated area where a strong increase in EC with depth was observed, corresponding to the freshwater and saltwater interface. Results of hydrochemical study revealed the presence of direct cation exchange linked to seawater intrusion and dissolution processes associated with cations exchange. These results, together with EC investigation, indicated that the groundwater is affected by seawater intrusion and is still major actor as a source of salinization of the groundwater in Korba coastal plain. Further isotopic and hydrological investigations will be necessary to identify and more understood the underlying mechanisms. Copyright © 2012 John Wiley & Sons, Ltd.     

Groundwater Quality: Analysis of Its Temporal and Spatial Variability in a Karst Aquifer

This study develops an approach based on hierarchical cluster analysis for investigating the spatial and temporal variation of water quality governing processes. The water quality data used in this study were collected in the karst aquifer of Yucatan, Mexico, the only source of drinking water for a population of nearly two million people. Hierarchical cluster analysis was applied to the quality data of all the sampling periods lumped together. This was motivated by the observation that, if water quality does not vary significantly in time, two samples from the same sampling site will belong to the same cluster. The resulting distribution maps of clusters and box‐plots of the major chemical components reveal the spatial and temporal variability of groundwater quality. Principal component analysis was used to verify the results of cluster analysis and to derive the variables that explained most of the variation of the groundwater quality data. Results of this work increase the knowledge about how precipitation and human contamination impact groundwater quality in Yucatan. Spatial variability of groundwater quality in the study area is caused by: a) seawater intrusion and groundwater rich in sulfates at the west and in the coast, b) water rock interactions and the average annual precipitation at the middle and east zones respectively, and c) human contamination present in two localized zones. Changes in the amount and distribution of precipitation cause temporal variation by diluting groundwater in the aquifer. This approach allows to analyze the variation of groundwater quality controlling processes efficiently and simultaneously.     

Assessment of seasonal groundwater quality and potential saltwater intrusion: a study case in Urmia coastal aquifer (NW Iran) using the groundwater quality index (GQI) and hydrochemical facies evolution diagram (HFE-D)

Coastal aquifers are at threat of salinization in most parts of the world. This work investigated the seasonal hydrochemical evolution of coastal groundwater resources in Urmia plain, NW Iran. Two recently proposed methods have been used to comparison, recognize and understand the temporal and spatial evolution of saltwater intrusion in a coastal alluvial aquifer. The study takes into account that saltwater intrusion is a dynamic process, and that seasonal variations in the balance of the aquifer cause changes in groundwater chemistry. Pattern diagrams, which constitute the outcome of several hydrochemical processes, have traditionally been used to characterize vulnerability to sea/saltwater intrusion. However, the formats of such diagrams do not facilitate the geospatial analysis of groundwater quality, thus limiting the ability of spatio-temporal mapping and monitoring. This deficiency calls for methodologies which can translate information from some diagrams such Piper diagram into a format that can be mapped spatially. Distribution of groundwater chemistry types in Urmia plain based on modified Piper diagram using GQI_Piper(mix) and GQI_Piper(dom) indices that Mixed Ca–Mg–Cl and Ca-HCO₃ are the dominant water types in the wet and dry seasons, respectively. In this study, a groundwater quality index specific to seawater intrusion (GQI_SWI) was used to check its efficiency for the groundwater samples affected by Urmia hypersaline Lake, Iran. Analysis of the main processes, by means of the Hydrochemical Facies Evolution Diagram (HFE-Diagram), provides essential knowledge about the main hydrochemical processes. Subsequently, analysis of the spatial distribution of hydrochemical facies using heatmaps helps to identify the general state of the aquifer with respect to saltwater intrusion during different sampling periods. The HFE-D results appear to be very successful for differentiating variations through time in the salinization processes caused by saltwater intrusion into the aquifer, distinguishing the phase of saltwater intrusion from the phase of recovery, and their respective evolutions. Both GQI and HFE-D methods show that hydrochemical variations can be read in terms of the pattern of saltwater intrusion and groundwater quality status. But generally, in this case (i.e. saltwater and not seawater intrusion) the HFE-D method was presented better efficiency than GQI method (including GQI_Piper and GQI_SWI).     

