Coal to gas: the influence of methane leakage

Carbon dioxide (CO₂) emissions from fossil fuel combustion may be reduced by using natural gas rather than coal to produce energy. Gas produces approximately half the amount of CO₂ per unit of primary energy compared with coal. Here we consider a scenario where a fraction of coal usage is replaced by natural gas (i.e., methane, CH₄) over a given time period, and where a percentage of the gas production is assumed to leak into the atmosphere. The additional CH₄ from leakage adds to the radiative forcing of the climate system, offsetting the reduction in CO₂ forcing that accompanies the transition from coal to gas. We also consider the effects of: methane leakage from coal mining; changes in radiative forcing due to changes in the emissions of sulfur dioxide and carbonaceous aerosols; and differences in the efficiency of electricity production between coal- and gas-fired power generation. On balance, these factors more than offset the reduction in warming due to reduced CO₂ emissions. When gas replaces coal there is additional warming out to 2,050 with an assumed leakage rate of 0%, and out to 2,140 if the leakage rate is as high as 10%. The overall effects on global-mean temperature over the 21st century, however, are small.     

Global fossil energy markets and climate change mitigation – an analysis with REMIND

We analyze the dynamics of global fossil resource markets under different assumptions for the supply of fossil fuel resources, development pathways for energy demand, and climate policy settings. Resource markets, in particular the oil market, are characterized by a large discrepancy between costs of resource extraction and commodity prices on international markets. We explain this observation in terms of (a) the intertemporal scarcity rent, (b) regional price differentials arising from trade and transport costs, (c) heterogeneity and inertia in the extraction sector. These effects are captured by the REMIND model. We use the model to explore economic effects of changes in coal, oil and gas markets induced by climate-change mitigation policies. A large share of fossil fuel reserves and resources will be used in the absence of climate policy leading to atmospheric GHG concentrations well beyond a level of 550 ppm CO₂-eq. This result holds independently of different assumptions about energy demand and fossil fuel availability. Achieving ambitious climate targets will drastically reduce fossil fuel consumption, in particular the consumption of coal. Conventional oil and gas as well as non-conventional oil reserves are still exhausted. We find the net present value of fossil fuel rent until 2100 at 30tril.US$ with a large share of oil and a small share of coal. This is reduced by 9 and 12tril.US$ to achieve climate stabilization at 550 and 450 ppm CO₂-eq, respectively. This loss is, however, overcompensated by revenues from carbon pricing that are 21 and 32tril.US$, respectively. The overcompensation also holds under variations of energy demand and fossil fuel supply.     

Implications of weak near-term climate policies on long-term mitigation pathways

While the international community has agreed on the long-term target of limiting global warming to no more than 2 °C above pre-industrial levels, only a few concrete climate policies and measures to reduce greenhouse gas (GHG) emissions have been implemented. We use a set of three global integrated assessment models to analyze the implications of current climate policies on long-term mitigation targets. We define a weak-policy baseline scenario, which extrapolates the current policy environment by assuming that the global climate regime remains fragmented and that emission reduction efforts remain unambitious in most of the world’s regions. These scenarios clearly fall short of limiting warming to 2 °C. We investigate the cost and achievability of the stabilization of atmospheric GHG concentrations at 450 ppm CO₂e by 2100, if countries follow the weak policy pathway until 2020 or 2030 before pursuing the long-term mitigation target with global cooperative action. We find that after a deferral of ambitious action the 450 ppm CO₂e is only achievable with a radical up-scaling of efforts after target adoption. This has severe effects on transformation pathways and exacerbates the challenges of climate stabilization, in particular for a delay of cooperative action until 2030. Specifically, reaching the target with weak near-term action implies (a) faster and more aggressive transformations of energy systems in the medium term, (b) more stranded investments in fossil-based capacities, (c) higher long-term mitigation costs and carbon prices and (d) stronger transitional economic impacts, rendering the political feasibility of such pathways questionable.     

