Transport of aurorally produced N(2D) by winds in the high latitude thermosphere

A time-dependent two-dimensional numerical model of the minor neutral constituents of the thermosphere NO, N(²D), and N(⁴S) is used to examine the effects of winds in transporting these constituents from their production region in auroral arcs. The calculations show that thermospheric winds flowing through regions of enhanced local auroral production produce downwind plumes of enhanced minor neutral constituent densities and that the densities depend upon the wind velocity. Below about 200 km N(²D) is in photochemical equilibrium and is not transported. Above 200 km N(²D) is transported by the wind and since quenching of N(²D) by O is small and the radiational lifetime is long, a downwind plume of emission at 5200 Å develops from the particle source region. We present data from a rocket flight in the vicinity of the magnetospheric cusp and data from the Atmosphere Explorer-D (AE-D) satellite that both show enhanced 5200 Å emission rates in a general downwind direction from a region of direct particle precipitation. The general wind speed and direction are obtained from predictions made by the NCAR thermospheric general circulation model. The results suggest that transport of N(²D) by the wind system is more important than the convection of O⁺ ions by electric fields in causing the enhanced 5200 Å emission rate in regions outside but in the vicinity of direct particle precipitation.     

Changes in thermospheric composition inferred from twilight O+(2P) emission

Measurements of the twilight enhancement of airglow emission from O⁺(²P) near 7325 Å reveal major changes which accompany geomagnetic activity, no significant distance between evening and morning and an increase in brightness paralleling the approach to solar maximum. The principal source for O⁺(²P) is direct photoionization from O(³P) but at low solar activity there appears to be a contribution from another source in early twilight which may be local photoelectron ionization into O⁺(²P). The geomagnetic and solar effects appear to reflect changes in the O and N₂ density in the thermosphere; ground based twilight measurements of O⁺ emissions thus provide a simple means for monitoring thermospheric structure from 300 km to ～ 500 km at solar minimum and to ～600 km at solar maximum.     

Aeronomical determination of the efficiency of O1D) production by dissociative recombination of O2+

Simultaneous measurements of the 6300 Å airglow intensity, the electron density profile, and F-region ion temperatures and vertical ion velocities taken at the Arecibo Observatory in March 1971 are utilized in the height integrated continuity equation to extract the number of photons'of 6300 Å emitted per recombination. After accounting for quenching of $\text{O}\text{(}{}^1\text{D}\text{)}$ and the electrons lost via NO⁺ recombination, the efficiency of $\text{O}\text{(}{}^1\text{D}\text{)}$ production by the dissociative recombination of O₂⁺ is determined to be 0.6 ± 0.2 including cascading from the $\text{O}\text{(}{}^1\text{S}\text{)}$ state. The uncertainty includes both random measurement errors and estimates of possible systematic errors.     

Associative ionization of N(2D) and O

Recent laboratory measurements have shown that N(²P) atoms, and thus probably hot N(²D) atoms, will recombine with atomic oxygen via an associative ionization process at the gas kinetic rate. While the reaction is endothermic, it has been suggested that this has interesting implications for the upper atmosphere in that N(²D) atoms in the tail of the velocity distribution could provide an additional source of NO⁺ through the reverse of the dissociative recombination reaction

$\text{NO}{}^{\mathrm{+}}\text{+ e ?}\text{N}\text{(}{}^2\text{D}\text{) +}\text{O}$

. It has also been suggested that this process might account for the difference between a laboratory determination of the rate coefficient and that determined from the Atmospheric Explorer Satellite data. In this paper we investigate further the likelihood of the associative ionization of N(²D) and O playing a significant role in the normal ionosphere, in the light of several recent relevant studies. We conclude that the associative ionization process is not an important factor and that a more probable cause for disagreements in the various determinations of the recombination coefficient, is the difference in excited states of the ions in the various experiments.     

Observations of horizontal transport effects on high latitude metastable O(1D), N(2D) auroral emissions

An analysis is presented of photometric measurements of the NI (λ = 520nm),OI(λ = 630nm)and other emissions made at Nord, where the invariant latitude is Λ = 80°4. The time variations of the intensities are interpreted in the following way by comparison with simultaneous ground based or satellite measurements.The N(²D) atoms formed in the dayside cleft are carried by the neutral wind in a plume across the polar cap, so that the ratio of λ(630 nm) to λ(520 nm) intensities decreases along the plume with increasing distance from the source region.In the polar cap, but outside the plume region, 630 nm emission is produced by electron impact of polar rain and by substorms that reach high latitudes. Ionization produced at the same time, especially by the substorms, will produce further 630 nm emission through dissociative recombination. In any case, the region outside the plume may be regarded as a source region, with a high value of the ratio $\text{I(630)}\text{I(520)}$. This explains in part the diurnal variations, since this ratio is depressed as Nord crosses the dayside plume.The electron energy along the oval increases progressively from the dayside to the nightside. The intensity ratio increases with increasing electron energy because N(²D) is quenched more rapidly than O(¹D). Thus the ratio rises progressively from noon to midnight.An effect of the interplanetary magnetic field is superimposed on this pattern : as its North-South component B_z increases, the oval contracts so that Nord becomes nearer from the cleft source and the intensity ratio increases on the dayside. The inverse effect is also observed. On the nightside, negative B_z is associated with substorms that produce poleward expansions of the poleward oval boundary, that brings more energetic precipitation to Nord. This causes the intensity ratio to increase with decreasing B_z in a way that is opposite to that for the dayside.     

