西太平洋暖池区第四纪钙质超微化石氧碳同位素特征及意义

对西太平洋暖池区MD97—2140柱状样1．75Ma以来的钙质超微化石进行了氧碳同位素分析．结果表明超微化石占δ^18O值与浮游有孔虫Globigerinoides ruber δ^18O值在变化趋势和周期上都具有明显相似性．根据超微化石占δ^18O值也可以划分出59个氧同位素期,1748ka到900ka期间超微化石占δ^18O值的变化周期以41ka为主．而850ka到6ka期间则以100ka为主．这说明超微化石氧同位素分析可以像有孔虫氧同位素分析一样在大洋地层学和古海洋学、古气候学研究中发挥重要作用．超微化石占δ^13C值变化则呈现阶段性变化的特点．以900ka,480ka和250ka时间面为界,可分四大阶段．同时,MD97—2140柱状样超微化石占δ^13C值的这种变化规律与邻近ODP807站揭示的海水初级生产力变化趋势极为相似,意味着超微化石占δ^13C值是反映海水初级生产力变化的一项重要指标．     

近190ka BP以来菲律宾海黑潮源区的碳酸盐旋回及其控制因素

对取自西菲律宾海黑潮源区的Ph05-5和WF3岩芯进行了CaCO3和钙质超微化石研究.在利用氧同位素曲线对比和AMS14C数据进行地层划分的基础上,结合钙质超微化石的碳酸盐溶解指数和初级生产力指标,分析了晚第四纪黑潮源区碳酸盐旋回特征及其控制因素.约190ka BP以来CaCO3含量整体上都表现为冰期高、间冰期低的"太平洋型"旋回特征,但菲律宾以东海区在末次冰期(MIS 4到MIS 2期)内部又显示出间冰段含量高、冰段含量低的"大西洋型"旋回特征.碳酸盐旋回的控制因素在黑潮源区内部也有明显的差异,菲律宾以东海区以碳酸盐溶解作用为主,初级生产力起次要作用;而台湾东南部海区的主要因素则是初级生产力变化引起的钙质生物输入量的波动.菲律宾以东海区末次冰期内部表现出的"大西洋型"旋回特征则是溶解作用和初级生产力共同影响的结果.     

中更新世转型时期南海北部上层水体结构演化特征——ODP1146站浮游有孔虫稳定同位素记录

文章以南海北部ODP1146站沉积物岩芯为研究材料,利用浮游有孔虫次表层水种Pulleniatina obliquiloculata壳体的氧、碳稳定同位素,结合该站位浮游及底栖有孔虫氧碳同位素数据,分析中更新世以来南海北部上层水体结构的演化。1.2 Ma以来ODP1146站P.obliquiloculata壳体δ^18O的变化可分3个阶段:1)1.2~0.9 Ma,冰期-间冰期变化幅度较小、主导周期为41 ka斜率周期;2)0.9~0.6 Ma,冰期旋回变化幅度逐渐增强、100 ka偏心率周期开始强化;3)0.6 Ma以来,冰期旋回呈现稳定且幅度较大的100 ka周期变化。0.9 Ma以来南海北部上层海水δ^18O的冰期旋回变幅增强,可能反映东亚冬季风在0.9 Ma之后显著强化。其中,表层水体δ^18O只在冰期变幅增强,P.obliquiloculata所反映的次表层水体δ^18O的变化幅度在冰期和间冰期都显著增强。约0.9 Ma浮游和底栖有孔虫δ^18O的100 ka周期几乎同时显现;但在0.9~0.6 Ma时期P.obliquiloculata的δ^18O偏心率周期更为显著、斜率周期的强度也更高。因此,冰期旋回周期转型及幅度变化两方面的证据共同反映温跃层结构演化在南海北部中更新世转型(MPT)气候转变过程中的特殊性。1.2 Ma以来ODP1146站P.obliquiloculata的δ^13C在0.02 Ma、0.49 Ma和0.99 Ma左右呈明显的碳重值,同时表层种-次表层种之间的δ^13C差值减小到近于0,可以解读为碳重值事件期间南海北部生产力相对减弱。     

