鲁西中生代高Mg闪长岩的成因:年代学与岩石地球化学证据

鲁西高Mg闪长岩分布较为广泛, 莱芜铁铜沟岩体和淄博金岭岩体是其典型代表.铁铜沟岩体早期苏长辉长岩和晚期辉石闪长岩、金岭黑云母闪长岩的LA-ICPMS U-Pb谐和加权平均年龄分别为(131.4±4.9)Ma(n=15)、(134.5±2.3) Ma(n=13)和(132.8±4.2)Ma(n=12), 它们代表了岩体的侵位结晶年龄——早白垩世.铁铜沟岩体晚期辉石闪长岩中浑圆状锆石的LA-ICPMS U-Pb谐和年龄为(2 513±54)Ma(n=8), 代表了华北克拉通基底的存在.该类岩石以高Mg# (> 60)、富钠、富含轻稀土元素、贫重稀土元素以及高场强元素(Nb、Ta、Zr、Hf)的明显亏损为特征, 显示埃达克岩(adakite) 的特征.该类岩石中地幔橄榄岩包体的广泛存在以及高Mg的特征表明原始岩浆的地幔成因, 而Sr-Nd同位素组成(I_sr为0.704 75-0.707 72和ε_Nd(t)值为-3.95--13.30)和高场强元素(Nb、Ta、Zr、Hf)的亏损以及太古代继承锆石的存在均暗示岩浆源区应有陆壳物质的涉入.铁铜沟岩体和金岭岩体闪长岩成分的差异应归因于岩浆源区性质的差异和部分熔融程度的不同.基于该类岩石的地球化学和所含包体, 同时结合华北克拉通东部中生代早期岩石圈演化历史, 可以认为鲁西中生代早白垩世高Mg闪长岩的形成应为拆沉的岩石圈(地幔+下地壳)与软流圈混熔的产物.      

华北克拉通东部中生代高Mg闪长岩——对岩石圈减薄机制的制约

在华北克拉通东部鲁西—徐淮地区,存在一套辉石闪长岩-二长闪长岩-花岗闪长岩组成的adakitic岩石。锆石SHRI MP和LA-ICP-MS U-Pb定年结果表明它们形成于早白垩世(130~132Ma)。该类岩石具有较高的MgO含量(质量分数为1·46%~9·76%)、高的Mg#值(0·46~0·68)和高的Sr/Y值(主体介于30~52之间,个别高达410)。这些特征类似于由俯冲大洋板片部分熔融形成的adakitic岩石。然而,它们所表现出来的相对较高的87Sr/86Sr初始比值(0·7051~0·7077)和较低的εNd(t)值(-4·43~-15·92)则反映岩浆形成或演化过程中应有陆壳物质的参与。徐淮地区该类岩石中榴辉岩类捕虏体和石榴石捕虏晶的存在和鲁西辉石闪长岩中众多地幔橄榄岩捕虏体的发现,以及这些捕虏体中普遍发育富硅质交代作用,由此可以判定该类岩浆应起源于拆沉下部大陆地壳的部分熔融及其在上升过程中与地幔橄榄岩的反应,石榴石作为残留相。华北克拉通东部早白垩世adakitic岩石的存在以及榴辉岩类捕虏体的年代学表明,中生代早期曾存在一次重要的陆壳加厚过程,之后相继出现的加厚岩石圈的拆沉应是中生代岩石圈减薄的主导机制。     

华北克拉通东部显生宙地幔演化

华北克拉通东部显生宙以来的地幔可以划分为3种类型:克拉通型地幔,大陆活动带型地幔和大陆裂谷型地幔。1 700 Ma—古生代末,地幔属于克拉通型:ε(Nd,t)值高于-5,为弱富集型;层圈相互作用以幔源的熔体和/或流体与古老的岩石圈地幔的作用为主,但规模较小,范围局部。100 Ma以前的中生代地幔属于“大陆活动带型”:ε(Nd,t)值低,在-5以下,为富集型;地幔中含有地壳的组分,层圈相互作用以下地壳与弱化的岩石圈地幔之间的作用为主;发生的时间为190~100 Ma,高峰期在130 Ma左右;发生的部位邻近莫霍面,导源的岩浆多为钙碱性系列,部位浅,活动范围广泛。100 Ma至新生代,地幔属于“大陆裂谷型”:为亏损型的软流圈地幔,ε(Nd,t)值高,几乎均为正值。层圈相互作用转变为软流圈岩石圈地幔之间的作用,转变的时间具有约40 Ma的过渡时期,前锋开始于100~109 Ma,导源的岩浆大致沿NWW和NEE向的大型断裂带分布。进一步证实了软流圈地幔上隆的不均匀性和主动性。     