Relative flow of H+ and O+ ions in the topside ionosphere at mid-latitudes

Theoretical results on the daily variation of O⁺ and H⁺ field-aligned velocities in the topside ionosphere are presented. The results are for an L = 3 magnetic field tube under sunspot minimum conditions at equinox. They come from calculations of time-dependent O⁺ and H⁺ continuity and momentum balance in a magnetic field tube which extends from the lower F2 region to the equatorial plane (Murphy et al., 1976).There are occasions when ion counterstreaming occurs, with the O⁺ velocity upward and H⁺ velocity downward. The conditions causing this counterstreaming are described: the H⁺ layer is descending whilst O⁺ is supplied from below either to increase the O⁺ concentration at fixed heights or to replace O⁺ ions lost by charge exchange with neutral H. It is suggested that the results of observations at Arecibo by Vickrey et al. (1976) of O⁺ and H⁺ concentrations and counterstreaming velocities are significantly affected by $\text{E}\text{×}\text{B}$ drift.     

Further quantification of the sources and sinks of thermospheric O1D) atoms

In this paper we confirm an earlier finding that the reaction

constitutes a major source of OI 6300 Å dayglow. The rate coefficient for this reaction is found to be consistent with an auroral result, namely k₁ ≈ 6 × 10^?12cm³s^?1. We correct an error in an earlier publication and demonstrate that reaction (1) is consistent with the laboratory determined quenching rate for the reaction

where $\text{k}{}_2\text{= 2.3 × 10}{}^{\mathrm{?11}}\text{cm}{}^3\text{s}{}^{\mathrm{?1}}$. Dissociative recombination of O⁺₂ with electrons is found to be a major daytime source in summer above ～220 km.     

On the diurnal and seasonal variations of H+, He+, N+, O+, and Ne at 1400-km altitude

The diurnal and seasonal variations of H⁺, He⁺, N⁺, O⁺ and Ne are analyzed at 1400-km altitude. Using longitudinally averaged observations of ISIS-2 (April 1971 to December 1972), the ion and electron densities are decomposed via spherical harmonics and Fourier series into time-independent, seasonal and diurnal terms. The time-independent terms of H⁺ and He⁺ show a plateauor trough-like structure at medium to low latitudes and a strong decrease towards the poles; N⁺ and O⁺, on the other hand, yield an almost inverse picture with a density increase at high latitudes. All constituents, except He⁺, show at polar latitudes an enhancement during local summer conditions and a depletion during local winter conditions; He⁺, however, exhibits a winter bulge and a density minimum during local summer. The diurnal variations are strongly latitude dependent; while the amplitudes (relative) of H⁺, He⁺, and Ne are rather small, the heavier ions N⁺ and O⁺ show a deep minimum early in the morning and a high but flat maximum during daytime.     

Line shape of the non-thermal 6300 Å O(1D) emission

The line shape of the non-thermal O(¹D) 6300 Å emission is calculated using the two population model of Schmitt, Abreu and Hays (Planet. Space Sci.29, 1095, 1981). The calculated line shapes simulate observations made from a space platform at different zenith angles and altitudes. The non-thermal line shapes observed at zenith angles other than the local vertical have been obtained by using the Addition theorem for spherical harmonics of a Legendre polynomial expansion of the non-thermal population distribution function.     

Recombination of electrons with H3+ and H5+ ions

The dissociative recombination coefficients α for capture of electrons by H₃⁺ and H₅⁺ ions have been determined as a function of electron temperature T_e using a microwave afterglow-mass spectrometer apparatus. At ion and neutral temperatures T_u+ = T_n = 240 K, the coefficient α (H₃⁺) is found to vary slowly with T_e at first, decreasing from 1.6 × 10^?7 cm³/s at T_e = 240 K to 1.2 × 10^?7 cm³/s at T_e = 500 K, thereafter falling as T_e^?1 over the range 500 K ? T_e, ? 3000 K. These results, which have a ± 20% uncertainty, agree satisfactorily over the common energy range (0.03–0.36 eV) with the recombination cross sections determined in merged beam measurements by Auerbach et al. At T₊ = T_n = 128 K, the coefficient α(H₅⁺) is found to be (1.8 ± 0.3) × 10^?6 [T_e(K)/300]^?0.69 cm³/s over the range 128 K ? T_e ? 3000 K, with a more rapid decrease, as T_e^?1, between 3000 K and 5500 K. The implications of these results for modelling planetary atmospheres and interstellar clouds are briefly touched on.     

