贵州省紫云县狗场地热水分析

紫云县地处贵州省南西部,区域上无岩浆活动,地表无温泉地热流体露头和无明显的其他地热显示,增加了地热勘查的难度。燕山期自东往西的构造应力作用下,产生了近南北向、北东向断层和近南北向褶皱的主体构造,以及碳酸盐岩—碎屑岩沉积建造为区内地热资源的产生提供了前提条件;采用基础地质结合物探方法研究优选出了层状热储较好的牛场坡背斜和带状热储F4小桥断裂结合的有利部位,施工了地热钻孔,取得了良好的地热水找矿成果。     

赫章片区地热地质条件特征及勘查远景探讨

区域性北西向紫云-垭都深大断裂带斜贯县境,其上下盘次级构造,层间破碎带及挽近期构造发育,具有中低温地热资源有利地热地质条件;潜在地热资源丰富,具有开发价值热储层为第一热储单元和第二热储单元的白云岩,以混合热储构造类型为主,其次是层状带状热储构造类型。根据地热地质条件,结合已成井成果资料,预测了六个靶区。     

天津周良庄地质构造背景和地热成因探讨

天津市宝坻区南部周良庄一带赋存较为丰富的地热资源。为查明该区各热储补给来源,地温场是否受断裂构造影响,利用人工地震结合钻探资料进行二次解译,分析该区地质构造背景和热储发育特征,同时在综合分析水化学和同位素等化探方法的基础上,对该区的地热成因进行探讨。查明该区主体构造为一背斜构造,地热属沉积盆地型层状热储,地热流体主要有孔隙型热水系统和基岩裂隙型热水系统2个类型,热储条件好。该区热流体矿化度较低的原因是接近补给区,补给水源来自北部山区大气降水;地热流体在深循环过程中与富氧岩石进行了氧交换,δ18O值存在不同程度的氧漂移。     

山东临沂地区古生代复合热储成矿模式研究

山东临沂地区地热资源丰富,前人对于临沂地区沂沭断裂带成热模式存在诸多争议。通过对研究区地热地质条件、地球物理特征和地热井数据进行综合研究,从地热产生的源、通、储、盖四要素进行分析,研究结果表明研究区地热成矿模式为古生代层状和带状复合热储地热成矿模式,断裂带为带状热储,断裂带周边稳定区域为层状热储。研究区热储为古生代砂岩,同时张性、张扭性断裂发育,导致热储为层状和带状的复合热储,较单一成因热储要复杂。对地热井数据归一化处理分析表明,盖层岩性及厚度对深部地热水温度存在较大影响,并且热储厚度对水温也存在影响,表现为表层有第四系覆盖的地热水温度,较无第四系覆盖的要高;盖层厚度越大,水温越高,热储厚度越大,水温也越高。这为进一步地热勘查与开采提供了理论指导。     

四川宜宾金沙江河谷区地热资源成藏条件分析

[摘 要] 本文从地热地质背景、水文地质条件、构造条件、热储条件等几方面对金沙江宜宾段河谷区 的地热成藏条件及开发潜力进行了较为深入的论述。研究表明:该区的古地理环境有利于地表水向深部 补给、运移、往更纵深循环以及形成与深部热储充分进行热交换,有利于形成保持相对封闭的热水构造,使 深部地热水处于承压状态;热储层盖层对地下热水具有良好的保温防热扩散作用,且阻隔浅层地表水向下 运移;东西向断裂与南北向断裂或与NE、NW 向断裂的多方向构造的交切复合部位为深部地热水向上运 移排泄的极为有利构造部位;区内地下热水其热源主要是地热增温,大气降水经由深循环加热,与深部热 储层岩石进行充分的热交换,温泉水以补给地高、运移途径长、循环深、滞留时间长为特征。     