Historical and future anthropogenic emission pathways derived from coupled climate�Ccarbon cycle simulations

Using a coupled climate?Ccarbon cycle model, fossil fuel carbon dioxide (CO₂) emissions are derived through a reverse approach of prescribing atmospheric CO₂ concentrations according to observations and future projections, respectively. In the second half of the twentieth century, the implied fossil fuel emissions, and also the carbon uptake by land and ocean, are within the range of observational estimates. Larger discrepancies exist in the earlier period (1860?C1960), with small fossil fuel emissions and uncertain emissions from anthropogenic land cover change. In the IPCC SRES A1B scenario, the simulated fossil fuel emissions more than double until 2050 (17 GtC/year) and then decrease to 12 GtC/year by 2100. In addition to A1B, an aggressive mitigation scenario was employed, developed within the European ENSEMBLES project, that peaks at 530 ppm CO₂(equiv) around 2050 and then decreases to approach 450 ppm during the twenty-second century. Consistent with the prescribed pathway of atmospheric CO₂ in E1, the implied fossil fuel emissions increase from currently 8 GtC/year to about 10 by 2015 and decrease thereafter. In the 2050s (2090s) the emissions decrease to 3.4 (0.5) GtC/year, respectively. As in previous studies, our model simulates a positive climate?Ccarbon cycle feedback which tends to reduce the implied emissions by roughly 1 GtC/year per degree global warming. Further, our results suggest that the 450 ppm stabilization scenario may not be sufficient to fulfill the European Union climate policy goal of limiting the global temperature increase to a maximum of 2°C compared to pre-industrial levels.     

Substitution of Natural Gas for Coal: Climatic Effects of Utility Sector Emissions

Substitution of natural gas for coal is one means of reducing carbon dioxide (CO₂) emissions. However, natural gas and coal use also results in emissions of other radiatively active substances including methane (CH₄), sulfur dioxide (SO₂), a sulfate aerosolprecursor, and black carbon (BC) particles. Will switching from coal to gas reduce the net impact of fossil fuel use on global climate? Using the electric utility sector as an example, changes in emissions of CO₂, CH₄,SO₂ and BC resulting from the replacement of coal by natural gas are evaluated, and their modeled net effect on global mean-annual temperature calculated. Coal-to-gas substitution initially produces higher temperatures relative to continued coal use. This warming is due to reduced SO₂ emissionsand possible increases in CH₄ emissions, and can last from 1 to 30years, depending on the sulfur controls assumed. This is followed by a net decrease in temperature relative to continued coal use, resulting from lower emissions of CO₂ and BC. The length of this period and the extent of the warming or cooling expected from coal-to-gas substitution is found to depend on key uncertainties and characteristics of the substitutions, especially those related to: (1) SO₂ emissions and consequentsulphate aerosol forcing; and (2) the relative efficiencies of the power plantsinvolved in the switch.     

Scenarios with MIT integrated global systems model: significant global warming regardless of different approaches

A wide variety of scenarios for future development have played significant roles in climate policy discussions. This paper presents projections of greenhouse gas (GHG) concentrations, sea level rise due to thermal expansion and glacial melt, oceanic acidity, and global mean temperature increases computed with the MIT Integrated Global Systems Model (IGSM) using scenarios for twenty-first century emissions developed by three different groups: intergovernmental (represented by the Intergovernmental Panel on Climate Change), government (represented by the U.S. government Climate Change Science Program) and industry (represented by Royal Dutch Shell plc). In all these scenarios the climate system undergoes substantial changes. By 2100, the CO₂ concentration ranges from 470 to 1020 ppm compared to a 2000 level of 365 ppm, the CO₂-equivalent concentration of all greenhouse gases ranges from 550 to 1780 ppm in comparison to a 2000 level of 415 ppm, oceanic acidity changes from a current pH of around 8 to a range from 7.63 to 7.91, in comparison to a pH change from a preindustrial level by 0.1 unit. The global mean temperature increases by 1.8 to 7.0°C relative to 2000. Such increases will require considerable adaptation of many human systems and will leave some aspects of the earth??s environment irreversibly changed. Thus, the remarkable aspect of these different approaches to scenario development is not the differences in detail and philosophy but rather the similar picture they paint of a world at risk from climate change even if there is substantial effort to reduce emissions.     