The role of bromide and iodide ions in the salinization mapping of the aquifer of Glafkos River basin (northwest Achaia,Greece)

Seawater intrusion causes many problems for groundwater quality, whereas natural remediation is time consuming. However, in cases where groundwater replenishment is feasible, groundwater quality remediation is possible and rapid. The alluvial aquifer in the lowland of the Glafkos River basin, which extends south of Patras city, was for over 30 years the major water source supplying the broader area. Groundwater quality has been degraded due to seawater intrusion, caused by overpumping and generally by inappropriate groundwater management. During the last decade, groundwater quality has been remedied due to diminished groundwater abstractions. The remediation rate was further higher because of rapid discharge of the brackish groundwater, through wells with freely flowing water in the coastal area, where, however, groundwater quality remains low. This paper deals with the hydrogeochemical processes that take place in the area. It is ascertained that ion exchange and mineral dilution processes are dominant. The ion relations between chloride, bromide and iodide, as well as the distribution maps of their concentrations, were used to determine the spatial distribution of the seawater intrusion front. In the lower part of the area in a distance from 1000 and 1500 m from the coast, the rBr^?/rCl^? ratio showed low values (<2·5 × 10^?3) similar to those of seawater. The rI^?/rCl^? ratio also presented low values (<7 × 10^?5), with the lowest one (2·7 × 10^?5) detected along the coastline. In the upper part of the area, a gradual change of those ratios was observed upstream, until they receive values similar to those of the surface waters of Glafkos River. Copyright © 2007 John Wiley & Sons, Ltd.     

Saltwater intrusion modelling in Jorf coastal aquifer,South‐eastern Tunisia: geochemical,geoelectrical and geostatistical application

Marine intrusion is the most serious problem facing the coastal Jorf shallow aquifer, located in south‐eastern Tunisia on the Mediterranean Sea. Jorf Aquifer is intensively exploited to supply the growing needs of agriculture and domestic sectors. This work proposes a multidisciplinary investigation, involving hydro‐geochemical, geoelectrical survey and geostatistical techniques for modelling the saltwater intrusion. For this purpose, 36 water samples were conducted and analysed. Electric conductivity, pH, total dissolved solids and major ions were measured and analysed. Pie and Durov Diagrams, Q‐mode hierarchical cluster and geostatistical analysis were considered to identify the main groundwater mineralization processes. Results revealed that the Na‐Cl‐Ca‐SO₄ is the dominant water type suggesting that dissolution of halite and gypsum was the main mineralization source of groundwater in the central and southern part of study area. However, saltwater intrusion was shown to control groundwater quality essentially in coastal areas. Variographic analyses were used to select the variographic model that best fits the spatial development of apparent resistivity. Kriged apparent resistivity profiles showed an abnormal decrease of resistivity values in the coastal zone, implying highly saline water because of seawater intrusion. Apparent resistivity values also decrease considerably in the faulted areas, suggesting a contribution of faults to seawater intrusion. Finally, saltwater mixing ratio was computed for each sample, and a refined seawater intrusion map was developed. Copyright © 2012 John Wiley & Sons, Ltd.     

Statistical approach to determine the salinized ground water flow path and hydrogeochemical features around the underground LPG cavern,Korea

The ground water flow path of the coastal area in the Yellow Sea, Korea, was interpreted using both the cross‐correlation analysis of hydraulic properties and the principal component analysis (PCA) of ground water chemistry. Data was obtained from observation wells in the underground liquefied petroleum gas (LPG) cavern constructed in the coastal area of Pyeongtaek. Cross‐correlation results showed that the operating pressure became more influenced on artificial factors for the variation of the groundwater level of the study area (45–66% of correlation coefficient) even though its affecting area was limited to the region with fractures or faults, and also showed that the delay time from the variation of operating pressure to the fluctuation of ground water level were relatively long periods (28–31 days). Three hydrogeochemical events (encrusted cement dissolution, host rock dissolution, and seawater intrusion), which were dominantly influenced on ground water quality, could be induced from the result of PCA. Quantitative evaluation for these events using the mixed equation with principal component scores suggest that the dissolution of encrusted cement materials was the predominant factor (39·0% of the total mixed proportion) to change the chemical composition of the seepage water during the ground water flow from the observation wells to the cavern. Integration of the statistical results also imply that ground water flow and hydrogeochemistry were predominantly affected by artificial factors such as cavern operation pressure and dissolution of encrusted cement materials, which were interdependent factors on the observation wells with high cross‐correlation coefficients and pH. Copyright © 2007 John Wiley & Sons, Ltd.     

