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1.
The late Volgian (early "Boreal" Berriasian) sapropels of the Hekkingen Formation of the central Barents Sea show total organic carbon (TOC) contents from 3 to 36 wt%. The relationship between TOC content and sedimentation rate (SR), and the high Mo/Al ratios indicate deposition under oxygen-free bottom-water conditions, and suggest that preservation under anoxic conditions has largely contributed to the high accumulation of organic carbon. Hydrogen index values obtained from Rock-Eval pyrolysis are exceptionally high, and the organic matter is characterized by well-preserved type II kerogen. However, the occurrence of spores, freshwater algae, coal fragments, and charred land-plant remains strongly suggests proximity to land. Short-term oscillations, probably reflecting Milankovitch-type cyclicity, are superimposed on the long-term trend of constantly changing depositional conditions during most of the late Volgian. Progressively smaller amounts of terrestrial organic matter and larger amounts of marine organic matter upwards in the core section may have been caused by a continuous sea-level rise.  相似文献   

2.
环雷州半岛近海表层沉积物有机碳分布及其控制因素分析   总被引:1,自引:0,他引:1  
对环雷州半岛近海43个海底表层沉积物的总有机碳(TOC)、总氮(TN)、沉积介质条件(包括沉积物粒度)进行了分析,探讨了沉积物TOC、TN的区域分布特征以及影响有机碳分布的主要因素。结果表明,环雷州半岛近海海域海底表层沉积物有机碳含量在0~0.79%之间,平均值为0.26%。与中国其它近海海域相比,环雷州半岛大部分近海区域海底表层沉积物有机碳含量明显偏低,为有机质贫乏区,仅雷州半岛西南部流沙湾近海海域为TOC相对高值区。总氮含量也不高,在0.011%到0.100%之间,TOC与TN存在较强的正相关性,且平面上TOC与TN分布高度重合,显示氮元素主要以有机化合物形式存在。TOC/TN比值在5.1~14.3之间,表明沉积有机质具有陆源输入和海洋自生来源的混合特征,但以雷州半岛西侧北部及东侧中部海域受陆源有机质输入影响更大。大多数站位海底沉积物粒度构成以粉砂为主、粘土次之,少数站位以砂质沉积为主。沉积物有机碳含量与粘土及粉砂含量呈弱正相关性,与沉积物pH值、Eh值及砂含量呈弱负相关性,这表明海底沉积物有机质丰度受有机质来源输入、海底氧化还原状态和沉积水动力条件(沉积物粒度)等因素综合控制。  相似文献   

3.
This study investigated the organic carbon accumulation rates (OCARs) and sulfate reduction rates (SRRs) in slope and basin sediments of the Ulleung Basin, East/Japan Sea. These sediments have high organic contents at depths greater than 2,000 m; this is rare for deep-sea sediments, except for those of the Black Sea and Chilean upwelling regions. The mean organic carbon to total nitrogen molar ratio was estimated to be 6.98 in the Ulleung Basin sediments, indicating that the organic matter is predominantly of marine origin. Strong organic carbon enrichment in the Ulleung Basin appears to result from high export production, and low dilution by inputs of terrestrial materials and calcium carbonate. Apparent sedimentation rates, calculated primarily from excess 210Pb distribution below the zone of sediment mixing, varied from 0.033 to 0.116 cm year−1, agreeing well with previous results for the basin. OCARs fluctuated strongly in the range of 2.06–12.5 g C m−2 year−1, these rates being four times higher at the slope sites than at the basin sites. Within the top 15 cm of the sediment, the integrated SRRs ranged from 0.72 to 1.89 mmol m−2 day−1, with rates approximately twice as high in the slope areas as in the basin areas. SRR values were consistently higher in areas of high sedimentation and of high organic carbon accumulation, correlating well with apparent sedimentation rates and OCARs. The sulfate reduction rates recorded in the basin and slope sediments of the Ulleung Basin are higher than those reported for other parts of the world, with the exception of the Peruvian and Chilean upwelling regions. This is consistent with the high organic carbon contents of surface sediments of the Ulleung Basin, suggesting enhanced organic matter fluxes.  相似文献   

