兴文县溶洞特征、成因及演化研究

兴文县位于四川省东南部山地,县内拥有大量溶洞资源,结合兴文县溶洞资源调查与保护规划项目野外调查,对区内溶洞数量、规模、分布、形态、洞穴沉积物、地质背景、发育方向、分布高程等进行了统计和研究。该地区溶洞数量多,洞穴规模中等;溶洞空间分布与发育规模受地层与岩性控制;溶洞发育方向受构造影响明显,具体每个溶洞的发育方向主要受构造裂隙与岩石层面裂隙控制;区内中小型溶洞发育演化主要集中在沿节理裂隙的岩溶早期阶段和顺层岩溶作用的岩溶中期阶段,大型溶洞则表现为水平溶蚀与垂向溶蚀交替出现的岩溶中晚期阶段。     

香溪河流域岩溶洞穴发育与分布特征

结合1∶5万水文地质调查,对香溪河岩溶流域溶洞特征进行了探究,统计其溶洞的规模、形态、发育地层、发育方向及分布高程,结果表明:该区洞穴规模中等,受岩性的控制,溶洞的发育表现出对碳酸盐岩岩组类型的选择性,其中寒武-奥陶系地层溶洞发育程度最高;溶洞的发育方向多为北北东和北北西向,与区域构造线一致,同时受本区构造运动间歇性抬升的影响,溶洞集中发育于4个高程区;从溶洞发育的构造部位来看,溶洞主要分布在宽缓向斜的东南翼及向斜核部,平面分布表现出分带性;该区溶洞多发育至早期就停止进一步发育,其规模、类型、分布特征等与鄂西南地区溶洞均存在差异。      

基于岩溶洞穴旅游活动中洞穴环境因子的研究

随着人们生活水平的不断提高,岩溶洞穴旅游活动日益频繁,使得对洞穴环境的综合研究以及洞穴旅游管理变得尤为重要。通过调研国内外岩溶洞穴旅游管理的现状,结合岩溶洞穴环境的研究成果,综合分析岩溶洞穴环境因子,如温度、相对湿度、洞穴CO2浓度等,对岩溶景观的影响,探讨溶洞环境的自净能力以及景观保护与修复措施等问题;针对目前岩溶洞穴旅游开发的有限空间与无序客流的矛盾,提出了合理调控洞穴旅游客流量,增强洞穴旅游景观资源保护意识,从地学、旅游、环境以及健康等角度评估和开发洞穴,使旅游活动对环境因子的影响限制在可控范围,实现洞穴旅游的可持续发展。      

贵州荔波岩溶洞穴发育特征

荔波位于云贵高原岩溶向广西岩溶丘陵和孤峰岩溶平原过渡的岩溶斜坡地带。区内岩溶洞穴极其发育,岩溶洞穴(在时空分布上受区域碳酸盐岩地层分布的控制,表现出对地层岩性的选择性和洞穴发育的成层性特点,岩溶洞穴的发育规模、方向明显受断裂、裂隙构造的控制,表现出极强的方向性。本文主要依据洞穴的形成条件、洞穴空间展布的控制特征以及洞穴沉积物的特征等,论述了区内岩溶洞穴的发育特征。      

塔河油田奥陶系油藏的储层特征和成因机理探讨

本文通过岩心、录井、测井、测试资料的综合研究，在塔河油田奥陶系碳酸盐岩剖面上识别出5类性质有别的储层（洞穴型、风化裂隙型、构造裂隙型、滩相颗粒灰岩溶蚀孔隙型、地表残积带裂隙-孔隙型），阐述了各类储层的储集性能及发育分布特征，并对碳酸盐岩古岩溶作用机制及岩溶洞穴型的发育控制因素进行了探讨。指出在不整合面下0～250m的深度内，区域性发育3套洞穴型储层，洞穴型储层的发育是油气高产、稳产的关键，风化裂隙型储层主要集中在海西早期不整合侵蚀面附近及洞穴层上下；构造裂隙型储层发育分布具有普遍性，海西早期构造裂隙发育状况与洞穴层发育状况之间有着良好的匹配关系，滩相颗粒灰岩溶蚀孔隙性储层具有相控和层控的特征，主要发育在塔河油田南平台-间房组上部（礁）滩相储集体中，岩溶洞穴层发育主要受岩溶地貌及裂缝发育程度控制，岩溶缓坡（特别是其上的丘丛）与阿克库勒凸起轴部的叠合部位是岩溶最发育的地区。     