Anticipating the effects of groundwater withdrawal on seawater intrusion and soil settlement in urban coastal areas

Intensive pumping in urban coastal areas is a common threat to water resource quality due to seawater intrusion. In those areas where subsurface water resources are not usually used for human consumption or irrigation, intensive pumping is associated with other activities like the lowering of the water table necessary to support underground structures and building foundations. This activity also increases the likelihood of soil settlement that affects building stability and the corrosion of concrete structures due to groundwater salinity. Under these circumstances, the awareness of a certain municipality (Calonge, NE Spain) of the potential effects of groundwater withdrawal upon foundations has led to an integrated approach to anticipate seawater intrusion related to urban development. Geological mapping and correlation of borehole logs, electrical resistivity tomography, and hydrochemical data provide comprehensive knowledge of the geology and hydrogeology of the area and act as screening tools necessary to discern the influence of hydrological processes in coastal areas. Developing Strack's analytical solution, new comprehensive, dimensionless expressions are herein derived to determine the critical pumping rate necessary to prevent seawater intrusion, as well as to reproduce the evolution of the wedge toe and the water table stagnation point under different withdrawal rates. Furthermore, the Dupuit–Forchheimer well discharge formula allows the estimation of the effects of the water table lowering due to such critical pumping in the surrounding building foundations. Field data from the Calonge coastal plain illustrate this approach and provide assessment criteria for future urban development and planning. Copyright © 2012 John Wiley & Sons, Ltd.     

Characterization and evaluation of processes governing the groundwater quality in parts of the Sabarmati basin,Gujarat using hydrochemistry integrated with GIS

Intense agricultural and industrial activities in any area are likely to make groundwater vulnerable with respect to its quality. In one such area which is a part of Sabarmati river basin of Gujarat, factors influencing the groundwater hydrochemistry in pre‐ and post‐monsoon season were evaluated. Groundwater samples were collected from 5 km × 5 km grids on the basis of spectral signature of vegetation and soil, observed on satellite image. Integration of Conventional graphical plots, Piper plot, saturation index values (estimated using PHREEQC) and GIS was helpful not only to create the database for analysis of spatial variation in respective water quality parameters but also to decipher the hydrogeochemical process occurring in such a large area. USSL diagram and % sodium were used to characterise the suitability of groundwater for irrigation. It was observed that leaching of wastes disposed from anthropogenic activities and agrichemicals is the major factor influencing the groundwater quality, in addition to the natural processes such as weathering, dissolution and ion exchange. Sea water relics are also impacting the groundwater quality. Control of indiscriminate and unplanned exploitation of groundwater, application of fertilizers and disposal of industrial wastes in the affected areas can possibly ensure groundwater protection from further pollution and depletion. Copyright © 2011 John Wiley & Sons, Ltd.     

Characterization of a coastal aquifer basin using gravity and resistivity methods: a case study from Aqaba in Jordan

The southern basin of Aqaba forms coastal aquifer and comprises an area of about 90 km². Alluviums and Pleistocene deposits fill the basin bounded by Precambrian Granite Basement to the east and north. Hydrogeophysical investigations were carried out to investigate its groundwater potentials and characteristics. Direct modeling on Bouger and residual gravity revealed some local subsurface faults that form subbasins and sub-grabens in the body of the basin, each one of them is bounded by two to three faults. The spatial distribution of groundwater was found to be affected by the presence of the sub-basins and grabens. Geoelectrical layers have been vertically digitized and put in a four variable space-lattice, 2D slices of the different depths and 3D visualizations have been produced. The extents of seawater intrusion and zones of water qualities were delineated. The geoelectric inferred some local subsurface faults that were found in spatial correlation with those inferred from the gravity. A good combination was made between gravity and resistivity methods to confirm the 3D distribution of groundwater in the basin.     

Using chlorofluorocarbons (CFCs) and tritium to improve conceptual model of groundwater flow in the South Coast Aquifers of Laizhou Bay,China

