皖南谭山岩体成因:年代学和地球化学制约

皖南地区广泛发育燕山期岩浆岩,可以划分为早、晚两个阶段,年龄分别为152~136 Ma和136~122 Ma。谭山岩体是其中一个出露面积较大的复式岩体,主要发育两个侵入期次,分别以二长花岗岩和钾长花岗岩为主。LA-ICP-MS锆石U-Pb定年获得二长花岗岩的成岩年龄为128.5±1.7~126.7±1.7 Ma,而钾长花岗岩形成年龄为128.2±1.6 Ma,均为晚阶段岩浆活动的产物。谭山岩体两种类型的岩性均表现出富碱、富铁、高Ga/Al比值、强烈亏损Ba、Sr,并具显著的Eu负异常,具有A型花岗岩的地球化学特征。两类岩石中锆石具有相似的Hf-O同位素组成,ε_(Hf)(t)值变化范围介于-8.04~-2.47之间,δ~(18)O值介于8.2‰~9.6‰之间,Hf-O同位素组成与下扬子广泛发育的新元古代地体中的锆石Hf-O同位素变化范围基本一致,指示谭山岩体的岩浆起源于高温低压环境,主体为下扬子中元古代增生地壳深熔作用的产物,并有少量地幔物质的混合,指示本地区在燕山期晚阶段岩浆作用期间处在强烈拉张的构造背景。     

南岭连阳复式岩体成因:锆石U-Pb年代学、地球化学和Nd-Hf同位素约束

报道了南岭地区连阳花岗质复式岩体的锆石U-Pb年代学、岩石地球化学和Nd-Hf同位素数据。LA-ICP MS锆石U-Pb定年结果表明,连阳岩体中的补体(细粒黑云母花岗岩)形成于100~104Ma,晚于主体(粗粒似斑状黑云母花岗岩)约40Ma,表明两者不是分离结晶关系。主体和补体均具有高硅(SiO265%~79%)、富碱(Na2O+K2O 6.9%~9.5%)、准铝质-过铝质特征(A/CNK=0.9~1.2),相对高钾(K2O/Na2O=1.3~2.5),亏损Ba、Sr、P和Ti,富集Rb、Pb和LREE。补体分异程度更高(SiO277%~79%),强烈亏损Eu(δEu=0.03~0.06)。两者εNd(t)值分别为-10.6~-8.4和-9.1~-6.6,补体εHf(t)值为-8.5~-1.8。研究表明连阳岩体的形成与华南燕山晚期陆内伸展作用有关,主要由成熟度较高的元古宙变泥质沉积岩陆壳熔融而成,存在少量幔源岩浆的贡献。通过与典型含W、含Sn和含Nb-Ta矿岩体的对比表明,连阳岩体的主体岩石成矿的可能性较小,而补体具有较好的Sn矿成矿潜力。     

蚌埠隆起区花岗岩形成时代及岩浆源区性质:锆石 LA-ICPMS U-Pb定年与示踪

蚌埠隆起区西庐山及女山花岗岩中岩浆锆石 206Pb/238U加权平均年龄分别为 (129.3± 4.8)Ma( n=7)和 (130.1± 3.2)Ma( n=9),这表明岩体的形成时代为早白垩世早期;曹山二长花岗岩和蚂蚁山花岗岩中岩浆锆石 206Pb/238U加权平均年龄分别为 (110.3± 2.8)Ma( n=17)和 (115.8± 3.1)Ma( n=18),其形成时代为早白垩世晚期.岩体的岩相学和具有震荡环带岩浆锆石的存在表明该类花岗岩均为岩浆结晶的产物,而非混合岩化成因.西庐山和女山花岗岩中新元古代岩浆锆石和印支期变质锆石的存在以及太古宙和古元古代继承锆石的存在暗示岩浆源区既有扬子地块基底物质又有华北地块基底物质,其中某些遭受了超高压变质作用的改造.蚌埠隆起区深部地壳中扬子地块基底物质的存在与扬子地块沿郯庐断裂带于北西方向俯冲于华北地块之下的地质事实相吻合.     