鲁西金岭地区含矿闪长岩体成因:来自锆石U-Pb年代学和地球化学证据

鲁西金岭闪长岩位于华北克拉通东南部,主要由辉石闪长岩-黑云母闪长岩组成。LA-ICP-MS锆石U-Pb定年测定闪长岩侵位年龄为(129.17±0.96)和(130.15±0.65)Ma,属于早白垩世岩浆活动的产物。闪长岩SiO2和K_2O的质量分数较低,MgO、Na_2O、Fe_2O_3、MgO和Al_2O_3的质量分数较高,Mg#为58.00~70.00。Na_2O/K_2O为1.08~2.96,相对富钠高铝,其里特曼指数为1.95~2.96,具有钙碱性系列的岩浆演化趋势。金岭闪长岩w(Ni)为99.00×10~(-6)~237.00×10~(-6),w(Cr)为270.00×10~(-6)~600.00×10~(-6),w(Co)为19.00×10~(-6)~44.00×10~(-6),表明其具有幔源岩浆的属性。稀土元素球粒陨石标准化曲线表明样品具有富集轻稀土元素(LREE),亏损重稀土元素(HREE)以及弱Eu(δEu为0.91~1.12)异常的特征。所有样品富集大离子亲石元素(Ba、K、Sr)和高场强元素Nd,亏损高场强元素Rb、Nb、Ta、Zr。样品中约2.5Ga古老锆石的存在证明岩浆源区受到古老下地壳物质的混染作用。鲁西金岭地区闪长岩应形成于太平洋板块俯冲后后撤引起的伸展环境,其岩浆源区是富集地幔起源的基性岩浆底侵华北古老下地壳并与下地壳熔融形成的壳源酸性岩浆混合过程的产物。     

高温高压微束衍射实验进展及其地学应用

同步辐射X射线微束衍射技术与静态高压装置(包括金刚石压砧设备和大腔体压力机设备)结合运用是研究高温高压下物质晶体结构、相变等的有效方法。金刚石压砧高温高压实验技术的发展体现在:在产生极端高温高压的同时,获得准确的实验温度压力值,采用充装气体传压介质等方法减小压力梯度,采用激光双面加温技术和改进激光光路以减小样品径向和轴向的温度梯度。大腔体压力机高温高压实验技术的发展主要表现在产生更高的实验压力,以及测试过程中使样品在一定幅度摆动以消除晶体生长和择优取向对衍射数据的影响。同步辐射X射线微束衍射技术的发展主要表现在更高亮度和更宽能量范围的同步辐射光源的使用、X射线聚焦技术的发展,以及角色散X射线衍射测试技术的进步。介绍了近年来高温高压微束衍射实验在地球科学领域所取得的一些最新进展,包括硅酸盐超钙钛矿的实验发现,铁的高温高压相变及熔融曲线、SiO2 超斯石英相变、橄榄石尖晶石相—超尖晶石相转变压力的精确测定等研究结果;认为硅酸盐超钙钛矿的进一步深入研究,水对地球深部矿物岩石力学性质及熔融行为的影响,高温高压下物质的化学反应性和地球深部元素的地球化学行为等,是今后高温高压实验研究的重要方向。     