4.
南极普里兹湾沉积物中有机碳和总氮的含量与分布   总被引:1,自引:1,他引:0  
利用中国多次南极科学考察获得的沉积物样品,对普里兹湾沉积物中有机碳(OC)、总氮(TN)的含量和分布以及OC/TN进行了分析。结果表明:普里兹湾表层沉积物中OC和TN的含量变化范围分别为0.14%~1.20%和0.02%~0.20%,平均值分别为0.63%和0.11%。OC/TN的变化范围为5.5~8.2,平均值为6.8。OC和TN含量呈现明显的正相关性,表明有机质来源相同,比值接近6.6,说明有机质主要为海洋生源沉积。两者平面分布趋势非常一致,且与沉积物中泥质含量呈显著正相关,湾内73°E以西区域OC和TN含量较低,而以东区域含量较高,这是上层水体生产过程和冰川携带陆源砂等因素共同作用的结果。垂直分布上,OC和TN含量总体上表层高于深层,OC含量随深度增加逐渐降低,达到一定深度后趋于稳定。较高的沉积速率加速OC的埋藏,5根柱样中OC的埋藏率为39%~91%,平均为66%,表明普里兹湾是重要的碳汇区。  相似文献   

5.
《Marine Geology》1999,153(1-4):177-197
Drilling of deep-water post-Messinian sedimentary sequences by ODP Legs 160 and 161 in the Mediterranean Sea has shown that occurrence of organic-carbon-rich sapropels and sapropel-like sediments extends from the Levantine Basin westward into the Alboran Basin. In the eastern Mediterranean, sapropel deposition started in the Early Pliocene, whereas in the Western Basin the onset of sapropel formation occurred later, in the Early Pleistocene. Precessional cycles are apparently the primary external forcing for sapropel formation. Nevertheless, the pattern of sapropel occurrence suggests that the precessional influence is modulated by the glaciation cycles. Large differences were observed in the organic carbon contents of sapropels recovered in the eastern and western Mediterranean. Correspondence between organic carbon contents, Rock-Eval hydrogen index values and elemental C/N ratios indicate that both variations in the production and preservation of marine organic matter have led to the accumulation of high amounts of organic matter in sapropels. Molecular organic geochemical compositions of sapropels from the eastern Mediterranean further confirm that the major fraction of organic matter in sapropels is derived from marine algal sources and has undergone variable oxidation. Enhanced marine productivity and improved preservation of organic matter is central to sapropel formation. Accumulation of increased amounts of land-derived material at times of sapropel formation is also evidenced, supporting the hypothesis of significant periodic freshwater discharges.  相似文献   

6.
 Sediment cores from the upper continental slope of the eastern Arabian Sea have high organic carbon (OC), CaCO3, and sand content at the top. The values decrease with increasing depth in the Holocene and Upper Pleistocene. Topographic highs show highest OC and lower CaCO3 in the Holocene clayey sediments and vice versa in the Pleistocene sandy sediments. The OC is immature and marine or a mixture of both marine and terrestrial in the Holocene sediments and is mostly terrestrial and/or reworked marine in the Pleistocene sediments. Productivity is the main controlling factor for the organic carbon enrichment. Texture and reworking also influence the organic carbon variations. Received: 29 May 1996/Revision received: 10 January 1997  相似文献   

7.
Using the authors’ data obtained during expeditions to the Sea of Okhotsk during the last decade, the primary phytoplankton production and the distribution of organic carbon and chlorophyll a degradation products (chlorin) in the bottom sediments were studied. Using the authors’ and published data, the spatial distribution of the production and paleoproduction indicators was plotted. The ratios of the chlorin and Corg content in the sediments was considered, and the correlation between these parameters was revealed. It was shown that the average annual primary production of phytoplankton and the paleoproduction indices were maximum in the coastal and upwelling zones and decreased towards the sea’s center. A quantitative correlation was found between the distribution of the present primary production in the photic layer and that of the rates of the accumulation of organic matter buried within the surface sediments. As a result, it was shown that the content of chlorin and Corg in the marine bottom sediments may be used to reconstruct the paleoproduction variability of the past.  相似文献   

