Evolution of a Paleoproterozoic “weak type” orogeny in the West African Craton (Ivory Coast)

The Paleoproterozoic domain of the Ivory Coast lies in the central part of the West African Craton (WAC) and is mainly constituted by TTG, greenstones, supracrustal rocks and leucogranites. A compilation of metamorphic and radiometric data highlights that: i) metamorphic conditions are rather homogeneous through the domain, without important metamorphic jumps, ii) HP-LT assemblages are absent and iii) important volumes of magmas emplaced during the overall Paleoproterozoic orogeny suggesting the occurrence of long-lived rather hot geotherms. Results of the structural analysis, focused on three areas within the Ivory Coast, suggest that the deformation is homogeneous and distributed through the Paleoproterozoic domain. In details, results of this study point out the long-lived character of vertical movements during the Eburnean orogeny with a two folds evolution. The first stage is characterized by the development of “domes and basins” geometries without any boundary tectonic forces and the second stage is marked by coeval diapiric movements and horizontal regional-scale shortening. These features suggest that the crust is affected by vertical movements during the overall orogeny. The Eburnean orogen can then be considered as an example of long-lived Paleoproterozoic “weak type” orogen.     

浙闽沿岸南部泥质沉积中心表层沉积物粒度特征及其季节性差异

通过对浙闽沿岸南部泥质沉积中心15个站位夏季和冬季表层沉积物的粒度分析和对比,探讨了表层沉积物粒度的分布特征、季节性差异及其影响因素。研究结果表明,各站样品以黏土质粉砂为主,各粒度参数差别较小,平均粒径和标准偏差呈显著的负相关,偏态和尖态呈弱负相关。粒级—标准偏差曲线上,在4.92～6.46和25.32～33.27 μm之间存在高峰值,在11.16～13.39 μm之间为低谷值。粒度分布具有季节性差异,冬季样品各粒度参数分布范围均高于夏季,平均粒径（值）总体上比夏季的要小,偏态和尖态等值线的梯度明显大于夏季的。在粒级—标准偏差曲线上,冬季样品的变化程度要显著高于夏季的。粒度分布的差异主要受物质来源和海洋动力环境的季节性变化影响。     

Geological comparison of precambrian and early palaeozoic terrains between the Southern West Coast of Africa and the South-East Coast of South America

This paper describes a geological comparison of similar lithostratigraphic sequences of Proterozoic and early Palaeozoic ages between the southern west coast of Africa (Namibia and South Africa) and the south-east coast of South America (Brazil and Uruguay). The oldest terrains present within the compared regions are those comprising the Rio de la Plata and the Richtersveld Provinces of ~ 2000 Ma. Both provinces appear to have evolved from earlier Archaean terrains, i.e., the Guapore Craton in South America and the Kalahari Craton in southern Africa, during the Transamazonic and Eburnian orogenic cycles, respectively. Both the Namaqua Province, affected by the Kibaran orogenesis at ~ 1200 Ma, and the Sinclair Group of 1300 Ma seem to have no comparable geological counterparts in southern Brazil and Uruguay.The late Precambrian—early Palaeozoic successions of the Gariep and Ribeira belts investigated here seem to be remarkably similar and it is suggested that they were parts of the same geological unit, i.e., a mobile belt, developed during the Pan-African-Brasil- iano orogenesis. Geological comparisons are particularly good between the Gariep, Porongos and Lavalleja Groups, and stratigraphic correlations can be successfully at- tempted even between geological formations, i.e., Marica, Piedra de Afilar and Stink- fontein Formations.The lack of detailed geological maps for South America makes it difficult to separate different geological formations from broad lithostratigraphic successions and, consequent- ly, comparisons can only be drawn between subgroups and several geological formations, i.e., Vacacai and Minas Subgroups with Grootderm Holgat and Oranjemund Formations. The extensive magmatic activity generated during the Brasiliano orogenesis and only present in the south-east coast of South America has not affected the southern west coast of Africa. However, two post-tectonic complexes, i.e., the Kuboos—Bremen line of intrusives and the Sierra de Animas Complex appear to be geochronologically analogous and petrologically they seem to have certain similarities. It is also suggested that the Camaqua Group in southern Brazil and the Nama Group could perhaps have certain similarities within their lithological successions and their ages may be also com- parable.The late stages of the geological evolution of the basin, represented by molassic sediments, are only present in south-east Brazil. Finally an interpretation is given of the geological evolution of the Proterozoic—early Palaeozoic terrains compared in this work.     