赣西蒙山岩体地球化学、锆石U-Pb年龄、Hf同位素特征及地质意义北大核心CSCD

以赣西地区蒙山岩体为研究对象,通过对该岩体地球化学、锆石U-Pb年龄及Hf同位素的研究,探讨其岩浆物质来源及构造背景。该岩体经历了印支期、燕山期岩浆侵入活动,形成六种岩石类型,LA-ICP-MS锆石U-Pb年龄分别为224.0±2.10 Ma(n=19,MSWD=1.9)、223.0±2.20 Ma(n=21,MSWD=2.6)、222.0±2.80 Ma(n=21,MSWD=2.7)、220.0±1.90 Ma(n=16,MSWD=1.5)、217.0±3.70 Ma(n=8,MSWD=1.8)、142.0±0.98 Ma(n=21,MSWD=1.4),表明岩体经历了印支期、燕山期两期岩浆活动。印支期花岗质岩石地球化学具高硅富钾、准铝-过铝质特征;微量元素富集高场强元素Zr、Hf、Th、U和稀土元素La、Ce、Sm、Nd、Y,明显亏损Rb、Ba、Sr、Ti、P;稀土元素分馏程度不高,δEu介于0.03~0.15,具强Eu负异常,Ce异常不明显,稀土配分曲线呈“V”型;为同源岩浆演化的特点。CaO/Na_(2) O比值<0.3、Rb/Sr>5,岩石二阶段模式年龄T DM2主体介于868~1465 Ma,为中-新元古代,εHf(t)对应的T DM2值显示,岩体物源起源于成熟地壳,后期有大量新生地壳物质的加入,表明岩石来源于含水矿物(如白云母、绿帘石/黝帘石)的脱水反应导致成熟度高地壳物质的熔融而形成。在花岗岩构造环境判别图上,投于碰撞大地构造背景上的花岗岩和造山后花岗岩类(POG)区域,锆石U-Pb年龄表明成岩时段滞后于印支运动高峰期(258~243 Ma),为受印支运动造成华南地壳加厚滞后,地壳进入伸展阶段,减压熔融形成的花岗质岩浆。     

滇西南澜沧江结合带中段云县花岗岩的地质特征及形成环境

南澜沧江结合带云县花岗岩体的岩石类型主要为黑云二长花岗岩,SiO2平均为68．57％,K2O／Na2O平均为1．67,相对富钾,岩石属高钾钙碱性系列。其岩石酸、碱度低于同类岩石平均值;而镁铁组分高于平均值,显示岩石偏中性,与同碰撞构造环境形成的花岗岩特征类似。Al2O3平均为13．66％,含量较高,ACNK平均为1.1,呈铝过饱和。CIPW计算结果,都出现标准矿物刚玉分子（〉1％）。岩石总体上相对富集大离子亲石元素,亏损高场强元素。稀土元素总量（EREE）高,平均240．75×10^-6。岩体轻稀土元素富集,重稀土亏损,（La／Yb）。为8．88-9．41,分异不是很大;Eu为中等负异常,δEu为0．52-0．57,经多种相关图解判别,岩石属S型花岗岩。其构造环境相当于大陆碰撞花岗岩类（CCG）。锆石颗粒U-Pb测年结果显示,源岩的形成年龄最晚是晋-7期（〉778Ma）,岩体主体形成于华力西晚期一印支期。0206024-5k号锆石是岩浆成因锆石,该样品的206^Ph/238^U和207^Pb/235^U两个年龄（49Ma和61Ma）反映在云县岩体中可能存在喜山期岩浆活动。     

南岭大东山花岗岩的形成时代与成因——SHRIMP锆石U-Pb年龄、元素和Sr-Nd-Hf同位素地球化学

中国东南部南岭地区广泛出露以弱过铝质黑云母二长花岗岩和黑云母钾长花岗岩为主的燕山早期花岗质岩石,其成因有待进一步研究。大东山岩体岩性主要为黑云母二长花岗岩和黑云母钾长花岗岩,两个样品的SHRIMP锆石U-Pb 年龄为165±2 Ma 和159±2 Ma,与区域南岭系列的黑云母花岗岩的主要形成时代一致。花岗岩样品以高硅（SiO2 > 72%）、高钾（K2O/Na2O > 1.6）、富碱（K2O + Na2O = 7.36% ~ 9.31%）和弱过铝质（集中于ASI = 1.00 ~ 1.11）为特征。微量和稀土元素组成上,岩体富Rb, Th 和LREE,贫Ba, Nb, Sr, P 和Ti, Eu 负异常显著（δEu = 0.06 ~ 0.34）。多数样品的Zr,Ce, Nb 和Y 含量总和小于350×10-6,10 000 × Ga/Al 值低于典型的A 型花岗岩。同位素组成上,样品具有高I sr（ 0.7123 ~ 0.7193）和低εN（d t）（-9.3~ -11.5）的特点,两阶段Nd 模式年龄为1.70~1.89 Ga ;与全岩εNd（t）不同,岩浆锆石的εHf（t）具有较大的变化范围（-3.5~ -11.8）。矿物学及地球化学结果表明大东山是一个高分异的I 型花岗岩岩体。岩体岩浆很可能是由元古代火成岩石部分熔融形成,并伴随有少量年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生混合、结晶分异作用。     