8.
During the extension of Deep Sea Drilling Project (DSDP) Leg 76 a new and previously unpenetrated lithological unit composed mainly of claystones was cored above basalt basement at Site 534 in the Blake-Bahama Basin. The Callovian part of the new unit contains interbedded ‘black shales’ which were hitherto unexpected in this part of the section. This Paper presents a brief palynological examination of lithofacies-kerogen relationships in these sediments and shows that their organic content is almost entirely a function of the re-deposition of terrestial and marine organic matter versus the ambient redox conditions of the depositional environment. Allochthonous organic matter inputs are highest in the interbedded turbidites and decline progressively toward the pelagic black shales in which marine organic matter is comparatively well preserved. The significance of various kerogen and palynomorph indices are discussed. The study emphasizes the absolute necessity for sedimentologically-aware sampling in all palynological and geochemical work on lithologically heterogeneous sequences.  相似文献   

9.
Abstract

An analysis of the relationship between organic matter and liquid and plastic limits, and grain‐specific gravity of a marine sediment was accomplished by making a stepwise adjustment in the organic content of that sediment. The sample used was from Santa Barbara Basin (off southern California) and is typical of fine‐grained marine sediments: it is a clayey silt with a common suite of minerals and other constituents. During the experiment, texture and composition (except organic content) were constant; only the quantity of natural, indigenous organic matter was changed.

A strong linear relationship exists between the independent variable, the amount of organic carbon present in the sample, and the dependent variables. Liquid limit, plastic limit, and plasticity index all increased with increasing organic content over the range studied (0.57–3.20% organic carbon). Grain‐specific gravity decreased. All had linear correlation coefficients (r) greater than |0.90| and r 2 values greater than 90%, except the plasticity index (83%).

Comparing the results of regression analyses from this and several similar studies shows that although there is good qualitative agreement, there are quantitative inconsistencies. In particular there is considerable overall variability in the regression coefficients. Among studies on marine sediments the inconsistencies are less pronounced, yet still evident. The increase in liquid limit as organic carbon increased by 1 % sediment dry weight ranged from 9 to 28% water content; in the plastic limit the range was from 4 to 18%. However, in these marine studies regression coefficients are relatively close in value in some cases, levels of significance of the regressions are high in most cases, and in all cases the relationships appear to be linear over the range of organic carbon percentage studied. Finally, we believe that a relatively clear relationship between plasticity and organic carbon begins to emerge when the latter exceeds a value of 2%.  相似文献   

10.
Grain-size distributions, total organic carbon (TOC) and total nitrogen (TN) concentrations, and TOC/TN ratios (C/N) were analysed for surface sediments from the Lower Yangtze River-East China Sea (ECS) shelf system. Hierarchical cluster analysis of grain-size parameters (mode, mean, sorting, skewness and kurtosis) has been employed to characterize grain-size compositions. The results suggest there are five grain-size compositional types (type-I–V) that fingerprint distinct depositional conditions. In areas with high sedimentation rates, hydrological sorting preferentially enriches the fraction coarser than 6.4ø (12 μm) in shallow seafloor sediments (water depth<30 m) by transporting the finer fraction to the deeper seafloor (water depth>30 m), and thus forms grain-size compositional type-I (shallow) and type-II (deep). In the open shelf, where modern sediment supply is very limited, grain-size types-III–V are identified according to different winnowing intensity. Overall TOC contents significantly correlate with mud proportions, suggesting muddy sediments are the primary control on OM accumulation. However, de-association of terrestrial OM from fine sediments in the Estuary and the occurrence of presumably relict OM in the open shelf exert additional controls on OM dispersal and carbon cycling in the ECS. By considering geography, oceanography, sediment source, and the relation between sedimentation conditions and sedimentary OM distributions, we define six depositional settings: the lower river, the estuary, the coast, the offshore upwelling area, the erosional area, and the open shelf. These settings describe the sediment dispersal and associated organic matter cycling in the Lower Yangtze River-ECS shelf system.  相似文献   

