230Th,226Ra and222Rn in abyssal sediments

A model that predicts the flux of²²²Rn out of deep-sea sediment is presented. The radon is ultimately generated by²³⁰Th which is stripped from the overlying water into the sediment. Data from many authors are compared with the model predictions. It is shown that the continental contribution of ionium is not significant, and that at low sedimentation rates, biological mixing and erosional processes strongly affect the surface concentration of the ionium. Two cores from areas of slow sediment accumulation, one from a manganese nodule region of the central Pacific and one from the Rio Grande Rise in the Atlantic were analyzed at closely spaced intervals for²³⁰Th,²²⁶Ra, and²¹⁰Pb. The Pacific core displayed evidence of biological mixing down to 12 cm and had a sedimentation rate of only 0.04 cm/kyr. The Atlantic core seemed to be mixed to 8 cm and had a sedimentation rate of 0.07 cm/kyr. Both cores had less total excess²³⁰Th than predicted.Radium sediment profiles are generated from the²³⁰Th model. Adsorbed, dissolved, and solid-phase radium is considered. According to the model, diffusional losses of radium are especially important at low sedimentation rates. Any particulate, or excess radium input is ignored in this model. The model fits the two analyzed cores if the fraction of total radium available for adsorption-desorption is about 0.5–0.7, and ifK, the distribution coefficient, is about 1000.Finally, the flux of radon out of the sediments is derived from the model-generated radium profiles. It is shown that the resulting standing crop of²²²Rn in the overlying water may be considered as an added constraint in budgeting²³⁰Th and²²⁶Ra in deep-sea sediments.     

The flux of226Ra from deep-sea sediments

The flux of²²⁶Ra from bottom sediments has been determined from patterns of²²⁶Ra/²³⁰Th disequilibrium in ten deep-sea cores from the world oceans. Values range from ? 0.0015 dpm/cm² yr (in the Atlantic) to 0.21 dpm/cm² yr (in the north equatorial Pacific). The flux is poorly related to sediment type, but is inversely correlated in a non-linear fashion with sediment accumulation rate. There is a direct relationship between the production rate of²²⁶Ra near the sediment-water interface (i.e. the integrated²³⁰Th activity in the biologically mixed zone) and the²²⁶Ra flux. The²²⁶Ra concentration in near-bottom water follows the geographic variation in the²²⁶Ra flux. The high flux from north equatorial Pacific sediments especially is reflected in the high bottom water²²⁶Ra concentrations in that area. The data suggest that both rate of circulation and the magnitude of the radium flux influence the near-bottom²²⁶Ra concentration.     

Uranium and thorium series nuclides in oriented ferromanganese nodules: growth rates,turnover times and nuclide behavior