Temporal Variability in the Concentration and Stable Carbon Isotope Composition of Dissolved Inorganic and Organic Carbon in Two Montana,USA Rivers

Here we report diel (24 h) and seasonal differences in the concentration and stable carbon isotope composition of dissolved inorganic (DIC) and organic carbon (DOC) in the Clark Fork (CFR) and Big Hole (BHR) Rivers of southwestern Montana, USA. In the CFR, DIC concentration decreased during the daytime and increased at night while DOC showed an inverse temporal relationship; increasing in the daytime most likely due to release of organic photosynthates and decreasing overnight due to heterotrophic consumption. The stable isotope composition of DIC (δ¹³C-DIC) became enriched during the day and depleted over night and the δ¹³C-DOC displayed the inverse temporal pattern. Additionally, the night time molar rate of decrease in the concentration of DOC was up to two orders of magnitude smaller than the rate of increase in the concentration of DIC indicating that oxidation of DOC was responsible for only a small part of the increase in inorganic carbon. In the BHR, in two successive years (late summer 2006 & 2007), the DIC displayed little diel concentration change, however, the δ¹³C-DIC did show a more typical diel pattern characteristic of the influences of photosynthesis and respiration indicating that the isotopic composition of DIC can change while the concentration stays relatively constant. During 2006, a sharp night time increase in DOC was measured; opposite to the result observed in the CFR and may be related to the night time increase in flow and pH also observed in that year. This night time increase in DOC, flow, and pH was not observed 1 year later at approximately the same time of year. An in-stream mesocosm chamber used during 2006 showed that the night time increase in pH and DOC did not occur in water that was isolated from upstream or hyporheic contributions. This result suggests that a “pulse” of high DOC and pH water was advected to the sampling site in the BHR in 2006 and a model is proposed to explain this temporal pattern.     

Cretaceous and Tertiary of the Iullemmeden Basin in Nigeria (West Africa)

The Iullemmeden Basin (Mali-Niger-Benin-Nigeria) of tectono-epeirogenic origin was invaded several times by epicontinental transgressions during the Cretaceous and Paleocene.Three major subdivisions are recognized in the Nigerian section of the basin (the “Sokoto Basin”): (1) the lower, continental beds (= Continental Intercalaire) of Late Jurassic to Early Cretaceous age, (2) intermediate marine and brackish water deposits and (3) “Continental T Terminal” of upper Eocene-Miocene age.The geology of the Iullemmeden Basin is reviewed and updated. The relationships between the “Continental Intercalaire” of francophone authors and the Illo and Gundumi Formations are analysed and the type sections of the latter described. It is suggested that the Illo and Gundumi Formations are lateral equivalents.Detailed information on the formations of the Maastrichtian Rima Group is presented. It is concluded that there is no age difference of consequence between the Paleocene Dange, Kalambaina and Gamba Formations.The epicontinental transgressions are interpreted as coming from the north-east, east of the Hoggar massif during the Cenomanian and Turonian and west of the Hoggar during the Maastrichtian and Paleocene. The Sokoto Paleocene molluscan fauna is considered to be terminal Paleocene to Eocene and somewhat younger than the Ewekoro association of coastal Nigeria.A new interpretation of the Continental Terminal is presented. The structural history of the Sokoto Basin is reviewed and partly re-interpreted in the light of new field evidence.     