250kaB.P.以来西太平洋暖池中心区——Ontong Java海台古生产力演化

多年平均表层水温超过28℃的"西太平洋暖池",是全球海平面高度的加热中心和大气三大环流的辐散中心。为评价西太平洋暖池中心区域海洋生物泵的演化特征、规律与机制,本文以位于热带西太平洋暖池核心区——Ontong Java海台的WP7柱状样为材料,通过提取浮游有孔虫^δ13C组成、底栖有孔虫群落和钙质超微化石下透光带属种Florisphaera profunda相对百分含量变化等指标,反演该区250kaB.P.以来的古生产力的演化历史。研究结果表明,250kaB.P.以来西太平洋暖池中心区的古生产力演化与地球轨道变化控制的冰期-间冰期旋回以及岁差控制的太阳辐照率密切相关。在冰期-间冰期尺度上,西太平洋暖池中心区距今250ka以来的生产力变化间冰期明显低于冰期,而且在间冰期阶段生产力相对稳定,冰期波动幅度较大。在冰期或间冰期背景下显著的岁差周期是该区古生产力演化的又一重要特征。而且在岁差波段生物生产力的变化可能领先极地冰体积变化2～4ka左右。热带东西太平洋的古生产力演化在冰期-间冰期变化和岁差尺度上存在ENSO式的变动机制,而且二者互相调谐,产生了似30ka和19ka周期,并出现了"半30ka周期"和半岁差周期。此外,WP7孔Neogloboqudrina dutertrei的^δ13C显示在MIS 1/2,MIS 3/4和MIS 5e/6的冰期向间冰期的过渡期的冰消期阶段存在变轻事件,可能与数千年尺度的大洋环流演化有关。     

冲绳海槽MIS6期以来底栖有孔虫碳氧同位素特征及其古海洋指示意义

基于AMS ¹⁴C年龄和底栖有孔虫氧同位素建立的地层年代框架,重点探讨了冲绳海槽中北部CSHC-15孔MIS6期以来(约200 ka)底栖有孔虫δ¹³C特征及其古海洋指示意义。结果显示,冰期-间冰期表层初级生产力和有机质通量的变化是导致底栖有孔虫δ¹³C值在MIS4和MIS6期负偏而在MIS1、MIS3和MIS5期正偏的主要原因。MIS2期的底栖有孔虫δ¹³C正偏,指示了NPIW侵入冲绳海槽,导致通风性加强,底层水呈弱氧化状态。甲烷渗漏引发的甲烷厌氧氧化作用(AOM)是导致CSHC-15孔底栖有孔虫在MIS4期碳同位素大幅负偏的原因。     

北冰洋西部晚第四纪浮游有孔虫氧碳同位素记录的海冰形成速率

北冰洋西部晚第四纪浮游有孔虫Neogloboquadrina pachyderma(sin.)(Nps)壳体的δ18O和δ13C与浮游有孔虫丰度和筏冰碎屑含量的综合研究表明,MIS 7晚期以来,Nps的δ18O和δ13C值出现7次明显的偏轻,可能与海冰形成速率的提高造成轻同位素卤水的生产和下沉相关.偏轻的Nps δ18O和δ13C值对应于极低的浮游有孔虫丰度和筏冰碎屑含量,因此这些轻值与温暖的大西洋水和淡水的输入无关,应当指示进入北冰洋的大西洋水减弱和楚科奇海陆架水的大量减少.相反,Nps δ18O的重值则反映输入北冰洋的淡水和太平洋水的减少;Nps δ13C的重值指示来自陆架流通性更好的表层和盐跃层水向北冰洋的输送.     

珠江口盆地东部陆坡末次冰期天然气水合物-冷泉活动的记录与时间

对珠江口盆地东部陆坡GMGS 08C孔的3层自生碳酸盐岩(结核状)和有孔虫(底栖和浮游)开展高分辨率氧碳同位素分析和AMS~(14) C测年,第1层自生碳酸盐岩δ~(13) C为-38.85‰,第2、3层的δ~(13) C介于-41.36‰~-56.74‰,平均值-51.64‰,均低于-40‰。δ~(18) O值介于2.94‰~4.18‰,平均值3.68‰,明显偏重。这表明其为天然气水合物分解的产物,形成于微生物对甲烷的缺氧氧化作用,甲烷主要源自生物成因;自生碳酸盐岩层位的底栖有孔虫Uvigerina peregrina和浮游有孔虫Globigerinoides ruber的δ~(13) C值几乎同时出现极负偏,最低值分别达到-12.17‰和-9.06‰,有孔虫δ~(18) O总体上正偏,最大正偏幅度达1.50‰,说明其负偏与后期源于甲烷厌氧氧化作用(Anaerobic Oxidation of Methane,简称AOM)的成岩作用有关。自生碳酸盐岩及其与有孔虫异常碳(偏负)氧(偏正)、粥状沉积是GMGS 08C孔水合物分解甲烷渗漏的重要指标,据此推断该孔在末次冰期(MIS2—MIS3)发生过至少2次天然气水合物分解释放-冷泉甲烷渗漏活动,分别距今36ka和31~26ka,主要发生在低海平面期,说明冷泉活动明显受海平面变化影响。     