Three ferromanganese nodules handpicked from the tops of 2500 cm² area box cores taken from the north equatorial Pacific have been analysed for their U-Th series nuclides.²³⁰Th_exc concentrations in the surface 1–2 mm of the top side of the nodules indicate growth rates of 1.8–4.6 mm/10⁶ yr. In two of the nodules a significant discontinuity in the²³⁰Th_exc depth profile has been observed at ～0.3 m.y. ago, suggesting that the nodule growth has been episodic. The concentration profiles of²³¹Pa_exc (measured via²²⁷Th) yield growth rates similar to the²³⁰Th_exc data. The bottom sides of the nodules display exponential decrease of²³⁰Th_exc/²³²Th activity ratio with depth, yielding growth rates of 1.5–3.3 mm/10⁶ yr.The²³⁰Th_exc and²³¹Pa_exc concentrations in the outermost layer of the bottom face are significantly lower than in the outermost layer of the top face. Comparison of the extrapolated²³⁰Th_exc/²³²Th and²³⁰Th_exc/²³¹Pa_exc activity ratios for the top and bottom surfaces yields an “age” of (5?15) × 10⁴ yr for the bottom relative to the top. This “age” most probably represents the time elapsed since the nodules have attained the present orientation.The²¹⁰Pb concentration in the surface ～0.1 mm of the top side is in large excess over its parent²²⁶Ra. Elsewhere in the nodule, up to ～1 mm depth in both top and bottom sides,²¹⁰Pb is deficient relative to²²⁶Ra, probably due to²²²Rn loss. The absence of²¹⁰Pb_exc below the outermost layer of the top face rules out the possibility of a sampling artifact as the cause of the observed exponentially decreasing²³⁰Th_exc and²³¹Pa_exc concentration profiles. The flux of²¹⁰Pb_exc to the nodules ranges between 0.31 and 0.58 dpm/cm² yr. The exhalation rate of²²²Rn, estimated from the²²⁶Ra-²¹⁰Pb disequilibrium is ～570 dpm/cm² yr from the top side and >2000 dpm/cm² yr from the bottom side.²²⁶Ra is deficient in the top side relative to²³⁰Th up to ～0.5–1 mm and is in large excess throughout the bottom. The data indicate a net gain of²²⁶Ra into the nodule, corresponding to a flux of (24?46) × 10^?3 dpm/cm² yr. On a total area basis the gain of²²⁶Ra into the nodules is <20% of the²²⁶Ra escaping from the sediments. A similar gain of²²⁸Ra into the bottom side of the nodules is reflected by the high²²⁸Th/²³²Th activity ratios observed in the outermost layer in contact with sediments.     

226Ra behavior in the Pee Dee River-Winyah Bay estuary

Concentrations of dissolved²²⁶Ra in Winyah Bay, South Carolina, and in the adjacent Atlantic Ocean are augmented by the desorption of radium from sediments in the low-salinity area of the estuary and diffusion from bottom sediments. Desorption of²²⁶Ra is reflected by lower concentrations in suspended sediments from higher-salinity regions of the estuary. Bottom sediments from the high-salinity region have lower²²⁶Ra/²³⁰Th activity ratios than those from the low-salinity end.The shape of the dissolved²²⁶Ra vs. salinity profile is influenced by the river discharge. During average-discharge conditions, desorption of²²⁶Ra from suspended and bottom sediments increases the dissolved²²⁶Ra concentrations by a factor of 3.5 as the water passes through Winyah Bay. High river discharge produces an initial increase of dissolved²²⁶Ra by a factor of 2 to 3 and apparently reflects only desorption from suspended sediments. By driving the salt wedge down the estuary and reducing the zone of contact of salt water with bottom sediments, the high-flow conditions sharply reduce the flux of²²⁶Ra from bottom sediments.     

The uranium and thorium decay series nuclides in Mt. St. Helens effusives

The concentrations of the radionuclides²³⁸U,²³⁰Th,²²⁶Ra,²¹⁰Pb,²¹⁰Po,²³²Th,²²⁸Ra and²²⁸Th and the abundances of major elements were determined in samples from all major eruptions of Mt. St. Helens from May 18, 1980 through June 21, 1981. During this time the effusives changed from plagioclase-phyric dacite to a more andesitic composition but the concentrations of U and Th series nuclides were measurably invariant. The average²³²Th/²³⁸U weight ratio in the rocks is 2.4 and the²³⁰Th/²³²Th activity ratio equals the²³⁸U/²³²Th activity ratio indicating no fractionation of U from Th during magma genesis.²²⁶Ra activity is in excess (～40% on average) of its parent²³⁰Th whereas²²⁸Ra is in radioactive equilibrium with its parent²³²Th, constraining the time of magma formation between 30 and 10⁴ years prior to eruption. The²¹⁰Pb/²²⁶Ra activity ratios in the samples average 1.0, with a 20% scatter on either side, but allowing for volatile²¹⁰Pb loss at time of eruption excess²¹⁰Pb over²²⁶Ra is inferred, indicating that the time of magma formation was within the last 150 years.²¹⁰Po was virtually absent in the samples immediately after eruption, indicating its total loss by volatilization during eruption. The quantity of²¹⁰Po volatilized during the May 18, 1980 event is estimated to be in the range of 300 Ci from the effusives and as much as 5000 Ci total including losses from heated slide material. The²²²Rn activity volatilized should have been comparable to the²¹⁰Po activity released.     