Gold metallogeny in the Birimian craton of Burkina Faso (West Africa)

Primary gold deposits in Burkina Faso occur in Paleoproterozoic Birimian belt formations (2.0 Ga). Mineralization was synchronous with regional metamorphism and deformation, and is either hosted within, or is adjacent to, quartz-bearing veins. These are classical characteristics of epigenetic gold deposits in Precambrian metamorphic terranes and permit to classify the mineralized sites from Burkina Faso as orogenic-type gold deposits. A review of data collected over the past decade by our team permits to recognize two main styles of gold mineralization: (1) Quartz-vein hosted; this style occurs in all lithologies, the veins are deformed and gold is principally concentrated within the veins, associated with either sulfides or tourmaline. (2) Disseminated; this style occurs exclusively in albitites (and to a lesser extent listvenites) with gold occurring mainly within alteration halos of generally undeformed quartz-albite-carbonate vein. Quartz-vein and disseminated styles of mineralization can be associated within the same deposit. Albitites and listvenites are alteration products of mainly calc-alkaline igneous rocks of felsic to ultramafic composition, respectively. The predominant alteration assemblage consists of chlorite, albite, carbonate, and pyrite. Sulfides occur as fine masses commonly in the alteration halos close to vein margins and consist mainly of pyrite and arsenopyrite, depending on host-rock composition. Gold occurs as free native metal and, locally, in form of tellurides, in fissures or as inclusions within pyrite and arsenopyrite. Two main populations of fluid inclusions are associated with the gold deposits, independently of the mineralization style: (1) carbonic inclusions consisting of up to 90 mol% CO₂ (plus N₂ and CH₄) and (2) aqueous-carbonic fluid inclusions with moderate salinities. Interestingly, the disseminated gold style deposits of Burkina Faso, which have the highest economic potential, show strong similarities with the world-class Ashanti deposit, in neighboring Ghana.     

Fog harvesting: An alternative source of water supply on the West Coast of South Africa

Experiments conducted during the 1990s investigated the feasibility of using fog water to supplement existing water supplies in the arid west coast region of South Africa. Based on these results, a project was initiated aimed at implementing an operational fog water collection system to provide potable water to a small, water-poor rural community. A 70 m² fog water collector was subsequently erected on the crest of the hill located next to the mission station called Lepelfontein. The volume of water collected was measured by means of a water flow meter and a tipping bucket. An automatic weather station recorded rainfall, wind speed and direction. The data record spans the period September 1999–August 2001. This paper gives a brief overview of the methods used to select the experimental site and describes the design of the fog water collection system. This is followed by a detailed account of the water yields, the contribution of fog and rainfall to the total yield, the characteristics of wet events, the factors associated with water collection and water quality. On average, yields of around 4.6 l of water were collected per square metre of collecting surface per day with maximum daily yields approaching 4000 l. The quality of the water was excellent. It thus appears that fog water collection may have considerable potential as an alternative water source at many other locations on the west coast of South Africa. This revised version was published online in July 2006 with corrections to the Cover Date.     

Impact of vertical structure on water mass circulation in a tropical lagoon (Ebrié, Ivory Coast)

A one-dimensional vertical model has been developed to simulate the water mass circulation along the vertical structure in all deep coastal areas. The model has hydrodynamic and transport components solved using finite difference scheme. The one-dimensional vertical model results are coupled to the vertically averaged two-dimensional model results at each point of a horizontal grid. A theoretical salinity profile is introduced for each vertically integrated value obtained from the 2DH model results. A viscosity profile, simulating a viscosity value close to zero at the surface and with large viscosity gradients, is applied along the water column. The model is applied to the Vridi channel, connecting the Ebrié lagoon to the sea (Ivory Coast).The response of the Ebrié lagoon is studied in terms of inflow and outflow of water in the system through the Vridi channel. Due to the abrupt variation of the surface slope, vertical velocities along the water column show an anticlockwise spiral from bottom to surface during a tidal cycle. Due to the bottom friction and to the vertical viscosity profile, velocities decrease from surface to bottom. However, the freshwater inflow slows down the tidal propagation during the flood and causes the surface velocity to be smaller than the bottom velocity at mid-tide. Close to the bottom, velocities follow an anticlockwise movement due to the tidal propagation. At the water surface, velocities follow only an alternative movement of either ebb or flood, along the channel direction. No cross shore velocities can develop at the surface in the channel.     

Magnetotellurics applied to the study of the crustal structures in Senegal (West Africa)

Abstract

In Senegal, magnetotellurie (MT) method has been used in an attempt to resolve the principal structural features by their electrical response. On the basis of numerical modelling of data, an unified model of possible crustal structure is presented for the West african margin. The results are in agreement with other independent geophysical and geological information.     

