Characterization of the shallow groundwater system in an alpine watershed: Handcart Gulch,Colorado, USA

Water-table elevation measurements and aquifer parameter estimates are rare in alpine settings because few wells exist in these environments. Alpine groundwater systems may be a primary source of recharge to regional groundwater flow systems. Handcart Gulch is an alpine watershed in Colorado, USA comprised of highly fractured Proterozoic metamorphic and igneous rocks with wells completed to various depths. Primary study objectives include determining hydrologic properties of shallow bedrock and surficial materials, developing a watershed water budget, and testing the consistency of measured hydrologic properties and water budget by constructing a simple model incorporating groundwater and surface water for water year 2005. Water enters the study area as precipitation and exits as discharge in the trunk stream or potential recharge for the deeper aquifer. Surficial infiltration rates ranged from 0.1–6.2×10^?5 m/s. Discharge was estimated at 1.28×10^?3 km³. Numerical modeling analysis of single-well aquifer tests predicted lower specific storage in crystalline bedrock than in ferricrete and colluvial material (6.7×10^?5–2.0×10^?3 l/m). Hydraulic conductivity in crystalline bedrock was significantly lower than in colluvial and alluvial material (4.3×10^?9–2.0×10^?4 m/s). Water budget results suggest that during normal precipitation and temperatures water is available to recharge the deeper groundwater flow system.     

Evidence for structurally controlled recharge in the Blue Ridge Province,Virginia, USA

Physical and geophysical data collected at a fractured-rock research site in the Blue Ridge Province of Virginia, USA indicate that recharge rates to a fractured-rock aquifer are controlled by a small-scale thrust fault associated with regional thrust faulting. Recharge rates appear to be correlated to spatial variation in the hydraulic conductivity of the regolith, which has been influenced by weathering rates and the metamorphic and structural history of the underlying parent material. The angle of dip of the thrust-fault shear zone and the fracturing within the crystalline rock adjacent to the fault plane appear to serve as geologic controls that preferentially direct infiltrated meteoric water to a deeper confined fractured-rock aquifer. In-situ analysis of electrical resistivity, matric potential and moisture content shows two distinctly different recharge processes which are spatially correlated with the structure of the shallow subsurface (regolith overlying the vertically oriented shear zone and regolith overlying the thrust-fault hanging wall), and which have strong temporal correlations with the dynamics of the underlying saturated conditions. Recharge flux within the regolith overlying the vertically oriented shear zone is strongly controlled by the orientation and areal extent of the thrust-fault shear zone, highlighting the importance of accurate delineation of recharge areas in crystalline rock aquifer systems.     

Hydrogeology of a montane headwater groundwater system downgradient of a coal-mine waste rock dump: Elk Valley,British Columbia,Canada

Steelmaking-coal waste rock placed in mountain catchments in the Elk Valley, British Columbia, Canada, drain constituents of interest (CIs) to surface water downgradient of the waste rock dumps. The role of groundwater in transporting CIs in the headwaters of mountain catchments is not well understood. This study characterizes the physical hydrogeology of a portion of a 10-km² headwater catchment (West Line Creek) downgradient of a 2.7-km² waste rock dump placed over a natural headwater valley-bottom groundwater system. The study site was instrumented with 13 monitoring wells. Drill core samples were collected to determine subsurface lithology and geotechnical properties. The groundwater system was characterized using field testing and water-level monitoring. The valley-bottom sediments were composed of unconsolidated glacial and meltwater successions (<64 m thick) deposited as a series of cut and fill structures overlying shale bedrock. An unconfined basal alluvial aquifer located above fractured bedrock was identified as the primary conduit for groundwater flow toward Line Creek (650 m from the toe of the dump). Discharge through the basal alluvial aquifer was estimated using the geometric mean hydraulic conductivity (±1 standard deviation). These calculations suggest groundwater discharge could account for approximately 15% (ranging from 2 to 60%) of the total water discharged from the watershed. The residence time from the base of the waste rock dump to Line Creek was estimated at <3 years. The groundwater system was defined as a snowmelt (i.e., nival) regime dominated by direct recharge (percolation of precipitation) across the catchment.     