The effects of alteration and the interpretation of heat flow and radioactivity data—a reply to R.U.M. Rao

The first²²⁴Ra (t_1/2 = 3.64days) measurements from mixing zones of estuarine systems are presented for the Pee Dee River-Winyah Bay and Delaware Bay Estuaries. High-resolution gamma-ray spectrometry was used to determine²²⁴Ra,²²⁸Ra (t_1/2 = 5.7years), and²²⁶Ra (t_1/2 = 1622years) activity ratios. Desorption and diffusion from suspended and bottom sediments contributes to the non-conservative increases of the three isotopes in each systems. In Delaware Bay²²⁴Ra concentrations were nearly constant over the 2.5‰ to 15‰ salinity range where two turbidity maximum zones are located.²²⁸Th scavenging onto the suspended particles in the turbid zones may supply a regenerative source of²²⁴Ra in this system. Samples collected on the ebb and flood tide from a salt marsh along Delaware Bay have a 5-fold increase in²²⁴Ra from flood to ebb and 3- and 2-fold increases for²²⁸Ra and²²⁶Ra respectively, indicating salt marshes are another source of radium to estuarine waters.     

226Ra distribution in the Antarctic Ocean

²²⁶Ra data on eleven vertical profiles taken during the GEOSECS program from the Antarctic Ocean and its vicinity in both the Atlantic and the Pacific are presented. Replicate measurements were made on each sample using the Rn-emanation method. The precision (1 σ) based on triplicate analyses averages about ±2.5%. Waters all around the Antarctic continent below 2 km depth appear to exhibit a uniform²²⁶Ra concentration of 21.5 ± 1dpm/100kg, except perhaps locally such as the Ross Sea and the Drake Passage where small variations may be present. Higher in the water column, the²²⁶Ra contents decrease toward the surface with gradients which vary as a function of the influence exerted by the Antarctic Convergence. Across this oceanic front, a north-to-south increase of²²⁶Ra occurs (the increase being the largest near the surface: from 8 to 18 dpm/100 kg), reflecting the combining effect of deep-water upwelling and meridional water mixing. The core layer of the Antarctic Intermediate Water contains about 14 dpm/100 kg of²²⁶Ra and that of the Circumpolar Intermediate Water (O₂ minimum and local T maximum) about 18 dpm/100 kg. To a first approximation,²²⁶Ra covaries with Si in the circumpolar waters.     

Radium isotopes in sub-Arctic waters

Measurements of the²²⁸Ra/²²⁶Ra activity ratio in the waters of the Greenland, Norwegian and Labrador Seas and Baffin Bay reveal strong horizontal gradients in the surface waters. The coastal waters are dominated by²²⁸Ra injection from nearshore sediments. There is an inverse correlation between the²²⁸Ra/²²⁶Ra activity ratio and salinity in the 30–36‰ salinity range. Vertical profiles indicate that the²²⁸Ra/²²⁶Ra activity ratio is also strongly coupled toσ_θ except for some regions where²²⁸Ra is being injected into higher density water as these isopycnals intersect coastal areas. We use these measurements in the area of formation of North Atlantic Deep Water to estimate that this water mass forms with a²²⁸Ra/²²⁶Ra activity ratio of 0.10.     