11.
Palaeo-bottom current strength of the West Spitsbergen Current (WSC) and the influence of the Svalbard-Barents Sea Ice Sheet (SBIS) on the depositional environment along the northern Svalbard margins are poorly known. Two gravity cores from the southern Yermak Plateau and the upper slope north of Nordaustlandet, covering marine isotope stage (MIS) 1 to MIS 5, are investigated. Five lithofacies, based on grain size distribution, silt/clay ratio, content and mean of sortable silt (SS), are distinguished to characterise the contourite-dominated sedimentary environments. In addition, depositional environments are described using total organic carbon (TOC), total sulphur (TS) and calcium carbonate (CaCO3) contents of sediments. Facies A, containing coarse SS, suggests strong bottom current activity and good bottom water ventilation conditions as inferred from low TOC content. This facies was deposited during the glacial periods MIS 4, MIS 2 and during the late Holocene. Facies B is dominated by fine SS indicating weak bottom current and poor ventilation (cf. high TOC content of 1.2–1.6%), and correlates with the MIS 4/3 and MIS 2/1 transition periods. With an equal amount of clay and sand, fine SS and high content of TOC, facies C indicates reduced bottom current strength for intervals with sediment supply from proximal sources such as icebergs, sea ice or meltwater discharge. This facies was deposited during the last glacial maximum. Facies D represents mass-flow deposits on the northern Svalbard margin attributed to the SBIS advance at or near the shelf edge. Facies E sediments indicating moderate bottom current strength were deposited during MIS 5 and MIS 3, and during parts of MIS 2. This first late Quaternary proxy record of the WSC flow and sedimentation history from the northern Svalbard margin suggests that the oceanographic conditions and ice sheet processes have exerted first-order control on sediment properties.  相似文献   

12.
东海颗粒碳的垂直转移过程   总被引:7,自引:3,他引:7  
在1993年和1994年两个航次中,利用震动式取样从东海陆架取得3个柱状岩芯样品。对其进行了POC,PIC,PON含量和粒度分析,并同其上覆水体的POC,PIC以及总颗粒物的垂直通量和悬浮体作了比较。  相似文献   

13.
Gravity flow deposits form a significant component of the stratigraphic record in ancient and modern deep-water basins worldwide. Analyses of high-resolution 3D seismic reflection data in a predominantly slope setting, the southern slope of Qiongdongnan Basin, South China Sea, reveal the extensive presence of gravity flow depositional elements in the Late Pliocene−Quaternary strata. Three key elements were observed: (1) mass transport deposits (MTDs) including slumps and debris flows, (2) turbidity current deposits including distributary channel complexes, leveed channel complexes and avulsion channel complexes, and (3) deep-water drapes (highstand condensed sections). Each depositional element displays a unique seismic expression and internal structures in seismic profiles and attribute maps. Based on seismic characteristics, the studied succession is subdivided into six units in which three depositional cycles are identified. Each cycle exhibits MTDs (slump or debris) at the base, overlain by turbidities or a deep-water drape. The genesis of these cycles is mainly controlled by frequent sea-level fluctuations and high sedimentation rates in the Late Pliocene–Quaternary. Moreover, tectonics, differential subsidence, and paleo-seafloor morphology may have also contributed to their formation processes. The present study is aimed to a better understanding of deep-water depositional systems, and to a successful hydrocarbon exploration and engineering-risk assessment.  相似文献   

14.
Approaches to quantify the organic carbon accumulation on a global scale generally do not consider the small-scale variability of sedimentary and oceanographic boundary conditions along continental margins. In this study, we present a new approach to regionalize the total organic carbon (TOC) content in surface sediments (<5 cm sediment depth). It is based on a compilation of more than 5500 single measurements from various sources. Global TOC distribution was determined by the application of a combined qualitative and quantitative-geostatistical method. Overall, 33 benthic TOC-based provinces were defined and used to process the global distribution pattern of the TOC content in surface sediments in a 1°×1° grid resolution. Regional dependencies of data points within each single province are expressed by modeled semi-variograms. Measured and estimated TOC values show good correlation, emphasizing the reasonable applicability of the method. The accumulation of organic carbon in marine surface sediments is a key parameter in the control of mineralization processes and the material exchange between the sediment and the ocean water. Our approach will help to improve global budgets of nutrient and carbon cycles.  相似文献   