庐枞早白垩世火山岩的地球化学特征及其源区意义

从中生代到新生代,华北东部岩石圈地幔发生了减薄以及地球化学性质置换, 而扬子地块东部中生代岩石圈地幔也表现出类似的过程,对中生代火山岩的地球化学研究有助于了解这一变化过程以及发生置换时的时空关系。庐枞火山岩出露于扬子地块东部,为一套包括粗玄岩–玄武粗安岩–粗面岩的富碱橄榄安粗岩系。研究了双庙组基性火山岩,这些岩石富集Rb,K,Sr,Th和轻稀土元素,亏损高场强元素。(87Sr/86Sr)i = 0.7060~0.7063,εNd(t )=-3.9~-6.2,(206Pb/204Pb)i=17.788~18.125,(207Pb/204Pb)i= 15.511~15.546,(208Pb/204Pb)i =37.735~38.184。在喷出地表过程中,火山岩没有受到明显的地壳物质混染,因此元素和同位素组成反映了地幔源区的地球化学特征。 其地幔源区具有同位素富集特征,表明火山岩源区曾受到地壳物质的影响,是富集地幔部分熔融的产物,并经历明显的结晶分异作用。庐枞火山岩的岩浆成分和源区特征反映该地区在晚中生代岩石圈地幔的伸展和软流圈地幔上涌的演化过程。     

太行山南段符山高镁闪长岩的成因 —— 拆沉陆壳物质熔融的熔体与地幔橄榄岩反应的结果

本文对太行山南段符山高镁闪长岩进行了年代学与地球化学研究,结合其中地幔橄榄岩包体的研究,对符山高镁闪长岩的成因和中生代岩石圈地幔的性质进行了探讨.研究表明,符山闪长岩体是由一套含橄榄石角闪闪长岩-角闪闪长岩-闪长岩构成.含橄榄岩包体的寄主岩--角闪闪长岩中的锆石可划分为两种:一是代表寄主岩浆结晶的锆石:内部结构均匀、呈条带状吸收、自形-半自形晶形,具有较高的Th/U比值(1.10～4.08),其206Pb/238U年龄介于123～128Ma之间,12个点的加权平均值为125±1Ma,这表明岩体的形成时代为早白垩世;二是捕获或继承锆石:具有核边结构、吸收程度不均匀、呈浑圆状和自形-半自形两种,它们的Th/U比值介于0.32～2.03之间,构成了3组207Pb/206Pb加权平均年龄:2503±11Ma、2181±26Ma和1778±36Ma.该类岩石的SiO2和MgO含量分别介于56.69%～59.21%和3.60%～6.33%之间;且以高:Mg#(0.51～0.64)、富Na(Na2O/K2O大于1)、高Cr(93.1×10-6～420×10-6)、Ni(35.1×10-6～137×10-6)为特征.该类岩石强烈富集轻稀土元素和大离子亲石元素、明显亏损高场强元素,(87Sr/86Sr)I、εNd(t)值和(206Pb/204Pb)I分别变化于0.70581～0.70641、-8.30～-16.56和17.052～17.512之间.综合上述特征,同时结合地幔橄榄岩包体的特征和古元古代捕获锆石的大量存在,认为符山高镁闪长岩的原始岩浆起源于拆沉陆壳物质的部分熔融,其后经历了与地幔橄榄岩的反应过程.     

华北晚中生代中基性侵入岩中橄榄岩捕虏体是岩石圈地幔直接样品？

华北东部晚中生代中基性侵入杂岩体（如山东莱芜地区铁铜沟岩体；山东潍坊地区金岭．湖田岩体；河北邯邢地区符山岩体）中常含有橄榄岩捕虏体。这些橄榄岩的来源和成因问题存在很大争议，主要有堆晶成因或代表古老洋壳蛇绿岩和岩石圈地幔来源两种观点。本文在对山东潍坊地区金岭一湖田岩体中橄榄岩捕虏体的研究成果和总结前人资料的基础上，通过岩石学、矿物学和地球化学研究认为这些橄榄岩捕虏体皆是堆晶成因或代表古老洋壳蛇绿岩，而非岩石圈地幔直接样品。因此，不能用这些橄榄岩捕虏体的组成来反演该地区晚中生代岩石圈地幔特征。     