U-series dating of Lake Nyos maar basalts,Cameroon (West Africa): Implications for potential hazards on the Lake Nyos dam

From previously published ¹⁴C and K–Ar data, the age of formation of Lake Nyos maar in Cameroon is still in dispute. Lake Nyos exploded in 1986, releasing CO₂ that killed 1750 people and over 3000 cattle. Here we report results of the first measurements of major elements, trace elements and U-series disequilibria in ten basanites/trachy-basalts and two olivine tholeiites from Lake Nyos. It is the first time tholeiites are described in Lake Nyos. But for the tholeiites which are in ²³⁸U–²³⁰Th equilibrium, all the other samples possess ²³⁸U–²³⁰Th disequilibrium with 15 to 28% enrichment of ²³⁰Th over ²³⁸U. The (²²⁶Ra/²³⁰Th) activity ratios of these samples indicate small (2 to 4%) but significant ²²⁶Ra excesses. U–Th systematics and evidence from oxygen isotopes of the basalts and Lake Nyos granitic quartz separates show that the U-series disequilibria in these samples are source-based and not due to crustal contamination or post-eruptive alteration. Enrichment of ²³⁰Th is strong prima facie evidence that Lake Nyos is younger than 350 ka. The ²³⁰Th–²²⁶Ra age of Nyos samples calculated with the (²²⁶Ra/²³⁰Th) ratio for zero-age Mt. Cameroon samples is 3.7 ± 0.5 ka, although this is a lower limit as the actual age is estimated to be older than 5 ka, based on the measured mean ²³⁰Th/²³⁸U activity ratio. The general stability of the Lake Nyos pyroclastic dam is a cause for concern, but judging from its ²³⁰Th–²²⁶Ra formation age, we do not think that in the absence of a big rock fall or landslide into the lake, a big earthquake or volcanic eruption close to the lake, collapse of the dam from erosion alone is as imminent and alarming as has been suggested.     

Meridional distribution of226Ra in the eastern Pacific along GEOSECS cruise tracks

We present the distribution of²²⁶Ra in eight vertical profiles from the eastern Pacific. The profiles are located along a meridional trend near 125°W, from 43°S to 29°N. Surface²²⁶Ra concentrations are about 7 dpm/100 kg, except for the two stations south of 30°S where the higher values are due to the Antarctic influence. Deep waters show a distinctive south-to-north increase in the²²⁶Ra content, from about 26 to 41 dpm/100 kg near the bottom. Unlike in the Atlantic and Antarctic Oceans, the effect of²²⁶Ra injection from bottom sediments is clearly discernible in the area. The presence of this primary²²⁶Ra can be traced up to at least 1–1.5 km above the ocean floor, making this part of the sea bed among the strongest source regions for the oceanic²²⁶Ra. Numerical solutions of a two-dimensional vertical advection-diffusion model applied to the deep (1.2–4 km)²²⁶Ra data give the following set of best fits: upwelling velocity(V_z) = 3.5m/yr, vertical eddy diffusivity(K_z) = 0.6cm²/s, horizontal (north-south) eddy diffusivity(K_y) = 1 × 10⁷cm²/s, and water-column regeneration flux of²²⁶Ra(J) = 3.3 × 10^?5dpmkg^?1yr^?1 as an upper limit. These parametric values are in general agreement with one-dimensional (vertical) model fits for the Ra-Ba system. However, consideration of²²⁶Ra balance leads us to suspect the appropriateness of describing the vertical exchange processes in the eastern Pacific with constantV_z and K_z. If future modeling is attempted, it may be preferable to treat the area as a diffusion-dominant mixing regime with depth-dependent diffusivities.     

The water column distributions of thorium isotopes in the western North Pacific

Four vertical profiles of²³⁰Th and²²⁸Th were determined using large volume water samples in the western North Pacific. An almost linear increase of²³⁰Th with depth was observed for all of the profiles for which the unidirectional first order scavenging model was difficult to explain. We developed a model which included a dissolved-particulate transformation as well as parameters of the scavenging model. Application of the model to the vertical distributions of total and the GEOSECS particulate Th isotopes (²³⁰Th and²³⁴Th) yielded the residence time of dissolved Th with respect to adsorption to particles and the turnover time of particulate Th to be 235 days and 57 days, respectively. The Th isotopes appeared to be carried down the water column by fine particles with a mean settling velocity of 1 m/day which continually release Th into sea water as well as pick up Th from the water along their journey to the bottom.For²²⁸Th, a large excess over²³²Th was observed throughout the water column with pronounced high concentrations in surface and bottom waters, suggesting that the²²⁸Th was derived from²²⁸Ra diffused out of sediments. The vertical distributions of²²⁸Th seemed to be significantly influenced by lateral mixing along isopycnals.     

