Biological effects of gold mine tailings on the intertidal marine environment in Nova Scotia,Canada

From 1861 to the 1940s, gold was produced from 64 mining districts in Nova Scotia, where mercury amalgamation was the dominant method for the extraction of gold from ore until the 1880s. As a result, wastes (tailings) from the milling process were contaminated by mercury and were high in naturally occurring arsenic. In 2004 and 2005, sediments, water and mollusc tissues were collected from 29 sampling stations at nine former gold mining areas along the Atlantic coastline and were analysed for arsenic and mercury. The resulting data were compared with environmental quality guidelines. Samples indicated high potential risk of adverse effects in the intertidal environments of Seal Harbour, Wine Harbour and Harrigan Cove. Arsenic in Seal Harbour was bioavailable, resulting in high concentrations of arsenic in soft-shell clam tissues. Mercury concentrations in tissues were below guidelines. This paper presents results of the sampling programs and implications of these findings.     

Assessment of Water Quality in the Elbe River at Low Water Conditions Based on Factor Analysis

An assessment of water quality measurements during a long‐lasting low water period in the Elbe River is presented. Weekly samples were taken from May to December 2003 at a sampling site in the middle part of the Elbe River. For multivariate data analysis, 34 parameters of 46 samplings were considered. As a result of this analysis, 78% of the variance of the data set is explained by five factors. They can be assigned to the following latent variables: season (37.5%) > tributaries (12.7%) > re‐suspension (10.4%) > discharge (9.4%) > complexation (8.5%). For the investigated sampling site, two key processes were identified as dominating factors on the water quality during low water conditions. First, seasonal phytoplankton development caused changes in redox conditions with consequences for re‐solution of pollutants from sediments. Second, tributaries have a higher impact on the main stream, due to changes in mixing processes. Therefore, in addition to flood investigations, monitoring strategies, and management plans should be developed in order to survey changes in water quality during low water conditions.     

城镇化下河流水质变化及其与景观格局关系分析——以太湖流域苏州市为例

以河流近域景观格局与水环境质量间的关系为研究对象,基于2001年及2010年两期土地利用类型以及7条典型河流的溶解氧、氨氮、高锰酸盐指数、总磷、总氮5项水质指标,分析城镇化下苏州市河流水质与景观格局之间的关系及其变化规律.结果表明:(1)苏州市河流水质状况总体较差,但呈现一定的好转趋势.(2)河流水质受到城镇用地、旱地及水田的综合影响,并表现出尺度效应.其中城镇用地与旱地对河流水质恶化具有明显的作用,水田则反之.2001-2010年城镇用地及水田对水质的影响程度有所减弱,旱地则增强.(3)蔓延度指数、最大面积斑块比例对河流水质呈现负相关,斑块数量、斑块密度、香农均匀度指数、香农多样性指数则与水质呈现正相关.景观格局对于水质的影响在大范围缓冲区更为显著.研究结果可为苏州水环境管理及太湖流域城市空间开发提供一定的参考依据.     

三峡工程调节作用对洞庭湖水面面积(2000-2010年)的影响

以洞庭湖为研究对象,以11年(2000-2010年)Terra/MODIS 16 d最大值合成的植被指数数据产品集MOD13Q1和同期城陵矶水文监测站的水位数据为主要数据源,通过对NDVI和NIR分别设定阈值的方法,实现了洞庭湖水面面积的综合提取,分析了三峡工程建设背景下,洞庭湖水面面积的年际变化特征和年内变化规律,再结合城陵矶水位数据,对水位与水面面积之间的定量关系进行了深入分析.研究结果表明:三峡工程的运行,很大程度上控制着洞庭湖的入湖水量,对洞庭湖防汛工作有利;在气候变化、三峡水库的共同影响下,洞庭湖区水面面积整体上呈减少趋势;水面面积与水位的拟合结果显示两者具有良好的相关性,其中2000-2003年两者的确定性系数达到0.975.     