山东铁铜沟橄榄岩的水含量:华北克拉通早白垩世富水岩石圈的分布

已有研究表明,华北克拉通东部的山东费县岩石圈地幔在克拉通破坏峰期(早白垩世)时是高度富水的,其中橄榄石的H₂O含量＞180×10-6;而同期克拉通西部的太行山符山地区岩石圈地幔具有贫水特征,其中橄榄石的H₂O含量为~10×10-6.这表明西向俯冲的古太平洋板块造成了华北东部早白垩世岩石圈地幔的富水特征,为克拉通破坏提供了力学前提.为了解古太平洋板块俯冲的影响范围,对介于费县和符山之间的山东铁铜沟地区早白垩世高镁闪长岩中的橄榄岩捕掳体进行了含水性分析,橄榄石的原始H₂O含量(6×10-6~24×10-6,平均值为(15±7)×10-6)与符山地区相当,暗示太平洋板块俯冲造成的岩石圈富水效应可能仅局限在华北最东部,这和最东部地区克拉通破坏程度最高是一致的.      

Episodic widespread magma underplating beneath the North China Craton in the Phanerozoic: Implications for craton destruction

A comprehensive synthesis of U–Pb geochronology and Hf isotopes of zircons from granulite/pyroxenite xenoliths entrained in Phanerozoic magmatic rocks and inherited xenocrysts from the associated lower crust rocks from various domains of the North China Craton (NCC) provides new insights into understanding the Phanerozoic evolution of the lower crust in this craton. Episodic widespread magma underplating into the ancient lower crust during Phanerozoic has been identified throughout the NCC from early Paleozoic to Cenozoic, broadly corresponding to the Caledonian, Hercynian, Indosinian, Yanshanian, and Himalayan orogenies on the circum-craton mobile belts. The early Paleozoic (410–490 Ma) ages come from xenoliths in the northern and southern margins as well as the central domain of the Eastern Block of the craton which mark the first phase of Phanerozoic magma underplating since the final cratonization of the NCC in the Paleoproterozoic. The magmatism coincided with the northward subduction of the Paleotethysian Ocean in the south and the southward subduction of the Paleoasian Ocean in the north. The subduction not only triggered magma underplating but also led to the emplacement of the diamondiferous kimberlites on the craton, marking the initiation of decratonization. The late Paleozoic event as represented by the 315 Ma garnet pyroxenite and/or lherzolite xenoliths in Hannuoba was restricted to the northern and southern margins of the craton, correlating with the arc magmatism continuous associated with the subduction of the Paleotethysian and Paleoasian Oceans and resulting in the interaction between the melts from subducted slabs and the lithospheric mantle/lower crust. The early Mesozoic event also dominantly occurred in the northern and southern margins and was related with the final closure of the Paleotethysian and Paleoasian Oceans as well as the collisional orogeny between the NCC and the Yangtze Craton. The late Mesozoic (ca. 120 Ma) was a major and widespread magmatic event which manifested throughout the NCC, associated with the geothermal overturn due to the giant south Pacific mantle plume. The Cenozoic magmatism, identified only in the dark clinopyroxenite xenoliths in the Hannuoba, was probably induced by the Himalayan movement in eastern Asia and might also have been influenced by the subduction of the Pacific Ocean to some extent. These widespread and episodic magma underplating or rejuvenation of the ancient lower crust beneath the NCC revealed by U–Pb and Hf isotope data resulted from the corresponding addition of juvenile materials from mantle to lower crust, with a mixing of the old crust with melts. The process inevitably resulted in the compositional modification of the ancient lower crust, similar to the compositional transformation from the refractory lithospheric mantle to a fertile one through the refractory peridotite — infiltrated melt reaction as revealed in the lithospheric mantle beneath the craton.     