Aquifer residence times for recycled water estimated using chemical tracers and the propagation of temperature signals at a managed aquifer recharge site in Australia

A prerequisite for minimizing contamination risk whilst conducting managed aquifer recharge (MAR) with recycled water is estimating the residence time in the zone where pathogen inactivation and biodegradation processes occur. MAR in Western Australia’s coastal aquifers is a potential major water source. As MAR with recycled water becomes increasingly considered in this region, better knowledge of applied and incidental tracer-based options from case studies is needed. Tracer data were collected at a MAR site in Floreat, Western Australia, under a controlled pumping regime over a distance of 50 m. Travel times for bromide-spiked groundwater were compared with two incidental tracers in recycled water: chloride and water temperature. The average travel time using bromide was 87?±?6 days, whereas the estimates were longer based on water temperature (102?±?17 days) and chloride (98?±?60 days). The estimate of average flow velocity based on water temperature data was identical to the estimate based on bromide within a 25-m section of the aquifer (0.57?±?0.04 m day^?1). This case study offers insights into the advantages, challenges and limitations of using incidental tracers in recycled water as a supplement to a controlled tracer test for estimating aquifer residence times.     

Delineation of recharge patterns and contaminant transport using 3H–3He in a shallow aquifer contaminated by chlorinated solvents in South Korea

Stable isotopes of water and ³H–³He were used to delineate recharge patterns and contaminant transport for a granitic regolith aquifer in an industrial complex in Wonju, South Korea, that has historically been contaminated with chlorinated solvents including trichloroethene (TCE) and carbon tetrachloride (CT). Groundwater recharge mainly occurred in upgradient forested areas while little recharge occurred in the downgradient industrial areas covered with extensive sections of impermeable pavement and paddy fields. δ¹⁸O and δD data indicated that groundwater was mainly derived from summer precipitation. The apparent groundwater ages using ³H–³He ranged from 1 to 4 yrs in the upgradient area and from 9 to 10 yrs in the downgradient area. Comparison of groundwater flow velocities based on Darcy’s law and those calculated with simple mass balance models and groundwater age supported the presence of preferential pathways for TCE movement in the study area. Measureable TCE was observed in groundwater irrespective of groundwater age. Considering the 3-yr duration of the TCE spill, 14 yrs before sampling, this indicates that TCE plumes were continuously fed from sources in the unsaturated zone after the spill ended and moved downgradient without significant degradation in the aquifer.     

Transient bacterial contamination of the dual-porosity aquifer at Walkerton,Ontario, Canada

Contamination of the Paleozoic carbonate aquifer at Walkerton (Ontario, Canada) by pathogenic bacteria following heavy rain in May 2000 resulted in 2,300 illnesses and seven deaths. Subsequent tracer testing showed that there was rapid groundwater flow in the aquifer, and also rapid exchange between the aquifer and the ground surface. Electrical conductivity (EC) profiling during a 3-day pumping test showed that most flow was through bedding-plane fractures spaced about 10 m apart, that there were substantial contrasts in EC in the major fracture flows, and that there were rapid changes over time. Total coliform sampling revealed transient groundwater contamination, particularly after heavy rain and lasting up to a few days. These characteristics can be understood in terms of the dual-porosity nature of the aquifer. Most of the storage is in the matrix, but this can be considered to be static in the short term. Almost all transport is through the fracture network, which has rapid groundwater flow (～100 m/day) and rapid transmission of pressure pulses due to the high hydraulic diffusivity. Rapid recharge can occur through thin and/or fractured overburden and at spring sites where flow is reversed by pumping during episodes of surface flooding. These characteristics facilitated the ingress of surface-derived bacteria into the aquifer, and their rapid transport within the aquifer to pumping wells. Bacterial presence is common in carbonate aquifers, and this can be explained by the well-connected, large-aperture fracture networks in these dual-porosity aquifers, even though many, such as at Walkerton, lack karst landforms.     