Emission scenarios and global climate protection

This paper evaluates the effectiveness of a wide range of emission scenarios in protecting climate (where ‘protecting climate’ Is used here to mean minimizing ‘dangerous anthropogenic interference with the climate system’ which results in impacts to society and the natural environment). Under baseline (no action) conditions there is a significant Increase in emissions, temperature and climate impacts. Controlling only CO₂ emissions (ie freezing emissions in year 2000 at 1990 levels, and decreasing them afterwards at 1%/yr) and only in Annex I countries, does not significantly reduce the impacts observed under the baseline scenario. However, impacts are substantially reduced when emissions are controlled in both Annex I and non-Annex I countries, and when both CO₂ and non-CO₂ emissions are controlled. It was also found that stabilizing CO₂ in the atmosphere below 450 ppm substantially reduces climate impacts. But in order to follow the pathway to stabilization at 450 ppm specified by the IPCC, global emissions can only slightly increase in the coming decades, and then must be sharply reduced. On the other hand, stabilizing CO₂ in the atmosphere above 450 ppm can have significant impacts, which indicates that stabilization of greenhouse gases in the atmosphere will not necessarily provide a high level of climate protection. Results from these and other scenarios are synthesized and related to climate protection goals through a new concept — ‘safe emission corridors’. These corridors indicate the allowable range of near-term global emissions (equivalent CO₂) which complies with specified short- and long-term climate goals. For an illustrative set of climate goals, the allowable anthropogenic global emissions in 2010 are computed to range from 7.3 to 14.5 GtC/yr equivalent CO₂ (1990 level = approximately 9.6 GtC/ yr); when these limits are set twice as strict (ie divided by two), the allowable range becomes 7.6 to 9.3 GtC/yr. To fall within this lower corridor, global emissions must be lower in 2010 than in 1990.     

Unleakable carbon†

Unleakable carbon, or the uncombusted methane and carbon dioxide associated with fossil fuel systems, constitutes a potentially large and heretofore unrecognized factor in determining use of Earth’s remaining fossil fuel reserves. Advances in extraction technology have encouraged a shift to natural gas, but the advantage of fuel switching depends strongly on mitigating current levels of unleakable carbon, which can be substantial enough to offset any climate benefit relative to oil or coal. To illustrate the potential warming effect of methane emissions associated with utilizable portions of our remaining natural gas reserves, we use recent data published in peer-reviewed journals to roughly estimate the impact of these emissions. We demonstrate that unless unleakable carbon is curtailed, up to 59–81% of our global natural gas reserves must remain underground if we hope to limit warming to 2°C from 2010 to 2050. Successful climate change mitigation depends on improved quantification of current levels of unleakable carbon and a determination of acceptable levels of these emissions within the context of international climate change agreements.

Policy relevance

It is imperative that companies, investors, and world leaders considering capital expenditures and policies towards continued investment in natural gas fuels do so with a complete understanding of how dependent the ultimate climate benefits are upon increased regulation of unleakable carbon, the uncombusted carbon-based gases associated with fossil fuel systems, otherwise referred to as ‘fugitive’, ‘leaked’, ‘vented’, ‘flared’, or ‘unintended’ emissions. Continued focus on combustion emissions alone, or unburnable carbon, undermines the importance of assessing the full climate impacts of fossil fuels, leading many stakeholders to support near-term mitigation strategies that rely on fuel switching from coal and oil to cleaner burning natural gas. The current lack of transparent accounting of unleakable carbon represents a significant gap in the understanding of what portions of the Earth’s remaining global fossil fuel reserves can be utilized while still limiting global warming to 2°C. Successful climate change mitigation requires that stakeholders confront the issue of both unburnable and unleakable carbon when considering continued investment in and potential expansion of natural gas systems as part of a climate change solution.     

How long is coal's future?

Nearly all scenarios for future U.S. energy supply systems show heavy dependence on coal. The magnitude depends on assumptions as to reliance on nuclear fission, degree of electrification, and rate of GNP growth, and ranges from 700 million tons to 2300 million tons per year. However, potential climate change resulting from increasing atmospheric carbon dioxide concentrations may prevent coal from playing a major role. The carbon in the carbon dioxide produced from fossil fuels each year is about 1/10 the net primary production by terrestrial plants, but the fossil fuel production has been growing exponentially at 4.3% per year. Observed atmospheric CO₂ concentrations have increased from 315 ppm in 1958 to 330 ppm in 1974 - in 1900, before much fossil fuel was burned, it was about 290–295 ppm. Slightly over one-half the CO₂ released from fossil fuels is accounted for by the increase observed in the atmosphere; at present growth rates the quantities are doubling every 15–18 years. Atmospheric models suggest a global warming of about 2 K if the concentration were to rise to two times its pre-1900 value - enough to change the global climate in major (but largely unknown) ways. With the current rate of increase in fossil fuel use, the atmospheric concentration should reach these levels by about 2030. A shift to coal as a replacement for oil and gas gives more carbon dioxide per unit of energy; thus if energy growth continues with a concurrent shift toward coal, high concentrations can be reached somewhat earlier. Even projections with very heavy reliance on non-fossil energy (Neihaus) after 2000 show atmospheric carbon dioxide concentrations reaching 475 ppm.First presented to the symposium, Coal Science and our National Expectations, Annual Meeting of the American Association for the Advancement of Science, Boston, Massachusetts, February 20, 1976.     