15.
酸洗法测定海洋沉积物有机碳和无机碳含量的致命缺陷   总被引:2,自引:0,他引:2  
Organic and inorganic carbon contents of marine sediments are important to reconstruct marine productivity,global carbon cycle, and climate change. A proper method to separate and determine organic and inorganic carbons is thus of great necessity. Although the best method is still disputable, the acid leaching method is widely used in many laboratories because of its ease-of-use and high accuracy. The results of the elemental analysis of sediment trap samples reveal that organic and inorganic carbon contents cannot be obtained using the acid leaching method, causing an infinitely amplified error when the carbon content of the decarbonated sample is 12%±1% according to a mathematical derivation. Acid fumigation and gasometric methods are used for comparison, which indicates that other methods can avoid this problem in organic carbon analysis. For the first time, this study uncovers the pitfalls of the acid leaching method, which limits the implication in practical laboratory measurement, and recommends alternative solutions of organic/inorganic carbon determination in marine sediments.  相似文献   

16.
An understanding of the carbon cycle within arctic sediments requires discrimination between the terrigenous and marine components of organic carbon, insight into the removal mechanisms for labile carbon during burial and appreciation of shelf-to-basin processes. Using a large data set of multiple molecular organic markers (alkanes, alkanols, sterols, saturated and unsaturated fatty acids, dicarboxylic acids), we apply (1) principal components analysis (PCA) to obtain a robust comparison of biomarker compositions in Arctic Ocean sediments, (2) geometric mean (GM) linear regression of the PCA variables to estimate the relative contributions of labile/marine and stable/terrigenous sources to each biomarker and (3) the slope of the GM regression of each biomarker with TOC to provide a novel measure of the removal rate of each biomarker relative to phytol. The PCA- and TOC-based indices generally increase together: biomarkers with very high TOC-based removal rates such as the saturated and unsaturated n-alkanoic acids generally have a high labile/marine content from PCA, while the sterols have low removal rates, but exhibit a range of labile/marine content values and the n-alkanes and n-alkanols have low values for both. A dominant feature of all PCA models examined is a progressive decrease in the autochthonous/marine biomarkers with each increase in sediment core depth, which points to a universal diagenetic alteration of organic carbon with depth in the cores. The PCA model also displays a shelf to basin trend that is non-diagenetic and implies the ongoing (centuries or more) delivery of long-chain n-alkanes, n-alcohols and n-alkanoic acids in a matrix that is pre-formed and well-preserved within the sediments. Terrigenous biomarker distributions within the PCA model suggest that atmospheric transport of plant waxes in aerosols and the water borne transport of very fine plant macerals likely have significant roles in the export of these vascular plant biomarkers to the basins. Biomarker ratios and profiles of the PCA-based labile/marine content with core depth indicate that the PCA model is more strongly influenced by the biomarker lability than the marine content, while increases in the marine content are largely responsible for the shifts in composition for near-surface core sections.  相似文献   

17.
Sediments of the continental slope are commonly bioturbated by endo- and epibenthic organisms, particularly in and around submarine canyons and channels. This study reviews the architecture and depositional environments associated with canyons and channels on the continental slope, and assesses the key physical and chemical conditions encountered in and around these conduits. Hydrodynamic energy, concentration and quality of organic carbon, dissolved oxygen concentration and sedimentation rate are identified as key controls on the composition of benthic ecosystems in slope environments. Submarine canyons and channels focus a variety of turbid and clear-water currents, all of which serve to increase the concentration of oxygen, labile organic carbon and other nutrients, which tend to elevate the abundance and biodiversity in the seafloor sediments, compared with those of the surrounding slope. Ancient slope channel and canyon systems reflect some of the variation in ichnological assemblages that is seen in modern analogues, although processes of erosion and trace fossil preservation mean that the benthic environment is often incompletely preserved in the ancient record. By integrating current understanding of sedimentology, oceanography, biology and ichnology of slope environments it is possible to provide a first order summary of the inter-relationships between ichnology and depositional environments on the continental slope. The combination of these data has the potential to improve our understanding of changes in deep marine benthic ecosystems through geological time, and to further the use of ichnology in assessing hydrocarbon reservoir presence, quality and performance from bioturbated slope, canyon and channel-levee hydrocarbon reservoirs.  相似文献   