Evaluation of groundwater residence time in a high mountain aquifer system (Sacramento Mountains,USA): insights gained from use of multiple environmental tracers

The New Mexico Bureau of Geology and Mineral Resources (USA) has conducted a regional investigation of groundwater residence time within the southern Sacramento Mountains aquifer system using multiple environmental tracers. Results of the tracer surveys indicate that groundwater in the southern Sacramento Mountains ranges in age from less than 1 year to greater than 50 years, although the calculated ages contain uncertainties and vary significantly depending on which tracer is used. A distinctive feature of the results is discordance among the methods used to date groundwater in the study area. This apparent ambiguity results from the effects of a thick unsaturated zone, which produces non-conservative behavior among the dissolved gas tracers, and the heterogeneous character and semi-karstic nature of the aquifer system, which may yield water from matrix porosity, fractures, solution-enlarged conduits, or a combination of the three. The data also indicate mixing of groundwater from two or more sources, including recent recharge originating from precipitation at high elevations, old groundwater stored in the matrix, and pre-modern groundwater upwelling along fault zones. The tracer data have also been influenced by surface-water/groundwater exchange via losing streams and lower elevation springs (groundwater recycling). This study highlights the importance of using multiple tracers when conducting large-scale investigations of a heterogeneous aquifer system, and sheds light on characteristics of groundwater flow systems that can produce discrepancies in calculations of groundwater age.     

Comparison of age distributions estimated from environmental tracers by using binary-dilution and numerical models of fractured and folded karst: Shenandoah Valley of Virginia and West Virginia, USA

Measured concentrations of environmental tracers in spring discharge from a karst aquifer in the Shenandoah Valley, USA, were used to refine a numerical groundwater flow model. The karst aquifer is folded and faulted carbonate bedrock dominated by diffuse flow along fractures. The numerical model represented bedrock structure and discrete features (fault zones and springs). Concentrations of ³H, ³He, ⁴He, and CFC-113 in spring discharge were interpreted as binary dilutions of young (0–8  years) water and old (tracer-free) water. Simulated mixtures of groundwater are derived from young water flowing along shallow paths, with the addition of old water flowing along deeper paths through the model domain that discharge to springs along fault zones. The simulated median age of young water discharged from springs (5.7  years) is slightly older than the median age estimated from ³H/³He data (4.4  years). The numerical model predicted a fraction of old water in spring discharge (0.07) that was half that determined by the binary-dilution model using the ³H/³He apparent age and ³H and CFC-113 data (0.14). This difference suggests that faults and lineaments are more numerous or extensive than those mapped and included in the numerical model.     

Hydrogeophysical investigation and estimation of groundwater potentials of the Lower Palaeozoic to Precambrian crystalline basement rocks in Keffi area, north-central Nigeria, using resistivity methods

The use of resistivity sounding and two-dimensional (2-D) resistivity imaging was investigated with the aim of delineating and estimating the groundwater potential in Keffi area. Rock types identified are mainly gneisses and granites. Twenty-five resistivity soundings employing the Schlumberger electrode array were conducted across the area. Resistivity sounding data obtained were interpreted using partial curve matching approach and 1-D inversion algorithm, RESIST version 1.0. The 2-D resistivity imaging was also carried out along two traverses using dipole–dipole array, and the data obtained were subjected to finite element method modeling using DIPRO inversion algorithm to produce a two-dimensional subsurface geological model. Interpretation of results showed three to four geoelectrical layers. Layer thickness values were generally less than 2 m for collapsed zone, and ranged from 5 to 30 m for weathered bedrock (saprolite). Two major aquifer units, namely weathered bedrock (saprolite) aquifer and fractured bedrock (saprock) aquifer, have been delineated with the latter usually occurring beneath the former in most areas. Aquifer potentials in the area were estimated using simple schemes that involved the use of three geoelectrical parameters, namely: depth to fresh bedrock, weathered bedrock (saprolite) resistivity and fractured bedrock (saprock) resistivity. The assessment delineated the area into prospective high, medium and low groundwater potential zones.     