湘南宜章地区辉绿岩、花岗斑岩、安山岩的形成时代和成因——锆石U-Pb年龄和Hf同位素组成

湘南宜章县长城岭地区广泛出露以辉绿岩、花岗斑岩为主的燕山早期岩体,而宜章平和地区主要分布安山岩体,其年龄和成因有待进一步研究。分别用SHRIMP和LA-ICP-MS法测试了它们的年龄和Hf同位素组成,长城岭辉绿岩的SHRIMP锆石U-Pb年龄为153.7Ma±3.1Ma、227.0Ma±4.2Ma;长城岭花岗斑岩的LA-ICP-MS锆石U-Pb测年结果为153Ma±14Ma和231.58Ma±0.67Ma;平和安山岩的SHRIMP锆石U-Pb测年结果为159Ma±14Ma和229.3Ma±7.6Ma,LA-ICP-MS锆石U-Pb测年结果为161Ma±1Ma,显示为燕山早期岩浆侵位和印支期基性岩浆底侵。锆石Lu-Hf同位素原位分析结果表明,εHf(t)值在正值和负值范围内变化,指示岩浆为壳幔混合来源。结合长城岭花岗岩体中继承锆石的年龄信息,认为花岗质岩石可能来源于中元古代基底的重熔。岩体岩浆很可能是由元古宙火成岩石部分熔融形成的,并伴有年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生了混合作用。     

华南桂东南地区加里东期Ⅰ型花岗岩类的岩石成因及构造意义

龙新岩体和夏郢岩体位于扬子地块与华夏地块拼合带的西南端,岩体中的Ⅰ型花岗岩成因研究对揭示桂东南地区早古生代的地球动力学背景及其构造演化具有重要的地质意义.对龙新岩体的寄主岩和其暗色微粒包体,以及夏郢岩体岩石进行了LA-ICP-MS锆石U-Pb定年、Lu-Hf同位素和全岩地球化学研究.锆石U-Pb定年结果显示,龙新岩体的寄主岩（花岗闪长岩）的年龄为440±2 Ma;龙新岩体的暗色包体（闪长岩）的年龄为441±1 Ma,寄主岩与暗色包体为同期岩浆作用的产物.夏郢岩体花岗闪长岩和二长花岗岩年龄分别为447±3 Ma和436±3 Ma,说明夏郢岩体至少发生了2期岩浆侵入事件.Hf同位素研究表明,龙新岩体寄主岩和暗色微粒包体的锆石ε_Hf（t）值分别为-3.32~-5.83和-17.89~-1.82,二阶段模式年龄（T_DM2）分别为1.62~1.76 Ga和1.57~2.54 Ga;夏郢岩体早期花岗岩闪长岩和晚期二长花岗岩的锆石ε_Hf（t）值分别为-15.43~3.03和-4.79~6.82,T_DM2分别为1.59~1.99 Ga和0.97~1.70 Ga,指示物源主要来自古-中元古代的地壳物质.地球化学特征表明龙新岩体寄主岩为准铝质高钾钙碱性Ⅰ型花岗岩,寄主岩和暗色微粒包体均富集轻稀土元素和大离子亲石元素,亏损重稀土元素及高场强元素;夏郢岩体早期的花岗闪长岩为弱过铝质高钾钙碱性Ⅰ型花岗岩,晚期的二长花岗岩则为强过铝质高钾钙碱性Ⅰ型花岗岩,主微量元素特征均与龙新岩体寄主岩相似.根据研究区花岗岩和镁铁质包体的岩相学、年代学、地球化学及Hf同位素组成特征,表明龙新岩体的暗色包体（闪长岩）为岩浆混合成因,而龙新岩体寄主岩（花岗闪长岩）和夏郢岩体（早期花岗岩闪长岩和晚期二长花岗岩）具有一致的岩石源区和岩石成因,但在后期的成岩过程中存在岩浆混合和结晶分异程度的差异.综合以往对华南地区构造背景的研究,认为龙新和夏郢岩体是在扬子地块和华夏地块陆内造山期后,岩石圈伸展减薄,热的幔源岩浆上涌底侵,中-下地壳受到地幔热影响发生部分熔融,形成的酸性岩浆在源区和基性岩浆经历了不均一且不强烈的壳-幔混合作用形成的.      