南海北部1144站中更新世浮游有孔虫的千年尺度古气候记录

南海北部ODP1144站中更新世气候转型时期的浮游有孔虫在千年尺度上以高频率变化为主要特征.冰期旋回主要周期在0.9Ma由41ka转变为100ka, 浮游有孔虫组合也随冰期旋回出现大量的冷水种.据转换函数得出的表层水降温高达10℃发生在0.9~0.6Ma间的转型过渡期, 跨越MIS22、20、18、16四大冰期.同时, 温跃层深度呈阶梯式变浅, 在MIS20上升至65m左右.所以, 南海北部上层水体环境在中更新世气候转型期出现比末次冰期更重的δ18O值, 温跃层变浅, 深水种含量降低或消失, 突出了边缘海区南北气候梯度反差和冬季风在冰期增强的讯号.南海南北部的环境差异与东西太平洋的差异, 共同表明低纬过程在气候变化中的重要性.      

南海北部晚第四纪高分辨率浮游氧同位素地层学及其古气候信息

对南海北部MD05-2904孔45 m的连续沉积物中提取的浮游有孔虫Globigerinoides ruber(白色)进行稳定同位素分析, 得到晚MIS 8以来(时间跨度257 ka, 平均时间分辨率228 a)的高分辨率沉积记录, δ18O和δ13C的频谱分析显示了强烈的岁差(23.4 ka、19.8 ka)、半岁差(11.7 ka、9.9 ka)周期.MD05-2904孔MIS 24时间段的氧同位素记录了格陵兰冰心中发现的Dansgaard/Oeschger和Heinrich事件.与葫芦洞石笋记录及南海邻区浮游有孔虫氧同位素记录的对比显示了受季风控制的区域因素, 如降雨、河流输入导致的盐度变化等对表层海水组成的影响.氧同位素在MIS 3、MIS 6的早期以及MIS 7.4偏轻; 而在MIS 5.5偏重, 这种现象解释为降雨量和蒸发量共同作用的结果.而末次冰盛期高达6570 cm/ka的沉积速率反映了低海平面时孔位离岸距离缩短带来丰富的沉积物源.      

南海西部浮游有孔虫记录的MIS 3期表层海洋环境变化

对南海西部越南岸外上升流区17954-2站浮游有孔虫属种组合变化、浮游有孔虫氧同位素、AMS14C测年的分析以及浮游有孔虫表层海水温度、温跃层转换函数的研究结果表明:在MIS3期,南海西部表层海水温度大体呈现暖-冷-暖的变化趋势;温跃层深度由浅到深阶段性变化;短时间尺度上温度与温跃层发生幅度较大的快速变化。暖事件（IS）对应于浮游有孔虫暖水种、混合层属种含量的增加,冷水种、温跃层属种含量的减少以及冬夏SST的升高;冷事件则与之相反。表层海水生产力亦大致呈现3个阶段（61～51ka,51～42ka和42～32ka）的变化,在千年尺度的快速气候事件中,暖事件对应浮游有孔虫生产力属种含量降低,冷事件对应升高。此外,在MIS3内部分暖事件（IS6和IS11～13）表现出表层海水温度降低,温跃层深度变浅和表层海水生产力升高的状况,表明该区此时上升流的存在,其形成原因推测是由于东亚夏季风加强的结果。     