Chemical analyses of Bosumtwi crater target rocks compared with the Ivory Coast tektites

The Bosumtwi crater, Ghana, was excavated in phyllites and greywackes with subordinate microgranite dykes and quartz veins of the 2000 Ma old Lower Birimian System with a granodiorite intrusion at Pepiakese on its northeastern side. New major and trace element analyses are presented for 7 phyllites, 5 greywackes, 2 microgranites, 3 Pepiakese intrusion rocks and 1 suevite using XRF and INNA.Means and standard deviations were calculated using all available modern analyses for each element in the Bosumtwi target rocks, Bosumtwi suevite glasses and Ivory Coast tektites. Good agreements between the means were found for the three groups with the suevite glasses and tektites having more limited compositional ranges than the target rocks. Least squares mixing between target rock types shows that the best fits to the tektite and suevite glass compositions require components of about a third or a quarter from the Pepiakese intrusion and some extra silica, derived from quartz veins, as well as the metasediments.The new data provide evidence for vapour phase fractionation of P₂O₅ and Na₂O in the tektites in addition to the previously reported Pb and Rb. Evidence for a meteoritic component in the tektites was found to be equivocal since the target rocks are probably a sufficient source of the meteorite indicator elements Ni and Ir.     

Palaeoproterozoic high-pressure granulite overprint of the Archean continental crust: evidence for homogeneous crustal thickening (Man Rise, Ivory Coast)

The character of mountain building processes in Palaeoproterozoic times is subject to much debate. Based on the discovery of high-pressure granulites in the Man Rise (Côte d'Ivoire), several authors have argued that Eburnean (Palaeoproterozoic) reworking of the Archean basement was achieved by modern-style thrust-dominated tectonics.
A mafic granulite of the Kouibli area (Archean part of the Man Rise, western Ivory Coast) displays a primary assemblage (M1) containing garnet, diopsidic clinopyroxene, red-brown pargasitic amphibole, plagioclase (andesine), rutile, ilmenite and quartz. This assemblage is associated with a subvertical regional foliation. Symplectites that developed at the expense of the M1 assemblage contain orthopyroxene, clinopyroxene, plagioclase (bytownite), green pargasitic amphibole, ilmenite and magnetite (M2). Multiequilibrium thermobarometric calculations and P–T pseudosections calculated with thermocalc suggest granulite facies conditions of ∼ 13 kbar, 850 °C and <7 kbar, 700–800 °C for M1 and M2, respectively. In agreement with the qualitative information obtained from reaction textures and chemical zoning of minerals, this suggests an evolution dominated by decompression accompanied by moderate cooling. A Sm–Nd garnet – whole-rock age of 2.03 Ga determined on this sample indicates that this evolution occurred during the Palaeoproterozoic. It is argued that from the geodynamic point of view the observed features are best explained by homogeneous thickening of the margin of the Archean craton, re-heated and softened due to the accretion of hot, juvenile Palaeoproterozoic crust, as well as coeval intrusion of juvenile magmas. Crustal shortening was mainly accommodated by transpressive shear zones and by lateral crustal spreading rather than large-scale thrust systems.     

Petrology and chemistry of the Picritic Shergottite North West Africa 1068 (NWA 1068)