Review: The distribution,flow, and quality of Grand Canyon Springs,Arizona (USA)

An understanding of the hydrogeology of Grand Canyon National Park (GRCA) in northern Arizona, USA, is critical for future resource protection. The ~750 springs in GRCA provide both perennial and seasonal flow to numerous desert streams, drinking water to wildlife and visitors in an otherwise arid environment, and habitat for rare, endemic and threatened species. Spring behavior and flow patterns represent local and regional patterns in aquifer recharge, reflect the geologic structure and stratigraphy, and are indicators of the overall biotic health of the canyon. These springs, however, are subject to pressures from water supply development, changes in recharge from forest fires and other land management activities, and potential contamination. Roaring Springs is the sole water supply for residents and visitors (>6 million/year), and all springs support valuable riparian habitats with very high species diversity. Most springs flow from the karstic Redwall-Muav aquifer and show seasonal patterns in flow and water chemistry indicative of variable aquifer porosities, including conduit flow. They have Ca/Mg-HCO₃ dominated chemistry and trace elements consistent with nearby deep wells drilled into the Redwall-Muav aquifer. Tracer techniques and water-age dating indicate a wide range of residence times for many springs, supporting the concept of multiple porosities. A perched aquifer produces small springs which issue from the contacts between sandstone and shale units, with variable groundwater residence times. Stable isotope data suggest both an elevational and seasonal difference in recharge between North and South Rim springs. This review highlights the complex nature of the groundwater system.     

Fractured bedrock and saprolite hydrogeologic controls on groundwater/surface-water interaction: a conceptual model (Australia)

Hydrologic conceptual models of groundwater/surface-water interaction in a saprolite-fractured bedrock geological setting often assume that the saprolite zone is hydraulically more active than the deeper bedrock system and ignore the contribution of deeper groundwater from the fractured bedrock aquifer. A hydraulic, hydrochemical, and tracer-based study was conducted at Scott Creek, Mount Lofty Ranges, South Australia, to explore the importance of both the deeper fractured bedrock aquifer system and the shallow saprolite layer on groundwater/surface-water interaction. The results of this study suggest that groundwater flow in the deeper fractured bedrock zone is highly dynamic and is an important groundwater flow pathway along the hillslope. Deep groundwater is therefore a contributing component in streamflow generation at Scott Creek. The findings of this study suggest that hydrologic conceptual models, which treat the saprolite-fractured bedrock interface as a no-flow boundary and do not consider the deeper fractured bedrock in hydrologic analyses, may be overly simplistic and inherently misleading in some groundwater/surface-water interaction analyses. The results emphasise the need to understand the relative importance of subsurface flow activity in both of these shallow saprolite and deeper bedrock compartments as a basis for developing reliable conceptual hydrologic models of these systems.     

Interactions between the surface water and groundwater in the western shoreline of Lake Nasser, Upper Egypt

The present study indicates that the factors controlling the hydraulic relation between surface water and groundwater at the western lake shoreline change from one locality to another. This depends upon the lithological characteristics and the major structures. In the southern sectors, sedimentation at the bottom and sides of the lake prevents the water movement to the Nubian sandstone aquifer. The potentiometric map reveals that the water level altitudes range between 170 m in the vicinity of the lakeshore line and 110 m west of the lake. The groundwater flow lines show that the main recharge to the aquifer comes from the southwest direction, as well as from the lake inland to variable distances (about 30 Km). During the present study, Darcy’s law was applied to calculate the recharge from the western shoreline of Lake Nasser to the adjacent Nubian aquifer. The maximum value of seepage was at Garf Hussein (27.71?×?10⁶ m³/year), which may be related to high permeability and hydraulic gradient. Also, it may be related to the N–S strike faults that cut the area on both sides of the Lake, and the groundwater is expected to have free circulation through the faults of this trend. The minimum value was recorded in Adindan section (0.61?×?10⁶ m³/year). This may be related to the limited recharge from the lake to the aquifer, due to the sedimentation that dislocates this recharge.     