20万年来南海古海洋研究的主要进展

南海第四纪古海洋学的研究,从ODP184航次以来获得了快速的发展,已经成为国内外古海洋研究的重点地区之一。试图对国内外文献作一综述,介绍近20万年以来高分辨率的南海古海洋研究进展。综述主要涉及温度、盐度、生产力和上层水体的变化,重点介绍南海季风的研究成果。南海浮游有孔虫氧同位素曲线具有MIS3.3和MIS6.5期偏轻,MIS5.5和MIS7.3期偏重的特征,已被称为"季风型氧同位素曲线"。不同于代表全球冰量变化的底栖有孔虫氧同位素曲线(即SPEC-MAP曲线),"季风型氧同位素曲线"具明显的2万年岁差周期,代表了季风降水的影响。快速气候变化事件也有较为完整的记录,揭示了热带地区在快速气候变化中也发挥着重要的作用。     

Integrated planktonic stratigraphy and paleoenvironments of the Lower-Middle Miocene successions in the central and southern parts of the Gulf of Suez,Egypt

Lower to Middle Miocene successions in three offshore wells named GS 160-2, QQ-89, and Ras Elush-2 located in the central and southern parts of the Gulf of Suez were examined for their planktonic foraminifera, calcareous nannofossil assemblages, and paleoenvironments. These successions are subdivided from older to younger into Aquitanian Nukhul, Burdigalian-Langhian Rudeis, Langhian Kareem, and Serravallian Belayim formations. The identified foraminifera includes 54 benthic species belonging to 25 genera and 47 planktonic species belonging to 11 genera, in addition to 64 calcareous nannofossil species belonging to 21 genera. The stratigraphic distribution of these assemblages suggests classifying the studied successions into seven planktonic foraminiferal and six calcareous nannoplankton biozones. The planktonic foraminiferal and calcareous nannoplankton biozones are integrated. Different environments ranging from shallow inner to outer shelf are recognized. This is based on quantitative analyses of foraminifera including benthic biofacies, planktonic/benthonic ratio, and diversity. Syn-rift tectonics played an important role in configuration of the Miocene depositional history in the Gulf of Suez region.     

Late Cretaceous calcareous nannofossil and planktonic foraminiferal bioevents of the shallow-marine carbonate platform in the Mitla Pass, west central Sinai, Egypt

The first detailed biostratigraphic analyses of the Coniacian-middle Campanian shallow-marine carbonate successions exposed in the Mitla Pass, west central Sinai, Egypt have revealed the stratigraphic distribution of diverse calcareous nannofossil and planktonic foraminiferal species. Thirty-six calcareous nannofossils and thirty-two planktonic foraminifera are identified, indicating a Coniacian to middle Campanian age and four Tethyan planktonic foraminiferal and five calcareous nannofossil zones. A comparison of these bioevents from different palaeolatitudes shows considerable variation in age.Three sequence boundaries coincident with the Turonian/Coniacian, Coniacian/Santonian and Santonian/Campanian stage boundaries are recognized. A fourth sequence boundary is marked by a major upper Campanian to early Ypresian (early Eocene) unconformity. These sequence boundaries are primarily related to regional tectonism associated with the Syrian Arc Fold System and secondarily to eustatic sea-level fluctuations.     

Time-Frequency Variations of Plio-Pleistocene Foraminiferal Isotopes： A Case Study from Southern South China Sea

The continuous wavelet transform (CWT) analysis reveals the instantaneous variability of the foraminiferal δ18O and δ13C of Site 1143 for the past 5 Ma at the eccentricity, obliquity and precession bands. The cross CWT analysis further demonstrates nonstationary phases of the benthic -δ18O relative to ETP at the three primary Milankovitch bands in the last 5 Ma. The instantaneous phases between benthic -δ18O and δ13C at the precession band display a prominent 128 ka period, probably the cyclicity of the nonstationary climate close to the eccentricity. To explain these nonstationary phases, it is desirable to introduce a nonlinear response model to the global climate system, in which the output has a prominent cycle around 100 ka to match the 128 ka cycle of the instantaneous phase of the δ13C and -δ18O on the precession band.     