太湖流域上游平原河网区水质空间差异与季节变化特征

在太湖流域上游的宜溧—洮滆水系主要河道设置67个监测点,分别于2014年1月(冬季)、4月(春季)、8月(夏季)、11月(秋季)进行水质监测,采用多元统计方法分析了水质的空间差异性和季节性变化,并利用水质标识指数法对水环境质量进行评价.结果表明,宜溧—洮滆水系污染程度较严重,总氮(TN)、总磷(TP)和高锰酸盐指数(CODMn)浓度年均值分别为4.93、0.26和7.63 mg/L;单因素多元方差分析和聚类分析显示污染物浓度具有显著时空差异性,时间上冬、春季污染程度较高而夏、秋季较低,空间上无锡和常州氮、磷污染较为严重,宜兴和溧阳市有机污染程度较高;水质标识评价结果显示流域内水质基本为IV类或V类,其中TN、TP及CODMn是关键污染指标.     

Investigating evidential reasoning for the interpretation of microbial water quality in a distribution network

Total coliforms are used as indicators for evaluating microbial water quality in distribution networks. However, total coliform provides only a weak “evidence” of possible fecal contamination because pathogens are subset of total coliform and therefore their presence in drinking water is not necessarily associated with fecal contamination. Heterotrophic plate counts are also commonly used to evaluate microbial water quality in the distribution networks, but they cover even a wider range of organisms. As a result, both of these indicators can provide incomplete and highly uncertain bodies of evidence when used individually. In this paper, it is shown that combing these two sources of information by an appropriate data fusion technique can provide improved insight into microbial water quality within distribution networks. Approximate reasoning methods like fuzzy logic and probabilistic reasoning are commonly used for data fusion where knowledge is uncertain (i.e., ambiguous, incomplete, and/or vague). Traditional probabilistic frameworks like Bayesian analysis, reasons through conditioning based on prior probabilities (which are hardly ever available). The Dempster–Shafer (DS) theory generalizes the Bayesian analysis without requiring prior probabilities. The DS theory can efficiently deal with the difficulties related to the interpretation of overall water quality where the redundancy of information is routinely observed and the credibility of available data continuously changes. In this paper, the DS rule of combination and its modifications including Yager’s modified rule, Dubois–Prade disjunctive rule and Dezert–Smarandache rule are described using an example of microbial water quality in a distribution network.     

On the development mechanism of the lacustrine high-grade hydrocarbon source rocks of Chang 9<Subscript>1</Subscript> member in Ordos Basin

As revealed from recent drilling and organic geochemical testing and research, a series of lacustrine high-grade hydrocarbon source rocks was discovered in the upper section of the Chang 9 oil reservoir member of upper Triassic in Ordos Basin. The hydrocarbon source rocks show average TOC content as high as 5.03%, average bitumen “A” content as high as 0.8603%, and good quality organic precursors, which are of the sapropelic type mainly derived from lower aquatic plants and have reached the thermal evolution stage featured by oil-producing climax. Generally the lacustrine high-grade hydrocarbon source rocks were developed in local depressions of a lake basin, and the Chang 9₁ member was particularly formed in a depositional environment characterized by fresh water to weakly saline water, weakly oxidizing to weakly reducing setting and semi-deep lake facies, as was demonstrated by a variety of organic to inorganic geochemical parameters. As a result, high productivity constitutes the principal controlling force for generation of this series of high-grade hydrocarbon source rocks. Deposition of thinly-bedded and laminated tuffs as well as positive Eu anomaly corroborate the possible occurrence of anoxic geological event closely related to contemporaneous volcanic eruption, which would play a key part in development of the Chang 9₁ member of high-grade hydrocarbon source rocks.     