北祁连东段冷龙岭地区毛藏寺岩体和黄羊河岩体的岩石成因及其构造意义

文中研究了北祁连东段冷龙岭地区毛藏寺岩体和黄羊河岩体的年代学、地球化学和Sr-Nd同位素组成。毛藏寺岩体主要岩石类型为花岗闪长岩。锆石U Pb定年获得花岗闪长岩岩浆结晶年龄为（424±4） Ma。花岗闪长岩具有高的Mg#（约55）,K2O/Na2O=0.77~0.91,A/CNK=0.92~0.94,表明岩石属准铝质。在微量元素组成上,花岗闪长岩富集LILE、亏损HFSE,轻重稀土分异明显［(La/Yb)N=16.9~19.5］,具有弱的Eu负异常（Eu/Eu*=0.75~0.83）;花岗闪长岩具有ISr=0.706 3~0.706 5,εNd(t) =-1.5~-1.1,TDM=1.10~1.16 Ga。这些地球化学特征和Sr Nd同位素组成表明,花岗闪长岩岩浆源区为基性下地壳变玄武质岩石,但在成岩过程中有少量幔源物质的加入。黄羊河岩体主要由钾长花岗岩组成,其岩浆结晶年龄为（402±4） Ma。岩石富碱（K2O+Na2O=6.91‰~7.66%）,K2O/Na2O>1,A/CNK=0.97~1.05。钾长花岗岩富集LILE及HFSE,轻重稀土元素分馏中等［(La/Yb)N =10.6~17.8］,并具有明显的负Eu异常（Eu/Eu*=0.43~0.68）,表明钾长花岗岩具有铝质A型花岗岩的地球化学特征。钾长花岗岩具有ISr=0.710 3~0.711 3,εNd(t)=-6.7~-6.0,TDM=1.46~1.55 Ga,反映岩浆主要来自地壳中长英质物质的部分熔融。冷龙岭地区花岗岩类的岩石成因及其岩浆演化揭示了北祁连山造山带从加里东早期的挤压构造体制向加里东晚期的伸展构造体制的演化。这些花岗岩类形成于碰撞后构造背景,岩浆的产生可能与俯冲的北祁连洋板片的断离作用有密切联系。     

浙东天台地区早白垩世花岗岩及暗色包体锆石U-Pb年龄、地球化学及其成因

在华南东部浙闽沿海一带普遍发育有大量晚中生代花岗质岩体及其中的暗色包体,这些岩体被认为是大规模壳幔相互作用和岩浆混合作用的产物。本文对浙东天台地区白鹤岩体中的寄主花岗岩及其中发育的暗色包体分别进行了LA-ICP-MS锆石U-Pb定年和详细的岩石地球化学研究,其锆石U-Pb年龄分别为(120.4±1.2)Ma和(120.6±1.1)Ma,属浙东燕山期侵入活动集中的早白垩世中晚期产物。岩石地球化学特征显示,寄主花岗岩为高硅、富碱、弱过铝质的高钾钙碱性花岗岩,具有较强的Eu负异常,富集Rb、Th、U、K,并有Sr、Ba、P、Ti、Nb、Ta等元素的亏损,岩石成因为高分异I型花岗岩;暗色包体多为低硅、富钠、偏铝质低钾拉斑玄武系列岩石,轻稀土富集、重稀土亏损,并具有弱的Eu正异常。锆石Hf同位素组成表现出不同物质来源(壳幔混源)花岗岩类岩石的特点。综合年代学及岩石地球化学特征,认为浙东地区早白垩世I型花岗岩及其暗色包体是在燕山期弧后碰撞伸展引张的构造背景下,由底侵的幔源岩浆与其诱发熔融的深部壳源岩浆经混合后,经过一定程度的分异演化,最后定位于浅成环境的产物。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。