Environmental tracers as indicators of karst conduits in groundwater in South Dakota,USA

Environmental tracers sampled from the carbonate Madison aquifer on the eastern flank of the Black Hills, South Dakota, USA indicated the approximate locations of four major karst conduits. Contamination issues are a major concern because these conduits are characterized by direct connections to sinking streams, high groundwater velocities, and proximity to public water supplies. Objectives of the study were to estimate approximate conduit locations and assess possible anthropogenic influences associated with conduits. Anomalies of young groundwater based on chlorofluorocarbons (CFCs), tritium, and electrical conductivity (EC) indicated fast moving, focused flow and thus the likely presence of conduits. δ¹⁸O was useful for determining sources of recharge for each conduit, and nitrate was a useful tracer for assessing flow paths for anthropogenic influences. Two of the four conduits terminate at or near a large spring complex. CFC apparent ages ranged from 15 years near conduits to >50 years in other areas. Nitrate-N concentrations >0.4 mg/L in groundwater were associated with each of the four conduits compared with concentrations ranging from <0.1 to 0.4 mg/L in other areas. These higher nitrate-N concentrations probably do not result from sinking streams but rather from other areas of infiltration.     

Assessment of groundwater recharge and water fluxes of the Guarani Aquifer System, Brazil

The groundwater recharge and water fluxes of the Guarani Aquifer System in the state of Sao Paulo in Brazil were assessed through a numeric model. The study area (6,748 km²) comprises Jacaré-Guaçú and Jacaré-Pepira River watersheds, tributaries of the Tietê River in the central region of the state. GIS based tools were used in the storage, processing and analysis of data. Main hydrologic phenomena were selected, leading to a groundwater conceptual model, taking into account the significant outcrops occurring in the study area. Six recharge zones were related to the geologic formation and structures of the semi-confined and phreatic aquifer. The model was calibrated against the baseflows and static water levels of the wells. The results emphasize the strong interaction of groundwater flows between watersheds and the groundwater inflow into the rivers. It has been concluded that lateral groundwater exchanges between basins, the deep discharges to the regional system, and well exploitation were not significant aquifer outflows when compared to the aquifer recharge. The results have shown that the inflows from the river into the aquifer are significant and have the utmost importance since the aquifer is potentially more vulnerable in these places.     

Inferring groundwater flow and recharge from time series analysis of storm responses in a karst aquifer of southeastern Kentucky (USA)

Epigenic karst systems exhibit strong connectivity to surface recharge. In land use dominated by extensive agriculture and farming, epigenic karst aquifers are highly vulnerable to surface contaminants from point and nonpoint sources. Currently, the karstic landscapes of the southeastern Kentucky platform (USA) are impacted by agriculture and the rapid proliferation of concentrated-animal-feeding operations. Analysis of karst aquifer responses to storm events provides qualitative information regarding aquifer–recharge flow paths and groundwater residence time, and knowledge of spatial and temporal variations in recharge and flow is crucial to the understanding of the fate of surface contaminants. Time-series correlation analyses on long-term physicochemical data recorded at the outlet of Grayson Gunnar Cave, an epigenic karst system located along the Cumberland escarpment in southeastern Kentucky, revealed the existence of two separate conduit branches responding 4–8 h apart from each other. Recorded storm response times range from 4 h for flushing and dilution to 7 h for recovery. An estimated 6 million L of stored groundwater is discharged from both branches during major storms, and the fastest responding branch accounts for the majority (80%) of the groundwater reserve being discharged through the spring. As evidenced by groundwater residence time (7 days), recharge is likely characterized by localized infiltration of rain water from subsurface sinkholes to the conduit branches with no contribution of regional or lateral groundwater flow.     