On the development mechanism of the lacustrine high-grade hydrocarbon source rocks of Chang 91 member in Ordos Basin

As revealed from recent drilling and organic geochemical testing and research, a series of lacustrine high-grade hydrocarbon source rocks was discovered in the upper section of the Chang 9 oil reservoir member of upper Triassic in Ordos Basin. The hydrocarbon source rocks show average TOC content as high as 5.03%, average bitumen “A” content as high as 0.8603%, and good quality organic precursors, which are of the sapropelic type mainly derived from lower aquatic plants and have reached the thermal evolution stage featured by oil-producing climax. Generally the lacustrine high-grade hydrocarbon source rocks were developed in local depressions of a lake basin, and the Chang 9₁ member was particularly formed in a depositional environment characterized by fresh water to weakly saline water, weakly oxidizing to weakly reducing setting and semi-deep lake facies, as was demonstrated by a variety of organic to inorganic geochemical parameters. As a result, high productivity constitutes the principal controlling force for generation of this series of high-grade hydrocarbon source rocks. Deposition of thinly-bedded and laminated tuffs as well as positive Eu anomaly corroborate the possible occurrence of anoxic geological event closely related to contemporaneous volcanic eruption, which would play a key part in development of the Chang 9₁ member of high-grade hydrocarbon source rocks.

     

基于ELCOM-CAEDYM模型的淀山湖营养物投入响应关系的模拟

针对淀山湖严重富营养化的问题,应用三维水动力-水质耦合模型ELCOM-CAEDYM对淀山湖水质进行了模拟,确定了一套可应用于淀山湖水质模拟的参数,并对模拟结果进行了验证;验证结果显示,ELCOM-CAEDYM耦合模型较好地模拟了常规水质和藻类浓度动态变化,模拟结果的总体变化趋势与实测结果相符合.同时运用该模型对淀山湖营...     

Comparing long term sediment records to current biological quality element data - Implications for bioassessment and management of a eutrophic lake

Defining reference conditions for lakes situated in areas of human settlement and agriculture is rarely straightforward, and is especially difficult within easily eroding and nutrient rich watersheds. We used diatoms, cyanobaterial akinetes, remains of green algae and chironomid head capsules from sediment samples of Lake Kirmanjärvi, Finland, to assess its deviation from the initial ecological status. These site-specific records of change were compared to current type-specific ecological status assessment. All paleolimnological data indicated deviation from natural conditions and mirrored the current, monitoring-based assessment of “moderate” ecological lake status. However, the sediment data showed that the lake should be re-typified as a naturally eutrophic lake. Sediment records as well as current monitoring data indicated temporary improvement in water quality in response to extensive fish manipulation. Our results suggest that paleolimnological records can be used to derive site-specific reference conditions and that extensive restoration efforts can result in gradual, observable improvements of water quality and ecological status.     

Application of the integrated NMR-TDEM method in groundwater exploration in Israel