Tracing anthropogenic carbon dioxide and methane emissions to fossil fuel and cement producers, 1854–2010

This paper presents a quantitative analysis of the historic fossil fuel and cement production records of the 50 leading investor-owned, 31 state-owned, and 9 nation-state producers of oil, natural gas, coal, and cement from as early as 1854 to 2010. This analysis traces emissions totaling 914 GtCO₂e—63 % of cumulative worldwide emissions of industrial CO₂ and methane between 1751 and 2010—to the 90 “carbon major” entities based on the carbon content of marketed hydrocarbon fuels (subtracting for non-energy uses), process CO₂ from cement manufacture, CO₂ from flaring, venting, and own fuel use, and fugitive or vented methane. Cumulatively, emissions of 315 GtCO₂e have been traced to investor-owned entities, 288 GtCO₂e to state-owned enterprises, and 312 GtCO₂e to nation-states. Of these emissions, half has been emitted since 1986. The carbon major entities possess fossil fuel reserves that will, if produced and emitted, intensify anthropogenic climate change. The purpose of the analysis is to understand the historic emissions as a factual matter, and to invite consideration of their possible relevance to public policy.     

Climate benefits of changing diet

Climate change mitigation policies tend to focus on the energy sector, while the livestock sector receives surprisingly little attention, despite the fact that it accounts for 18% of the greenhouse gas emissions and for 80% of total anthropogenic land use. From a dietary perspective, new insights in the adverse health effects of beef and pork have lead to a revision of meat consumption recommendations. Here, we explored the potential impact of dietary changes on achieving ambitious climate stabilization levels. By using an integrated assessment model, we found a global food transition to less meat, or even a complete switch to plant-based protein food to have a dramatic effect on land use. Up to 2,700 Mha of pasture and 100 Mha of cropland could be abandoned, resulting in a large carbon uptake from regrowing vegetation. Additionally, methane and nitrous oxide emission would be reduced substantially. A global transition to a low meat-diet as recommended for health reasons would reduce the mitigation costs to achieve a 450 ppm CO₂-eq. stabilisation target by about 50% in 2050 compared to the reference case. Dietary changes could therefore not only create substantial benefits for human health and global land use, but can also play an important role in future climate change mitigation policies.     

Climate change mitigation: trade-offs between delay and strength of action required

Climate change mitigation via a reduction in the anthropogenic emissions of carbon dioxide (CO₂) is the principle requirement for reducing global warming, its impacts, and the degree of adaptation required. We present a simple conceptual model of anthropogenic CO₂ emissions to highlight the trade off between delay in commencing mitigation, and the strength of mitigation then required to meet specific atmospheric CO₂ stabilization targets. We calculate the effects of alternative emission profiles on atmospheric CO₂ and global temperature change over a millennial timescale using a simple coupled carbon cycle-climate model. For example, if it takes 50 years to transform the energy sector and the maximum rate at which emissions can be reduced is ?2.5% $\text{year}^{-1}$ , delaying action until 2020 would lead to stabilization at 540 ppm. A further 20 year delay would result in a stabilization level of 730 ppm, and a delay until 2060 would mean stabilising at over 1,000 ppm. If stabilization targets are met through delayed action, combined with strong rates of mitigation, the emissions profiles result in transient peaks of atmospheric CO₂ (and potentially temperature) that exceed the stabilization targets. Stabilization at 450 ppm requires maximum mitigation rates of ?3% to ?5% $\text{year}^{-1}$ , and when delay exceeds 2020, transient peaks in excess of 550 ppm occur. Consequently tipping points for certain Earth system components may be transgressed. Avoiding dangerous climate change is more easily achievable if global mitigation action commences as soon as possible. Starting mitigation earlier is also more effective than acting more aggressively once mitigation has begun.     