鲁西中生代高镁闪长岩的地球化学特征及其成因探讨

鲁西中生代侵入岩包括辉长岩,闪长岩,花岗闪长岩和花岗岩,以闪长岩最为常见。莱芜和沂南等地的闪长岩具有高Mg#(0.45～0.69),Cr(<278μg/g)的特点,并富集大离子亲石元素(LILE)和亏损高场强元素(HFSE),其总体成分特点类似于北美苏必利尔省的太古代高镁闪长岩和产于现代俯冲带的高镁安山岩。不过鲁西高镁闪长岩的HREE含量相对较高(Yb=1.1～1.9μg/g),La/Yb比值相对较低(6.7～20),其成分更接近于Piip型高镁安山岩。鲁西高镁闪长岩代表了华北地台早期拉张环境下的岩浆活动,可能是受深俯冲扬子大陆下地壳释放的埃达克质熔体交代的岩石圈地幔直接熔融的产物。     

华北克拉通东部中生代岩石圈减薄的过程与机制:中生代火成岩和深源捕虏体证据

基于最新的同位素年代学资料 ,华北克拉通东部中生代的岩浆作用可划分成四个阶段 ,即晚三叠世 ( 2 0 5～ 2 2 5Ma)碱性岩浆作用 ;中晚侏罗世 ( 1 5 5～ 1 6 0Ma)花岗质岩浆作用 ;早白垩世 ( 1 1 2～ 1 32Ma)双峰式岩浆作用和晚白垩世 ( 92～ 73Ma)碱性玄武质岩浆作用。徐淮地区中生代侵入岩中榴辉岩捕虏体的发现及其地质年代学资料 ( 2 1 9Ma)表明 ,华北克拉通东部中生代早期曾发生过一次重要的陆壳加厚过程。俯冲板片的断离以及高压—超高压变质岩的快速折返和晚三叠世 ( 2 0 5～ 2 2 5Ma)的碱性岩浆作用的存在均暗示 ,华北克拉通中生代岩石圈减薄已经开始。拆沉作用则是引起中生代早期岩石圈减薄的主要机制。中、晚侏罗世 ( 1 5 5～ 1 6 0Ma)花岗质岩浆作用形成于造山期后的伸展环境 ,代表了中生代岩石圈减薄的继续和发展。早白垩世 ( 1 1 2～ 1 32Ma)双峰式岩浆作用表明中生代岩石圈减薄达到了峰期。而幔源纯橄岩捕虏体中富硅质熔体的交代作用和玄武岩的高87Sr/ 86Sr值、低ε(Nd ,t)值特征表明 ,软流圈对岩石圈底部的化学侵蚀可能是导致该阶段岩石圈减薄的主导机制。晚白垩世 ( 92～ 73Ma)碱性玄武质岩浆作用和“海洋型”地幔捕虏体的存在代表了等温面的下降和岩石圈地幔的增生     

Mechanism and timing of lithospheric modification and replacement beneath the eastern North China Craton: Peridotitic xenoliths from the 100 Ma Fuxin basalts and a regional synthesis

Lithospheric thinning beneath the eastern North China Craton is widely recognized, but the mechanism and timing of the thinning are contentious. New data on peridotitic xenoliths from the Cretaceous (∼100 Ma) Fuxin basalts at the northern edge of the craton have been integrated with data from other localities across the craton, to provide an overview of the processes involved. The Fuxin peridotite xenoliths can be subdivided into three types, which can also be recognized in other xenolith suites across the craton. The dominant Type 1, lherzolites with olivine Mg^# ∼90, represents fertile mantle (5-12% partial-melt extraction) that makes up much of the Late Mesozoic-Cenozoic lithosphere beneath the craton. Type 2 consists of magnesian (olivine Mg^# >92) harzburgites, interpreted as shallow relics of the Archean cratonic mantle. Type 3, minor lherzolite xenoliths with olivine Mg^# ∼86 reflect the interaction of the lithosphere with magmas similar to the host basalts. In-situ Re-Os data on sulfides in xenoliths from Hebi (4 Ma, interior of the craton) and Hannuoba (22 Ma, northern edge of the Trans-North China Orogen within the craton) basalts give model ages of 3.1-3.0, 2.5, 2.2-2.1, 1.4 and 0.8 Ga, These correspond to the U-Pb ages of zircons from early Mesozoic (178 Ma) peridotitic xenoliths at the southern margin of the craton, and record events during which the Archean lithospheric mantle was modified. The dominance of fertile peridotite xenoliths in the 100 Ma Fuxin basalts indicates that the mantle replacement beneath the eastern North China Craton at least partly took place before that time. The regional synthesis suggests that Mesozoic-Cenozoic lithospheric thinning and mantle replacement was heterogeneously distributed across the North China Craton in space and time. Lateral spreading of the lithosphere, accompanied by asthenospheric upwelling and melt-peridotite interaction, is the most probable mechanism for the lithospheric thinning beneath the eastern part of the craton. Subsequent cooling of the upwelled asthenosphere caused some re-thickening of the lithosphere; this overall more fertile and hence denser lithosphere resulted in widespread basin formation.     