We report on the petrology and chemistry of North West Africa 1068 (NWA 1068), a shergottite recently recovered in Morocco. This meteorite has a total known mass of about 577 g and comprises 23 fragments. The largest fragment is a greenish-brown rock devoid of fusion crust. It displays a porphyritic texture consisting of a fine-grained groundmass and olivine grains. Excluding the impact melt pockets and the minor carbonate veins produced by terrestrial weathering, modal analyses indicate the following mineral proportions: 52 vol% pyroxenes, 22% maskelynite, 21% olivine, 2% phosphates (merrillite and chlorapatite), 2% opaque oxides (mainly ilmenite and chromite) and sulfides, and 1% K-rich mesostasis. Olivines with various habits occur as clusters often associated with chromite, or single crystals ranging in size from 50 μm to 2 millimeters (“megacrysts”). These crystals originate probably from disrupted cumulates with strong affinities with peridotitic shergottites.The bulk composition of NWA 1068 has been determined for 45 elements. It is an Al-poor ferroan basaltic rock, rich in MgO. Its major element composition is similar to those reported for other picritic shergottites, especially EETA79001A. Furthermore, key element ratios such as Fe/Mn (45), Al/Ti (6.6), Na/Ti (1.83), Ga/Al (4.4 × 10⁻⁴) and Na/Al (0.28) are typical of Martian meteorites. The trace elements demonstrate unambiguously that NWA 1068 is unpaired with any of the other hot desert finds: it is the first picritic shergottite with a REE pattern similar to those of Shergotty, Zagami, and Los Angeles.Incompatible element abundances indicate that NWA 1068 was not formed from a “primitive” shergottitic melt. It derived more likely from a basaltic shergottite, which has accumulated (and possibly partly digested) fragments of an olivine-rich lithology, in full agreement with major element abundances and petrographical interpretations.     

Geodynamic evolution of the mauritanide,bassaride, and rokelide orogens (West Africa)

The Mauritanide, Bassaride and Rokelide orogens occur along the western edge of the West African Craton. These record a polyphase tectonothermal evolution, including Pan African I (c. 650 Ma) and Pan African II (c. 550 Ma) events together with local Hercynian (late Paleozoic) overprinting. Pan African I activity is most penetratively recorded in the Bassarides, and resulted from late Proterozoic collision of a western continental structural block. Pan African II orogenesis increases in intensity from the southern Mauritanides through the Bassarides and dominates the Rokelides. This tectonothermal activity appears to reflect collision of the West African and Guyanean Cratons during assembly of Gondwana. Hercynian activity is concentrated along the margin of a western continental block which underwent relative eastward translation during collision of Gondwana and Laurentia. This resulted in extensive thrusting of intracontinental foreland sequences (external nappes) and more ductile imbrications of pre-deformed and metamorphosed late Proterozoic rift sequences and western calc-alkaline igneous successions (internal nappes).     

Seasonal Prevalence of Hematodinium sp. Infections of Blue Crabs in Three South Carolina (USA) Rivers

Blue crab, Callinectes sapidus, commercial landings in the USA have been declining at an alarming rate. In South Carolina, these declines are significantly correlated with years of decreased rainfall and elevated salt marsh salinity. Previous studies suggest that higher salinity increases the risk of infection by Hematodinium sp., a dinoflagellate parasite of blue crabs, C. sapidus. A 4-year survey (June 2008 to March 2012) of blue crabs in the ACE Basin National Estuarine Research Reserve documented (1) the temporal and spatial patterns of Hematodinium sp. infection in relation to salinity, (2) some environmental correlates of disease prevalence, and (3) the characteristics of infected blue crabs. Sampling was conducted four times a year in March, June, September, and December in the South Edisto, Ashepoo, and Combahee rivers beginning in June 2008. Crab hemolymph samples were collected and preserved and DNA was successfully amplified for 2,303 individuals. Hematodinium sp. infection was evaluated by PCR amplification of its 18S rRNA gene and adjacent regions. Prevalence was highest in December 2008 in the Combahee River at sites closest to St. Helena Sound. The spatial and temporal pattern of Hematodinium sp. infection was correlated with several environmental parameters. Infected crabs exhibited differences in carapace shape and body condition compared to uninfected crabs. Overall, these results suggest that blue crabs in regions of higher salinity are at greater risk of infection by Hematodinium sp. and infected individuals exhibit sub-lethal effects of the disease.     