Upper quaternary laminated sapropelic sediments from the continental slope of Baja California

Core MD02-2508 retrieved from the plateau of the continental slope off Baja California recovered a 40-m-thick section of sapropel (up to 15% C_org), calcareous clay, and diatom ooze with the age of 120 ka at the core bottom. The section is subdivided into three units: Unit I (Holocene) consists of the laminated sapropel; Unit II comprising oxygen isotope stages (MIS) 2, 3, and 4 is represented by homogeneous calcareous clay with interbeds of slightly siliceous sapropelic mud; and Unit III (MIS-5) is composed of laminated sapropelic diatom ooze. Laminated intervals are characterized by the intercalation of two lamina types: (1) dark-colored organic-rich laminae containing multi-species “oceanic” diatom assemblages, as well as radiolarians, coccoliths, planktonic and benthic foraminifera; (2) lighter-colored laminae consisting of diatom ooze with the neritic colonial diatom assemblages commonly composed of one to three species of a single genera. The dark laminae are assumed to be generated within a high productivity zone over the slope, whereas light ones likely represent diatom mats produced by short-term boisterous phytoplankton blooms, possibly in the coastal upwelling.     

Bentho-planktonic evidence from the Austrian Alps for a decline in sea-surface carbonate production at the end of the Triassic

A high-resolution micropalaeontological study, combined with geochemical and sedimentological analyses was performed on the Tiefengraben, Schlossgraben and Eiberg sections (Austrian Alps) in order to characterize sea-surface carbonate production during the end-Triassic crisis. At the end-Rhaetian, the dominant calcareous nannofossil Prinsiosphaera triassica shows a decrease in abundance and size and this is correlated with a increase in δ¹⁸O and a gradual decline in δ¹³C_carb values. Simultaneously, benthic foraminiferal assemblages show a decrease in diversity and abundance of calcareous taxa and a dominance of infaunal agglutinated taxa. The smaller size of calcareous nannofossils disturbed the vertical export balance of the biological carbon pump towards the sea-bottom, resulting in changes in feeding strategies within the benthic foraminiferal assemblages from deposit feeders to detritus feeders and bacterial scavengers. These micropalaeontological data combined with geochemical proxies suggest that changes in seawater chemistry and/or cooling episodes might have occurred in the latest Triassic, leading to a marked decrease of carbonate production. This in turn culminated in the quasi-absence of calcareous nannofossils and benthic foraminifers in the latest Triassic. The aftermath (latest Triassic earliest Jurassic) was characterised by abundance peaks of “disaster” epifaunal agglutinated foraminifera Trochammina on the sea-floor. Central Atlantic Magmatic Province (CAMP) paroxysmal activity, superimposed on a major worldwide regressive phase, is assumed to be responsible for a deterioration in marine palaeoenvironments. CAMP sulfuric emissions might have been the trigger for cooling episodes and seawater acidification leading to disturbance of the surface carbonate production at the very end-Triassic.     

Planktonic foraminiferal distribution record productivity cycles: evidence from the Aptian-Albian Piobbico core (central Italy)

The Aptian-Albian 'Scisti a Fucoidi' varicoloured pelagic sediments in central Italy, show a 'couplet' alternation of carbonate-rich/carbonate-poor layers, which are interpreted as the sedimentary expression of precession (frequency 19–23 kyr). Carbonate content, chromatic variation, and planktonic foraminiferal abundance were analysed at a 1-cm spacing for a 10-m interval of the Piobbico core, specifically drilled through this formation. Spectral analysis of these parameters shows a prominent signal equated to the c . 100 kyr cycle of orbital eccentricity at a sedimentation rate of 5 mm kyr⁻¹. The coherency of the spectral response of each parameter suggests that a single mechanism controlled the whole sedimentary record. Detailed study of planktonic foraminiferal distribution of the same section at 1-mm scale resolves the Milankovitch frequencies of 41 kyr and 18 to 23 kyr, equated with the obliquity and precessional cycles. But foraminiferal abundance is not in phase with carbonate content, which was largely controlled by calcareous nannofossils, but peaked at intermediate carbonate values. The proposed model for explaining the discrepancy at the precessional level is that foraminifera thrived at intermediate values of the precession index, when the environment was only moderately fertile but stable, while during highs of the precession index, mixing of the water column increased fertility and caused calcareous nannofossil blooms and restriction of planktonic foraminifera to few and tolerant species. The resulting bimodality of foraminiferal abundance per precessional cycle appears to be recorded in the spectrum by peaks at the 11 and 14 kyr levels. Cross correlation of foraminiferal abundances with the calcium carbonate curve over 1–2 Myr intervals produces discrepant results (apparent phase lags) which we attribute to differences in the response to the fundamental eccentricity cycles.