Dissociative recombination of electrons with NO+ ions

Resonant scattering theory is applied to the calculation of the rate of dissociative recombination in e-NO⁺ collisions. For ground state ions at 300 K, the recombination rate is 4.3 × 10^?7 cm³ s^?1, in good agreement with the afterglow data. At higher electron temperatures, the calculated rate lies between the values measured in afterglow and trapped-ion experiments. A possible explanation of this discrepancy is offered. For vibrationally excited ions, the recombination coefficient is significantly lower than that of the ground state.     

Fluorescence efficiencies of electrons in second positive bands of N2 and first negative bands of N2+

Fluorescence efficiencies of electrons in a large number of bands of N₂ second positive and N_2⁺ first negative groups lying in the 3000–5200 Å region are calculated. At very low pressure where quenching is negligible the present values are within 15 per cent of the experimental data of Hartmann (1968). The efficiencies are found to be independent of the impact energies greater than 200 eV which is in accordance with other theoretical and experimental results. The ratio of the total efficiencies in N₂ second positive and N_2⁺ first negative groups is 1·31 and is about 20 per cent lower than the experimental values. The efficiencies at a higher pressure equal to 600 torr are compared with the experimental data of Davidson and O'Neil (1964a).     

The dissociative recombination of O2+ in the ionosphere

Aeronomical determinations of the dissociative recombination reaction rate coefficient for O₂⁺, α, depend directly on a knowledge of the rate coefficient for the charge exchange of O⁺ with O₂, k. A re-evaluation of the aeronomical determination of α using Atmosphere Explorer satellite data is necessary in the light of a subsequent laboratory measurement of k. The results reported here are in reasonable agreement with laboratory determinations to within the uncertainty of the analysis for night-time conditions. However, for data obtained under sunlit conditions the aeronomical determination differs significantly from the laboratory measurements. The results imply that the state of the O₂⁺ molecule resulting from the major thermospheric processes requires further examination.     

The excitation of O2(b1Σg+) in the nightglow

It is proposed that the available measurements of the O₂(b¹Σ_g⁺ ?X³Σ_g^?) atmospheric bands both in the nightglow and in the laboratory indicate that the excitation mechanism is a two-step process rather than the direct three body recombination of atomic oxygen. It is shown that such a two-step mechanism can explain observations of the atmospheric bands both in altitude and intensity.     

Reaction paths leading from O+2 to water clusters under cold mesospheric conditions

Arnold and Krankowsky (Int. Symp. Solar-Terrestrial Physics, Sao Paulo, 1974) have reported D-region positive ion measurements in which a number of new cluster ions of minor abundance were apparent. These ions, which they attributed to clusters with N₂, O₂, and CO₂ ligands, were observable due to enhanced O⁺₂ production and to the low temperatures during the flight. Here we consider these in situ ion data in view of recent laboratory ion-molecule reaction experiments which cast light on the mechanism leading from O⁺₂ to water clusters in air mixtures. Possible intermediates are discussed in terms of ion stability and existence of effective reaction paths under the given atmospheric conditions. These proposed intermediates are then fitted into a coherent reaction mechanism resulting in significant new pathways for the formation of protonated water clusters. A semiquantitative measure of the importance of each of the pathways is then calculated by the use of signal flow graph theory.     

The broadening of strong lines of Ca+, Mg+ and Ba+ by collisions with neutral hydrogen atoms

The theory of Anstee &38; O'Mara is extended to the line broadening of transitions of singly ionized atoms by collisions with neutral hydrogen atoms. The theory is used to calculate broadening cross-sections for strong lines of singly ionized calcium, magnesium and barium. The broadening cross-sections calculated are compared with both theoretical and empirical results of other workers.     

The altitude dependence of the O2(A3Σu+) vibrational distribution in the terrestrial nightglow

A simple vibrational relaxation model which reproduces the observed altitude integrated vibrational distribution of the Herzberg I bands in the nightglow is used to derive the altitude profiles of the individual vibrational levels at 1 km intervals in the 85–115 km height range. The possible errors associated with using rocket-borne photometer measurements of a limited number of bands in the O₂(A³Σ_u⁺?X³Σ_g^?) system to infer the total Herzberg I emission profile are assessed.     

Frank-Condon factors for H2O+ molecular bands

Frank-Condon factors for H₂O⁺ bands have been calculated. They are used to estimate the photon scattering coefficient g_8.0 for the (8,0) band at 6158 Å.