The Nuclear Magnetic Resonance (NMR) method is the only physical tool currently available which is able to detect directly the presence of fresh water in the subsurface. The Time Domain Electromagnetic (TDEM) method, in turn, has been proven highly efficient in detecting saline groundwater. The combined application of these two methods is the most promising way to delineate accurately groundwater-bearing aquifers and to evaluate the quality of the water. This idea was tested during the feasibility study carried out under different hydrogeological conditions throughout Israel during August–September 1992. The Russian Hydroscope and Geonics PROTEM-IV instruments were used for the NMR and TDEM measurements, respectively.A total of 36 NMR and 12 TDEM stations was established, mostly in close proximity to existing observation wells. Among these only 19 NMR measurements showed reasonable signal-to-noise characteristics, while the rest were obviously distorted by ambient noise. The number of distorted measurements could have been even greater had they been carried out at all points planned. However, a significant number of the NMR stations were cancelled due to their proximity (less than 1–1.5 km) to electric power lines. As a result almost the entire Mediterranean coast of Israel, which was originally chosen as the main test site for this survey, turned out to be unsuitable owing to the low ambient noise protection of the Hydroscope. Another serious limitation of NMR measurements is the maximum penetration depth. The deepest information obtained during the feasibility study was from a depth of 74 m.Nevertheless, within the framework of its applicability, the NMR measurements proved to be sufficiently accurate and to have a high resolving capability. A comparison with the borehole data shows that, in most cases, NMR is able not only to detect the presence of water, but also to delineate different subaquifers. At the same time, however, the transmissivity and aquifer texture are much less reliably detected. The combined application of the NMR and TDEM methods may essentially improve the reliability of the interpretation. In all cases where the NMR anomaly fits the drop in TDEM resistivity, water of a different salinity is found at approximately the same depth. A reasonable correlation between the interpreted resistivities and water salinities is obtained for these horizons. However, if only one method indicates the presence of water, this, in many cases, was not confirmed by the borehole data. The TDEM anomalies were obviously caused by low-resistivity lithologies, while some of the false NMR signals could be explained by a low signal-to-noise ratio.As regards the freshwater/seawater interface, this was, in all cases, accurately detected by the TDEM measurements alone. It is interesting to note that at the same depth, NMR measurements indicated a drastically increasing anomaly followed by the absence of water at greater depths. The latter can most likely be explained by the very low resistivity of the sea water, which is not taken into account by the existing NMR interpretation.     

Solute Transport Simulation of Aquifer Restoration after In Situ Uranium Mining

In situ mining of uranium was conducted in two well fields at a research and development site in the Powder River Basin of Wyoming from March 1980 to July 1981. Subsequent aquifer restoration activities continued until December 1982. During the restoration phases of operation, complex pumping-injection schemes, necessitated by the absence of adequate disposal facilities, were employed by the mining company in an attempt to satisfy the conditions imposed by the mine permit.
An analytical "Random Walk" solute transport model was used to simulate mass transport mechanisms associated with the pumping-injection schemes used in the A-1 well field. Because the hydrogeology at the site is relatively simple; a more sophisticated model requiring extensive calibration was not required. The model was not used as a "predictive" tool, but as an analytical supplement to existing water quality and hydrogeologic data. As such, it provided a very useful and inexpensive means by which to evaluate the adequacy of the restoration techniques employed at the site and the effectiveness of the water quality monitoring program.
Model simulations suggest that the restoration methods used by the mining company were not adequate to remove residual lixiviant and actually tended to displace contaminants to a circular region between the well field and peripheral monitoring wells. An analysis of the water quality and operational history at the site suggests that the model results may be accurate. If this is true, the postrestoration water quality data collected at the site may not be an accurate measure of the effectiveness of aquifer restoration.     

Assessing Water Quality of Mamasın Dam,Turkey: Using Water Quality Index Method,Ecological and Health Risk Assessments

The water quality of Mamas?n Dam, the drinking water source for Aksaray in Turkey, is investigated for assessment of ecological and health risks according to data between December 2015 and November 2016. Water quality index, ecological risk, and health risk assessments are determined to depend on the intensity of occurrence of parameters and seasonal and spatial distributions at different depth ranges. As a result, some ions such as Al, As, B, Ba, Co, F, Mn, Ni, Pb, Se, and Zn were found to be exceeding the limit values of the national regulatory standards. Besides, Pb is listed in Priority Substances and Certain Other Pollutants according to Annex II. Because the WQI values of the water quality are low (below 60), the source is suitable for industrial and agricultural usage; however, it cannot be used for drinking water supply without treatment. The trace element levels, especially Ag, Ba, Cu, Cr, and Zn, are potential pollutants for organisms. The non‐carcinogenic health risks of As threaten both adults and children at “medium” and “high” levels through oral ingestion. The B, F, and Pb elements have Hazard Index values above 0.1 and may cause a “low” level risk chronic disease for children by oral ingestion.     