The southern coastal plain of Laizhou Bay, which is the area most seriously affected by salt water intrusion in north China, is a large alluvial depression, which represents one of the most important hydrogeological units in the coastal region of northern China. Chlorofluorocarbons (CFCs, including CFC‐11, CFC‐12 and CFC‐113) and tritium were used together for dating groundwater up to 50 years old in the study area. There are two cones of depression, caused by intensive over‐exploitation of fresh groundwater in the south and brine water in the north. The assigned CFC apparent ages for shallow groundwater range from 8 a to >50 a. A binary mixing model based on CFC‐113 and CFC‐12 concentrations in groundwater was used to estimate fractions of young and pre‐modern water in shallow aquifers and to identify groundwater mixing processes during saltwater intrusion. Discordance between concentrations of different CFC compounds indicate that shallow groundwater around the Changyi cone of depression is vulnerable to contamination. Pumping activities, CFC contamination, mixing and/or a large unsaturated zone thickness (e.g. >20 m) may be reasons for some groundwater containing CFCs without tritium. Saline intrusion mainly occurs because of large head gradients between fresh groundwater in the south and saline water bodies in the north, forming a wedge of saline water below/within fresh aquifer layers. Both CFC and tritium dates indicate that the majority of the saline water is from >50 a, with little or no modern seawater component. Based on the distribution of CFC apparent ages, tritium contents plus chemical and physical data, a conceptual model of groundwater flow along the investigated Changyi‐Xiaying transect has been developed to describe the hydrogeological processes. Three regimes are identified from south to north: (i) fresh groundwater zone, with a mixing fraction of 0.80–0.65 ‘young’ water calculated with the CFC binary mixing model (groundwater ages <34 a) and 1.9–7.8TU of tritium; (ii) mixing zone characterized by a mixing fraction of 0.05–0.65 young groundwater (ages of 23–44 a), accompanied by local vertical recharge and upward leakage of older groundwater; and (iii) salt water zone, mostly comprising waters with ages beyond the dating range of both CFCs and tritium. Some shallow groundwater in the north of the Changyi groundwater depression belongs to the >50a water group (iii), indicating slow velocity of groundwater circulation and possible drawing in of saline or deep groundwater that is tracer‐free. Copyright © 2012 John Wiley & Sons, Ltd.     

Seawater–freshwater mixing and resulting calcite dissolution: an example from a coastal alluvial aquifer in eastern South Korea

Abstract

In order to evaluate groundwater quality and geochemical reactions arising from mixing between seawater and dilute groundwater, we performed a hydrochemical investigation of alluvial groundwater in a limestone-rich coastal area of eastern South Korea. Two sites were chosen for comparison: an upstream site and a downstream site. Data of major ion chemistry and ratios of oxygen–hydrogen isotopes (δ¹⁸O, δD) revealed different major sources of groundwater salinity: recharge by sea-spray-affected precipitation in the upstream site, and seawater intrusion and diffusion zone fluctuation in the downstream site. The results of geochemical modelling showed that Ca²⁺ enrichment in the downstream area is caused by calcite dissolution enhanced by the ionic strength increase, as a result of seawater–groundwater mixing under open system conditions with a constant P_CO2 value (about 10^?1.5 atm). The results show that, for coastal alluvial groundwater residing on limestone, significant hydrochemical change (especially increased hardness) due to calcite dissolution enhanced by seawater mixing should be taken into account for better groundwater management. This process can be effectively evaluated using geochemical modelling.

Editor D. Koutsoyiannis; Associate editor Y. Guttman

Citation Chae, G.-T., Yun, S.-T., Yun, S.-M., Kim, K.-H., and So, C.-S., 2012. Seawater–freshwater mixing and resulting calcite dissolution: an example from a coastal alluvial aquifer in eastern South Korea. Hydrological Sciences Journal, 57 (8),1–12.     

Hydrochemistry of groundwaters in a spa area of Korea: an implication for water quality degradation by intensive pumping

A geochemical study was carried out in a small spa area (Onyang Spa, Korea) where intensive pumping of deep thermal groundwater (1 300 000 m³ year⁻¹) is taking place. This has caused the deep fractures to lose their artesian pressure and the upper shallow fractures have been encroached by shallow, cold waters. To quantify the influence of long‐term heavy pumping on the quality of the geothermal water, groundwater sampling and chemical analysis, water‐level measurement, and well loggings were performed for the selected deep thermal wells and shallow cold wells. Chemical analysis results indicate a big contrast in water chemistry and origins between the two water types. Shallow groundwater shows a wider concentration ranges in solutes that are closely related to human activity, illustrating the water's vulnerability to contamination near the land surface. Plots of water chemistry as a function of fluoride reveal that the quality of the thermal water was greatly influenced by the shallow, cold groundwater and that intensive pumping of the deep thermal groundwater has caused the introduction of shallow groundwater into the deeper fractures. Although the deep and the shallow fractures were piezometrically separated to some extent, a mixing model based on fluoride and nitrate indicated that the cold‐water fractions in the thermal wells are up to 50%. This suggests that the thermal water is faced with water quality degradation by the downward flow of the shallow, cold water. Restriction on the total of all the pumpage permits per unit area is suggested to restore the artesian pressure of the deep thermal aquifer and to prevent cold‐water intrusion in the study area. Copyright © 2004 John Wiley & Sons, Ltd.     