川北诺水河景区溶洞分布特征及影响因素探析

选取诺水河景区48个典型溶洞为研究对象,参阅本地区区域地质图和水文地质图,在对洞穴发育高度、层位、构造位置、发育方向、节理走向,以及地下水和地表水系部分特征进行详细调查前提下,利用最邻近距离法、节理分析法、GIS缓冲区法等方法,对溶洞群的洞口高程分布、洞穴发育方向、空间分布格局、洞穴与构造及地表水系关系等分布特征进行了分析,并对溶洞群分布特征的影响因素进行了探析。结果表明,① 洞口高程分布在空间上具有层级性,在时间上具有阶段性,研究区洞穴主要沿北西西、北东东向发育,并且越接近地表河流洞穴出口分布越多,洞穴群呈凝聚态分布,越接近构造转折端洞穴分布越密集;② 影响洞穴分布的主要因素包括：地层和碳酸盐岩岩性差异,构造派生节理发育状况以及多期次构造变形和构造隆升,地下水的类型和作用,地表水系对地下水系的影响,以及北亚热带季风气候条件下地形的影响等。     

塔里木盆地轮南区块奥陶纪缝洞型储层发育特征浅析

在区域地质背景研究及大量文献调研的基础上,结合地质地震资料,通过单井分析及连井对比研究,探讨研究区古岩溶的形成机理和控制因素、储层的空间发育及岩溶洞穴的充填特征。认为轮古地区奥陶系古潜山发育岩溶旋回,纵向上形成了四套与洞穴有关的古岩溶储层,其中第Ⅱ岩溶层主要分布在岩溶斜坡区,洞穴广泛发育,充填程度低且位于构造高部位,是最有利的油气聚集层段。     

广西东兰-凤山地区石炭纪-二叠纪碳酸盐岩洞穴发育特点及其控制因素

碳酸盐岩次生溶蚀孔洞是优质的储集空间,为油气的运聚提供条件。为研究溶洞发育的控制因素,选取广西东兰-凤山地区石炭纪-二叠纪碳酸盐岩溶蚀特征进行分析。镜下显示,研究区岩石类型为亮晶生屑灰岩、颗粒灰泥灰岩、含颗粒灰泥灰岩、晶粒灰岩和灰泥颗粒灰岩等,孔隙类型主要为粒间溶蚀孔、粒内溶蚀孔、晶间孔和微裂缝。研究发现,影响洞穴发育的主要因素有构造、岩组类型、流体性质、气候及岩溶古地貌。构造控制洞穴发育规模,在构造破碎带及其附近容易发育大规模洞穴;目的层大套灰岩是溶蚀的物质基础,力学强度较大的亮晶生屑灰岩易于形成大型洞穴,当岩石含较多灰泥或发生重结晶时,溶蚀难度增加;酸性流体、温暖潮湿气候和岩溶斜坡地貌,为洞穴发育的有利条件。其中,构造对洞穴发育的控制作用最大。     

四川盆地北部方山地区砂岩洞穴特征、成因分析——以四川营山地质公园为例

以四川盆地北部营山县的四川营山地质公园中蓬莱镇组砂岩洞穴为研究对象,在资料文献收集、野外考察的基础上,对研究区砂岩洞穴的分布和类型等特征进行了分析。利用地貌学的研究方法,采用导线法原理对洞穴进行测量,对研究区不同类型砂岩洞穴的成因进行了探讨。结果表明,莲花状构造背景下和缓的褶皱构造、构造裂隙和风化裂隙是该区域形成方山地貌乃至砂岩洞穴群的构造条件;蓬莱镇组含钙质长石砂岩夹泥页岩地层是洞穴发育的物质基础;砂岩中发育的裂隙水是水洞形成的重要水文地质条件;岩层差异性风化是旱洞形成的主要原因;岩溶作用、水解作用和崩塌作用是砂岩水洞形成的主要原因。     

清江半峡地区岩溶洞穴发育特征及其旅游资源

半峡是清江流域岩溶洞穴集中发育的地区之一,本文着重介绍该区岩溶洞穴发育的地质背景条件、主要特征及其旅游资源的基本特色,旨在为该区旅游业的发展提供依据      

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.