On the development mechanism of the lacustrine high-grade hydrocarbon source rocks of Chang 91 member in Ordos Basin

As revealed from recent drilling and organic geochemical testing and research, a series of lacustrine high-grade hydrocarbon source rocks was discovered in the upper section of the Chang 9 oil reservoir member of upper Triassic in Ordos Basin. The hydrocarbon source rocks show average TOC content as high as 5.03%, average bitumen "A" content as high as 0.8603%, and good quality organic precursors, which are of the sapropelic type mainly derived from lower aquatic plants and have reached the thermal evolution stage featured by oil-producing climax. Generally the lacustrine high-grade hydrocarbon source rocks were developed in local depressions of a lake basin, and the Chang 91 member was particularly formed in a depositional environment characterized by fresh water to weakly saline water, weakly oxidizing to weakly reducing setting and semi-deep lake facies, as was demonstrated by a variety of organic to inorganic geochemical parameters. As a result, high productivity constitutes the principal controlling force for generation of this series of high-grade hydrocarbon source rocks. Deposition of thinly-bedded and laminated tuffs as well as positive Eu anomaly corroborate the possible occurrence of anoxic geological event closely related to contemporaneous volcanic eruption, which would play a key part in development of the Chang 91 member of high-grade hydrocarbon source rocks.     

西湖引水前后氮 , 磷 , 叶绿素 A 含量的年周期变化

研究了杭州西湖引水前后主要湖区水体中的氮、磷、叶绿素a的年周期动态变化。结果表明:外湖等五个湖区的总氮含量在春季和秋季有两个高峰值,与引水前相比变化不大。硝酸盐氮各湖区均在1～4月呈现高峰。各湖区的总磷含量5月开始急剧上升,9月后降至最低;氮、磷在各湖区的年平均含量也略有差异,一般以岳湖和北里湖湖区的含量较高,而三潭内湖和小南湖湖区相对较低。对各湖区水样检测的相关分析表明:总磷和叶绿素a的年周期动态变化密切相关,而可溶性磷与各湖区的叶绿素a含量相关不显著,但其动态变化一致。从西湖水质改善的程度来看,引水工程只是治理西湖的一项重要措施,但不是根本措施,还需进一步加强截污、科学疏挖、控制游船数量等综合治理。     

洪泽湖水质的时空相关性分析

时空相关性分析方法在生态环境空间分异笥以及湖泊湿地自然保护区建设等方面的研究上,具有重要的应用价值。将湖泊水质监测数据与空间数据结合,建立了具有时空特征的洪渗湖水质数据库。基于相关系数矩阵,利用GIS和Origin等分析软件,对洪泽湖水质的时空相关性及其时间和空间分布规律进行了研究。结果表明,洪泽湖水质存在着时空相关性,目前这种时空相关性已受到人类活动的强烈干扰,因此,建议洪泽湖湿地自然保护区应该选择在时空间相关性小,具有一定离群性的“岛屿”区域。     

青海湖最近25年变化的遥感调查与研究

青海湖是我国最大的内陆水体,它及其流域的生态环境近来一直倍受广泛关注．其水位下降、湖水面积缩小、湖体分离等更是研究的热点问题．本文针对这些问题展开遥感调查与研究,收集了多时相、多种信息源的影像数据;分析了1975年至2000年25年以来湖泊的变迁及成因,湖岸变化及湖体分离状况;用遥感方法反推25年以来湖水位的变化;计算了1975、2000年两个年份的湖水面积,并遥感分析了湖水面积萎缩的原因．此外,对青海湖进行了实地调查与水深测量,建立了该湖泊水深反演模型．     

A comparison of methods to estimate groundwater recharge from bare soil based on data observed by a large-scale lysimeter