Hydrogeochemical and isotopic evidence of groundwater evolution and recharge in aquifers in Beijing Plain, China

An investigation was conducted in Beijing to identify the groundwater evolution and recharge in the quaternary aquifers. Water samples were collected from precipitation, rivers, wells, and springs for hydrochemical and isotopic measurements. The recharge and the origin of groundwater and its residence time were further studied. The groundwater in the upper aquifer is characterized by Ca-Mg-HCO₃ type in the upstream area and Na-HCO₃ type in the downstream area of the groundwater flow field. The groundwater in the lower aquifer is mainly characterized by Ca-Mg-HCO₃ type in the upstream area and Ca-Na-Mg-HCO₃ and Na-Ca-Mg-HCO₃ type in the downstream area. The δD and δ¹⁸O in precipitation are linearly correlated, which is similar to WMWL. The δD and δ¹⁸O values of river, well and spring water are within the same ranges as those found in the alluvial fan zone, and lay slightly above or below LMWL. The δD and δ¹⁸O values have a decreasing trend generally following the precipitation → surface water → shallow groundwater → spring water → deep groundwater direction. There is evidence of enrichment of heavy isotopes in groundwater due to evaporation. Tritium values of unconfined groundwater give evidence for ongoing recharge in modern times with mean residence times <50 a. It shows a clear renewal evolution along the groundwater flow paths and represents modern recharge locally from precipitation and surface water to the shallow aquifers (<150 m). In contrast, according to ¹⁴C ages in the confined aquifers and residence time of groundwater flow lines, the deep groundwater is approximately or older than 10 ka, and was recharged during a period when the climate was wetter and colder mainly from the piedmont surrounding the plain. The groundwater exploitation is considered to be “mined unsustainably” because more water is withdrawn than it is replenished.     

Regional recharge estimation using multiple methods: an application in the Annapolis Valley, Nova Scotia (Canada)

Recharge is a key parameter in groundwater resources management, and a reliable estimate of recharge is required for their sustainable development. Several methods are available to evaluate recharge; however, selecting the appropriate one is made difficult because each method has its advantages and drawbacks, and results can vary greatly from one method to another. Recharge methods can actually refer to different processes. This paper compares and discusses the results obtained from five regional-scale recharge assessment approaches applied to a fractured rock aquifer in a region with a temperate and humid climate (Annapolis Valley, Nova Scotia, Canada). These methods are distinguished between those providing estimates of the net infiltration (I) into the subsurface (river hydrograph separation and soil moisture balance) from those considering the net recharge (W) to the regional bedrock aquifer (river 7-day low-flows, the corrected soil moisture balance, a numerical groundwater flow model developed with FEFLOW and an infiltration model developed with HELP). The estimated net infiltration ranges from 160 to 250 mm/year, whereas the net recharge estimates range from 80 to 175 mm/year for the entire study area. Although different assessment methods were used, the estimated recharge range is still quite large, demonstrating the importance of using several methods. This case study should provide guidance on choices to be made in the development of a strategy for assessing representative values of aquifer recharge at the regional scale under similar geological and climatic conditions. The use of multiple complementary approaches should lead to a better understanding of the system dynamics and to better defined a representative range of recharge estimates.     