Hydrogeochemical and isotopic evidence of groundwater salinization in a coastal aquifer: a case study in Jeju volcanic island, Korea

In order to identify the origin of saline groundwater in the eastern part of Jeju volcanic island, Korea, a hydrogeochemical and isotopic study has been carried out for 18 observation wells located in east and southeast coastal regions. The total dissolved solid contents of groundwaters are highly variable (77–21,782 mg/l). Oxygen, hydrogen, sulfur, and strontium isotopic data clearly show that the saline water results from mixing of groundwater with seawater. Strontium isotopic compositions and Br/Cl and I/Cl ratios strongly suggest that the source of salinity is modern seawater intrusion. Hydrogeochemical characteristics based on bivariate diagrams of major and minor ions show that changes in the chemical composition of groundwater are mainly controlled by the salinization process followed by cation-exchange reactions. The highly permeable aquifers at the east coastal region are characterized by low hydraulic gradient and discharge rate and high hydraulic conductivity as compared with other regions. These properties enhance the salinization of groundwater observed in the study area. Based on the Cl, Br, and δ¹⁸O data, seawater was determined to have intruded inland some 2.5 km from the coastline. Considering the poor correlation of sampling depth and Cl concentrations observed, the position of seawater-freshwater interface is not uniformly distributed in the study area, due to heterogeneities of the basaltic aquifers.     

Application of Multivariate Statistical Techniques for Characterization of Groundwater Quality in the Coastal Aquifer of Nador,Tipaza (Algeria)

The study focuses on the characterization of the groundwater salinity on the Nador coastal aquifer (Algeria). The groundwater quality has undergone serious deterioration due to overexploitation. Groundwater samplings were carried out in high and low waters in 2013, in order to study the evolution of groundwater hydrochemistry from the recharge to the coastal area. Different kinds of statistical analysis were made in order to identify the main hydrogeochemical processes occurring in the aquifer and to discriminate between different groups of groundwater. These statistical methods provide a better understanding of the aquifer hydrochem-istry, and put in evidence a hydrochemical classification of wells, showing that the area with higher salinity is located close to the coast, in the first two kilometers, where the salinity gradually increases as one approaches the seaside and suggests the groundwater salinization by sea-water intrusion.     

Large seasonal changes in the recharge of seawater in a subterranean estuary revealed by a radon tracer

Activities of radon (²²²Rn) in groundwater were continuously monitored in a saline aquifer from September 2010 to July 2011. The activities of ²²²Rn ranged from 200 to 4300 Bq m^?3, with a large seasonal variation. Because the activity of ²²²Rn in seawater is low, ²²²Rn in saline groundwater must be produced in the aquifer from radium (²²⁶Ra) in rocks and sediments. The ²²²Rn activities were higher in the warm‐dry seasons (September–November 2010 and April–May 2011) when the saline aquifer was stable. In contrast, the lowest ²²²Rn activities were observed in the cold‐dry season (December 2010 and January–March 2011), because of the effective exchange between groundwater and seawater. In addition, sudden decreases of ²²²Rn activities coincided with episodic drops in groundwater temperatures. These results reveal that lower seawater temperature in winter may result in density‐driven seawater intrusion. During the wet season (June–July 2011), ²²²Rn activities were more clearly affected by semi‐monthly and diurnal tidal pumping, showing higher ²²²Rn activities during low and spring tides. Such a tidal effect was not clearly observed during the warm‐dry and cold‐dry seasons. This result implies that the residence time of SGD in coastal zones is significantly affected by seasonal changes in driving forces such as tidal pumping and seawater intrusion. Copyright © 2016 John Wiley & Sons, Ltd.     