Quality of geological CO2 storage to avoid jeopardizing climate targets

We explore allowable leakage for carbon capture and geological storage to be consistent with maximum global warming targets of 2.5 and 3 °C by 2100. Given plausible fossil fuel use and carbon capture and storage scenarios, and based on modeling of time-dependent leakage of CO₂, we employ a climate model to calculate the long-term temperature response of CO₂ emissions. We assume that half of the stored CO₂ is permanently trapped by fast mechanisms. If 40?% of global CO₂ emissions are stored in the second half of this century, the temperature effect of escaped CO₂ is too small to compromise a 2.5 °C target. If 80?% of CO₂ is captured, escaped CO₂ must peak 300?years or later for consistency with this climate target. Due to much more CO₂ stored for the 3 than the 2.5 °C target, quality of storage becomes more important. Thus for the 3 °C target escaped CO₂ must peak 400?years or later in the 40?% scenario, and 3000?years or later in the 80?% scenario. Consequently CO₂ escaped from geological storage can compromise the less stringent 3 °C target in the long-run if most of global CO₂ emissions have been stored. If less CO₂ is stored only a very high escape scenario can compromise the more stringent 2.5 °C target. For the two remaining combinations of storage scenarios and climate targets, leakage must be high to compromise these climate targets.     

The feasibility of low CO2 concentration targets and the role of bio-energy with carbon capture and storage (BECCS)

The United Nations Framework Convention on Climate Change (UNFCCC 1992) calls for stabilization of atmospheric greenhouse gas (GHG) concentrations at a level that would prevent dangerous anthropogenic interference with the climate system. We use three global energy system models to investigate the technological and economic attainability of meeting CO₂ concentration targets below current levels. Our scenario studies reveal that while energy portfolios from a broad range of energy technologies are needed to attain low concentrations, negative emission technologies—e.g., biomass energy with carbon capture and storage (BECCS)—significantly enhances the possibility to meet low concentration targets (at around 350 ppm CO₂).     

Meeting the EU 2°C climate target: global and regional emission implications

Abstract

This article presents a set of multi-gas emission pathways for different CO₂-equivalent concentration stabilization levels, i.e. 400, 450, 500 and 550 ppm CO₂-equivalent, along with an analysis of their global and regional reduction implications and implied probability of achieving the EU climate target of 2°C. For achieving the 2°C target with a probability of more than 60%, greenhouse gas concentrations need to be stabilized at 450 ppm CO₂-equivalent or below, if the 90% uncertainty range for climate sensitivity is believed to be 1.5–4.5°C. A stabilization at 450 ppm CO₂-equivalent or below (400 ppm) requires global emissions to peak around 2015, followed by substantial overall reductions of as much as 25% (45% for 400 ppm) compared to 1990 levels in 2050. In 2020, Annex I emissions need to be approximately 15% (30%) below 1990 levels, and non-Annex I emissions also need to be reduced by 15–20% compared to their baseline emissions. A further delay in peaking of global emissions by 10 years doubles maximum reduction rates to about 5% per year, and very probably leads to high costs. In order to keep the option open of stabilizing at 400 and 450 ppm CO₂-equivalent, the USA and major advanced non-Annex I countries will have to participate in the reductions within the next 10–15 years.     

Leaking methane from natural gas vehicles: Implications for transportation policy in the greenhouse era

A model of the U.S. automobile market is used to test the role that natural gas vehicles (NGVs) might play in reducing greenhouse-gas emissions. Since natural gas (primarily methane) emits less CO₂ per unit of energy than petroleum products, NGVs are an obvious pathway to lower CO₂ emissions. High-and low-demand scenarios are used to forecast the emissions from unrestricted growth and a modest program of conservation, respectively. Based on these scenarios, a reference scenario is developed that projects a possible future path of automobile use and efficiency. It is found that without a dramatic increase in automobile use, fuel consumption and greenhouse-gas emissions from automobiles in the United States will probably decrease in the future, provided that efficiency continues to improve at modest rates. In theory, NGVs can help shift emissions even further down.A second objective is to quantify the role that leaking methane might play in offsetting some of the greenhouse advantages of NGVs. To do this, a simple atmospheric chemistry model is applied to the reference scenario; several leak rates and feedback factors are used to test the sensitivity of the projected green-house forcing from now until 2050. Committed warming beyond 2050 is not included, and the results should be interpreted with that in mind.It is highly unlikely that switching automobiles from gasoline to natural gas will appreciably lower future greenhouse forcing. Constraints on vehicle miles travelled as well as continued improvements in vehicle efficiency will make a much larger contribution towards controlling global warming.     