18.
Research has been conducted in Nha Trang Bay (Southern Vietnam, the South China Sea) at the section from the estuary of the Cai River to the marine part of the bay, as well as in the area of coral reefs. The objects of the studies are the river and sea waters, the suspended matter, and the bottom sediments. Data on the dissolved organic carbon and the total nitrogen in the water are obtained. The organic carbon content is estimated in the suspended matter; the organic carbon and the molecular and group composition of the n-alkanes are determined in the bottom sediments. The molecular and group composition of the n-alkanes in the bottom sediments of the landfill have made it possible to identify three types of organic matter (OM): marine, mixed, and of mainly terrigenous origin. All the types of OM are closely related to the specificity of the sedimentation and the hydrodynamics of the waters in this water area.  相似文献   

19.
基于全球海洋及其上空大气中关于有机磷酸酯(OPEs)的数据,分析了目前OPEs在全球海洋及其上空大气的分布特征、影响因素以及当前研究存在的不足。总结发现,海水中的OPEs主要来自河流输送,且浓度分布特征表现为由近及远、由浅及深逐渐递减。磷酸三(2-氯乙基)酯(TCEP)、磷酸三(1-氯-2-丙基)酯(TCPP)和磷酸三(1,3-二氯异丙基)酯(TDCPP)三种卤化OPEs是海水中主要污染物;输入到海水中的OPEs经过颗粒沉降等作用沉积到海洋沉积物中,随之,沉积物中的OPEs可能反析出或直接累积,在海洋沉积物中形成一个大的OPEs储存库。分析北太平洋到北冰洋表层沉积物中OPEs的浓度发现,从白令海峡到北冰洋,随着纬度的增加OPEs的浓度也普遍增加,且相对于非卤化OPEs,卤化OPEs更易被运输到偏远海域。总有机碳(TOC)与大洋沉积物中OPEs的浓度无相关性,但与近海海洋沉积物中OPEs的浓度呈正相关,TCEP和磷酸三异丁酯(TiBP)为海洋沉积物中主要污染物;海洋上空大气与水体中的OPEs是不可分割的,海洋上空大气中的OPEs一部分通过大气沉降进入海水,一部分继续迁移到更偏远区域,气团来源是影响其分布的主要因素。对比OPEs在全球海洋上空大气中的浓度分布发现,南北半球并无明显差异,TCEP和TCPP是海洋上空大气中主要污染物。  相似文献   

20.
Detailed bulk geochemistry and organo-petrography of outcrop Cretaceous sediments (with no significant effects of weathering) from the Calabar Flank, southeast Nigeria were performed to understand the organic carbon source, accumulation and degradation, and paleo-climatic, paleoceanographic and paleoenvironmental conditions in West Africa during Early Cretaceous (Aptian) to Maastrichtian times. This study was based on microscopic, elemental analyses (organic carbon, nitrogen, iron and sulphur), Rock-eval pyrolysis and carbon-isotope analyses. In general, the Calabar Flank shales are characterised by highly variable total organic carbon (TOC) contents, which range between 0.1% in Aptian–Albian Mfamosing Limestone and 9.9% in the Awi Formation sediments. The organic matter (OM) is a mixture of immature to early-mature marine and terrigenous OM of types III and IV. This is indicated by low hydrogen indices (HI value (10–190 mg HC/g TOC), Tmax (417–460 °C), vitrinite reflectance %Ro (0.39–0.62 %Ro), low to high C/N ratios (3.4–1158.0) and high amounts of terrigenous macerals (vitrinite + inertinite). Based on carbon isotope, C/N ratios and sulphate reduction index (SRI), OM degradation (up to 70%, SRI > 2.5) is most pronounced for shales deposited in a marine environment. The geochemical and petrographic data indicate that local factors such as low bioproductivity, down slope transport and redeposition of sediments from a fluvial–deltaic basin to nearshore facies, shallower, oxic and mildly oxygen-deficient environments, humid–arid paleogeographic conditions, specifically controlled the amount and quality of the OM during Aptian–Mastrichtian stages where marine sediments have been assumed to be deposited during the global anoxic events. Therefore, the order of the main factors controlling OM content in sediments are: input of terrigenous material transported from the land > low OM productivity by marine photoautotrophs > low preservation.  相似文献   

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