Radium and thorium isotopes in the surface waters of the East Pacific and coastal Southern California

A fiber extraction technique is used to concentrate Ra and Th isotopes from 1000 liters or more of seawater. Natural²²⁶Ra and²³⁴Th are used as yield tracers. In the equatorial Pacific the²²⁸Ra activity of surface water varies from 20 to 1 dpm/1000 kg and generally decreases away from continental shelf areas. Across the Peru Current System, this decrease is modeled as one-dimensional diffusion and indicates the possibility of two flow regimes with distinct characteristic mixing lengths and apparent eddy diffusivities of 10⁵ and 10⁷ cm²/s. The perturbing effects of advection and equatorial upwelling west of the Galapagos Islands are noted. Off the coast of Southern California a vertical²²⁸Ra distribution gives an apparent diffusivity of 1.6 cm²/s for the upper thermocline.²²⁶Ra concentrations near the coast appear to be higher than the open ocean values at comparable depths, which may reflect supply of this isotope from continental shelf sediments and/or upwelling. The insoluble daughter/soluble parent activity ratios²²⁸Th/²²⁸Ra and²³⁴Th/²³⁸U in the equatorial Pacific surface water display latitudinal trends which may be correlated with productivity variations. Near the coast of California these ratios reflect the differing oceanographic conditions north and south of Pt. Conception indicating a mean chemical removal time constant on the order of 4 months for Th and other highly reactive elements within the Southern California Bight. The²³²Th content of seawater sampled is less than 0.1 μg/1000 1; most of the published values for seawater²³²Th could well be too high. A comparison of the two methods of determining²²⁸Ra (via²²⁸Ac and via²²⁸Th) made on 64 seawater samples shows that the time delay required by the²²⁸Th method is more than compensated by its better analytical simplicity and precision.     

Investigations of gram quantities of Atlantic and Pacific surface particulates

Particulates amounting to 0.1–2.0 g efficiently collected from large volumes of Atlantic and Pacific surface waters have been analyzed for carbonate, opal, quartz and several natural and man-made radioisotopes.The concentrations of particles range between 10 and 600 μg/kg. In the equatorial regions particle concentrations are low and similar in both the oceans. At higher latitudes (>30°N or S), the Atlantic waters, however, have higher concentrations of particles compared to those in the Pacific. The latitudinal distribution exhibits a north-south symmetry with higher concentrations in the 30°–60° belt. Based on the particulate abundance for CaCO₃ and opal and their sedimentation, we have estimated their production and in-situ integrated dissolution rates for a few regions.Radioisotopes having different source functions, namely¹⁴C and²³⁹Pu injected due to nuclear weapon tests,²³⁴Th,²³⁰Th and²²⁸Th produced in-situ in seawater,²³²Th which derives primarily from land,²¹⁰Pb introduced via wet precipitations and²²⁶Ra introduced through diffusion from deep-sea sediments have been measured in the particulates. The relative enrichment factors for these nuclides in particles vary as Th ? Pu > Pb > Ra. The atmospheric bomb fallout pattern is discernible in the surface particulates; the²³⁹Pu concentration increases with latitude in both the hemispheres; however, the values are about a factor of two lower in the southern hemisphere.The distribution pattern of radioisotopes is found to be complex, even for²³⁴Th whose source function in the oceans is uniform. In view of the differences in the source functions it becomes possible to delineate the principal geochemical/geophysical processes which determine the concentrations of these nuclides in surface waters.     