柴北缘西段晚古生代牛鼻子梁高镁闪长岩成因机制及地球动力学过程

牛鼻子梁地区首次发现的高镁闪长岩对于探讨柴北缘地区岩石圈地幔演化历史具有重要意义.为确定该类岩石成因及地球动力学过程,对其开展矿物学、岩石主-微量元素分析、锆石U-Pb定年和Hf同位素分析工作.岩石地球化学特征显示,岩石均为钙碱性岩石,具有富Mg（Mg#=62~72）、Cr、Ni、LREE（LREE/HREE=2.84~4.61）值、低FeOT/MgO（0.70~1.12）比值特征,属于高镁闪长岩;所有样品均表现出富集大离子亲石元素（Rb、Ba、Th、U、K）和LREE,而相对亏损高场强元素Nb、Ta、Ti、P和HREE,与典型的"赞岐岩"地球化学特征一致;锆石U-Pb同位素年代学研究表明岩石形成时代为388 Ma,为中泥盆世岩浆作用的产物.锆石Hf同位素特征显示岩石ε_Hf（t）均为正值（4.4~11.6）,表明岩浆起源于亏损地幔.结合区域构造演化过程认为,牛鼻子梁高镁闪长岩是由早古生代（540~520 Ma）消减带流体交代地幔楔后的富集地幔经历晚古生代（400~388 Ma）岩石圈伸展作用部分熔融的产物.      

Late Mesozoic magmatism in the Jiaodong Peninsula,East China:Implications for crust-mantle interactions and lithospheric thinning of the eastern North China Craton

A section from the Linglong gold deposit on the northwestern Jiaodong Peninsula,East China,containing Late Mesozoic magmatic rocks from mafic and intermediate dikes and felsic intrusions,was chosen to investigate the lithospheric evolution of the eastern North China Craton(NCC).Zircon U-Pb data showed that low-Mg adakitic monzogranites and granodiorite intrusions were emplaced during the Late Jurassic(～145 Ma) and late Early Cretaceous(112-107 Ma),respectively;high-Mg adakitic diorite and mafic dikes were also emplaced during the Early Cretaceous at～139 Ma and ～118 Ma,and 125-145 Ma and 115-120 Ma,respectively.The geochemical data,including whole-rock major and trace element compositions and Sr-Nd-Pb isotopes,imply that the mafic dikes originated from the partial melting of a lithospheric mantle metasomatised through hydrous fluids from a subducted oceanic slab.Low-Mg adakitic monzogranites and granodiorite intrusions originated from the partial melting of the thickened lower crust of the NCC,while high-Mg adakitic diorite dikes originated from the mixing of mafic and felsic melts.Late Mesozoic magmatism showed that lithosphere-derived melts showed a similar source depth and that crust-derived felsic melts originated from the continuously thickened lower crust of the Jiaodong Peninsula from the Late Jurassic to Early Cretaceous.We infer that the lower crust of the eastern NCC was thickened through compression and subduction of the Palaeo-Pacific plate beneath the NCC during the Middle Jurassic.Slab rollback of the plate from ～160 Ma resulted in lithospheric thinning and accompanied Late Mesozoic magmatism.     