Stabilizing greenhouse gas concentrations at low levels: an assessment of reduction strategies and costs

On the basis of the IPCC B2, A1b and B1 baseline scenarios, mitigation scenarios were developed that stabilize greenhouse gas concentrations at 650, 550 and 450 and – subject to specific assumptions – 400 ppm CO₂-eq. The analysis takes into account a large number of reduction options, such as reductions of non-CO₂ gases, carbon plantations and measures in the energy system. The study shows stabilization as low as 450 ppm CO₂-eq. to be technically feasible, even given relatively high baseline scenarios. To achieve these lower concentration levels, global emissions need to peak within the first two decades. The net present value of abatement costs for the B2 baseline scenario (a medium scenario) increases from 0.2% of cumulative GDP to 1.1% as the shift is made from 650 to 450 ppm. On the other hand, the probability of meeting a two-degree target increases from 0%–10% to 20%–70%. The mitigation scenarios lead to lower emissions of regional air pollutants but also to increased land use. The uncertainty in the cost estimates is at least in the order of 50%, with the most important uncertainties including land-use emissions, the potential for bio-energy and the contribution of energy efficiency. Furthermore, creating the right socio-economic and political conditions for mitigation is more important than any of the technical constraints.     

The economics of decarbonizing the energy system—results and insights from the RECIPE model intercomparison

This paper synthesizes the results from the model intercomparison exercise among regionalized global energy-economy models conducted in the context of the RECIPE project. The economic adjustment effects of long-term climate policy are investigated based on the cross-comparison of the intertemporal optimization models ReMIND-R and WITCH as well as the recursive dynamic computable general equilibrium model IMACLIM-R. A number of robust findings emerge. If the international community takes immediate action to mitigate climate change, the costs of stabilizing atmospheric CO₂ concentrations at 450?ppm (roughly 530?C550?ppm-e) discounted at 3% are estimated to be 1.4% or lower of global consumption over the twenty-first century. Second best settings with either a delay in climate policy or restrictions to the deployment of low-carbon technologies can result in substantial increases of mitigation costs. A delay of global climate policy until 2030 would render the 450?ppm target unachievable. Renewables and CCS are found to be the most critical mitigation technologies, and all models project a rapid switch of investments away from freely emitting energy conversion technologies towards renewables, CCS and nuclear. Concerning end use sectors, the models consistently show an almost full scale decarbonization of the electricity sector by the middle of the twenty-first century, while the decarbonization of non-electric energy demand, in particular in the transport sector remains incomplete in all mitigation scenarios. The results suggest that assumptions about low-carbon alternatives for non-electric energy demand are of key importance for the costs and achievability of very low stabilization scenarios.     

Carbon dioxide emissions in a methane economy

Increasing reliance on natural gas (methane) to meet global energy demands holds implications for atmospheric CO₂ concentrations. Analysis of these implications is presented, based on a logistic substitution model viewing energy technologies like biological species invading an econiche and substituting in case of superiority for existing species. This model suggests gas will become the dominant energy source and remain so for 50 years, peaking near 70 percent of world supply. Two scenarios of energy demand are explored, one holding per capita consumption at current levels, the second raising the global average in the year 2100 to the current U.S. level. In the first (efficiency) scenario concentrations peak about 450 ppm, while in the second (long wave) they near 600 ppm. Although projected CO₂ concentrations in a methane economy are low in relation to other scenarios, the projections confirm that global climate warming is likely to be a major planetary concern throughout the twenty-first century. A second finding is that data on past growth of world per capita energy consumption group neatly into two pulses consistent with longwave theories in economics.     

Multi-gas Emissions Pathways to Meet Climate Targets

So far, climate change mitigation pathways focus mostly on CO₂ and a limited number of climate targets. Comprehensive studies of emission implications have been hindered by the absence of a flexible method to generate multi-gas emissions pathways, user-definable in shape and the climate target. The presented method ‘Equal Quantile Walk’ (EQW) is intended to fill this gap, building upon and complementing existing multi-gas emission scenarios. The EQW method generates new mitigation pathways by ‘walking along equal quantile paths’ of the emission distributions derived from existing multi-gas IPCC baseline and stabilization scenarios. Considered emissions include those of CO₂ and all other major radiative forcing agents (greenhouse gases, ozone precursors and sulphur aerosols). Sample EQW pathways are derived for stabilization at 350 ppm to 750 ppm CO₂ concentrations and compared to WRE profiles. Furthermore, the ability of the method to analyze emission implications in a probabilistic multi-gas framework is demonstrated. The probability of overshooting a 2 ^∘C climate target is derived by using different sets of EQW radiative forcing peaking pathways. If the probability shall not be increased above 30%, it seems necessary to peak CO₂ equivalence concentrations around 475 ppm and return to lower levels after peaking (below 400 ppm). EQW emissions pathways can be applied in studies relating to Article 2 of the UNFCCC, for the analysis of climate impacts, adaptation and emission control implications associated with certain climate targets. See for EQW-software and data.