Ra in the Japan Sea and the residence time of the Japan Sea water

The surface water of the Japan Sea contained²²⁶Ra of70 ± 4dpm m⁻³ which was nearly equal to that of the surface water in the North Pacific. The concentration of²²⁶Ra in the Japan Sea deep water below 500 m was151 ± 8dpm m⁻³, showing a vertically and regionally small variation. This concentration of²²⁶Ra in the deep water is unexpectedly high, because the Japan Sea deep water has a higher Δ¹⁴ C value by about 50‰ than the Atlantic deep water containing the same²²⁶Ra. One of the causes to be considered is larger contribution of²²⁶Ra from biogenic particles dissolving in the Japan Sea deep water, but the Japan Sea is not so fertile in comparison to the Bering Sea. The other more plausible cause is the internal ventilation of the Japan Sea water, which means that the residence time of the Japan Sea Proper water is considerably long although the water is vertically mixed fairly well especially in winter. The ventilation may supply some amounts of radiocarbon and oxygen but does not change the inventory of²²⁶Ra. The residence times of the Japan Sea deep water and of water within the Japan Sea are calculated by solving simultaneous equations for²²⁶Ra and¹⁴C with a three-box model to be 300–400 years and 700–1000 years, respectively.     

Variability of natural and bomb-produced radionuclide distributions in abyssal red clay sediments

The nature of sedimentation and mixing are examined in abyssal red clay sediments from the North Central Pacific using three types of indicators: ²³⁰Th/²³²Th, organic¹⁴C, and¹³⁷Cs and ^239.240Pu.²³⁰Th/²³²Th analysed revealed that the clay sedimentation rate in three box cores collected within a 50 km radius was less than 1.0 mm/10³ yr. However, analyses of the organic carbon in thin layers of sediment revealed that radiocarbon was present much deeper in the cores (down to 20 cm) than was expected from the ²³⁰Th/²³²Th distribution. In addition, both the stratigraphy and inventory of radiocarbon was significantly different between box cores. The distributions and inventories of¹³⁷Cs and^239.240Pu were similar to that found for radiocarbon, further illustrating the spatial variability of radionuclides in oligotrophic North Pacific red clays. These data suggest that bioturbational processes are important for transporting organic carbon down into the sediment column.     

Uranium and thorium isotopes in the rivers of the Amazonian basin: hydrology and weathering processes

Two expeditions (October 1989 and May 1992) were carried out to two points of the main Amazon River channel and four tributaries. The Solimões and Madeira rivers, taking their origin in the Andes, are whitewater rivers. The Negro River is a typical acid, blackwater river. The Trombetas River flows through bauxite‐rich areas, and is characterized by low concentrations of dissolved humic substances. The ²³⁸U, ²³⁴U, ²³²Th and ²³⁰Th activities were recorded from dissolved, suspended particulate phases and river bank sediments. The latter were analysed for their ²²⁶Ra, ²²⁸Ra and ²¹⁰Pb contents, and also subjected to leaching with 0·2 M hydroxylamine–hydrochloride solution to determine the concentrations of radionuclides bound to amorphous Fe hydroxides and Mn oxides and hydroxides. The dissolved U average concentration in the Amazon system is ten times lower than the mean world river concentration. The uranium concentration observed at Óbidos in the lower Amazon (0·095 µg L^?1), where the U content in the river bank sediments and suspended matter is lowest, suggests U release from the solid phase during river transport. About 485 t of U are transported annually to the Amazon delta area in dissolved form, and 1943 t bound to suspended particulate matter. Total U and Th concentrations in the river bank sediments ranged from 1·59 to 7·14 µg g^?1 and from 6·74 to 32 µg g^?1, respectively. The highest concentrations were observed in the Trombetas River. The proportion extracted by means of the hydroxylamine solution (HL) was relatively high for U in the Trombetas river bank sediment (31%) and for Th in the Solimões sediment (30%). According to the alpha recoil effects, the ²³⁴U/²³⁸U activity ratios of the Andean river waters and downstream Amazon water (Óbidos) were >1, but were <1 in the Negro River (at Manaus). The activity ratios of dissolved U correlate with pH and also with the U activity ratios in the river bank sediment hydroxylamine extracts. As expected, the ²³⁴U/²³⁸U activity ratios in river bank sediments were <1 in the Andean rivers and in the downstream Amazon, but they were >1 in the Trombetas and Negro rivers. Such ratios probably result from the binding of dissolved uranium to solid sediment. The ²²⁸Th/²³²Th ratios of river bank sediments were close to unity (except for the Negro River, where it is lower), suggesting no significant Th exchanges between the river water and the sediment. The ²²⁶Ra/²³²Th activity ratios were <1, and the ²²⁶Ra/²²⁸Ra activity ratios generally were significantly higher than the activity ratios of their respective parents. This perhaps is the result of easier leaching of the ²²⁶Ra parent, ²³⁰Th, from solid material (owing to the alpha recoil effect) than of the ²²⁸Ra parent. Uranium and thorium isotopes were used as tools to evaluate the chemical weathering rate of rocks in the Amazon system, which was estimated to be 2·7 cm 1000 year^?1 s^?1. Copyright © 2002 John Wiley & Sons, Ltd.     