Carbon Dioxide and Methane Dynamics in Three Coastal Systems of Cadiz Bay (SW Spain)

The partial pressure of CO₂ (pCO₂) and concentration of dissolved CH₄ in surface waters have been studied in three coastal systems connected to Cadiz Bay (southwestern coast of Spain) over different time scales. The concentration of CH₄ varied from 1 to 4200 nmol kg^?1 (192.1 ± 463.6 nmol kg^?1) and the saturation percent from 19 to 159,577% (6645 ± 16,921%), and pCO₂ from 315 to 3240 μatm (841.9 ± 466.3 μatm), with saturation percent values varying between 72 and 981% (220 ± 133%). The seasonal variation of pCO₂ mainly depends on the temperature. On the contrary, the annual distribution of dissolved CH₄ is associated with the precipitation regime. In addition, pCO₂ and dissolved CH₄ showed spatial variation. pCO₂ increased toward the inner part of the systems, with the proximity to the discharge points from human activities. Dissolved CH₄ is influenced by both anthropogenic inputs and natural processes such as benthic supply and exchange with the adjacent salt marshes. pCO₂ and dissolved CH₄ also varied with the tides: The highest concentrations were measured during the ebb, which suggests that the systems export CO₂ and CH₄ to the Bay and adjacent Atlantic Ocean.     

Glaciations of the West Coast Range,Tasmania

Geomorphic, stratigraphic, palynologic and ¹⁴C evidence indicates that the West Coast Range, Tasmania, was glaciated at least three times during the late Cenozoic. The last or Margaret Glaciation commenced after 30,000 yr B.P., culminated about 19,000 yr B.P., and ended by 10,000 yr B.P. During this period a small ice cap, ca. 250 m thick, and cirque and valley glaciers covered 108 km². The glacial deposits show little chemical weathering or erosional dissection. The snow line ranged from 690 to 1000 m with an average of 830 m for the ice cap. Mean temperature was 6.5°C below the present temperature. During the preceding Henty Glaciation a 300- to 400-m-thick ice cap and outlet glaciers exceeded 1000 km². The glacial deposits are beyond ¹⁴C assay. They are more weathered chemically and more dissected than Margaret age deposits, and the degree suggests a pre-last interglaciation age (> 130,000 yr B.P.). The snow line of the ice cap lay at 740 m, and annual temperature was reduced by 7°C. Ice of the earliest Linda Glaciation slightly exceeded that of the Henty Glaciation but had a similar distribution. The glacial deposits are intensely weathered, have reversed magnetization, and overlie a paleosol containing pollen of Tertiary type. An early Pleistocene or Tertiary age is indicated.     

Seasonal uranium distributions in the coastal waters off the Amazon and Mississippi Rivers

The chemical reactivity of uranium was investigated across estuarine gradients from two of the world’s largest river systems: the Amazon and Mississippi. Concentrations of dissolved (<0.45 μm) uranium (U) were measured in surface waters of the Amazon shelf during rising (March 1990), flood (June 1990) and low (November 1991) discharge regimes. The dissolved U content was also examined in surface waters collected across estuarine gradients of the Mississippi outflow region during April 1992, August 1993, and November (1993). All water samples were analyzed for U by isotope dilution inductively coupled plasma mass spectrometry (ICP-MS). In Amazon shelf surface waters uranium increased nonconservatively from about 0.01 μg I^?1 at the river’s mouth to over 3 μg I^?1 at the distal site, irrespective of river discharge stage. Observed large-scale U removal at salinities generally less than 15 implies a) that riverine dissolved U was extensively adsorbed by freshly-precipitated hydrous metal oxides (e.g., FeOOH, MnO₂) as a result of flocculation and aggregation, and b) that energetic resuspension and reworking of shelf sediments and fluid muds on the Amazon shelf released a chemically reactive particle/colloid to the water column which can further scavenge dissolved U across much of the estuarine gradient. In contrast, the estuarine chemistry of U is inconclusive within surface waters of the Mississippi shelf-break region. U behavior is most likely controlled less by traditional sorption and/or desorption reactions involving metal oxides or colloids than by the river’s variable discharge regime (e.g., water parcel residence time during estuarine mixing, nature of particulates, sediment storage and resuspension in, the confined lower river), and plume dispersal. Mixing of the thin freshwater lens into ambient seawater is largely defined by wind-driven rather than physical processes. As a consequence, in the Mississippi outflow region uranium predominantly displays conservative behavior; removal is evident only during anomalous river discharge regimes. ‘Products-approach’ mixing experiments conducted during the Flood of 1993 suggest the importance of small particles and/or colloids in defining a depleted U versus salinity distribution.