Source speciation resolving hydrochemical complexity of coastal aquifers

There is a growing concern of seawater intrusion to freshwater aquifers due to groundwater overexploitation in the eastern coastal belt of Southern India. The problem becomes complex in the regions where industrial effluents are also contaminating the freshwater aquifers. In order to understand the hydrochemical complexity of the system, topographic elevation, static water level measurements, major ion chemistry, ionic cross plots, water type contours and factor analysis were applied for 144 groundwater samples of shallow and deep sources from Quaternary and Tertiary coastal aquifers, located within the industrial zone of 25 km² area near Cuddalore, Southern India. The ionic cross plots indicates dissolution of halite minerals from marine sources and seawater mixing into inland aquifers up to the level of 9.3%. The factor analysis explains three significant factors totaling 86.3% of cumulative sample variance which includes varying contribution from marine, industrial effluent and freshwater sources.     

Impact of the Use of Reclaimed Water on the Quality of Groundwater Resources in the Jordan Valley,Jordan

The use of reclaimed water and its impact on groundwater quality in the middle and southern parts of the Jordan Valley are investigated. The chemical analyses indicate that nitrate and bacteriological pollution is widespread, and thus, seriously affects groundwater use. During the study, 365 water samples were collected from wells and springs to determine the water chemistry and the extent of nitrate pollution. Three hydrochemical facies are identifed, i. e., (Ca–(Mg)–Na–HCO₃), (Ca–Na–SO₄–Cl) and (Ca–Na–Cl). The change of facies is accompanied by a gradual increase in the groundwater total dissolved solids (TDS), which is mainly controlled by evaporates and carbonates dissolution in the aquifer matrix. Water analyses indicate that the shallow aquifer in the study area is affected by non‐point pollution sources, primarily from natural (manure) and chemical nitrogen (N)‐fertilizers and treated wastewater used for agriculture. The concentration of nitrate in the groundwater ranges from 10 to 355 mg/L. Considerable seasonal fluctuations in groundwater quality are observed as a consequence of agricultural practices and other factors such as annual rainfall distribution and the Zarqa River flow. The noticeable levels of total coliform and Escherichia coli in the northern part of the study area may be attributed to contamination from the urban areas, intensive livestock production, and illegal dumping of sewage. Heavy metal concentrations in all samples were found to be significantly lower than the permissible limits for drinking water standards.     

Electrical resistivity imaging and hydrochemical analysis for groundwater investigation in Kuala Langat,Malaysia

ABSTRACT

Integrated two-dimensional electrical resistivity imaging (ERI) and hydrochemical surveys were used to investigate the groundwater alluvial aquifer in Kuala Langat, Malaysia. The study in the Langat basin considered the thickness of the aquifer, the depth of the bedrock, the regions influenced by seawater intrusion, and the monitoring of water levels. The resistivity imaging results show that the upper layer consists of clay, while the second layer is an aquifer whose thickness varies mostly in the range of 10–30 m, and in some cases extends to 40 m. The bedrock depth varies from 30 to 65 m. The chemical analyses were carried out on groundwater samples from nine boreholes collected between 2008 and 2012. The analyses indicate that the total dissolved solids (TDS) exceed 1000 mg L^-1 near the coastal area and are often less than 500 mg L^-1 further inland. The ERI and hydrochemical analyses reveal that groundwater in the study area, especially towards the coast, is a mixture of brackish and fresh waters.

EDITOR D. Koutsoyiannis; ASSOCIATE EDITOR M.D. Fidelibus     

Groundwater modelling and marine intrusion in the semi‐arid systems (Cap‐Bon,Tunisia)

This article studies the effect of drought and pumping discharge on groundwater supplies and marine intrusion in the Korba aquifer (Cap‐Bon peninsula, Tunisia). The Groundwater Modelling System has been used to model the groundwater flow and to simulate the seawater intrusion. The calibration is based on the groundwater levels in the steady state from 1963, and in the transient state from the groundwater levels from 1963 to 2005. The main objective is to quantify the components of the groundwater mass balance and to estimate the hydraulic conductivity distribution. The impact of pumping discharge on the groundwater level evolution has been examined by two pumping scenarios P1 (no. 8420) and P2 (no. 8862) wells. The hydrodynamic modelling shows the increasing drawdowns after 14 years of pumping: 4 m in P1 well and about 5 m in P2 well below sea level. The drawdowns are accompanied by the inverse hydraulic gradient. The numerical model was used to discuss the management of the groundwater resources of Cap‐Bon. As the population continues to grow and the demand for groundwater pumping intensifies beyond the 1963 level, it can be expected that the actual extent of seawater intrusion in the future would be more severe than the model prediction. Better strategies for groundwater development and management will be necessary to protect the freshwater aquifers to the marine intrusion. Copyright © 2011 John Wiley & Sons, Ltd.