Radium in the near-surface Caribbean Sea

Recent radium measurements from the near-surface Caribbean Sea are presented. The surface horizontal and vertical distributions of²²⁶Ra are essentially the same as reported by Szabo et al. (1967) for the early 1960's. The²²⁶Ra activity at the surface is relatively uniform across the Caribbean, with an average of8.2±0.4dpm/100kg. The subsurface distribution to ～200 m averages7.8±0.4dpm/100kg and increases slowly below 200 m. reaching ～9.5 dpm/100 kg at 560 m. In contrast to²²⁶Ra, the surface concentration of²²⁸Ra was much more variable in both time and space. An average increase of 33% was found between 1968 and 1976 in the western Caribbean and during both years an anomalously high²²⁸Ra activity was found in the eastern Caribbean. These data support previous hypotheses that water entering the eastern Caribbean has been enriched in²²⁸Ra prior to entry and that variable mixing of the Atlantic water masses found to the northeast and southeast of the Lesser Antilles may produce temporal variations in the near-surface²²⁸Ra activity. Scatter plots of²²⁸Ra vs. salinity and sigma-t indicate that the near-surface vertical distribution of²²⁸Ra in the Caribbean Sea is predominantly influenced by advection. Thus²²⁸Ra cannot be used to study near-surface vertical mixing rates in this region.     

Growth rates of manganese nodules in Oneida Lake,New York

²²⁶Ra is used to document the growth histories of six manganese nodules from Oneida Lake, New York. Detailed sectioning and analysis reveal that there are discontinuous gradients in²²⁶Ra content in these samples. These gradients result from periods of rapid growth (>1 mm/100 years) separated by periods of no growth of erosion. Although the²²⁶Ra “age” of the nodules approximates the age of Oneida Lake, the nodules are not sediment-covered because they occur only in areas of the lake where fine-grained sediments are not accumulating.     

Desorption of Ba and226Ra from river-borne sediments in the Hudson estuary

The pronounced desorption of Ba and²²⁶Ra from river-borne sediments in the Hudson estuary can be explained quantitatively by the drastic decrease in the distribution coefficients of both elements from a fresh to a salty water medium. The desorption in estuaries can augment, at least, the total global river fluxes of dissolved Ba and²²⁶Ra by one and nine times, respectively. The desorptive flux of²²⁶Ra from estuaries accounts for 17–43% of the total²²⁶Ra flux from coastal sediments. Two mass balance models depicting mixing and adsorption-desorption processes in estuaries are discussed.