Potential contaminant transport in the regional Carbonate Aquifer beneath Yucca Mountain, Nevada, USA

Yucca Mountain, Nevada is the site of the proposed US geologic repository for spent nuclear fuel and high-level radioactive waste. The repository is to be a mine, sited approximately 300 m below the crest of the mountain, in a sequence of variably welded and fractured mid-Miocene rhylolite tuffs, in the unsaturated zone, approximately 300 m above the water table. Beneath the proposed repository, at a depth of 2 km, is a thick sequence of Paleozoic carbonate rocks that contain the highly transmissive Lower Carbonate Aquifer. In the area of Yucca Mountain the Carbonate Aquifer integrates groundwater flow from north of the mountain, through the Amargosa Valley, through the Funeral Mountains to Furnace Creek in Death Valley, California where the groundwater discharges in a set of large springs. Data that describe the Carbonate Aquifer suggest a concept for flow through the aquifer, and based upon the conceptual model, a one-layer numerical model was constructed to simulate groundwater flow in the Carbonate Aquifer. Advective transport analyses suggest that the predicted travel time of a particle from Yucca Mountain to Death Valley through the Carbonate Aquifer might be as short as 100 years to as long 2,000 years, depending upon the porosity.     

Characterisation of recharge processes and groundwater flow mechanisms in weathered-fractured granites of Hyderabad (India) using isotopes

In order to address the problem of realistic assessment of groundwater potential and its sustainability, it is vital to study the recharge processes and mechanism of groundwater flow in fractured hard rocks, where inhomogeneties and discontinuities have a dominant role to play. Wide variations in chloride, δ¹⁸O and ¹⁴C concentrations of the studied groundwaters observed in space and time could only reflect the heterogeneous hydrogeological setting in the fractured granites of Hyderabad (India). This paper, based on the observed isotopic and environmental chloride variations of the groundwater system, puts forth two broad types of groundwaters involving various recharge processes and flow mechanisms in the studied granitic hard rock aquifers. Relatively high ¹⁴C ages (1300 to ～6000 yr B.P.), δ¹⁸O content (?3.2 to ?1.5‰) and chloride concentration (<100 mg/l) are the signatures that identified one broad set of groundwaters resulting from recharge through weathered zone and subsequent movement through extensive sheet joints. The second set of groundwaters possessed an age range Modern to ～1000 yr B.P., chloride in the range 100 to ～350 mg/l and δ¹⁸O from ?3.2 to +1.7‰. The δ¹⁸O enrichment and chloride concentration, further helped in the segregation of the second set of groundwaters into three sub-sets characterized by different recharge processes and sources. Based on these processes and mechanisms, a conceptual hydrogeologic model has evolved suggesting that the fracture network is connected either to a distant recharge source or to a surface reservoir (evaporating water bodies) apart from overlying weathered zone, explaining various resultant groundwaters having varying ¹⁴C ages, chloride and δ¹⁸O concentrations. The surface reservoir contribution to groundwater is evaluated to be significant (40 to 70%) in one subset of groundwaters. The conceptual hydrogeologic model, thus evolved, can aid in understanding the mechanism of groundwater flow as well as migration of contaminants to deep groundwater in other fractured granitic areas.     

Delineating spring recharge areas in a fractured sandstone aquifer (Luxembourg) based on pesticide mass balance

A simple method to delineate the recharge areas of a series of springs draining a fractured aquifer is presented. Instead of solving the flow and transport equations, the delineation is reformulated as a mass balance problem assigning arable land in proportion to the pesticide mass discharged annually in a spring at minimum total transport cost. The approach was applied to the Luxembourg Sandstone, a fractured-rock aquifer supplying half of the drinking water for Luxembourg, using the herbicide atrazine. Predictions of the recharge areas were most robust in situations of strong competition by neighbouring springs while the catchment boundaries for isolated springs were extremely sensitive to the parameter controlling flow direction. Validation using a different pesticide showed the best agreement with the simplest model used, whereas using historical crop-rotation data and spatially distributed soil-leaching data did not improve predictions. The whole approach presents the advantage of integrating objectively information on land use and pesticide concentration in spring water into the delineation of groundwater recharge zones in a fractured-rock aquifer.