北京东南城区热田可持续开发利用问题的思考

北京东南城区热田从20世纪70年代进行开发,经历了快速增长、缓慢减小和快速减小等几个阶段。本论文经过对该热田可持续开发条件的探讨,提出热储压力保持不下降的条件是地热净开采量控制在65万m~3以内,发现目前热储温度和流体化学成分没有发生较大变化,采取措施可以实现资源的可持续开发,但应谨防大规模回灌可能对热储产生"热突破"。论文最后结合规划提出几点建议,包括建立热储温度监测系统、研究地热评价方法、推广地热供暖项目和重新进行地热勘查评价工作。     

带状(构造裂隙型)热储地热单井保护范围确定方法探讨

带状(构造裂隙型)热储和层状(沉积盆地型)热储皆可采用热储法进行地热资源量计算,但热储分布面积及厚度两个参数应根据两种类型热储的不同空间分布特征,采取相应的确定方法。文章根据带状(构造裂隙型)热储的空间展布特征,提出了其三维空间展布参数的确立方法,并建立了该类型地热资源单井保护范围的数学模型。苏州市浒关地区两口地热井勘查结果表明,两处地热水资源受同一条断裂控制,经理论计算,两者同时开采将产生相互影响,由于开采时间较短,需要根据长期监测资料才能实际验证。     

带状（构造裂隙型）热储地热单井保护范围确定方法探讨

带状（构造裂隙型）热储和层状（沉积盆地型）热储皆可采用热储法进行地热资源量计算,但热储分布面积及厚度两个参数应根据两种类型热储的不同空间分布特征,采取相应的确定方法。文章根据带状（构造裂隙型）热储的空间展布特征,提出了其三维空间展布参数的确立方法,并建立了该类型地热资源单井保护范围的数学模型。苏州市浒关地区两口地热井勘查结果表明,两处地热水资源受同一条断裂控制,经理论计算,两者同时开采将产生相互影响,由于开采时间较短,需要根据长期监测资料才能实际验证。     

浙江省湖州地区地热资源储存特征及开发利用方向分析

湖州地区地处杭嘉湖平原,地热资源开发具有良好的前提条件。以往的地质勘查工作中,由于上部白垩系和侏罗系较厚,对深部钻探控制程度不够,影响了该区地热资源的开发利用。在分析该区地层、含水层,特别是断裂构造的基础上,对区内的热储特征进行了研究,指出:区内热源主要来自区域大地热流;盖层主要为分布连续是,且受断裂构造影响相对较少的侏罗系及白垩系;热储层有二叠系长兴组、栖霞组,石炭系船组、黄龙组以灰岩为主的灰岩热储和由泥盆系五通组、志留系茅口组砂岩组成的砂岩热储;热储通道为区内发育的深大断裂及其次生构造。构建了区域地热模式。根据地热赋存状态、盖层条件等,结合当前地热开发现状,将湖州地区划分为四个地热分区,认为Ⅲ区地热开发条件为最好,是首选区域,以控制层状热储(石炭、二叠系灰岩)为主;Ⅱ区次之;Ⅰ区断裂发育,缺乏有效盖层条件,若开发地热资源,则应以寻找深层对流型热储(深大断裂)为主;Ⅳ区因盖层厚度偏大,地质情况不明,现阶段开发地热资源需慎重。该研究对指导下一阶段区域性地热勘查工作具有重要意义。     

京西隆起北京大学医学部地区地热地质条件

北京大学医学部位于京西隆起地区,处于八宝山断裂和黄庄-高丽营断裂之间,断裂构造较为复杂,加之周边地热井距离较远,在该区进行地热资源勘查有一定的风险。北京大学医学部地热勘查的成功,对于评价本区的热储盖层、热储层、地热增温率和热储构造等地热地质条件起到了积极作用。查明了该区涌水量一般大于1000m~3/d、出水温度大于50℃、水化学类型为重碳酸钙镁型、热矿水类型为氟型淡温泉水;该区热储盖层地热增温率不是十分理想,但厚度较大也能起到保温作用,出水温度较为理想,但成井深度偏大。同时在研究区发现了一条F1断裂,分析认为是黄庄-高丽营断裂的次级断裂,其与主断裂基本同时形成,逐级下掉,共同组成了构造分区断裂。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.