Linking continental deep subduction with destruction of a cratonic margin: strongly reworked North China SCLM intruded in the Triassic Sulu UHP belt

The collision between the North and South China cratons in Middle Triassic time (240–225 Ma) created the world’s largest belt of ultrahigh-pressure (UHP) metamorphism. U–Pb ages, Hf isotope systematics and trace element compositions of zircons from the Xugou, Yangkou and Hujialing peridotites in the Sulu UHP terrane mainly record a ~470 Ma tectonothermal event, coeval with the Early Paleozoic kimberlite eruptions within the North China craton. This event is interpreted as the result of metasomatism by fluids/melts derived from multiple sources including a subducting continental slab. The peridotites also contain zircons with ages of ~3.1 Ga, and Hf isotope data imply a component ≥3.2 Ga old. Most zircon Hf depleted mantle model ages are ~1.3 Ga, suggesting that the deep subcontinental lithospheric mantle beneath the southeastern margin of the North China craton experienced a intense mid-Mesoproterozoic metasomatism by asthenospheric components, similar to the case for the eastern part of this craton. Integrating data from peridotites along the southern margin of the craton, we argue that the deep lithosphere of the cratonic margin (≥3.2 Ga old), from which the Xugou, Yangkou and Hujialing peridotites were derived, experienced Proterozoic metasomatic modification, followed by a strong Early Paleozoic (~470 Ma) tectonothermal event and the Early Mesozoic (~230 Ma) collision and northward subduction of the Yangtze craton. The Phanerozoic decratonization of the eastern North China craton, especially along its southern margin, was not earlier than the Triassic continental collision. This work also demonstrates that although zircons are rare in peridotitic rocks, they can be used to unravel the history of specific lithospheric domains and thus contribute to our understanding of the evolution of continental cratons and their margins.     

辽东青城子矿集区姚家沟钼矿床成矿物质来源、成矿年代及成矿动力学背景

本文对辽东青城子矿集区姚家沟钼矿床与成矿密切的姚家沟花岗岩进行了元素地球化学、锆石LA-ICP-MS U-Pb定年和矿床金属硫化物硫同位素系统分析。结果表明:姚家沟花岗岩侵入时代为(167.47±0.87)Ma,具有富硅、富铝、全碱含量中等、过铝质-强过铝质的特征;稀土配分模式呈现轻稀土富集、重稀土亏损的右倾型,Eu弱正异常;富集K、Rb、U、Sr、Pb等大离子亲石元素,亏损Nb、Ti、P等高场强元素,δ34S值为2.0‰~3.9‰,平均值为2.7‰。结合姚家沟矿床辉钼矿Re-Os同位素研究成果进一步得出,姚家沟岩体至少为两期岩浆活动的产物,辉钼矿成矿与本次获得的(167.47±0.87)Ma岩浆活动有关,二者成岩、成矿时代一致。硫同位素指示成矿物质来源于岩浆。姚家沟钼矿成岩、成矿构造背景为受古亚洲洋闭合影响,华北板块与西伯利亚板块后碰撞造山阶段构造-岩浆-流体活动的环境。     

青海治多地区晚三叠世石英闪长岩地球化学特征及成岩动力学背景

对羌塘地块东北缘甘孜-理塘缝合带南侧日啊日曲石英闪长岩进行了系统的锆石U-Pb年龄、主量-微量元素及Sr-Nd同位素分析, 以探讨其岩石成因及地球动力学意义.LA-ICP-MS锆石U-Pb定年结果表明, 石英闪长岩侵位年龄为218±1 Ma, 为晚三叠世岩浆活动的产物.岩石SiO₂含量介于53.02%~62.06%之间, 富Al₂O₃(15.84%~17.00%)和CaO(6.71%~8.94%), 贫TiO₂(0.49%~1.01%)和P₂O₅(0.04%~0.12%), 具有较高的MgO(3.31%~5.66%)和Mg#(50~62), 属准铝质钙碱性系列; 岩体稀土元素总量较低(38.05×10-6~61.58×10-6), 轻重稀土分馏不明显, LILE富集, HFSE亏损, 具有含量较高的Cr(33.45×10-6~176.64×10-6)和Ni(13.34×10-6~43.62×10-6).全岩(87Sr/86Sr)_i比值较为一致(0.706 8~0.707 9), ε_Nd(t)变化于-5.5~-1.6.主微量元素及同位素结果表明日啊日曲石英闪长岩具有高镁闪长岩的特征, 与赞岐岩地球化学特征类似, 为俯冲沉积物来源的熔体交代岩石圈地幔形成的尖晶石相金云母二辉橄榄岩低度(10%~15%)部分熔融的产物, 岩浆演化过程中经历了辉石、角闪石等矿物的分离结晶.微量元素构造判别图解表明岩石为俯冲环境下的弧岩浆岩, 结合区内蛇绿岩、研究区南部陆缘弧火山岩和义敦岛弧埃达克岩的发现, 认为古特提斯洋在晚三叠世时期可能仍处于消减状态, 日啊日曲高镁石英闪长岩形成于甘孜-理塘洋南西向俯冲过程中.      