Effectively estimating groundwater recharge is critical to manage water resources, especially in arid and semi-arid regions as impacted by intensive human activities and climate changes. Rare insights have been gained into groundwater recharge since direct observation is hard to carry out. Although several methods are currently available to estimate groundwater recharge, the estimated results may cover noticeable bias. The behaviours of different methods based on different conceptual frameworks and exhibiting different levels of complexity should be examined to estimate actual groundwater recharge. This study aims to assess the performance of four common methods to estimate groundwater recharge. For this end, large-scale lysimeters equipped with soil water content sensors and water table sensors were set up at a research site established in Guanzhong Basin of China. The data achieved by 1-year observation were employed to compare four estimation methods. As revealed from the results, the following findings are drawn. (a) Groundwater level fluctuation (GLF) method is simple, whereas its accuracy is determined by specific yield, and adopting a water balance method to estimate specific yield can considerably enhance the accuracy of GLF. (b) The calibrated numerical model can obtain the optimal result compared with the other methods, whereas long-term observation data are required for parameter calibration. (c) In the water balance method, the maximum entropy production (MEP) model and a practical method (estimating evaporation between two rainfall events) were used to calculate evaporation. As indicated by the results, water balance method combined with MEP is capable of obtaining more reliable results of groundwater recharge compared with the practical method. (d) With an analytical model based on linearized Richards' equation, accurate results can be achieved. What is more, the analytical model only needs the measurement of soil moisture near the surface. The limitation of this method is that it is difficult to determine the maximal water flux. The mentioned findings are of critical implications to the management and sustainable development of groundwater.     

1990年以来北京密云水库主要水环境因子时空分布特征

根据19902011年密云水库共12个监测点的月监测资料,采用聚类分析研究各监测点水环境相似性及空间分布特征,采用因子分析识别影响水质的主要因子并评价各采样点的综合水质.通过绝对主成分多元回归分析,获得汛期和非汛期各因子对各水质指标的贡献率.利用季节性Kendall检验及流量调节检验对密云水库库区水化学特征和水质状况时空分布特征进行了研究.结果表明：汛期水质主要受到农业营养物质的影响,其次为生物化学因素和有机物的影响.非汛期水质主要受到农牧业排放因素的影响,其次为人类活动和生物化学因素的影响.因子得分综合评价显示,汛期辛庄桥、内湖和大关桥综合水质较差,潮河、库西和白河综合水质较好.非汛期辛庄桥、石佛桥和大关桥综合水质较差,库东、套里和恒河综合水质较好.主要水质指标的年际变化规律不同,但最终都趋于平稳.与潮河、白河入库水质变化相比,库区水质变化趋势较小,上游入库水质和库区水质都整体趋好.除白河入库的总氮和总磷外,其他监测指标的变化趋势经流量调节前后基本一致,表明流量并不是引起水质趋势变化的主要因素,水质的变化主要是由于污染源变化而引起.     

黄河流域多时空尺度土地利用与水质的关系

为探究不同时空尺度土地利用与水质的相互关系,以黄河流域为研究对象,基于2018年河流水质与土地利用数据,提取3种空间尺度(1000 m河段缓冲区、500 m河岸带缓冲区、子流域)的景观格局指数,结合4个季节河流水质指标,采用冗余分析方法定量探讨土地利用对河流水质的多时空尺度影响,获得水质资源管理最有效的时空尺度.结果表明:(1)在3种空间尺度下,耕地和草地占比最大.斑块密度(PD)在1000 m河段缓冲区尺度下更大,香农多样性指数(SHDI)在3种空间尺度下变化不大;(2)水质指标季节性和空间性存在显著差异,夏季水质优于冬季;(3)土地利用在夏季和1000 m河段缓冲区尺度下对水质影响最显著;(4)不同景观格局指数对河流水质产生的影响不同,耕地面积占比和林地面积占比、未利用地面积占比和SHDI对水质影响最为显著,除了耕地面积占比和PD值的增加会导致水质下降外,其余土地利用指数在大多数时空尺度下均可改善水质.该研究基于不同的时空尺度对土地利用与水质的关系进行定量研究,为合理规划土地资源提供参考,从而保护流域水质安全.