Late Mesozoic magmatism from the Daye region,eastern China: U–Pb ages,petrogenesis, and geodynamic implications

Late Mesozoic dioritic and quartz dioritic plutons are widespread in the Daye region, eastern Yangtze craton, eastern China. Detailed geochronological, geochemical, and Sr–Nd isotopic studies have been undertaken for most of these plutons, in an attempt to provide a comprehensive understanding in the age, genesis and geodynamical control of the extensive magmatism. SHRIMP and LA-ICP-MS zircon U–Pb dating indicate that the plutons were emplaced in the range of latest Jurassic (ca. 152 Ma) to early Cretaceous (ca. 132 Ma), which was followed by dyke emplacement between 127 and 121 Ma and volcanism during the 130–113 Ma interval. Both diorites and quartz diorites are sodic, metaluminous, high-K calc-alkaline, and characterized by strongly fractionated, sub-parallel REE patterns without obvious Eu anomalies. The rocks are enriched in highly incompatible elements and large ion lithophile elements, but depleted in high field strength elements. Samples of diorite and quartz diorite have similar Sr–Nd isotopic compositions that are consistent with the early Cretaceous basalts and mafic intrusions throughout the eastern Yangtze craton. The geochemical and isotopic data, together with results of geochemical modeling, indicate an enriched mantle source for the plutonic rocks. The quartz diorites have geochemical signatures resembling adakites, such as high Al₂O₃ (15–19 wt.%), Sr (630–2,080 ppm), Na₂O (>3.5 wt.%), negative Nb–Ta anomalies, low Y (7–19 ppm), Yb (0.5–1.8 ppm), Sc (5–15 ppm), and resultant high Sr/Y (45–200) and La/Yb (31–63) ratios. Genesis of the adakitic quartz diorites is best explained in terms of low-pressure intracrustal fractional crystallization of cumulates consisting of hornblende, plagioclase, K-feldspar, magnetite, and apatite from mantle-derived dioritic magmas. Mantle-derived magmatism broadly coeval with that of the Daye region also is widespread in other regions of the eastern Yangtze craton, reflecting large-scale melting of the lithospheric mantle during the Late Mesozoic. The large-scale magmatism was most likely driven by lithospheric extension associated with thinning of lithospheric mantle beneath the eastern China continent.     

内蒙古乌拉特中旗哈达呼舒基性岩体形成的构造背景与古亚洲洋的早期俯冲历史

内蒙古乌拉特中旗地区在大地构造上横跨华北板块边缘和兴蒙造山带,区域基性岩体多以小岩株形式产出,侵入时代缺少可靠的资料.对乌拉特中旗哈达呼舒基性岩进行锆石U-Pb年代学、岩石地球化学以及Hf同位素研究,对其岩石成因和古亚洲洋板块俯冲作用的开始时间给予制约.哈达呼舒基性岩锆石LA-ICP-MS U-Pb定年结果表明,该岩体形成于晚寒武世(513±2 Ma).在地球化学上,它们属于钙碱性系列,富集大离子亲石元素(如K、Rb、Ba),亏损高场强元素(如Nb、Ta、Zr、Ti)和LREE.岩石的ε_Hf(t)值为14.15~15.03,单阶段模式年龄(T_DM1)为518~556 Ma,与岩石原岩形成时代513 Ma相近,认为其原始岩浆起源于亏损岩石圈地幔.综合区域同时代火成岩的研究成果,认为哈达呼舒基性岩体形成于古亚洲洋俯冲消减环境.